Thermodynamic uncertainty relation, quantifying a trade-off among average current, the associated fluctuation (precision), and entropy production (cost), has been formulated in nonequilibrium steady state and various stochastic systems. Herein, we study the thermodynamic uncertainty relation in generic thermoelectric heat engines under a periodic control protocol, by uncovering the underlying Berry-phase-like contribution. We show that our thermodynamic uncertainty relation breaks the seminal steady-state results, originating from the non-vanishing geometric effect. Furthermore, by deriving the consequent trade-off relation binding efficiency, power, and constancy, we prove that the periodically driven thermoelectric heat engines can generally outperform the steady-state analogies. The general bounds are illustrated by an analytically solvable two-terminal single quantum dot heat engine under the periodic modulation. Our work provides a geometric framework in bounding and optimizing a wide range of periodically driven thermoelectric thermal machines.
We show theoretically that a thermoelectric heat engine, operating exclusively due to quantum-mechanical interference, can reach optimal linear-response performance. A chiral edge state implementation of a close-to-optimal heat engine is proposed in an electronic Mach-Zehnder interferometer with a mesoscopic capacitor coupled to one arm. We demonstrate that the maximum power and corresponding efficiency can reach 90\% and 83\%, respectively, of the theoretical maximum. The proposed heat engine can be realized with existing experimental techniques and has a performance robust against moderate d…
We establish a theory of optimal efficiency and power for three-terminal thermoelectric engines which have two independent output electric currents and one input heat current. This set-up goes beyond the conventional heat engines with only one output electric current. For such a set-up, we derive the optimal efficiency and power and their trade-off for three-terminal heat engines with and without time-reversal symmetry. The formalism goes beyond the known optimal efficiency and power for systems with or without time-reversal symmetry, showing interesting features that have not been revealed be…
This paper examines the thermoelectric response of a dissipative quantum dot heat engine based on the Anderson-Holstein model in two relevant operating limits: (i) when the dot phonon modes are out of equilibrium, and (ii) when the dot phonon modes are strongly coupled to a heat bath. In the first case, a detailed analysis of the physics related to the interplay between the quantum dot level quantization, the on-site Coulomb interaction and the electron-phonon coupling on the thermoelectric performance reveals that an n-type heat engine performs better than a p-type heat engine. In the second …
We propose a simple classical dynamical model of a thermoelectric (or thermochemical) heat engine based on a pair of ideal gas containers connected by two unequal scattering channels. The model is solved analytically and it is shown that a suitable combination of parameters can be chosen such that the engine operates at Carnot's efficiency.
We investigate a thermoelectric nano-engine whose properties are steered by Coulomb interaction. The device whose design decouples charge and energy currents is made up of two interacting quantum dots connected to three different reservoirs. We show that, by tailoring the tunnel couplings, this setup can be made very attractive for energy-harvesting prospects, due to a delivered power that can be of the order of the quantum bound [R. S. Whitney, Phys. Rev. Lett. 112, 130601 (2014); Entropy 18, 208 (2016)], with a concomitant fair efficiency. To unveil its properties beyond the sequential quant…
We analyze the noise properties of both electric charge and heat currents as well as their correlations in a quantum-dot based thermoelectric engine. The engine is a three-terminal conductor with crossed heat and charge flows where heat fluctuations can be monitored by a charge detector. We investigate the mutual influence of charge and heat dynamics and how it is manifested in the current and noise properties. In the presence of energy-dependent tunneling, operating conditions are discussed where a charge current can be generated by heat conversion. In addition, heat can be pumped into the ho…
Thermodynamic bound on the Fano factor of a coherent thermoelectric heat engine
The Abdus Salam International Centre for Theoretical Physics（阿卜杜斯·萨拉姆国际理论物理中心）；Dipartimento di Fisica, Università di Napoli “Federico II”（那不勒斯费德里科二世大学物理系）
The thermoelectric properties of a three terminal quantum spin Hall (QSH) sample are examined. Inherent helicity of the QSH sample helps to generate a large charge power efficiently. Along with charge the system can be designed to work as a highly efficient spin heat engine too. The advantage of a helical over a chiral sample is that, while a multiterminal quantum Hall sample can only work as a quantum heat engine due to broken time reversal(TR) symmetry, a multiterminal QSH system can work effectively both as a charge/spin heat engine as well as a charge/spin refrigerator as TR symmetry is pr…
Efficiency at maximum power (EMP) is a very important specification for a heat engine to evaluate the capacity of outputting adequate power with high efficiency. It has been proved theoretically that the limit EMP of thermoelectric heat engine can be achieved with the hypothetical boxcar-shaped electron transmission, which is realized here by the resonant tunneling in the one-dimensional symmetric InP/InSe superlattice. It is found with the transfer matrix method that a symmetric mode is robust that regardless of the periodicity, and the obtained boxcar-like electron transmission stems from th…
We propose a near-field inelastic thermoelectric heat engine where quantum-dots are used to effectively rectify the charge flow of photo-carriers. The device converts near-field heat radiation into useful electrical power. Heat absorption and inelastic transport can be enhanced by introducing two continuous spectra separated by an energy gap. The thermoelectric transport properties of the heat engine are studied in the linear-response regime. Using a small band-gap semiconductor as the absorption material, we show that the device achieves very large thermopower and thermoelectric figure-of-mer…
We review recent theoretical work on thermoelectric energy harvesting in multi-terminal quantum-dot setups. We first discuss several examples of nanoscale heat engines based on Coulomb-coupled conductors. In particular, we focus on quantum dots in the Coulomb-blockade regime, chaotic cavities and resonant tunneling through quantum dots and wells. We then turn towards quantum-dot heat engines that are driven by bosonic degrees of freedom such as phonons, magnons and microwave photons. These systems provide interesting connections to spin caloritronics and circuit quantum electrodynamics.
Enhanced thermoelectric effects in a driven one-dimensional system
NEST, Istituto Nanoscienze-CNR and Scuola Normale Superiore（NEST，意大利国家研究委员会纳米科学研究所和比萨高等师范学院）；Institute for Quantum Studies, Chapman University（查普曼大学量子研究学院）；Department of Physics, Lancaster University（兰开斯特大学物理系）
The trade-off between large power output, high efficiency and small fluctuations in the operation of heat engines has recently received interest in the context of thermodynamic uncertainty relations (TURs). Here we provide a concrete illustration of this trade-off by theoretically investigating the operation of a quantum point contact (QPC) with an energy-dependent transmission function as a steady-state thermoelectric heat engine. As a starting point, we review and extend previous analysis of the power production and efficiency. Thereafter the power fluctuations and the bound jointly imposed …
We study the thermoelectric properties and heat-to-work conversion performance of an interacting, multi-level quantum dot (QD) weakly coupled to electronic reservoirs. We focus on the sequential tunneling regime. The dynamics of the charge in the QD is studied by means of master equations for the probabilities of occupation. From here we compute the charge and heat currents in the linear response regime. Assuming a generic multi-terminal setup, and for low temperatures (quantum limit), we obtain analytical expressions for the transport coefficients which account for the interplay between inter…
The energy efficiency and power of a quantum thermoelectric system with multiple electric currents and only one heat currents are studied. The system is connected to the hot heat bath with one terminal but the cold bath with multiple terminals or vice versal. We find that the cooperative effects can be a potentially useful tool in improving the energy efficiency and output power in multi-terminal mesoscopic thermoelectric systems. As an example, we show that the cooperation between the two thermoelectric effects in three-terminal thermoelectric systems leads to markedly improved performance of…
Thermoelectric effects, such as the generation of a particle current by a temperature gradient, have their origin in a reversible coupling between heat and particle flows. These effects are fundamental probes for materials and have applications to cooling and power generation. Here we demonstrate thermoelectricity in a fermionic cold atoms channel, ballistic or diffusive, connected to two reservoirs. We show that the magnitude of the effect and the efficiency of energy conversion can be optimized by controlling the geometry or disorder strength. Our observations are in quantitative agreement w…
In a previous work, we predicted that a thermally biased tunnel junction between two different superconductors can display a thermoelectric effect of nonlinear nature in the temperature gradient, under proper conditions. In this work we give a more extended discussion, and we focus on the two main features of the nonlinear contributions: i) the $linear-in-bias$ thermoelectricity, that can be associated to a spontaneous breaking of electron-hole symmetry, ii) the strong contribution at the matching peak singularity, which is typically associated to the maximum output power and efficiency. We di…
The thermoelectric performance of a topological Josephson nonlocal heat engine is thoroughly investigated. The nonlocal response is obtained by using a normal metal probe coupled with only one of the proximized helical edges in the middle of the junction. In this configuration, we investigate how the flux bias and the phase bias trigger the nonlocal thermoelectric effects under the application of a thermal difference between the superconducting terminals. Possible experimental nonidealities such as asymmetric proximized superconducting gaps are considered showing how the nonlocal response can …
The quest for good thermoelectric materials and/or high-efficiency thermoelectric devices is of primary importance from theoretical and practical points of view. Low-dimensional structures with quantum dots or molecules are promising candidates to achieve the goal. Interactions between electrons, far-from-equilibrium conditions and strongly non-linear transport are important factors affecting the usefulness of the devices. This paper analyses the thermoelectric power of a two-terminal quantum dot under large thermal $ΔT$ and voltage $V$ biases as well as the performance of the three-terminal s…
Investigating the non-linear transport regime in a quantum dot heat engine described by the Anderson-Holstein model, it is shown that a finite electron-phonon interaction leads to a charge induced phonon generation that stimulates a phonon current even in the absence of a thermal gradient. This gives rise to the non-linear phonon Peltier effect which shows a non-trivial dependence on varying the electron-phonon interaction. Utilizing the reversal of phonon currents via charge induced phonon accumulation, we demonstrate that the heat engine surprisingly can be cooled when coupled to a hot reser…
We consider a single-level quantum dot coupled to two leads which are ferromagnetic in general. Apart from tunneling processes conserving electron spin, we also include processes associated with spin-flip of tunneling electrons, which appear due to Rashba spin-orbit coupling. Charge and heat currents are calculated within the non-equilibrium Green's function technique. When the electrodes are half-metallic (fully spin polarized), the Rashba spin-orbit coupling leads to Fano-like interference effects, which result in an enhanced thermoelectric response. It is also shown that such a system can o…
We theoretically investigate the thermoelectric properties of heat engines based on Mach-Zehnder interferometers. The energy dependence of the transmission amplitudes in such setups arises from a difference in the interferometer arm lengths. Any thermoelectric response is thus of purely quantum mechanical origin. In addition to an experimentally established three-terminal setup, we also consider a two-terminal geometry as well as a four-terminal setup consisting of two interferometers. We find that Mach-Zehnder interferometers can be used as powerful and efficient heat engines which perform we…
We generalize the theory of thermoelectrics to include coherent electron systems under adiabatic ac driving, accounting for quantum pumping of charge and heat as well as the associated work exchange between electron system and driving potentials. We derive the relevant response coefficients in the adiabatic regime and show that they obey Onsager reciprocity relations. We analyze the consequences of our generalized thermoelectric framework for quantum motors, generators, heat engines, and heat pumps, characterizing them in terms of efficiencies and figures of merit.
Mesoscopic thermoelectric heat engine is much anticipated as a device that allows us to utilize with high efficiency wasted heat inaccessible by conventional heat engines. However, the derivation of the heat current in this engine seems to be either not general or described too briefly, even inappropriate in some cases. In this paper, we give a clear-cut derivation of the heat current of the engine with suitable assumptions beyond the linear-response regime. It resolves the confusion in the definition of the heat current in the linear-response regime. After verifying that we can construct the …
The quest to identify the best heat engine has been at the center of science and technology. Thermoelectric nanoscale heat engines convert heat flows into useful work in the form of electrical power and promise the realization of on-chip power production. Considerable studies have so far revealed the potentials to yield an enhanced efficiency originating from quantum confinement effects and energy-dependent transport properties. However, the full benefit of many-body interactions in thermoelectric is yet to be investigated; identifying the optimal interaction is a hard problem due to combinato…
We analyze a steady-state thermoelectric engine, whose working substance consists of two capacitively coupled quantum dots. One dot is tunnel-coupled to a hot reservoir serving as a heat source, the other one to two electrically biased reservoirs at a colder temperature, such that work is extracted under the form of a steady-state current against the bias. In single realizations of the dynamics of this steady-state engine autonomous, 4-stroke cycles can be identified. The cycles are purely stochastic, in contrast to mechanical autonomous engines which exhibit self-oscillations. In particular, …
We study thermoelectric effects in Coulomb-coupled quantum-dot (CCQD) systems beyond lowest-order tunneling processes and the often applied wide-band approximation. To this end, we present a master-equation (ME) approach based on a perturbative $T$-matrix calculation of the charge and heat tunneling rates and transport currents. Applying the method to transport through a non-interacting single-level QD, we demonstrate excellent agreement with the Landauer-B{ü}ttiker theory when higher-order (cotunneling) processes are included in the ME. Next, we study the effect of cotunneling and energy-depe…
Power and efficiency of heat engines are two conflicting objectives, and a tight efficiency bound is expected to give insights on the fundamental properties of the power-efficiency tradeoff. Here we derive an upper bound on the efficiency of steady-state heat engines, which incorporates higher-order fluctuations of the power. In a prototypical model of nonlinear nanostructured thermoelectrics, we show that the obtained bound is tighter than a well-established efficiency bound based on the thermodynamic uncertainty relation, demonstrating that the higher-order terms have rich information about …
Recent developments in nanoscale experimental techniques made it possible to utilize single molecule junctions as devices for electronics and energy transfer with quantum coherence playing an important role in their thermoelectric characteristics. Theoretical studies on the efficiency of nanoscale devices usually employ rate (Pauli) equations, which do not account for quantum coherence. Therefore, the question whether quantum coherence could improve the efficiency of a molecular device cannot be fully addressed within such considerations. Here, we employ a nonequilibrium Green function approac…
We investigate direct energy and heat transfer between two distant sites of a triple quantum dot connected to reservoirs, where one of the edge dots is driven by an ac-gate voltage. We theoretically propose how to implement heat and cooling engines mediated by long range photoassisted transport. Additionally we propose a simple set up to heat up coherently the two reservoirs symmetrically and a mechanism to store energy in the closed system. The present proposals can be experimentally implemented and easily controlled by tunning the external parameters.
Thermoelectric transport involving an arbitrary number of terminals is discussed in the presence of a magnetic field breaking time-reversal symmetry within the linear response regime using the Landauer-Büttiker formalism. We derive a universal bound on the Onsager coefficients that depends only on the number of terminals. This bound implies bounds on the efficiency and on efficiency at maximum power for heat engines and refrigerators. For isothermal engines pumping particles and for absorption refrigerators these bounds become independent even of the number of terminals. On a technical level, …
Heat engines made of quantum-dot (QD) superlattice nanowires (SLNWs) offer promising applications in energy harvesting due to the reduction of phonon thermal conductivity. In solid state electrical generators (refrigerators), one needs to generate (remove) large amount of charge current (heat current). Consequently, a high QD SLNW density is required for realistic applications. This study theoretically investigated the properties of power factor and electron heat rectification for an SLNW array under the transition from a one dimensional system to a two dimensional system. The SLNW arrays show…
Quantum dots (QDs) can serve as near perfect energy filters and are therefore of significant interest for the study of thermoelectric energy conversion close to thermodynamic efficiency limits. Indeed, recent experiments in [Nat. Nano. 13, 920 (2018)] realized a QD heat engine with performance near these limits and in excellent agreement with theoretical predictions. However, these experiments also highlighted a need for more theory to help guide and understand the practical optimization of QD heat engines, in particular regarding the role of tunnel couplings on the performance at maximum powe…
We present an analytical study of a strongly correlated quantum dot-based thermoelectric particle-exchange heat engine for both finite and infinite on-dot Coulomb interaction. Employing Keldysh's non-equilibrium Green's function formalism for different decoupling schemes in the equation of motion, we have analyzed the thermoelectric properties within the non-linear transport regime. As the simplest mean-field approximation is insufficient for analyzing thermoelectric properties in the Coulomb blockade regime, one needs to employ a higher-order approximation to study strongly correlated QD-base…
Solid-state thermoelectric devices are currently used in applications ranging from thermocouple sensors to power generators in satellites, to portable air-conditioners and refrigerators. With the ever-rising demand throughout the world for energy consumption and CO2 reduction, thermoelectric energy conversion has been receiving intensified attention as a potential candidate for waste-heat harvesting as well as for power generation from renewable sources. Efficient thermoelectric energy conversion critically depends on the performance of thermoelectric materials and devices. In this review, we …
Whereas thermoelectric performance is normally limited by the figure of merit ZT, transverse thermoelectrics can achieve arbitrarily large temperature differences in a single leg even with inferior ZT by being geometrically tapered. We introduce a band-engineered transverse thermoelectric with p-type Seebeck in one direction and n-type orthogonal, resulting in off-diagonal terms that drive heat flow transverse to electrical current. Such materials are advantageous for microscale devices and cryogenic temperatures -- exactly the regimes where standard longitudinal thermoelectrics fail. InAs/GaS…
Recently, a thermodynamic uncertainty relation (TUR) has been formulated for classical Markovian systems demonstrating trade-off between precision (current fluctuation) and cost (dissipation). Systems that violate the TUR are interesting as they overcome another trade-off relation concerning the efficiency of a heat engine, its power, and its stability (power fluctuations). Here, we analyze the root, extent, and impact on performance of TUR violations in quantum thermoelectric junctions at steady state. Considering noninteracting electrons, first we show that only the "classical" component of …
We construct a scattering theory of weakly nonlinear thermoelectric transport through sub-micron scale conductors. The theory incorporates the leading nonlinear contributions in temperature and voltage biases to the charge and heat currents. Because of the finite capacitances of sub-micron scale conducting circuits, fundamental conservation laws such as gauge invariance and current conservation require special care to be preserved. We do this by extending the approach of Christen and Büttiker [Europhys. Lett. 35, 523 (1996)] to coupled charge and heat transport. In this way we write relations …
We consider the performance of periodically driven stochastic heat engines in the linear response regime. Reaching the theoretical bounds for efficiency and efficiency at maximum power typically requires full control over the design and the driving of the system. We develop a framework which allows to quantify the role that limited control over the system has on the performance. Specifically, we show that optimizing the driving entering the work extraction for a given temperature protocol leads to a universal, one-parameter dependence for both maximum efficiency and maximum power as a function…
Floquet engineering, modulating quantum systems in a time periodic way, lies at the central part for realizing novel topological dynamical states. Thanks to the Floquet engineering, various new realms on experimentally simulating topological materials have emerged. Conventional Floquet engineering, however, only applies to time periodic non-dissipative Hermitian systems, and for the quantum systems in reality, non-Hermitian process with dissipation usually occurs. So far, it remains unclear how to characterize topological phases of periodically driven non-Hermitian systems via the frequency sp…
Thermoelectric devices are heat engines, which operate as generators or refrigerators using the conduction electrons as a working fluid. The thermoelectric heat-to-work conversion efficiency has always been typically quite low, but much effort continues to be devoted to the design of new materials boasting improved transport properties that would make them of the electron crystal-phonon glass type of systems. On the other hand, there are comparatively few studies where a proper thermodynamic treatment of the electronic working fluid is proposed. The present article aims to contribute to bridge…
This mini-review is intended as a short introduction to electron flow in nanostructures. Its aim is to provide a brief overview of this topic for people who are interested in the thermodynamics of quantum systems but know little about nanostructures. We particularly emphasize devices that work in the steady-state, such as simple thermoelectrics, but also mention cyclically driven heat engines. We do not aim to be either complete or rigorous, but use a few pages to outline some of the main ideas in the topic.
Driving a quantum system periodically in time can profoundly alter its long-time dynamics and trigger topological order. Such schemes are particularly promising for generating non-trivial energy bands and gauge structures in quantum-matter systems. Here, we develop a general formalism that captures the essential features ruling the dynamics: the effective Hamiltonian, but also the effects related to the initial phase of the modulation and the micro-motion. This framework allows for the identification of driving schemes, based on general N-step modulations, which lead to configurations relevant…
We show how the formalism used for thermoelectric transport may be adapted to Smoluchowski's seminal thought experiment also known as Feynman's ratchet and pawl system. Our analysis rests on the notion of useful flux, which for a thermoelectric system is the electrical current and for Feynman's ratchet is the effective jump frequency. Our approach yields original insight into the derivation and analysis of the system's properties. In particular we define an entropy per tooth in analogy with the entropy per carrier or Seebeck coefficient, and we derive the analogue to Kelvin's second relation f…
Nonequilibrium quantum states can be controlled via the driving field in periodically driven systems. Such control, which is called Floquet engineering, has opened various phenomena, such as the light-induced anomalous Hall effect. There are expected to be some essential differences between the anomalous Hall and spin Hall effects of periodically driven systems because of the difference in time-reversal symmetry. However, these differences remain unclear due to the lack of Floquet engineering of the spin Hall effect. Here we show that when the helicity of circularly polarized light is changed …
I propose a design strategy to enhance the performance of heat engine via absorption of thermal energy from the channel region. The absorption of thermal energy can be actuated by inelastic processes and may be accomplished by an energy restrictive flow of electrons into the channel. The proposed design strategy employs dual energy filters to inject and extract electrons through the contact to channel interface. The first filter injects a compressed stream of electrons from the hot contact, at an effective temperature much lower than the channel temperature. The compressed stream of injected e…
