We derive total (atomic + molecular) hydrogen densities in giant molecular clouds (GMCs) in the nearby spiral galaxy M33 using a method that views the atomic hydrogen near regions of recent star formation as the product of photodissociation. Far-UV photons emanating from a nearby OB association produce a layer of atomic hydrogen on the surfaces of nearby GMCs. Our approach provides an estimate of the total hydrogen density in these GMCs from observations of the excess far-UV emission that reaches the GMC from the OB association, and the excess 21-cm radio HI emission produced after these far-UV photons convert H2 into HI on the GMC surface. The method provides an alternative approach to the use of CO emission as a tracer of H2 in GMCs, and is especially sensitive to a range of density well below the critical density for CO(1-0) emission. We describe our "PDR method" in more detail and apply it using GALEX far-UV and VLA 21-cm radio data to obtain volume densities in a selection of GMCs in the nearby spiral galaxy M33. We have also examined the sensitivity of the method to the linear resolution of the observations used; the results obtained at 20 pc are similar to those for the larger set of data at 80 pc resolution. The cloud densities we derive range from 1 to 500 cm-3, with no clear dependence on galactocentric radius; these results are generally similar to those obtained earlier in M81, M83, and M101 using the same method.
Molecular hydrogen is the most abundant molecule in the Universe. It is thought that a large portion of H2 forms by association of hydrogen atoms to polycyclic aromatic hydrocarbons (PAHs). We model the influence of PAHs on total H2 formation rates in photodissociation regions (PDRs) and assess the effect of these formation rates on the total cloud structure. We set up a chemical kinetic model at steady state in a PDR environment and included adiative transfer to calculate the chemistry at different depths in the PDR. This model includes known dust grain chemistry for the formation of H2 and a…
Various studies have emphasized variations of the charge state and composition of the interstellar polycyclic aromatic hydrocarbon (PAH) population in photodissociation regions (PDRs). We aim to model the spatial evolution of the charge and hydrogenation states of PAHs in PDRs. We focus on the specific case of the north-west (NW) PDR of NGC 7023 and also discuss the case of the diffuse interstellar medium (ISM). The physical conditions in NGC 7023 NW are modelled using a state-of-the-art PDR code. We then use a new PAH chemical evolution model that includes recent experimental data on PAHs and…
We consider the evolution of an isentropic thermal instability in the atomic zone of a photodissociation region (PDR). In this zone, gas heating and cooling are associated mainly with photoelectric emission from dust grains and fine-structure lines ([\ion{C}{ii}] 158, [\ion{O}{i}] 63, and [\ion{O}{i}] 146 {\micron}), respectively. The instability criterion has a multi-parametric dependence on the conditions of the interstellar medium. We found that instability occurs when the intensity of the incident far-ultraviolet field $G_0$ and gas density $n$ are high. For example, we have $3\times10^3<G…
We present a comparative study of the near-infrared (NIR) H$_2$ line emission from five regions near hot young stars: Sharpless 140, NGC 2023, IC 63, the Horsehead Nebula, and the Orion Bar. This emission originates in photodissociation or photon-dominated regions (PDRs), interfaces between photoionized and molecular gas near hot (O) stars or reflection nebulae illuminated by somewhat cooler (B) stars. In these environments, the dominant excitation mechanism for NIR emission lines originating from excited rotational-vibrational (rovibrational) levels of the ground electronic state is radiative…
We present a deep near-infrared spectrum of the Orion Bar Photodissociation Region (PDR) taken with the Immersion Grating INfrared Spectrometer (IGRINS) on the 2.7 m telescope at the McDonald Observatory. IGRINS has high spectral resolution (R~45000) and instantaneous broad wavelength coverage (1.45-2.45 microns), enabling us to detect 87 emission lines from rovibrationally excited molecular hydrogen (H_2) that arise from transitions out of 69 upper rovibration levels of the electronic ground state. These levels cover a large range of rotational and vibrational quantum numbers and excitation e…
Broad Raman-scattered wings of hydrogen lines can be used to map neutral gas illuminated by high-mass stars in star forming regions. Raman scattering transforms far-ultraviolet starlight from the wings of the Lyman beta line (1022 Angstrom to 1029 Angstrom) to red visual light in the wings of the H alpha line (6400 Angstrom to 6700 Angstrom). Analysis of spatially resolved spectra of the Orion Bar and other regions in the Orion Nebula shows that this process occurs in the neutral photo-dissociation region between the ionization front and dissociation front. The inner Raman wings are optically …
The most usual tracer of molecular gas is line emission from CO. However, the reliability of that tracer has long been questioned in environments different from the Milky Way. We study the relationship between H2 and CO abundances using a fully dynamical model of magnetized turbulence coupled to a chemical network simplified to follow only the dominant pathways for H2 and CO formation and destruction, and including photodissociation using a six-ray approximation. We find that the abundance of H2 is primarily determined by the amount of time available for its formation, which is proportional to…
The physical and chemical conditions in photodissociation regions (PDRs) are largely determined by the influence of far ultraviolet radiation. Far-UV photons can efficiently dissociate molecular hydrogen, a process that must be balanced at the HI/H2 interface of the PDR. Given that reactions involving hydrogen atoms in the gas phase are highly inefficient under interstellar conditions, H2 formation models mostly rely on catalytic reactions on the surface of dust grains. Additionally, molecular hydrogen formation in polycyclic aromatic hydrocarbons (PAHs) through the Eley-Rideal mechanism has b…
Radiative association and photodissociation rates are calculated for quadrupole transitions of H2. A complete set of bound and unbound states are included in a self-consistent master equation to obtain steady-state concentrations for a dilute system of hydrogen atoms and molecules. Phenomenological rate constants computed from the steady-state concentrations satisfy detailed balance for any combination of matter and radiation temperature. Simple formulas are derived for expressing the steady-state distributions in terms of equilibrium distributions. The rate constant for radiative association …
The determination of the physical conditions in molecular clouds is a key step towards our understanding of their formation and evolution of associated star formation. We investigate the density, temperature, and column density of both dust and gas in the photodissociation regions (PDRs) located at the interface between the atomic and cold molecular gas of the NGC 7023 reflection nebula. We study how young stars affect the gas and dust in their environment. Our approach combining both dust and gas delivers strong constraints on the physical conditions of the PDRs. We find dense and warm molecu…
Using a simple model of photodissociated atomic hydrogen on a galactic scale, it is possible to derive total hydrogen volume densities. These densities, obtained through a combination of atomic hydrogen, far-ultraviolet and metallicity data, provide an independent probe of the combined atomic and molecular hydrogen gas in galactic disks. We present a new, flexible and fully automated procedure using this simple model. This automated method will allow us to take full advantage of a host of available data on galaxies in order to calculate total hydrogen volume densities of giant molecular clouds…
We present the first fully calibrated H$_2$, 1-0 S(1) image of the entire 30 Doradus nebula. The observations were conducted using the NOAO Extremely Wide-Field Infrared Imager on the CTIO 4-meter Blanco Telescope. Together with a NEWFIRM Br$γ$ image of 30 Doradus, our data reveal the morphologies of the warm molecular gas and ionized gas in 30 Doradus. The brightest H$_2$-emitting area, which extends from the northeast to the southwest of R136, is a photodissociation region viewed face-on, while many clumps and pillar features located at the outer shells of 30 Doradus are photodissociation re…
The mid-infrared (MIR) spectra of dense photodissociation regions (PDRs) are typically dominated by emission from polycyclic aromatic hydrocarbons (PAHs) and the lowest pure rotational states of molecular hydrogen (H2); two species which are probes of the physical properties of gas and dust in intense UV radiation fields. We utilize the high angular resolution of the Infrared Spectrograph on the Spitzer Space Telescope to construct spectral maps of the PAH and H2 features for three of the best studied PDRs in the galaxy, NGC 7023, NGC 2023 and IC 63. We present spatially resolved maps of the p…
We investigate the importance of the shielding of chemical photorates by molecular hydrogen photodissociation lines and the carbon photoionization continuum deep within models of photon dominated regions. In particular, the photodissociation of N2 and CN are significantly shielded by the H2 photodissociation line spectrum. We model this by switching off the photodissociation channels for these species behind the HI to H2 transition. We also model the shielding effect of the carbon photoionization continuum as an attenuation of the incident radiation field shortwards of 1102Å. Using recent line…
Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation and excitation processes, and the connection between C$_{60}$ and other carbonaceous compounds in the interstellar medium, in particular polycyclic aromatic hydrocarbons (PAHs). In this paper we study several photodissociation regions (PDRs) where C$_{60}$ and PAHs are detected and the local physical conditions are reasonably well constrained, to provide obs…
We present the detection and analysis of molecular hydrogen emission toward ten interstellar regions in the Large Magellanic Cloud. We examined low-resolution infrared spectral maps of twelve regions obtained with the Spitzer infrared spectrograph (IRS). The pure rotational 0--0 transitions of H$_2$ at 28.2 and 17.1${\,\rm μm}$ are detected in the IRS spectra for ten regions. The higher level transitions are mostly upper limit measurements except for three regions, where a 3$σ$ detection threshold is achieved for lines at 12.2 and 8.6${\,\rm μm}$. The excitation diagrams of the detected H$_2$ …
The Helix Nebula (NGC 7293) is the closest planetary nebulae. Therefore, it is an ideal template for photochemical studies at small spatial scales in planetary nebulae. We aim to study the spatial distribution of the atomic and the molecular gas, and the structure of the photodissociation region along the western rims of the Helix Nebula as seen in the submillimeter range with Herschel. We use 5 SPIRE FTS pointing observations to make atomic and molecular spectral maps. We analyze the molecular gas by modeling the CO rotational lines using a non-local thermodynamic equilibrium (non-LTE) radiat…
We present a model of the photodissociation regions of NGC 4038, which is part of the Antennae galaxies. We have considered one-dimensional slabs of uniform density all having a maximum $A_V=10\,{\rm mag}$, interacting with plane-parallel radiation. The density range in our simulations spans four orders of magnitude ($100\le n\le 10^6\,{\rm cm}^{-3}$) and the UV field strength spans more than three orders of magnitude ($10\leχ\le10^{4.5}$ multiples of the ${\rm Draine}$ field), from which we generated a grid of about 1400 simulations. We compare our results with Herschel SPIRE-FTS, CSO and ISO…
The radiation from stars and active galactic nuclei (AGN) creates photodissociation regions (PDRs) and X-ray dominated regions (XDRs), where the chemistry or heating are dominated by far-ultraviolet (FUV) radiation or X-ray radiation, respectively. PDRs include a wide range of environments from the diffuse interstellar medium to dense star-forming regions. XDRs are found in the center of galaxies hosting AGN, in protostellar disks, and in the vicinity of X-ray binaries. In this review, we describe the dominant thermal, chemical, and radiation transfer processes in PDRs and XDRs, as well as a b…
Measuring interstellar magnetic fields is extremely important for understanding their role in different evolutionary stages of interstellar clouds and of star formation. However, detecting the weak field is observationally challenging. We present measurements of the Zeeman effect in the 1665 and 1667~MHz (18~cm) lines of the hydroxyl radical (OH) lines toward the dense photodissociation region (PDR) associated with the compact H{\sc ii} region DR~21~(Main). From the OH 18~cm absorption, observed with the Karl G. Jansky Very Large Array, we find that the line of sight magnetic field in this reg…
We present a simple analytic procedure for generating atomic-to-molecular (HI-to-H$_2$) density profiles for optically thick clouds illuminated by far-ultraviolet radiation. Our procedure is based on the analytic theory for the structure of one-dimensional HI/H$_2$ photon-dominated regions, presented by Sternberg et al. (2014). Depth-dependent HI and H$_2$ density fractions may be computed for arbitrary gas density, far-ultraviolet field intensity, and the metallicity dependent H$_2$ formation rate coefficient, and dust absorption cross section. We use our procedure to generate a set of HI-to-…
We present the far-ultraviolet (FUV) fluorescent molecular hydrogen (H_2) emission map of the Milky Way Galaxy obtained with FIMS/SPEAR covering ~76% of the sky. The extinction-corrected intensity of the fluorescent H_2 emission has a strong linear correlation with the well-known tracers of the cold interstellar medium (ISM), including color excess E(B-V), neutral hydrogen column density N(H I), and H_alpha emission. The all-sky H_2 column density map was also obtained using a simple photodissociation region model and interstellar radiation fields derived from UV star catalogs. We estimated th…
We describe a population of small, high velocity, atomic hydrogen clouds, loops, and filaments found above and below the disk near the Galactic Center. The objects have a mean radius of 15 pc, velocity widths of $\sim 14$ km/s and are observed at $|z|$ heights up to 700 pc. The velocity distribution of the clouds shows no signature of Galactic rotation. We propose a scenario where the clouds are associated with an outflow from a central star-forming region at the Galactic Center. We discuss the clouds as entrained material traveling at $\sim 200$ km/s in a Galactic wind.
Photodissociation by ultraviolet radiation is the key destruction pathway for CS in photon-dominated regions, such as diffuse clouds. However, the large uncertainties of photodissociation cross sections and rates of CS, resulting from a lack of both laboratory experiments and theoretical calculations, limit the accuracy of calculated abundances of S-bearing molecules by modern astrochemical models. Here we show a detailed \textit{ab initio} study of CS photodissociation. Accurate potential energy curves of CS electronic states were obtained by choosing an active space CAS(8,10) in MRCI+Q/aug-c…
Using the Five-hundred-meter Aperture Spherical radio Telescope (FAST) in Guizhou, China, we detect the 21cm neutral atomic hydrogen absorption in the young planetary nebula IC 4997. The absorption arises from a shell also associated with Na I D lines. The H I shell has a mass of $1.46\times10^{-2}$ M$_\odot$ and a dynamic age of 990yr. The column density of H I is estimated to be $7.1\times10^{20}$ cm$^{-2}$, which can be well explained in terms of a photodissociation region around the ionized nebula, limited by self shielding of H$_2$. We find that the atomic-to-ionized hydrogen ratio is 0.6…
The interaction of ionizing and far-ultraviolet radiation with the interstellar medium is of great importance. It results in the formation of regions in which the gas is ionized, beyond which are photodissociation regions (PDRs) in which the gas transitions to its atomic and molecular form. Several numerical codes have been implemented to study these two main phases of the interstellar medium either dynamically or chemically. In this paper we present TORUS-3DPDR, a new self-consistent code for treating the chemistry of three-dimensional photoionization and photodissociation regions. It is an i…
A new model for three dimensional distribution of atomic hydrogen gas in the Milky Way is derived using the 21cm LAB survey data. The global features of the gas distribution such as spiral arms are reproduced. The Galactic plane warps outside the solar orbit and the thickness of the gas disk flares outward the Galaxy. It is found that the mass of atomic hydrogen gas within a radius of 20 kpc is 4.3*10^9 M_Sun.
The presence of small amounts of atomic hydrogen, detected as absorption dips in the 21 cm line spectrum, is a well-known characteristic of dark clouds. The abundance of hydrogen atoms measured in the densest regions of molecular clouds can be only explained by the dissociation of H$_2$ due to cosmic rays. We want to assess the role of Galactic cosmic rays in the formation of atomic hydrogen, by using recent developments in the characterisation of the low-energy spectra of cosmic rays and advances in the modelling of their propagation in molecular clouds. We model the attenuation of the inters…
Theory predicts that a plane wave scattered by a thin slab of gas yields, in the forward direction and under specific circumstances, a larger irradiance than would be observed in the absence of the gas. This enhanced Rayleigh scattering depends on the size of the Fresnel zones at the slab location, as seen from the observer's position, and results from the coherence of the scattering. On astronomical scales the exceptional size of Fresnel zones (~1500km) has particular relevance when considering forward-scattered starlight by an interstellar cloud of atomic hydrogen.
