Bubble bursting at the surface of the sea water produce drops and is the main source of sea spay aerosol. The mechanisms underlying the drops production from a single bubble bursting event have been intensively studied and the influence of the bubble size and liquid parameters (density, viscosity and surface tension) has been unified. However, despite the diversity of the surfactant molecules present in the oceans, their influence has been overlooked. In this paper we experimentally explore the influence of the surfactant concentration (Sodium Dodecyl Surfate - SDS) in a water solution on a single bubble collapse and subsequent drop production. We show that these surfactant molecules have an astonishing effect. In particular, we quantitatively show that they modify the bubble collapse, they induce less, smaller and faster drops and they can even completely prevent the drop production for a particular concentration. These results are presented in the existing dimensionless framework and they allow us to affirme that these effects are mainly a consequence of the surface tension gradients (Marangoni stresses) more than just the surface tension lowering. Finally, this study shows that the role of water contamination by surface-active agents is important and needs to be understood to improve the prediction of the sea spray aerosol.
We study the effect of surfactant on the dynamics of a bubble bursting through an interface. We perform fully three-dimensional direct numerical simulations using a hybrid interface-tracking/level-set method accounting for surfactant-induced Marangoni stresses, sorption kinetics, and diffusive effects. We select an initial bubble shape corresponding to a large Laplace number and a vanishingly small Bond number in order to neglect gravity, and isolate the effects of surfactant on the flow. Our results demonstrate that the presence of surfactant affects the dynamics of the system through Marango…
We present a parametric study of the unsteady phenomena associated with the flow of elongated gas bubbles travelling through liquid-filled square capillaries under high Weber number conditions. These conditions consistently induce the formation of a re-entrant jet at the back of the bubble that commonly gives way to a deep liquid cavity. Subsequent steps include pinch-off events in the cavity to generate one or multiple encapsulated drops which may coalesce, in conjunction with the bursting of the bubble-liquid interface by either the cavity or the drops. Some of these interfacial instabilitie…
We use experiments to explore the effect of surfactants on bubble-induced turbulence (BIT) at different scales, considering how the bubbles affect the flow kinetic energy, anisotropy and extreme events. To this end, high-resolution Particle Shadow Velocimetry measurements are carried out in a bubble column in which the flow is generated by bubble swarms rising in water for two different bubble diameters ($3$ mm $\&$ $4$ mm) and moderate gas volume fractions ($0.5\%\sim1.3\%$). To contaminate the flow, different amounts of 1-Pentanol were added to the flow, leading to different bubble shapes an…
Bubbles dispersed in liquids are widely present in many natural and industrial processes, and play a key role in mediating mass transfer during their lifetime from formation to rising to bursting. In particular, nano/micro-sized particulates and organisms, present in the bulk water can be highly enriched in the jet drops ejected during bubble bursting, impacting global climate and public health. However, the detailed mechanism of this enrichment remains obscure, with the enrichment factor being difficult to predict. Here, we experimentally investigate the enrichment of nano/micro-sized particl…
Bubbles at a free surface surface usually burst in ejecting myriads of droplets. Focusing on the bubble bursting jet, prelude for these aerosols, we propose a simple scaling for the jet velocity and we unravel experimentally the intricate roles of bubble shape, capillary waves, gravity and liquid properties. We demonstrate that droplets ejection unexpectedly changes with liquid properties. In particular, using damping action of viscosity, self-similar collapse can be sheltered from capillary ripples and continue closer to the singular limit, therefore producing faster and smaller droplets.Thes…
As a bubble bursts at a liquid-air interface, a tiny liquid jet rises and can release the so-called \textit{jet drops}. In this paper, the size of the top jet drop produced by a bubble bursting is investigated experimentally. We determine, and discuss, the first scaling law enabling the determination of the top jet drop size as a function of the corresponding mother bubble radius and the liquid properties (viscosity, surface tension, density), along with its regime of existence. Furthermore, in the aim of decoupling experimentally the effects of bubble collapse and jet dynamics on the drop det…
The effect of surfactants on the tail and film dynamics of elongated gas bubbles propagating through circular capillary tubes is investigated by means of an extensive three-dimensional numerical study using a hybrid front-tracking/level-set method. The focus is on the visco-inertial regime, which occurs when the Reynolds number of the flow is much larger than unity. Under these conditions, `clean' bubbles exhibit interface undulations in the proximity of the tail \cite{Magnini_prf_2017}, with an amplitude that increases with the Reynolds number. We perform a systematic analysis of the impact o…
This paper presents novel insights about the influence of soluble surfactants on bubble flows obtained by Direct Numerical Simulation (DNS). Surfactants are amphiphilic compounds which accumulate at fluid interfaces and significantly modify the respective interfacial properties, influencing also the overall dynamics of the flow. With the aid of DNS local quantities like the surfactant distribution on the bubble surface can be accessed for a better understanding of the physical phenomena occurring close to the interface. The core part of the physical model consists in the description of the sur…
In the present study, simulations are directed to capture the dynamics of evacuating inner gas of a bubble bursting at the free surface, using Eulerian based volume of fluid (VOF) method. The rate by which surrounding air rushing inside the bubble cavity through the inner gas evacuation is estimated and compared by the collapsing bubble cavity during the sequential stages of the bubble bursting at the free surface. Further, the reachability of inner gas over the free surface is evaluated by establishing the comparison of the same through various horizontal planes, lying at different altitudes …
The transient ejection due to a bubble bursting at the interface of a liquid with a gas environment is here described using a dynamical scaling analysis along the process. We show here that the ejection of a liquid microjet requires the backfire of a vortex ring inside the liquid to preserve physical symmetry, which involves a non-trivial scaling. We present the first single uniformly valid expression for the size and speed of ejected droplets for the whole range of the Ohnesorge and Bond numbers where droplet ejection occurs. The evolution of the flow variables, the apparent singularity for a…
Bubbles appear when a carbonated drink is poured in a glass. Very stable bubble chains are clearly observed in champagne, showing an almost straight line from microscopic nucleation sites from which they are continuously formed. In some other drinks such as soda, such chains are not straight (not stable). Considering pair interactions for spherical clean bubbles, bubble chains should not be stable which contradicts these observations. The aim of this work is to explain the conditions for bubble chain stability. For this purpose, experiments and direct numerical simulation are conducted. The bu…
The analysis of numerical simulations describing the collapse of capillary cavities reveals that the jets originated from the bursting of bubbles are driven by the condition that the dimensionless liquid flow rate per unit length directed towards the axis of symmetry, $q_\infty$, remains nearly constant in time. This observation, which is justified in physical terms because liquid inertia prevents appreciable changes in $q_\infty$ during the short time scale characterizing the jet ejection process, together with the fact that bubble bursting jets are produced from the bottom of a conical cavit…
Jet droplets from bubble bursting are determined by a limited parametrical space: the liquid properties (surface tension, viscosity, and density), mother bubble size and acceleration of gravity. Thus, the two resulting parameters from dimensional analysis (usually, the Ohnesorge and Bond numbers, Oh and Bo) completely define this phenomenon when both the trapped gas in the bubble and the environment gas have negligible density. A detailed physical description of the ejection process to model both the ejected droplet radius and its initial launch speed is provided, leading to a scaling law incl…
Interface-resolved direct numerical simulations are performed to examine the combined effects of soluble surfactant and viscoelasticity on the structure of a bubbly turbulent channel flow. The incompressible flow equations are solved fully coupled with the FENE-P viscoelastic model and the equations governing interfacial and bulk surfactant concentrations. The latter coupling is achieved through a non-linear equation of state which relates the surface tension to the surfactant concentration at the interface. The two-fluid Navier-Stokes equations are solved using a front-tracking method, augmen…
This study examines the effects of angle of attack on the characteristics of the laminar separation bubble (LSB), its associated low-frequency flow oscillation (LFO), and the flow-field around a NACA-0012 aerofoil at $Re_c = 5\times 10^4$ and $M_{\infty} = 0.4$. In the range of the investigated angles of attack, statistics of the flow-field suggest the existence of three distinct angle-of-attack regimes: 1) the flow and aerodynamic characteristics are not much affected by the LFO for angles of attack $α< 9.25^{\circ}$; 2) the flow-field undergoes a transition regime in which the bubble burstin…
Polymer additives are commonly utilized to manipulate bubbly flows in various applications. Here, we investigate the effects of clean and contaminated bubbles driven upwards (upflow) in Newtonian and viscoelastic turbulent channel flows. Interface-resolved direct numerical simulations are performed to examine sole and combined effects of soluble surfactant and viscoelasticity using an efficient 3D finite-difference/front-tracking method. The incompressible flow equations are solved fully coupled with the FENE-P viscoelastic model and the equations governing interfacial and bulk surfactant conc…
Soap bubbles are by essence fragile and ephemeral. Depending on their composition and environment, bubble bursting can be triggered by gravity-induced drainage and/or the evaporation of the liquid and/or the presence of nuclei. They can also shrink due to the diffusion of the inner gas in the outside atmosphere induced by Laplace overpressure. In this paper, we design bubbles made of a composite liquid film able to neutralize all these effects and keep their integrity for more than one year in a standard atmosphere. The unique properties of this composite film are rationalized with a nonlinear…
The merging of two soap bubbles is a fundamental fluid mechanical process in foam formation. In the present experimental study the liquid films from two soap bubbles are brought together. Once the liquid layers initially separated by a gas sheet are bridged on a single spot the rapid merging of the two liquid films proceed. Thereby the connecting rim is rapidly accelerated into the separating gas layer. We show that due to the dimple formation the velocity is not uniform and the high acceleration causes initially a Rayleigh-Taylor instability of the liquid rim. At later times, the rim takes he…
In the maritime industry, the injection of air bubbles into the turbulent boundary layer under the ship hull is seen as one of the most promising techniques to reduce the overall fuel consumption. However, the exact mechanism behind bubble drag reduction is unknown. Here we show that bubble drag reduction in turbulent flow dramatically depends on the bubble size. By adding minute concentrations (6 ppm) of the surfactant Triton X-100 into otherwise completely unchanged strongly turbulent Taylor-Couette flow containing bubbles, we dramatically reduce the drag reduction from more than 40% to abou…
The bursting of bubbles at an air/liquid interface is a familiar occurrence important to foam stability, cell cultures in bioreactors and mass transfer between the sea and atmosphere. Here we document the hitherto unreported formation and dispersal into the water column of submicrometre oil droplets following bubble bursting at a compound air/oil/water-with-surfactant interface. We show that dispersal results from the detachment of an oil spray from the bottom of the bubble towards water during bubble collapse. We provide evidence that droplet size is selected by physicochemical interactions b…
The present investigation shows that a triad of three vortices, two co-rotating vortices (TCV) and a secondary vortex lies beneath them and counter-rotating with them, is behind the quasi-periodic self-sustained bursting and reformation of the laminar separation bubble (LSB) and its associated low-frequency flow oscillation (LFO). The upstream vortex of the TCV (UV) is driven by the gradient of the oscillating-velocity across the laminar portion of the separated shear layer and is faithfully aligned with it. The secondary vortex acts as a roller support that facilitates the rotation and orient…
We study the instabilities occurring during the burst of an air balloon in a liquid. These instabilities are typical for the deformation of an interface between two fluids of different densities, similar to fingering in Rayleigh-Taylor instability (see e.g. Sharp, 1984). In the Video a series of bursts are shown for air balloons in different liquids. When the balloon tears it tracks the surface, generating wrinkles and releasing the pressure inside. Apparently, the texture of the surface during the burst becomes smoother as the viscosity increases. During the burst the surface breaks and gener…
In this review article, we discuss recent studies on drops and bubbles in Hele-Shaw cells, focusing on how scaling laws exhibit crossovers from the three-dimensional counterparts and focusing on topics in which viscosity plays an important role. By virtue of progresses in analytical theory and high-speed imaging, dynamics of drops and bubbles have actively been studied with the aid of scaling arguments. However, compared with three dimensional problems, studies on the corresponding problems in Hele-Shaw cells are still limited. This review demonstrates that the effect of confinement in the Hel…
The physico-chemistry of surfactants (amphiphilic surface active agents) is often used to control the dynamics of viscous drops and bubbles. Surfactant sorption kinetics has been shown to play a critical role in the deformation of drops in extensional and shear flows, yet to the best of our knowledge these kinetics effects on a viscous drop in an electric fieldhave not been accounted for. In this paper we numerically investigate the effects of sorption kinetics on a surfactant-covered viscous drop in an electric field. Over a range of electric conductivity and permittivity ratios between the i…
Previous observations of the nontransient oscillations of rising bubbles and falling spheres in wormlike micellar fluids were limited to a single surfactant system. We present an extensive survey of rising bubbles in another system, an aqueous solution of cetylpyridinium chloride and sodium salicylate, with and without NaCl, across a range of concentrations and temperatures. Two different types of oscillation are seen in different concentration ranges, each with its own temperature dependence. Rheological data allows for the identification of these different hydrodynamic states with different …
Understanding the behavior of nanobubbles (NBs) in various aqueous solutions is a challenging task. The present work investigates the effects of various surfactants (i.e., anionic, cationic, and nonionic) and pH medium on bulk NBs formation, size, concentration, bubble size distribution (BSD), zeta potential, and stability. The effect of surfactant was investigated at various concentrations above and below critical micelle concentrations. NBs were created in DI water using a piezoelectric transducer. The stability of NBs was assessed by tracking the change in size and concentration over time. …
Detailed flow dissection using Dynamic Mode Decomposition (DMD) and Proper Orthogonal Decomposition (POD) is carried out to investigate the dynamics of the flow-field around a NACA-0012 aerofoil at a Reynolds number of $5\times 10^4$, Mach number of $0.4$, and at various angles of attack around the onset of stall. Three distinct dominant flow modes are identified by the DMD and the POD: 1) a globally oscillating flow mode at a low-frequency (LFO mode 1); 2) a locally oscillating flow mode on the suction surface of the aerofoil at a low-frequency (LFO mode 2); and 3) a locally oscillating flow …
