A solar-type system starts from an initial molecular core that acquires organic complexity as it evolves. The so-called prestellar cores that can be studied are rare, which has hampered our understanding of how organic chemistry sets in and grows. Aims. We selected the best prestellar core targets from the cold core catalogue that represent a diversity in terms of their environment to explore their chemical complexity: 1390 (in the compressed shell of Lambda Ori), 869 (in the MBM12 cloud), and 4149 (in the California nebula). We obtained a spectral survey with the IRAM 30 m telescope in order to explore the molecular complexity of the cores. We carried out a radiative transfer analysis of the detected transitions in order to place some constraints on the physical conditions of the cores and on the molecular column densities. We also used the molecular ions in the survey to estimate the cosmic-ray ionisation rate and the S/H initial elemental abundance using a gas-phase chemical model to reproduce their abundances. We found large differences in the molecular complexity (deuteration, complex organic molecules, sulphur, carbon chains, and ions) and compared their chemical properties with a cold core and two prestellar cores. The chemical diversity we found in the three cores seems to be correlated with their chemical evolution: two of them are prestellar (1390 and 4149), and one is in an earlier stage (869). The influence of the environment is likely limited because cold cores are strongly shielded from their surroundings. The high extinction prevents interstellar UV radiation from penetrating deeply into the cores. Higher spatial resolution observations of the cores are therefore needed to constrain the physical structure of the cores, as well as a larger-scale distribution of molecular ions to understand the influence of the environment on their molecular complexity.
Influence of galactic arm scale dynamics on the molecular composition of the cold and dense ISM II. Molecular oxygen abundance
分子氧一直是许多观测研究的主题,因为化学模型预测它是氧气的储存库。虽然它已经在星际介质的两个区域被探测到,但它的稀有性对天体化学模型来说是一个挑战。在本文中,我们结合了计算的物理条件与光滑粒子流体动力学(SPH)模拟与我们的全气体颗粒化学模型鹦鹉螺,研究预测的O2丰度在星际物质形成冷芯。因此,我们遵循的气体和冰的化学演化的物质包裹从弥漫的星际条件冷致密的核心。我们的大多数预测的O2丰度低于1 e-8(相对于总质子密度)和预测的柱密度在模拟冷芯是在最大的几个1 e 14 cm-2,在协议的非检测限。这种低的O2丰度可以通过以下事实来解释,即在大部分星际材料中,在O2可以在气相中形成并且免受UV光解离之前,原子氧被耗尽到晶粒表面上(并且被氢化以形成H2O)。我们之所以能得到这个结果,是因为我们考虑了从弥散介质到冷核的物理条件演化的全部历史。
Influence of galactic arm scale dynamics on the molecular composition of the cold and dense ISM III. Elemental depletion and shortcomings of the current physico-chemical models
本文研究了星际介质中的元素损耗。我们结合了银河系模型的结果,描述了致密核形成过程中的气体物理条件与全气体颗粒化学模型。在扩散和稠密介质之间的过渡期间,最初在气体中的原子元素的储存器逐渐在尘埃颗粒上耗尽(对于那些离子来说,有一个中和阶段)。当密度大于100 cm $^{-3}$时,该过程变得有效。如果致密材料回到扩散状态,这些元素又回到气相,因为冰上分子的光离解,然后从颗粒上热解吸。对于密度低于10 cm $^{-3}$的颗粒或气相中的分子形式,颗粒上没有残留物。一个例外是氯,它在低密度下有效地转化。我们现有的气体颗粒化学模型不能再现在扩散介质中观察到的原子的耗尽,除了Cl,其气体丰度遵循在密度小于10 cm $^{-3}$的介质中观察到的气体丰度。这表明关键的过程(可能涉及化学吸附和/或冰辐射深刻改变冰的性质)缺失。
Testing various assumptions for radiolysis, non-diffusive chemistry, and chemical desorption in cold cores
Laboratoire d’astrophysique de Bordeaux, Univ. Bordeaux, CNRS(波尔多天体物理学实验室,波尔多大学,法国国家科学研究中心);School of Astronomy & Space Science, Nanjing University(南京大学天文与空间科学学院)
我们用詹姆斯·克拉克·麦克斯韦望远镜/SCUBA-2和野边山45米射电望远镜观测了13个普朗克冷团。用Nobeyama望远镜得到的N $_2$ H $^+$分布与SCUBA-2尘埃分布非常相似。82 GHz HC $_3$ N、82 GHz CCS和94 GHz CCS发射通常相对于N $_2$ H $^+$发射不同地分布。CCS发射,这是众所周知的,是丰富的无星分子云的核心,往往是非常clusive的观测目标。我们在DNC、HN $^{13}$ C、N $_2$ D $^+$、cyclic-C $_3$ H $_2$中对9个团块进行了深单点观测。N $_2$ D $^+$的检出率为50%。此外,我们还观测了$_3$向15普朗克冷团簇的发射,以估计动力学温度,并证实大多数靶是冷的($\lesssim$ 20 K)。在观测到的两个无星团块中,CCS辐射分布在N $_2$ H $^+$核心(化学演化气体)周围,这与L1544的情况类似,L1544是一个显示坍缩的星前核心。此外,我们还检测到DNC和N $_2$ D $^+$。这两个团块极有可能处于恒星形成的边缘。引入化学演化因子(CEF)来描述无星核的化学演化阶段,并对观测到的普朗克冷团进行了分析。
Discovery of the propargyl radical (CH2CCH) in TMC-1: one of the most abundant radicals ever found and a key species for cyclization to benzene in cold dark clouds
Astrochemistry Focus and Research on Planck Cold Clumps
在天体化学焦点小组,我们讨论了我们的理解中仍然缺少的东西,即使在这次会议上给出了新的知识,以及从现在开始的10年内可以做些什么。目前尚缺乏对紫外光子和宇宙射线与冰尘埃颗粒的相互作用、硫和磷化学、金属丰度效应、持续时间效应、COM的形成和破坏、相变、尘埃-气体界面、尘埃演化等的认识。我们应该做的是多尺度高光谱分辨率分子观测、实验室工作、理论、辐射转移、我们需要仔细建模,而不是简化事物。接下来,我介绍我们对普朗克冷团簇的研究。我们用詹姆斯·克拉克·麦克斯韦望远镜/SCUBA-2和野边山45米射电望远镜观测了13个普朗克冷团。用Nobeyama望远镜得到的N $_2$ H $^+$分布与SCUBA-2尘埃分布非常相似。82 GHz HC $_3$ N、82 GHz CCS和94 GHz CCS发射通常相对于N $_2$ H $^+$发射不同地分布。CCS发射,这是众所周知的,是丰富的无星分子云的核心,往往是非常clusive的观测目标。我们对DNC、HN $^{13}$ C、N $_2$ D $^+$、cyclic C $_3$ H $_2$等9个星系团进行了单点观测。N $_2$ D $^+$的检出率为50%。在观测到的两个无星团块中,CCS辐射分布在N $_2$ H $^+$核心(化学演化气体)周围,这与L1544的情况类似,L1544是一个显示坍缩的星前核心。此外,我们还检测到DN…