We present a comparative study of the near-infrared (NIR) H$_2$ line emission from five regions near hot young stars: Sharpless 140, NGC 2023, IC 63, the Horsehead Nebula, and the Orion Bar. This emission originates in photodissociation or photon-dominated regions (PDRs), interfaces between photoionized and molecular gas near hot (O) stars or reflection nebulae illuminated by somewhat cooler (B) stars. In these environments, the dominant excitation mechanism for NIR emission lines originating from excited rotational-vibrational (rovibrational) levels of the ground electronic state is radiative or UV excitation (fluorescence), wherein absorption of far-UV photons pumps H$_2$ molecules into excited electronic states from which they decay into the upper levels of the NIR lines. Our sources span a range of UV radiation fields ($G_0 = 10^2$-$10^5$) and gas densities ($n_H = 10^4$-$10^6$ cm$^{-3}$), enabling examination of how these properties affect the emergent spectrum. We obtained high-resolution ($R \approx 45,000$) spectra spanning $1.45$-$2.45$~$μ$m on the 2.7m Harlan J. Smith Telescope at McDonald Observatory with the Immersion Grating INfrared Spectrometer (IGRINS), detecting up to over 170 transitions per source from excited vibrational states ($v = 1$-$14$). The populations of individual rovibrational levels derived from these data clearly confirm UV excitation. Among the five PDRs in our survey, the Orion Bar shows the greatest deviation of the populations and spectrum from pure UV excitation, while Sharpless 140 shows the least deviation. However, we find that all five PDRs exhibit at least some modification of the level populations relative to their values under pure UV excitation, a result we attribute to collisional effects.
Molecular hydrogen is the most abundant molecule in the Universe. It is thought that a large portion of H2 forms by association of hydrogen atoms to polycyclic aromatic hydrocarbons (PAHs). We model the influence of PAHs on total H2 formation rates in photodissociation regions (PDRs) and assess the effect of these formation rates on the total cloud structure. We set up a chemical kinetic model at steady state in a PDR environment and included adiative transfer to calculate the chemistry at different depths in the PDR. This model includes known dust grain chemistry for the formation of H2 and a…
Accurate photodissociation cross sections have been computed for transitions from the X $^1Σ^+$ ground electronic state of CS to six low-lying excited electronic states. New ab initio potential curves and transition dipole moment functions have been obtained for these computations using the multi-reference configuration interaction approach with the Davidson correction (MRCI+Q) and aug-cc-pV6Z basis sets. State-resolved cross sections have been computed for transitions from nearly the full range of rovibrational levels of the X $^1Σ^+$ state and for photon wavelengths ranging from 500 $\textÅ$…
Photodissociation by ultraviolet radiation is the key destruction pathway for CS in photon-dominated regions, such as diffuse clouds. However, the large uncertainties of photodissociation cross sections and rates of CS, resulting from a lack of both laboratory experiments and theoretical calculations, limit the accuracy of calculated abundances of S-bearing molecules by modern astrochemical models. Here we show a detailed \textit{ab initio} study of CS photodissociation. Accurate potential energy curves of CS electronic states were obtained by choosing an active space CAS(8,10) in MRCI+Q/aug-c…
We present a deep near-infrared spectrum of the Orion Bar Photodissociation Region (PDR) taken with the Immersion Grating INfrared Spectrometer (IGRINS) on the 2.7 m telescope at the McDonald Observatory. IGRINS has high spectral resolution (R~45000) and instantaneous broad wavelength coverage (1.45-2.45 microns), enabling us to detect 87 emission lines from rovibrationally excited molecular hydrogen (H_2) that arise from transitions out of 69 upper rovibration levels of the electronic ground state. These levels cover a large range of rotational and vibrational quantum numbers and excitation e…
Broad Raman-scattered wings of hydrogen lines can be used to map neutral gas illuminated by high-mass stars in star forming regions. Raman scattering transforms far-ultraviolet starlight from the wings of the Lyman beta line (1022 Angstrom to 1029 Angstrom) to red visual light in the wings of the H alpha line (6400 Angstrom to 6700 Angstrom). Analysis of spatially resolved spectra of the Orion Bar and other regions in the Orion Nebula shows that this process occurs in the neutral photo-dissociation region between the ionization front and dissociation front. The inner Raman wings are optically …
We introduce non-equilibrium molecular hydrogen chemistry into the radiation hydrodynamics code Ramses-RT. This is an adaptive mesh refinement grid code with radiation hydrodynamics that couples the thermal chemistry of hydrogen and helium to moment-based radiative transfer with the Eddington tensor closure model. The H2 physics that we include are formation on dust grains, gas phase formation, formation by three-body collisions, collisional destruction, photodissociation, photoionization, cosmic ray ionization, and self-shielding. In particular, we implement the first model for H2 self-shield…
Statistical universal branching ratios for cosmic ray dissociation, photodissociation, and dissociative recombination of the C(n=2-10), C(n=2-4)H and C3H2 neutral and cationic species
The physical and chemical conditions in photodissociation regions (PDRs) are largely determined by the influence of far ultraviolet radiation. Far-UV photons can efficiently dissociate molecular hydrogen, a process that must be balanced at the HI/H2 interface of the PDR. Given that reactions involving hydrogen atoms in the gas phase are highly inefficient under interstellar conditions, H2 formation models mostly rely on catalytic reactions on the surface of dust grains. Additionally, molecular hydrogen formation in polycyclic aromatic hydrocarbons (PAHs) through the Eley-Rideal mechanism has b…
Radiative association and photodissociation rates are calculated for quadrupole transitions of H2. A complete set of bound and unbound states are included in a self-consistent master equation to obtain steady-state concentrations for a dilute system of hydrogen atoms and molecules. Phenomenological rate constants computed from the steady-state concentrations satisfy detailed balance for any combination of matter and radiation temperature. Simple formulas are derived for expressing the steady-state distributions in terms of equilibrium distributions. The rate constant for radiative association …
JWST observations of photodissociation regions: II. Warm molecular Hydrogen spectroscopy in the Horsehead nebula
Université Paris-Saclay, CNRS, Institut d’Astrophysique Spatiale（巴黎萨克雷大学）；Sorbonne Université, CNRS, Institut d’Astrophysique de Paris（索邦大学）；Space Telescope Science Institute（太空望远镜科学研究所）；LUX, Observatoire de Paris, Université PSL, Sorbonne Université, CNRS（巴黎天文台）；Université Paris-Cité（巴黎西岱大学）；Steward Observatory, University of Arizona（亚利桑那大学斯图尔德天文台）；Department of Physics & Astronomy, The University of Western Ontario（韦仕敦大学物理与天文学系）；Ritter Astrophysical Research Center, University of Toledo（托莱多大学里特天体物理研究中心）
Water photodissociation in the 114 - 144 nm UV range forms excited OH which emits at mid-infrared wavelengths via highly excited rotational lines. These lines have only been detected with Spitzer in several proto-planetary disks and shocks. Previous studies have shown they are a unique diagnostic for water photodissociation. Thanks to its high sensitivity and angular resolution, the James Webb Space Telescope (JWST) could be able to detect them in other environments such as interstellar Photo-Dissociation Regions (PDRs). In order to predict the emerging spectrum of OH, we use the Meudon PDR Co…
We present the first fully calibrated H$_2$, 1-0 S(1) image of the entire 30 Doradus nebula. The observations were conducted using the NOAO Extremely Wide-Field Infrared Imager on the CTIO 4-meter Blanco Telescope. Together with a NEWFIRM Br$γ$ image of 30 Doradus, our data reveal the morphologies of the warm molecular gas and ionized gas in 30 Doradus. The brightest H$_2$-emitting area, which extends from the northeast to the southwest of R136, is a photodissociation region viewed face-on, while many clumps and pillar features located at the outer shells of 30 Doradus are photodissociation re…
Carbon monoxide (CO) is the most abundant molecule after molecular hydrogen and is important for the chemistry in circumstellar envelopes around evolved stars. When modelling the strength and shape of molecular lines, the size of the CO envelope is an input parameter and influences the derived mass-loss rates. In particular the low-J transition CO lines are sensitive to the CO photodissociation radius. Recently, new CO photodissociation radii have been published using different formalisms that differ considerably. One set of calculations is based on an escape-probability formalisms that uses n…
Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation and excitation processes, and the connection between C$_{60}$ and other carbonaceous compounds in the interstellar medium, in particular polycyclic aromatic hydrocarbons (PAHs). In this paper we study several photodissociation regions (PDRs) where C$_{60}$ and PAHs are detected and the local physical conditions are reasonably well constrained, to provide obs…
We present the detection and analysis of molecular hydrogen emission toward ten interstellar regions in the Large Magellanic Cloud. We examined low-resolution infrared spectral maps of twelve regions obtained with the Spitzer infrared spectrograph (IRS). The pure rotational 0--0 transitions of H$_2$ at 28.2 and 17.1${\,\rm μm}$ are detected in the IRS spectra for ten regions. The higher level transitions are mostly upper limit measurements except for three regions, where a 3$σ$ detection threshold is achieved for lines at 12.2 and 8.6${\,\rm μm}$. The excitation diagrams of the detected H$_2$ …
We present spectroscopic observations obtained with the infrared Spitzer Space Telescope, which provide insight into the H$_2$ physics and gas energetics in photodissociation Regions (PDRs) of low to moderate far-ultraviolet (FUV) fields and densities. We analyze data on six well known Galactic PDRs (L1721, California, N7023E, Horsehead, rho Oph, N2023N), sampling a poorly explored range of excitation conditions ($χ\sim 5-10^3$), relevant to the bulk of molecular clouds in galaxies. Spitzer observations of H$_2$ rotational lines are complemented with H$_2$ data, including ro-vibrational line m…
Many of the baryons in our Galaxy probably lie outside the well known disk and bulge components. Despite a wealth of evidence for the presence of some gas in galactic halos, including absorption line systems in the spectra of quasars, high velocity neutral hydrogen clouds in our Galaxy halo, line emitting ionised hydrogen originating from galactic winds in nearby starburst galaxies, and the X-ray coronas surrounding the most massive galaxies, accounting for the gas in the halo of any galaxy has been observationally challenging primarily because of its low density in the expansive halo. The mos…
PDRs4All XVII: Formation and excitation of HD in photodissociation regions. Application to the Orion Bar
Institut d’Astrophysique Spatiale, Université Paris-Saclay, CNRS（空间天体物理研究所，巴黎萨克雷大学，法国国家科学研究中心）；LUX, Observatoire de Paris, Université PSL, Sorbonne Université, CNRS（LUX，巴黎天文台，巴黎文理研究大学，索邦大学，法国国家科学研究中心）；Université Paris-Cité（巴黎西岱大学）；Department of Physics, College of Science, United Arab Emirates University (UAEU)（阿拉伯联合酋长国大学理学院物理学系）；Instituto de Física Fundamental (CSIC)（基础物理研究所（西班牙国家研究委员会））；Department of Space, Earth and Environment, Chalmers University of Technology, Onsala Space Observatory（查尔姆斯理工大学空间、地球与环境系，翁萨拉空间观测站）
Measuring interstellar magnetic fields is extremely important for understanding their role in different evolutionary stages of interstellar clouds and of star formation. However, detecting the weak field is observationally challenging. We present measurements of the Zeeman effect in the 1665 and 1667~MHz (18~cm) lines of the hydroxyl radical (OH) lines toward the dense photodissociation region (PDR) associated with the compact H{\sc ii} region DR~21~(Main). From the OH 18~cm absorption, observed with the Karl G. Jansky Very Large Array, we find that the line of sight magnetic field in this reg…
We present the far-ultraviolet (FUV) fluorescent molecular hydrogen (H_2) emission map of the Milky Way Galaxy obtained with FIMS/SPEAR covering ~76% of the sky. The extinction-corrected intensity of the fluorescent H_2 emission has a strong linear correlation with the well-known tracers of the cold interstellar medium (ISM), including color excess E(B-V), neutral hydrogen column density N(H I), and H_alpha emission. The all-sky H_2 column density map was also obtained using a simple photodissociation region model and interstellar radiation fields derived from UV star catalogs. We estimated th…
Photodissociation regions (PDRs) contain a large fraction of all of the interstellar matter in galaxies. Classical examples include the boundaries between ionized regions and molecular clouds in regions of massive star formation, marking the point where all of the photons energetic enough to ionize hydrogen have been absorbed. In this paper we determine the physical properties of the PDRs associated with the star forming regions IRAS 23133+6050 and S 106 and present them in the context of other Galactic PDRs associated with massive star forming regions. We employ Herschel PACS and SPIRE spectr…
Water is an important molecule in interstellar and circumstellar environments. Previous observations of mid-infrared rotational lines of OH suggest that these lines may be used to probe the photodissociation of water. In this work, cross sections for the photodissociation of H$_2$O resolving the state of the OH fragment are collected and incorporated in a new molecular excitation code called GROSBETA, which includes radiative pumping, collisional (de)excitation, and prompt emission (i.e., following the production of OH in excited states). We find that the OH rotational line intensities in the …
The infrared data from the Spitzer Space Telescope has provided an invaluable tool for identifying physical processes in star formation. In this study we calculate the IRAC color space of UV fluorescent molecular hydrogen (H$_2$) and Polycyclic Aromatic Hydrocarbon (PAH) emission in photodissociation regions (PDRs) using the Cloudy code with PAH opacities from Draine & Li 2007. We create a set of color diagnostics that can be applied to study the structure of PDRs and to distinguish between FUV excited and shock excited H$_2$ emission. To test this method we apply these diagnostics to Spitzer …
