One-dimensional (1D) subwavelength atom arrays display multiply excited subradiant eigenstates which are reminiscent of free fermions. So far, these states have been associated with subradiant states with decay rates $\propto N^{-3}$, with N the number of atoms, which fundamentally prevents detection of their fermionic features by optical means. In this Letter, we show that free-fermion states generally appear whenever the band of singly excited states has a quadratic dispersion relation at the band edge and, hence, may also be obtained with radiant and even superradiant states. 1D arrays have free-fermion multiply excited eigenstates that are typically either subradiant or (super)radiant, and we show that a simple transformation acts between the two families. Based on this correspondence, we propose different means for their preparation and analyze their experimental signature in optical detection.
We generalize the theoretical modeling of collective atomic super- and subradiance to the multilevel case including spontaneous emission from several excited states towards a common ground state. We show that in a closely packed ensemble of $N$ atoms with $N-1$ distinct excited states each, one can find a new class of non-radiating dark states,, which allows for long-term storage of $N-1$ photonic excitations. Via dipole-dipole coupling only a single atom in the ground state is sufficient in order to suppress the decay of all $N-1$ other atoms. By means of some generic geometric configurations…
The Markovian approximation is widely applied in the field of quantum optics due to the weak frequency dependence of the vacuum field amplitude, and in consequence non-Markovian effects are typically regarded to play a minor role in the optical electron-photon interaction. Here, we give an example where non-Markovianity changes the qualitative behavior of a quantum optical system, rendering the Markovian approximation quantitatively and qualitatively insufficient. Namely, we study a multiple-emitter, multiple-excitation waveguide quantum-electrodynamic (waveguide-QED) system and include propag…
We study the structure of the eigenstates and the dynamics of a system that undergoes an excited state quantum phase transition (ESQPT). The analysis is performed for two-level pairing models characterized by a U(n+1) algebraic structure. They exhibit a second order phase transition between two limiting dynamical symmetries represented by the U(n) and SO(n+1) subalgebras. They are, or can be mapped onto, models of interacting bosons. We show that the eigenstates with energies very close to the ESQPT critical point, E_{ESQPT}, are highly localized in the U(n)-basis. Consequently, the dynamics o…
Using the Wherl entropy, we study the delocalization in phase-space of energy eigenstates in the vicinity of avoided crossing in the Lipkin-Meshkov-Glick model. These avoided crossing, appearing at intermediate energies in a certain parameter region of the model, originate classically from pairs of trajectories lying in different phase space regions, which contrary to the low energy regime, are not connected by the discrete parity symmetry of the model. As coupling parameters are varied, a sudden increase of the Wherl entropy is observed for eigenstates close to the critical energy of the exci…
A new supersymmetry method for the generation of the quasi-exactly solvable (QES) potentials with two known eigenstates is proposed. Using this method we obtained new QES potentials for which we found in explicit form the energy levels and wave functions of the ground state and first excited state.
Eigenstates in finite systems such as nuclei, atoms, atomic clusters and quantum dots with few excited particles are chaotic superpositions of shell model basis states. We study criterion for the equilibrium distribution of basis components (ergodicity, or Quantum Chaos), effects of level density variation and transition from the Breit-Wigner to the Gaussian shape of eigenstates and strength functions. In the model of $n$ interacting particles distributed over $m$ orbitals, the shape is given by the Breit-Wigner function with the width in the form of gaussian dependence on energy.
Much has been learned about universal properties of entanglement entropies in ground states of quantum many-body lattice systems. Here we unveil universal properties of the average bipartite entanglement entropy of eigenstates of the paradigmatic quantum Ising model in one dimension. The leading term exhibits a volume-law scaling that we argue is universal for translationally invariant quadratic models. The subleading term is constant at the critical field for the quantum phase transition and vanishes otherwise (in the thermodynamic limit), i.e., the critical field can be identified from suble…
Entanglement properties of excited eigenstates (or of thermal mixed states) are difficult to study with conventional analytical methods. We approach this problem for random spin chains using a recently developed real-space renormalization group technique for excited states ("RSRG-X"). For the random $XX$ and quantum Ising chains, which have logarithmic divergences in the entanglement entropy of their (infinite-randomness) critical ground states, we show that the entanglement entropy of excited eigenstates retains a logarithmic divergence while the mutual information of thermal mixed states doe…
In analogy to spontaneous breaking of continuous space translation symmetry in the process of space crystal formation, it was proposed that spontaneous breaking of continuous time translation symmetry could lead to time crystal formation. In other words, a time-independent system prepared in the energy ground state is expected to reveal periodic motion under infinitely weak perturbation. In the case of the system proposed originally by Frank Wilczek, spontaneous breaking of time translation symmetry can not be observed if one starts with the ground state. We point out that the symmetry breakin…
Highly accurate closed-form approximations are given for the ground state and first excited state wavefunctions and energies for a nonrelativistic particle in a one-dimensional double square well potential with a square barrier in between (so that the potential is a sequence of five constant pieces that alternate in value from being above and below the ground state and first excited state energies), under the assumption that the barrier is sufficiently wide that the tunneling across it is very small.
We benchmark a variant of the recently introduced DMRG-X algorithm against exact results for the localized random field XX chain. We find that the eigenstates obtained via DMRG-X exhibit a highly accurate l-bit description for system sizes much bigger than the direct, many body, exact diagonalization in the spin variables is able to access. We take advantage of the underlying free fermion description of the XX model to accurately test the strengths and limitations of this algorithm for large system sizes. We discuss the theoretical constraints on the performance of the algorithm from the entan…
Recently, the subradiant states of one-dimensional two-level atom chains coupled to light modes were found to have decay rates obeying a universal scaling, and an unexpected fermionic character of the multiply-excited subradiant states was discovered. In this Letter, we theoretically obtain the singly-excited subradiant states, and by eliminating the superradiant modes, we demonstrate a relation between the multiply-excited subradiant states and the Tonks-Girardeau limit of the Lieb-Liniger model which explains the fermionic behavior. In addition, we identify a new family of states with correl…
The efficient calculation of Hamiltonian spectra, a problem often intractable on classical machines, can find application in many fields, from physics to chemistry. Here, we introduce the concept of an "eigenstate witness" and through it provide a new quantum approach which combines variational methods and phase estimation to approximate eigenvalues for both ground and excited states. This protocol is experimentally verified on a programmable silicon quantum photonic chip, a mass-manufacturable platform, which embeds entangled state generation, arbitrary controlled-unitary operations, and proj…
We investigate the behavior of entanglement-entropy on a broad scale, that is, a large class of systems, Hamiltonians and states describing the interaction of many degrees of freedom. It is one of our aims to show which general characteristics are responsible for the different types of quantitative behavior of entantglement-entropy. Our main lesson is that what really matters is the degree of degeneracy of the spectrum of certain nearby reference Hamiltonians. For calculational convenience we study primarily systems defined on large but finite regions of regular lattices. We show that general …
We characterize excited state quantum phase transitions in the two dimensional limit of the vibron model with the quantum fidelity susceptibility, comparing the obtained results with the information provided by the participation ratio. As an application, we perform fits using a four-body algebraic Hamiltonian to bending vibrational data for several molecular species and, using the optimized eigenvalues and eigenstates, we locate the eigenstate closest to the barrier to linearity and determine the linear or bent character of the different overtones.
Imaginary Time Spectral Transforms for Excited State Preparation
IBM Quantum, IBM Research Europe（IBM量子，IBM欧洲研究院）；University of Southampton（南安普顿大学）；The Hartree Centre, STFC（哈特里中心，STFC）；Yusuf Hamied Department of Chemistry, University of Cambridge（剑桥大学尤素夫·哈米德化学系）；Clarendon Laboratory, University of Oxford（牛津大学克拉伦登实验室）；SUPA, School of Physics and Astronomy, University of Edinburgh（爱丁堡大学物理与天文学学院，SUPA）
We demonstrate that the entanglement entropy area law for free fermion ground states and the corresponding volume law for highly excited states are related by a position-momentum duality, thus of the same origin. For a typical excited state in the thermodynamic limit, we further show that the reduced density matrix of a subsystem approaches thermal density matrix, provided the subsystem's linear size is small compared to that of the whole system in all directions, a property we dub eigenstate typicality. This provides an explicit example of thermalization via entanglement, and reveals how stat…
The quantum mechanical expression relating two commuting operators is reformulated such that the power method (also called method of moments) for iteratively calculating eigenvalues and eigenvectors becomes applicable. The new iterative scheme thus obtained allows to pre-select a quantum number of one of the two commuting operators and then calculate a corresponding eigenvalue of the other operator. The result is the common eigenvector of the eigenvalue pair. Among others the method may be used to calculate excited states, cope with degeneracy and/or accelerate convergence. Small example calcu…
We present a formula for the body-assisted van der Waals interaction potential between two atoms, one or both being prepared in an excited energy eigenstate. The presence of arbitrary arrangement for material environment is taken into account via the Green function. The resulting formula supports one of two conflicting findings recorded. The consistency of our formula is investigated by applying it for the case of two atoms in free space and comparing the resulting expression with the one found from the limiting Casimir-Polder potential between an excited atom and a small dielectric sphere.
We study the entanglement spectrum of highly excited eigenstates of two known models that exhibit a many-body localization transition, namely the one-dimensional random-field Heisenberg model and the quantum random energy model. Our results indicate that the entanglement spectrum shows a "two-component" structure: a universal part that is associated with random matrix theory, and a nonuniversal part that is model dependent. The non-universal part manifests the deviation of the highly excited eigenstate from a true random state even in the thermalized phase where the eigenstate thermalization h…
The accurate computation of Hamiltonian ground, excited, and thermal states on quantum computers stands to impact many problems in the physical and computer sciences, from quantum simulation to machine learning. Given the challenges posed in constructing large-scale quantum computers, these tasks should be carried out in a resource-efficient way. In this regard, existing techniques based on phase estimation or variational algorithms display potential disadvantages; phase estimation requires deep circuits with ancillae, that are hard to execute reliably without error correction, while variation…
Confining light in open structures is a long-sought goal in nanophotonics and cavity quantum electrodynamics. Embedded eigenstates provide infinite lifetime despite the presence of available leakage channels, but in linear time-invariant systems they cannot be excited from the outside, due to reciprocity. Here, we investigate how atomic nonlinearities may support single-photon embedded eigenstates, which can be populated by a multi-photon excitation followed by internal relaxation. We calculate the system dynamics and show that photon trapping, as well as the reverse release process, can be ac…
We investigate signatures of the excited-state quantum phase transition in the periodic dynamics of the Lipkin-Meshkov-Glick model and the Tavis-Cummings model. In the thermodynamic limit, expectation values of observables in eigenstates of the system can be calculated using classical trajectories. Motivated by this, we suggest a method based on the time evolution of the finite-size system, to find singularities in observables, which arise due to the excited-state quantum phase transition.
The collective emission from a one-dimensional chain of interacting two-level atoms coupled to a common electromagnetic reservoir is investigated. We derive the system's dissipative few-excitation eigenstates, and analyze their static properties, including the collective dipole moments and branching ratios between different eigenstates. Next, we study the dynamics, and characterize the light emitted or scattered by such a system via different far-field observables. Throughout the analysis, we consider spontaneous emission from an excited state as well as two different pump field setups, and co…
We discuss the proposal that the "Darmstadt oscillations" of the orbital K-shell electron capture decay (EC) rate of the H-like heavy ions are caused by quantum beats of two coherently excited, closely spaced mass-eigenstates of decaying H-like heavy ions. We show that such a mechanism to explain the time modulation of the EC-decay rates of the H-like heavy ions leads to the time modulation of the beta^+ decay rate of these ions with the same period. Such a time-dependence of the beta^+ decay rate of the H-like heavy ions contradicts the experimental data of GSI.
Recent developments on intense laser sources is opening a new field of optical sciences. An intense coherent light beam strongly interacting with the matter causes a coherent motion of a particle, forming a strongly dressed excited particle. A photon emission from this dressed excited particle is a strong nonlinear process causing high-harmonic generation(HHG), where the perturbation analysis is broken down. In this work, we study a coherent photon emission from a strongly dressed excited atom in terms of complex spectral analysis in the extended Floquet-Hilbert-space. We have obtained the eig…
Excited state quantum phase transitions (ESQPTs) are generalizations of quantum phase transitions (QPTs) to excited levels. They are associated with local divergences in the density of states. Here, we investigate how the presence of an ESQPT can be detected from the analysis of the structure of the Hamiltonian matrix, the level of localization of the eigenstates, the onset of bifurcation, and the speed of the system evolution. Our findings are illustrated for a Hamiltonian with infinite-range Ising interaction in a transverse field. This is a version of the Lipkin-Meshkov-Glick (LMG) model an…
Variational quantum eigensolver (VQE) is an appealing candidate for the application of near-term quantum computers. A technique introduced in [Higgot et al., Quantum 3, 156 (2019)], which is named variational quantum deflation (VQD), has extended the ability of the VQE framework for finding excited states of a Hamiltonian. However, no method to evaluate transition amplitudes between the eigenstates found by the VQD without using any costly Hadamard-test-like circuit has been proposed despite its importance for computing properties of the system such as oscillator strengths of molecules. Here w…
We consider free fermion systems in arbitrary dimensions and represent the occupation pattern of each eigenstate as a classical binary string. We find that the Kolmogorov complexity of the string correctly captures the scaling behavior of its entanglement entropy (EE). In particular, the logarithmically-enhanced area law for EE in the ground state and the volume law for EE in typical highly excited states are reproduced. Since our approach does not require bipartitioning the system, it allows us to distinguish typical and atypical eigenstates directly by their intrinsic complexity. We reveal t…
We consider two families of extensions of the oscillator in a $d$-dimensional constant-curvature space and analyze them in a deformed supersymmetric framework, wherein the starting oscillator is known to exhibit a deformed shape invariance property. We show that the first two members of each extension family are also endowed with such a property provided some constraint conditions relating the potential parameters are satisfied, in other words they are conditionally deformed shape invariant. Since, in the second step of the construction of a partner potential hierarchy, the constraint conditio…
We study general entanglement properties of the excited states of the one dimensional translational invariant free fermions and coupled harmonic oscillators. In particular, using the integrals of motion, we prove that these Hamiltonians independent of the gap (mass) has infinite excited states that can be described by conformal field theories with integer or half-integer central charges. In the case of free fermions, we also show that because of the huge degeneracy in the spectrum, even a gapless Hamiltonian can have excited states with an area-law. Finally, we study the universal average enta…
We report the observation of subradiance in dense ensembles of cold $^{87}$Rb atoms operating near Dicke's regime of a large number of atoms in a volume with dimensions smaller than the transition wavelength. We validate that the atom number is the only cooperativity parameter governing subradiance. We probe the dynamics in the many-body regime and support the picture that multiply-excited subradiant states are built as a superposition of singly-excited states that decay independently. Moreover, we implement an experimental procedure to release the excitation stored in the long-lived modes in …
