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arXiv 2201.07506cond-mat.soft
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纤维素纳米晶体凝胶中的慢动力学与时间-组成叠加

Slow dynamics and time-composition superposition in gels of cellulose nanocrystals

Lise Morlet-Decarnin, Thibaut Divoux, Sebastien Manneville

AI总结:

本研究探讨了盐浓度对纤维素纳米晶体(CNC)凝胶慢老化动力学的影响,发现弹性模量遵循时间-组成叠加原理,可重新标度到一条跨越13个数量级时间的通用S型主曲线上,为CNC凝胶老化动力学的普适性提供了有力证据。

摘要:

纤维素纳米晶体(CNCs)是棒状生物源胶体颗粒,作为关键结构单元被用于越来越多具有创新力学或光学性能的材料中。虽然CNCs在纯水中以低体积分数形成稳定的悬浮液,但它们在盐存在下会发生聚集,并形成具有时间依赖性的胶体凝胶。在此,我们研究了在完全使样品流体化的高剪切流动停止后,盐浓度对CNC凝胶慢老化动力学的影响。我们表明,盐含量越高,流动停止后弹性的恢复越快。最值得注意的是,弹性模量 $G'$ 遵循时间-组成叠加原理:在广泛的盐浓度范围内,$G'$ 的时间演化可以重新标度到一条跨越13个数量级时间的通用S型主曲线上。这种重新标度是通过一个时间偏移因子实现的,该因子随着盐浓度的增加呈现陡峭的幂律衰减,直到在高盐含量下达到饱和。这些发现对盐类型和CNC含量的变化具有鲁棒性。我们进一步表明,不同组成CNC凝胶的线性和非线性流变特性,例如粘弹性谱的频率依赖性和屈服应变,都可以基于样品沿通用主曲线的老化年龄进行重新标度。我们的结果为CNC凝胶老化动力学的普适性提供了强有力的证据,并呼吁在恢复期间进行微观结构研究,以及棒状胶体中时间-组成叠加的理论建模。

英文摘要:

Cellulose nanocrystals (CNCs) are rodlike biosourced colloidal particles used as key building blocks in a growing number of materials with innovative mechanical or optical properties. While CNCs form stable suspensions at low volume fractions in pure water, they aggregate in the presence of salt and form colloidal gels with time-dependent properties. Here, we study the impact of salt concentration on the slow aging dynamics of CNC gels following the cessation of a high-shear flow that fully fluidizes the sample. We show that the higher the salt content, the faster the recovery of elasticity upon flow cessation. Most remarkably, the elastic modulus $G'$ obeys a time-composition superposition principle: the temporal evolution of $G'$ can be rescaled onto a universal sigmoidal master curve spanning 13 orders of magnitude in time for a wide range of salt concentrations. Such a rescaling is obtained through a time-shift factor that follows a steep power-law decay with increasing salt concentration, until it saturates at large salt content. These findings are robust to changes in the type of salt and in the CNC content. We further show that both linear and nonlinear rheological properties of CNC gels of various compositions, including, e.g., the frequency-dependence of viscoelastic spectra and the yield strain, can be rescaled based on the sample age along the general master curve. Our results provide strong evidence for universality in the aging dynamics of CNC gels, and call for microstructural investigations during recovery as well as theoretical modelling of time-composition superposition in rodlike colloids.

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