Carbon is an essential element for the existence and evolution of life on Earth. Its abundance in Earth's crust and mantle (the Bulk Silicate Earth, BSE) is surprisingly high given that carbon is strongly siderophile (metal-loving) at low pressures and temperatures, and hence should have segregated almost completely into Earth's core during accretion. Estimates of the concentration of carbon in the BSE lie in the range 100-260 ppm and are much higher than expected based on simple models of core-mantle differentiation. Here we show through experiments at the putative conditions of Earth's core formation (49-71 GPa and 3600-4000 K) that carbon is significantly less siderophile at these conditions than at the low pressures ($\leq$13 GPa) and temperatures ($\leq$2500 K) of previous large volume press studies, but at least an order of magnitude more siderophile than proposed recently based on an experimental approach that is similar to ours. Using our new data along with previously published results, we derive a new parameterization of the pressure-temperature dependence of the metal-silicate partitioning of carbon. We apply this parameterization in a model that combines planet formation and core-mantle differentiation that is based on astrophysical N-body accretion simulations. Because differentiated planetesimals were almost completely depleted in carbon due to sublimation at high temperatures, almost all carbon in the BSE was added by the accretion of fully-oxidized carbonaceous chondrite material from the outer solar system. Carbon is added to the mantle continuously throughout accretion and its concentration reaches values within the BSE range (e.g. 140$\pm$40 ppm) at the end of accretion. The corresponding final core and bulk Earth carbon concentrations are 1270$\pm$300 ppm and 495$\pm$125 ppm respectively.
The liquid metal-liquid silicate partitioning of molybdenum and tungsten during core formation must be well-constrained in order to understand the evolution of Earth and other planetary bodies, in particular because the Hf-W isotopic system is used to date early planetary evolution. We combine 48 new high pressure and temperature experimental results with a comprehensive database of previous experiments to re-examine the systematics of Mo and W partitioning. W partitioning is particularly sensitive to silicate and metallic melt compositions and becomes more siderophile with increasing temperat…
Zinc metal-silicate fractionation provides experimental access to the conditions of core formation and Zn has been used to estimate the S contents of the Earth's core and of the bulk Earth, assuming that they share similar volatility and that Zn was not partitioned into the Earth's core. We have conducted a suite of partitioning experiments to characterize Zn metal-silicate elemental and isotopic fractionation as a function of time, temperature, and composition. Experiments were conducted at temperatures from 1473-2273K, with run durations from 5-240 minutes for four starting materials. Chemic…
Terrestrial planets in the solar system, such as the Earth, are oxygen-rich, with silicates and iron being the most common minerals in their interiors. However, the true chemical diversity of rocky planets orbiting other stars is yet unknown. Mass and radius measurements are used to constrain the interior compositions of super-Earths (exoplanets with masses of 1 - 10 Earth masses), and are typically interpreted with planetary interior models that assume Earth-centric oxygen-rich compositions. Using such models, the super-Earth 55 Cancri e (mass of 8 Earth masses, radius of 2 Earth radii) has b…
Possible bulk compositions of the super-Earth exoplanets, CoRoT-7b, Kepler-9d, and Kepler-10b are investigated by applying a commonly used silicate and a non-standard carbon model. Their internal structures are deduced using the suitable equation of state of the materials. The degeneracy problems of their compositions can be partly overcome, based on the fact that all three planets are extremely close to their host stars. By analyzing the numerical results, we conclude: 1) The iron core of CoRoT-7b is not more than 27% of its total mass within 1 $σ$ mass-radius error bars, so an Earth-like com…
The NASA/Dawn mission has acquired an unprecedented amount of data from the surface of the dwarf planet Ceres, providing a thorough characterization of its surface composition. The current favorite compositional model includes a mixture of ultra-carbonaceous material, phyllosilicates, carbonates, organic, Fe-oxides, and volatiles, as determined by the Dawn/VIR-IR imaging spectrometer, with the constraints on the elemental composition provided by the Dawn/GRAND instrument. The recent calibration of the VIS channel of the VIR spectrometer provided further constraints on the overall compositional…
We construct a theoretical model for low-temperature crystallization of amorphous silicate grains induced by exothermic chemical reactions. As a first step, the model is applied to the annealing experiments, in which the samples are (1) amorphous silicate grains and (2) amorphous silicate grains covered with an amorphous carbon layer. We derive the activation energies of crystallization for amorphous silicate and amorphous carbon from the analysis of the experiments. Furthermore, we apply the model to the experiment of low-temperature crystallization of amorphous silicate core covered with an …
In the conventional habitable zone (HZ) concept, a CO$_{2}$-H$_2$O greenhouse maintains surface liquid water. Through the water-mediated carbonate-silicate weathering cycle, atmospheric CO$_{2}$ partial pressure (pCO$_{2}$) responds to changes in surface temperature, stabilizing the climate over geologic timescales. We show that this weathering feedback ought to produce a log-linear relationship between pCO$_{2}$ and incident flux on Earth-like planets in the HZ. However, this trend has scatter because geophysical and physicochemical parameters can vary, such as land area for weathering and CO…
For decades, scientists have tried to explain the evidence for fluvial activity on early Mars, but a consensus has yet to emerge regarding the mechanism for producing it. One hypothesis suggests early Mars was warmed by a thick greenhouse atmosphere. Another suggests that early Mars was generally cold but was warmed occasionally by impacts or by episodes of enhanced volcanism. These latter hypotheses struggle to produce the amounts of rainfall needed to form the martian valleys, but are consistent with inferred low rates of weathering compared to Earth. Here, we provide a geophysical mechanism…
Carbon-enriched rocky exoplanets have been proposed around dwarf stars as well as around binary stars, white dwarfs and pulsars. However, the mineralogical make up of such planets is poorly constrained. We performed high-pressure high-temperature laboratory experiments ($P$ = 1$-$2 GPa, $T$ = 1523$-$1823 K) on carbon-enriched chemical mixtures to investigate the deep interiors of Pluto- to Mars-size planets the upper mantles of larger planets. Our results show that these exoplanets, when fully-differentiated, comprise a metallic core, a silicate mantle and a graphite layer on top of the silica…
We introduce a fast and versatile computer code, GGchem, to determine the chemical composition of gases in thermo-chemical equilibrium down to 100 K, with or without equilibrium condensation. We review the data for molecular equilibrium constants, kp(T), from several sources and discuss which functional fits are most suitable for low temperatures. We benchmark our results against another chemical equilibrium code. We collect Gibbs free energies, dG(T), for about 200 solid and liquid species from the NIST-JANAF database and the geophysical database SUPCRTBL. We discuss the condensation sequence…
The potential habitability of an exoplanet is traditionally assessed by determining if its orbit falls within the circumstellar `habitable zone' of its star, defined as the distance at which water could be liquid on the surface of a planet (Kopparapu et al., 2013). Traditionally, these limits are determined by radiative-convective climate models, which are used to predict surface temperatures at user-specified levels of greenhouse gases. This approach ignores the vital question of the (bio)geochemical plausibility of the proposed chemical abundances. Carbon dioxide is the most important greenh…
Comet C/2013 US10 (Catalina) was an dynamically new Oort cloud comet whose apparition presented a favorable geometry for observations near close Earth approach (~0.93au) at heliocentric distances ~2au when insolation and sublimation of volatiles drive maximum activity. Here we present mid-infrared spectrophotometric observations at two temporal epochs from NASA's Stratospheric Observatory for Infrared Astronomy and the NASA Infrared Telescope Facility. The grain composition is dominated by dark dust grains (modeled as amorphous carbon) with a silicate-to-carbon ratio ~0.9, little of crystallin…
Astrophysical measurements have shown that some stars have sufficiently high carbon-to-oxygen ratios such that the planets they host would be mainly composed of carbides instead of silicates. We studied the behavior of silicon carbide in the presence of water under the high pressure-temperature conditions relevant to planetary interiors in the laser-heated diamond-anvil cell (LHDAC). When reacting with water, silicon carbide converts to silica (stishovite) and diamond at pressures up to 50 GPa and temperatures up to 2500 K: SiC + 2H$_2$O -> SiO$_2$ + C + 2H$_2$. Therefore, if water can be inco…
The carbon-silicate cycle regulates the atmospheric $CO_2$ content of terrestrial planets on geological timescales through a balance between the rates of $CO_2$ volcanic outgassing and planetary intake from rock weathering. It is thought to act as an efficient climatic thermostat on Earth and, by extension, on other habitable planets. If, however, the weathering rate increases with the atmospheric $CO_2$ content, as expected on planets lacking land vascular plants, the carbon-silicate cycle feedback can become severely limited. Here we show that Earth-like planets receiving less sunlight than …
University of Nevada, Las Vegas（内华达大学拉斯维加斯分校）；Nevada Center for Astrophysics（内华达天体物理学中心）；Department of Astronomy, University of Wisconsin–Madison（威斯康星大学麦迪逊分校天文学系）
During the formation of terrestrial planets, volatile loss may occur through nebular processing, planetesimal differentiation, and planetary accretion. We investigate iron meteorites as an archive of volatile loss during planetesimal processing. The carbon contents of the parent bodies of magmatic iron meteorites are reconstructed by thermodynamic modelling. Calculated solid/molten alloy partitioning of C increases greatly with liquid S concentration and inferred parent body C concentrations range from 0.0004 to 0.11 wt.%. Parent bodies fall into 2 compositional clusters characterized by cores…
The atmospheres of the terrestrial planets are known to have been modified as a consequence of the impact degassing and atmospheric erosion during the late accretion. Despite the commonality of these processes, there are distinct gaps -- roughly two orders of magnitude -- between the abundances of noble gases and nitrogen in the present-day atmospheres on Venus, Earth, and Mars. The element partitioning on planetary surfaces is thought to be significantly different between the three planets ~4 Ga: the runaway greenhouse on Venus, the carbon-silicate cycle and ocean formation on Earth, and the …
The Dawn mission confirms predictions that the asteroid 4 Vesta is differentiated with an iron-rich core, a silicate mantle and a basaltic crust, and confirms Vesta as the parent body of the HED meteorites. To better understand its early evolution, we perform numerical calculations of the thermo-chemical evolution adopting new data obtained by the Dawn mission such as mass, bulk density and size of the asteroid. We have expanded the model of Neumann et al. (2012) that includes accretion, compaction, melting and associated changes of material properties and partitioning of 26Al, advective heat …
The poor stickiness of silicate dust grains is a major obstacle to the formation of rocky planetesimals. In this study, we examine the possibility that silicate grains with an organic mantle, which we call Organic-Mantled Grains (OMGs), form planetesimals through direct coagulation. Organic mantles are commonly found in interplanetary dust particles, and laboratory experiments show that they are softer than silicates, in particular in warm environments. This, combined with the theory of particle adhesion, implies that OMGs are stickier than bare silicate grains. Because organic mantles can sur…
Despite a surface dominated by carbon-based life, the bulk composition of the Earth is dramatically carbon poor when compared to the material available at formation. Bulk carbon deficiency extends into the asteroid belt representing a fossil record of the conditions under which planets are born. The initial steps of planet formation involve the growth of primitive sub-micron silicate and carbon grains in the Solar Nebula. We present a solution wherein primordial carbon grains are preferentially destroyed by oxygen atoms ignited by heating due to stellar accretion at radii < 5 AU. This solution…
Planetary rotation rate has a significant effect on atmospheric circulation, where the strength of the Coriolis effect in part determines the efficiency of latitudinal heat transport, altering cloud distributions, surface temperatures, and precipitation patterns. In this study we use the ROCKE-3D dynamic-ocean general circulation model to study the effects of slow rotations and increased insolations on the 'fractional habitability' and silicate weathering rate of an Earth-like world. Defining the fractional habitability f_h to be the percentage of a planet's surface which falls in the 0 <= T <…
Organic matter and hydrous silicates are intimately mixed in the matrix of chondrites and in-situ determination of their individual D/H ratios is therefore challenging. Nevertheless, the D/H ratio of each pure component in this mixture should yield a comprehensible signature of the origin and evolution of water and organic matter in our solar system. We measured hydrogen isotope ratios of organic and hydrous silicates in the matrices of two carbonaceous chondrites (Orgueil CI1 and Renazzo CR2) and one unequilibrated ordinary chondrite (Semarkona, LL3.0). A novel protocol was adopted, involving…
We present mid-infrared spectra and images from the GEMINI-N (+Michelle) observations of fragments SW3-[B] and SW3-[C] of the ecliptic (Jupiter Family) comet 73P/Schwassmann-Wachmann 3 pre-perihelion. We observed fragment B soon after an outburst event (between 2006 April 16 - 26 UT) and detected crystalline silicates. The mineralogy of both fragments was dominated by amorphous carbon and amorphous pyroxene. The grain size distribution (assuming a Hanner modified power-law) for fragment SW3-[B] has a peak grain radius of a_p ~ 0.5 micron, and for fragment SW3-[C], a_p ~ 0.3 micron; both values…
The carbon to oxygen ratio in a protoplanetary disk can have a dramatic influence on the compositions of any terrestrial planets formed. In regions of high C/O, planets form primarily from carbonates and in regions of low C/O, the ratio of magnesium to silicon determines the types of silicates which dominate the compositions. We present C/O and Mg/Si ratios for 849 F, G, and K dwarfs in the solar neighborhood. We find that the frequency of carbon-rich dwarfs in the solar neighborhood is < 0.13% and that 156 known planet hosts in the sample follow a similar distribution as all of the stars as a…
When the extent of protoplanetary melting approached magma ocean (MO)-like conditions, alloy melts efficiently segregated from the silicates to form metallic cores. The nature of the MO of a differentiating protoplanet, i.e., internal or external MO (IMO or EMO), not only determines the abundances of life-essential volatiles like nitrogen (N) and carbon (C) in its core and mantle reservoirs but also the timing and mechanism of volatile loss. Whether the earliest formed protoplanets had IMOs or EMOs is, however, poorly understood. Here we model equilibrium N and C partitioning between alloy and…
Ascertaining rocky exoplanets dynamic evolution requires better understanding of key internal thermophysical processes that shaped their geological surfaces, heat fluxes, volatiles and atmospheric content. New high-pressure experiments on iron and silicates compressible, melting and transport properties are providing new constraints that demand reassessments of super-Earths thermal and magnetic evolution models. We examine the interior structure, temperature distribution, thermal states and dynamo action of these planets with masses ranging from 1-10 ME. We show that the shallow adiabaticity o…
The Moon-forming giant impact extensively melts and partially vaporizes the silicate Earth and delivers a substantial mass of metal to Earth's core. Subsequent evolution of the magma ocean and overlying atmosphere has been described by theoretical models but observable constraints on this epoch have proved elusive. Here, we report calculations of the primordial atmosphere during the magma ocean and water ocean epochs and forge new links with observations to gain insight into the behavior of volatiles on the early Earth. As Earth's magma ocean crystallizes, it outgasses the bulk of the volatile…
The stability of Earth's climate on geological timescales is enabled by the carbon-silicate cycle that acts as a negative feedback mechanism stabilizing surface temperatures via the intake and outgas of atmospheric carbon. On Earth, this thermostat is enabled by plate tectonics that sequesters outgassed CO2 back into the mantle via weathering and subduction at convergent margins. Here we propose a separate tectonic mechanism -- vertical recycling -- that can serve as the vehicle for CO2 outgassing and sequestration over long timescales. The mechanism requires continuous tidal heating, which ma…
In order to test planetary accretion and differentiation scenarios, we integrated a multistage core-mantle differentiation model with N-body accretion simulations. Impacts between embryos and planetesimals result in magma ocean formation and episodes of core formation. The core formation model combines rigorous chemical mass balance with metal-silicate element partitioning data. The primary constraint on the combined model is the composition of the Earth's primitive mantle, the composition of the Martian mantle, and the mass fractions of the metallic cores of Earth and Mars. The model is refin…
Volatile molecules containing hydrogen, carbon, and nitrogen are key components of planetary atmospheres. In the pebble accretion model for rocky planet formation, these volatile species are accreted during the main planetary formation phase. For this study, we modelled the partitioning of volatiles within a growing planet and the outgassing to the surface. The core stores more than 90\% of the hydrogen and carbon budgets of Earth for realistic values of the partition coefficients of H and C between metal and silicate melts. The magma oceans of Earth and Venus are sufficiently deep to undergo …
Recent observations indicate potentially carbon-rich exoplanet atmospheres. Spectral fitting methods for brown dwarfs and exoplanets have invoked the C/O ratio as additional parameter but carbon-rich cloud formation modeling is a challenge for the models applied. The determination of the habitable zone for exoplanets requires the treatment of cloud formation in chemically different regimes. Disk models show that carbon-rich or near-carbon-rich niches may emerge and cool carbon planets may trace these particular stages of planetary evolution. We extend our kinetic cloud formation model by inclu…
