Solar system bodies with surface and sub-surface volatiles will show observational evidence of activity when they reach a temperature where those volatiles change from solid to gas and are released. This is most frequently seen in comets, where activity is driven by the sublimation of water, carbon dioxide, or carbon monoxide ices. However, some bodies (notably the asteroid (3200) Phaethon) show initiation of activity at very small heliocentric distances, long after they have reached the sublimation temperatures of these ices. We investigate whether the sodium present in the mineral matrix could act as the volatile element responsible for this activity. We conduct theoretical modeling which indicates that sodium has the potential to sublimate in the conditions that Phaethon experiences, depending on the mineral phase it is held in. To test this, we then exposed samples of the carbonaceous chondrite Allende to varying heating events similar to what would be experienced by low perihelion asteroids. We measured the change in sodium present in each sample, and find that the highest temperature samples show a significant loss of sodium from specific mineral phases over a single heating event, comparable to a day on the surface of Phaethon. Under specific thermal histories possible for Phaethon, this outgassing could be sufficient to explain this object's observed activity. This effect would also be expected to be observed for other low-perihelia asteroids as well, and may act as a critical step in the process of disrupting small low-albedo asteroids.
We measured 3-micron reflectance spectra of 21 meteorites that represent all carbonaceous chondrite types available in terrestrial meteorite collections. The measurements were conducted at the Laboratory for Spectroscopy under Planetary Environmental Conditions (LabSPEC) at the Johns Hopkins University Applied Physics Laboratory (JHU APL) under vacuum and thermally-desiccated conditions (asteroid-like conditions). This is the most comprehensive 3-micron dataset of carbonaceous chondrites ever acquired in environments similar to the ones experienced by asteroids. The 3-micron reflectance spectr…
Non-differentiated asteroids are among the most primitive objects in our Solar System, having escaped intense heating mechanisms. To help us understand the information contained in reflectance spectra measured on asteroids, we analyzed meteorites in the laboratory. We present an in-depth analysis of a large set of reflectance spectra: 23 CV3, 15 CO3, 4 CR2 and 31 Unequilibrated Ordinary Chondrites (UOCs). Each of the samples has a well characterized thermal history . Variations in the reflectance spectra are observed between and within each chondrite group. UOCs systematically exhibit deeper a…
Despite being all roughly of solar composition, primitive meteorites (chondrites) present a diversity in their chemical, isotopic and petrographic properties, and in particular a first-order dichotomy between carbonaceous and non-carbonaceous chondrites. We investigate here analytically the dynamics of their components (chondrules, refractory inclusions, metal/sulfide and matrix grains) in protoplanetary disks prior to their incorporation in chondrite parent bodies. We find the dynamics of the solids, subject to gas drag, to be essentially controlled by the "gas-solid decoupling parameter" $S\…
Carbonaceous asteroids represent the principal source of water in the inner Solar System and might correspond to the main contributors for the delivery of water to Earth. Hydrogen isotopes in water-bearing primitive meteorites, e.g. carbonaceous chondrites, constitute a unique tool for deciphering the sources of water reservoirs at the time of asteroid formation. However, fine-scale isotopic measurements are required to unravel the effects of parent body processes on the pre-accretion isotopic distributions. Here we report in situ micrometer-scale analyses of hydrogen isotopes in six CM-type c…
We present here several laboratory analyses performed on the freshly fallen Mukundpura CM chondrite. Results of infrared transmission spectroscopy, thermogravimetry analysis and reflectance spectroscopy show that Mukundpura is mainly composed of phyllosilicates. The rare earth trace elements composition and ultrahigh resolution mass spectrometry of the soluble organic matter (SOM) give results consistent with CM chondrites. Finally, Raman spectroscopy shows no signs of thermal alteration of the meteorite. All the results agree that Mukundpura has been strongly altered by water on its parent bo…
Carbonaceous chondrite meteorites are so far the only available samples representing carbon-rich asteroids and in order to allow future comparison with samples returned by missions such as Hayabusa 2 and OSIRIS-Rex, is important to understand their physical properties. Future characterization of asteroid primitive classes, some of them targeted by sample-return missions, requires a better understanding of their mineralogy, the consequences of the exposure to space weathering, and how both affect the reflectance behavior of these objects. In this paper, the reflectance spectra of two chemically…
A crucial topic in planetology research is establishing links between primitive meteorites and their parent asteroids. In this study we investigate the feasibility of a connection between asteroids similar to 21 Lutetia, encountered by the Rosetta mission in July 2010, and the CH3 carbonaceous chondrite Pecora Escarpment 91467 (PCA 91467). Several spectra of this meteorite were acquired in the ultraviolet to near-infrared (0.3 to 2.2 μm) and in the mid-infrared to thermal infrared (2.5 to 30.0 μm or 4000 to ~333 cm^-1), and they are compared here to spectra from the asteroid 21 Lutetia. There …
Understanding the origin of chondritic components and their accretion pathways is critical to unravel the magnitude of mass transport in the protoplanetary disk, the accretionary history of the terrestrial planet region and, by extension, its prebiotic inventory. Here, we trace the heritage of pristine components from the relatively unaltered CV chondrite Leoville through their mass-independent Cr and mass-dependent Zn isotope compositions. Investigating these chondritic fractions in such detail reveals an onion-shell structure of chondrules, which is characterized by 54Cr- and 66Zn-poor cores…
The valence of iron has been used in terrestrial studies to trace the hydrolysis of primary silicate rocks. Here, we use a similar approach to characterize the secondary processes, namely thermal metamorphism and aqueous alteration, that have affected carbonaceous chondrites. X-ray absorption near-edge structure spectroscopy at the Fe-K- edge was performed on a series of 36 CM, 9 CR, 10 CV, and 2 CI chondrites. Among the four carbonaceous chondrites groups studied, a correlation between the iron oxidation index (IOI = [2 ((Fe2+) + 3(Fe3+))/FeTOT) and the hydrogen content is observed. However, …
Aims. The existence of asteroid complexes produced by the disruption of these comets suggests that evolved comets could also produce high-strength materials able to survive as meteorites. We chose as an example comet 2P/Encke, one of the largest object of the so-called Taurid complex. We compare the reflectance spectrum of this comet with the laboratory spectra of some Antarctic ungrouped carbonaceous chondrites to investigate whether some of these meteorites could be associated with evolved comets. Methods. We compared the spectral behaviour of 2P/Encke with laboratory spectra of carbonaceous…
We report microscopic, cathodoluminescence, chemical and O isotopic measurements of FeO-poor isolated olivine grains (IOG) in the carbonaceous chondrites Allende (CV3), Northwest Africa 5958 (C2-ung), Northwest Africa 11086 (CM2-an), Allan Hills 77307 (CO3.0). The general petrographic, chemical and isotopic similarity with bona fide type I chondrules confirms that the IOG derived from them. The concentric CL zoning, reflecting a decrease in refractory elements toward the margins, and frequent rimming by enstatite are taken as evidence of interaction of the IOG with the gas as stand-alone objec…
Carbonaceous chondrite meteorites are some of the oldest Solar System planetary materials available for study. The CI group has bulk abundances of elements similar to those of the solar photosphere. Of particular interest in carbonaceous chondrite compositions are labile elements, which vaporize and mobilize efficiently during post-accretionary parent-body heating events. Thus, they can record low-temperature alteration events throughout asteroid evolution. However, the precise nature of labile-element mobilization in planetary materials is unknown. Here we characterize the thermally induced m…
The Al/Si and Mg/Si ratios in non-carbonaceous chondrites are lower than the solar (i.e., CI-chondritic) values, in sharp contrast to the non-CI carbonaceous meteorites and the Earth, which are enriched in refractory elements and have Mg/Si ratios that are solar or larger. We show that the formation of a first generation of planetesimals during the condensation of refractory elements implies the subsequent formation of residual condensates with strongly sub-solar Al/Si and Mg/Si ratios. The mixing of residual condensates with different amounts of material with solar refractory/Si element ratio…
A hypothesis based on observational and theoretical results on the origin of C-type asteroids and carbonaceous chondrites is proposed. Asteroids of C-type and close BGF-types could form from hydrated silicate-organic matter accumulated in the cores of water-differentiated (due to 26Al and other short-lived isotopes decay) bodies existed in the growth zones of Jupiter. Gravitational scattering of such bodies by Jupiter at its final stage of formation to the main asteroid belt might have led to fragmentation and re-accretion of their primitive materials on the surfaces of many asteroids and/or a…
Carbonaceous chondrites (CCs) may have been the carriers of water, volatile and moderately volatile elements to Earth. Investigating the abundances of these elements, their relative volatility, and isotopes of state-change tracer elements such as Zn, and linking these observations to water contents, provide vital information on the processes that govern the abundances and isotopic signatures of these species in CCs and other planetary bodies. Here we report Zn isotopic data for 28 CCs (20 CM, 6 CR, 1 C2-ung, and 1 CV3), as well as trace element data for Zn, In, Sn, Tl, Pb, and Bi in 16 samples…
Protoplanetary disks are dust-rich structures around young stars. The crystalline and amorphous materials contained within these disks are variably thermally processed and accreted to make bodies of a wide range of sizes and compositions, depending on the heliocentric distance of formation. The chondritic meteorites are fragments of relatively small and undifferentiated bodies, and the minerals that they contain carry chemical signatures providing information about the early environment available for planetesimal formation. A current hot topic of debate is the delivery of volatiles to terrestr…
Chondrules formed by the melting of dust aggregates in the solar protoplanetary disk and as such provide unique insights into how solid material was transported and mixed within the disk. Here we show that chondrules from enstatite and ordinary chondrites show only small 50Ti variations and scatter closely around the 50Ti composition of their host chondrites. By contrast, chondrules from carbonaceous chondrites have highly variable 50Ti compositions, which, relative to the terrestrial standard, range from the small 50Ti deficits measured for enstatite and ordinary chondrite chondrules to the l…
We analyze images of a rock on Ryugu acquired in situ by MASCam, camera of the MASCOT lander, with the aim of identifying possible carbonaceous chondrite (CC) analogs. The rock's reflectance ($r_{\rm F} = 0.034 \pm 0.003$ at phase angle $4.5^\circ \pm 0.1^\circ$) is consistent with Ryugu's average reflectance, suggesting that the rock is typical for this asteroid. A spectrophotometric analysis of the rock's inclusions provides clues to CC group membership. Inclusions are generally brighter than the matrix. The dominant variation in their color is a change of the visible spectral slope, with ma…
Northwest Africa (NWA) 5958 is a carbonaceous chondrite found in Morocco in 2009. Preliminary chemical and isotopic data leading to its initial classification as C3.0 ungrouped have prompted us to conduct a multi-technique study of this meteorite and present a general description here. The petrography and chemistry of NWA 5958 is most similar to a CM chondrite, with a low degree of aqueous alteration, apparently under oxidizing conditions, and evidence of a second, limited alteration episode manifested by alteration fronts. The oxygen isotopic composition, with $Δ^{17}$O = -4.3 $\permil$, is m…
The insoluble organic matter (IOM) of an unequilibrated enstatite chondrite Sahara (SAH) 97096 has been investigated using a battery of analytical techniques. As the enstatite chondrites are thought to have formed in a reduced environment at higher temperatures than carbonaceous chondrites, they constitute an interesting comparative material to test the heterogeneities of the IOM in the solar system and to constrain the processes that could affect IOM during solar system evolution. The SAH 97096 IOM is found in situ: as submicrometer grains in the network of fine-grained matrix occurring mostl…
This study reports the bulk rare earth element (REEs, La-Lu) compositions of 41 chondrites, including 32 falls and 9 finds from carbonaceous (CI, CM, CO and CV), enstatite (EH and EL) and ordinary (H, L and LL) groups, as well as 2 enstatite achondrites (aubrite). The CI-chondrite-normalized REE patterns and Eu anomalies in ordinary and enstatite chondrites show more scatter in more metamorphosed than in unequilibrated chondrites. This is due to parent-body redistribution of the REEs in various carrier phases during metamorphism. The dispersion in REE patterns of equilibrated ordinary chondrit…
Prebiotic molecules, fundamental building blocks for the origin of life, have been found in carbonaceous chondrites. The exogenous delivery of these organic molecules onto the Hadean Earth could have sparked the polymerization of the first RNA molecules in Darwinian ponds during wet-dry cycles. Here, we investigate the formation of the RNA and DNA nucleobases adenine, uracil, cytosine, guanine, and thymine inside parent body planetesimals of carbonaceous chondrites. An up-to-date thermochemical equilibrium model coupled with a 1D thermodynamic planetesimal model is used to calculate the nucleo…
The CM carbonaceous chondrite meteorites provide a record of low temperature aqueous reactions in the early solar system. A number of CM chondrites also experienced short-lived, post-hydration thermal metamorphism at temperatures of 200C to over 750C. The exact conditions of thermal metamorphism and the relationship between the unheated and heated CM chondrites are not well constrained but are crucial to understanding the formation and evolution of hydrous asteroids. Here we have used position-sensitive-detector X-ray diffraction (PSD-XRD), thermogravimetric analysis (TGA) and transmission inf…
We report a correlated NanoSIMS-transmission electron microscopy study of the ungrouped carbonaceous chondrite Northwest Africa (NWA) 5958. We identified 10 presolar SiC grains, 2 likely presolar graphite grains, and 20 presolar silicate and/or oxide grains in NWA 5958. We suggest a slight modification of the commonly used classification system for presolar oxides and silicates that better reflects the grains' likely stellar origins. The matrix-normalized presolar SiC abundance in NWA 5958 is $18_{-10}^{+15}$ ppm (2$σ$), similar to that seen in many classes of unmetamorphosed chondrites. In co…
We analyze here a wide sample of carbonaceous chondrites from historic falls (e.g. Allende, Cold Bokkeveld, Kainsaz, Leoville, Murchison, Murray and Orgueil), and from NASA Antarctic collection in order to get clues on the role of aqueous alteration in promoting the reflectance spectra diversity evidenced in the most primitive chondrite groups. We particularly focus in the identification of spectral features and behavior that can be used to remotely identify primitive carbonaceous asteroids. The selected meteorite specimens are a sample large enough to exemplify how laboratory reflectance spec…
Solar system materials are variably depleted in moderately volatile elements (MVEs) relative to the proto-solar composition. To address the origin of this MVE depletion, we conducted a systematic study of high-precision K isotopic composition on 16 carbonaceous chondrites (CCs) of types CM1-2, CO3, CV3, CR2, CK4-5 and CH3 and 28 ordinary chondrites (OCs) covering petrological types 3 to 6 and chemical groups H, L, and LL. We observed significant overall K isotope (delta41K) variations (-1.54 to 0.70 permil). The K isotope compositions of CCs are largely higher than the Bulk Silicate Earth (BSE…
The origin of life might be sparked by the polymerization of the first RNA molecules in Darwinian ponds during wet-dry cycles. The key life-building block ribose was found in carbonaceous chondrites. Its exogenous delivery onto the Hadean Earth could be a crucial step toward the emergence of the RNA world. Here, we investigate the formation of ribose through a simplified version of the formose reaction inside carbonaceous chondrite parent bodies. Following up on our previous studies regarding nucleobases with the same coupled physico-chemical model, we calculate the abundance of ribose within …
The recent publication by Siraj & Loeb (2021; Nature Scientific Reports 11, 3803) attempts to revive the debate over whether the Chicxulub impactor was a comet or an asteroid. They calculate that ~20% of long-period comets impacting Earth will have first been disrupted by passage inside the Sun's Roche limit, generating thousands of fragments, each the needed size of the Chicxulub impactor. This would increase the impact rate of comets by a factor ~15, making them as likely to hit the Earth as an asteroid. They also argue that a comet would be a factor of 10 more likely to match the geochemica…
Least-processed carbonaceous chondrites (carbonaceous chondrites that have experienced minimal aqueous alteration and thermal metamorphism) are characterized by their predominately amorphous iron-rich silicate interchondrule matrices and chondrule rims. The presence of abundant amorphous material in a meteorite indicates that the parent body, or at least a region of the parent body, experienced minimal processing since the time of accretion. The CO chemical group of carbonaceous chondrites has a significant number of these least-processed samples. We present visible/near-infrared and mid-infra…
Carbonaceous chondrites are a class of meteorite known for having a high content of water and organics. In this study, abundances of the nucleobases, i.e., the building blocks of RNA and DNA, found in carbonaceous chondrites are collated from a variety of published data and compared across various meteorite classes. An extensive review of abiotic chemical reactions producing nucleobases is then performed. These reactions are then reduced to a list of 15 individual reaction pathways that could potentially occur within meteorite parent bodies. The nucleobases guanine, adenine and uracil are foun…
Here we report a comparison between reflectance spectroscopy of meteorites under asteroidal environment (high vacuum and temperature) and Main Belt and Near Earth Asteroids spectra. Focusing on the OH absorption feature around 3μm, we show that the asteroidal environment induces a reduction of depth and width of the band, as well as a shift of the reflectance minimum. We then decompose the OH feature into several components with a new model using Exponentially Modified Gaussians. Unlike previous studies, we confirme the link between these components, the aqueous alteration history and the amou…
A recent paper by Siraj & Loeb (2021) entitled "Breakup of a long-period comet as the origin of the dinosaur extinction" attempts to revive the perennial debate about what type of body hit the Earth 66 million years ago, triggering the end-Cretaceous extinction. Here we critique the paper and assess the evidence it presents. To consider a comet more likely than an asteroid requires extreme assumptions about how comets fragment, conflation of carbonaceous chondrites with specific types of carbonaceous chondrites, and a blind eye to the evidence of the iridium layer.
Meteorite matrices from primitive chondrites are an interplay of ingredients at the sub-micron scale, which requires analytical techniques with the nanometer spatial resolution to decipher the composition of individual components in their petrographic context. Infrared spectroscopy is an effective method that enables to probe of vibrations at the molecule-atomic scale of organic and inorganic compounds but is often limited to a few micrometers in spatial resolution. To efficiently distinguish spectral signatures of the different constituents, we apply here nano-IR spectroscopy (AFM-IR), based …
Presolar grains are trace components in chondrite matrices. Their abundances and compositions have been systematically studied in carbonaceous chondrites but rarely in situ in other major chondrite classes. We have conducted a NanoSIMS isotopic search for presolar grains with O- and C-anomalous isotopic compositions in the matrices of the unequilibrated ordinary chondrites Semarkona, Meteorite Hills 00526, and Northwest Africa 8276. The matrices of even the most primitive ordinary chondrites have been aqueously altered and/or thermally metamorphosed, destroying their presolar grain populations…
The Visible-Infrared Mapping Spectrometer (VIR) on board the Dawn spacecraft revealed that aqueous secondary minerals -- Mg-phyllosilicates, NH4-bearing phases, and Mg/Ca carbonates -- are ubiquitous on Ceres. Ceres' low reflectance requires dark phases, which were assumed to be amorphous carbon and/or magnetite (~80 wt.%). In contrast, the Gamma Ray and Neutron Detector (GRaND) constrained the abundances of C (8-14 wt.%) and Fe (15-17 wt.%). Here, we reconcile the VIR-derived mineral composition with the GRaND-derived elemental composition. First, we model mineral abundances from VIR data, in…
Carbonaceous chondrites are often considered potential contributors of water and other volatiles to terrestrial planets as most of them contain significant amounts of hydrous mineral phases. As such, carbonaceous chondrites are candidate building blocks for Earth, and elucidating their thermal histories is of direct important for understanding the volatile element history of Earth and the terrestrial planets. A significant fraction of CM type carbonaceous chondrites are thermally metamorphosed or heated and have lost part of their water content. The origin and the timing of such heating events…
Miller Range (MIL) 07687 is a peculiar carbonaceous chondrite officially classified as a CO3. However, it has been found to display unique petrographic properties that are atypical of this group. Moreover, Raman spectra of its polyaromatic carbonaceous matter does not reflect a structural order consistent with the metamorphic history of a type 3 chondrite. As a result, it has been suggested to be an ungrouped C2 chondrite with CO affinities, although it has not been fully excluded as a CO chondrite. The ambiguity of the meteorite classification is the motivation behind the present study. We co…
Although spectral surveys and spacecraft missions provide information on small bodies, many important analyses can only be performed in terrestrial laboratories. For now, the total number of parent bodies represented in our meteorites collection is estimated to about 150 parent bodies, of which 50 parent bodies represented by the poorly studied ungrouped chondrites. Linking ungrouped meteorites to their parent bodies is thus crucial to significantly increase our knowledge of asteroids. To this end, the petrography of 25 ungrouped chondrites and rare meteorite groups was studied, allowing group…
(16) Psyche is the largest M-type asteroid in the main belt and the target of the NASA Discovery-class Psyche mission. Despite gaining considerable interest in the scientific community, Psyche's composition and formation remain unconstrained. Originally, Psyche was considered to be almost entirely composed of metal due to its high radar albedo and spectral similarities to iron meteorites. More recent telescopic observations suggest the additional presence of low-Fe pyroxene and exogenic carbonaceous chondrites on the asteroid's surface. To better understand the abundances of these additional m…
Volatile compositions of asteroids provide information on the Solar System history and the origins of Earth's volatiles. Visible to near-infrared observations at wavelengths of $<2.5\ {\rm μm}$ have suggested a genetic link between outer main belt asteroids located at $2.5$-$4\ {\rm au}$ and carbonaceous chondrite meteorites (CCs) that show isotopic similarities to volatile elements on Earth. However, recent longer wavelength data for large outer main belt asteroids show $3.1\ {\rm μm}$ absorption features of ammoniated phyllosilicates that are absent in CCs and cannot easily form from materia…
The evolution and lifetime of protoplanetary disks (PPDs) play a central role in the formation and architecture of planetary systems. Astronomical observations suggest that PPDs evolve in two timescales, accreting onto the star for up to several million years (Myr) followed by gas dissipation within <1 Myr. Because solar nebula magnetic fields are sustained by the gas of the protoplanetary disk, we can use paleomagnetic measurements to infer the lifetime of the solar nebula. Here, we use paleomagnetic measurements of meteorites to constrain this lifetime and investigate whether the solar nebul…
FTIR measurement on MK immediately after its fall, shows a unique doublet around 10 micrometer, significantly different from many ordinary CM2 chondrites, where only a singlet around 10 micrometer is observed. Also, a very faint 11.2 micrometer feature in MK indicates the absence of anhydrous silicates, olivine and thus complete serpentinization of anhydrous silicates due to severe aqueous alteration on parent body. Raman studies show a low peak metamorphic temperature around 0 °C and consistent with the absence of peak corresponding to tochilinite in FTIR spectrum, which forms at higher tempe…
Near-mid infrared spectroscopy of carbonaceous chondrites: Insights into spectral variation due to aqueous alteration and thermal metamorphism in asteroids
NASA's Dawn spacecraft observations of asteroid (4) Vesta reveal a surface with the highest albedo and color variation of any asteroid we have observed so far. Terrains rich in low albedo dark material (DM) have been identified using Dawn Framing Camera (FC) 0.75 μm filter images in several geologic settings: associated with impact craters (in the ejecta blanket material and/or on the crater walls and rims); as flow-like deposits or rays commonly associated with topographic highs; and as dark spots (likely secondary impacts) nearby impact craters. This DM could be a relic of ancient volcanic a…
Bottke et al. (2007) linked the catastrophic formation of Baptistina Asteroid Family (BAF) to the K/T impact event. This linkage was based on dynamical and compositional evidence, which suggested the impactor had a composition similar to CM2 carbonaceous chondrites. However, our recent study (Reddy et al. 2009) suggests that the composition of (298) Baptistina is similar to LL-type ordinary chondrites rather than CM2 carbonaceous chondrites. This rules out any possibility of it being related to the source of the K/T impactor, if the impactor was of CM-type composition. Mineralogical study of a…
To evaluate the feasibility of measuring differences in bulk composition among carbonaceous meteorite parent bodies from an asteroid or comet orbiter, we present the results of a performance simulation of an orbital gamma-ray spectroscopy ("GRS") experiment in a Dawn-like orbit around spherical model asteroids with a range of carbonaceous compositions. The orbital altitude was held equal to the asteroid radius for 4.5 months. Both the asteroid gamma-ray spectrum and the spacecraft background flux were calculated using the MCNPX Monte-Carlo code. GRS is sensitive to depths below the optical sur…
We have measured the concentration, isotopic composition and thermal release profiles of Mercury (Hg) in a suite of meteorites, including both chondrites and achondrites. We find large variations in Hg concentration between different meteorites (ca. 10 ppb to 14'000 ppb), with the highest concentration orders of magnitude above the expected bulk solar system silicates value. From the presence of several different Hg carrier phases in thermal release profiles (150 to 650 °C), we argue that these variations are unlikely to be mainly due to terrestrial contamination. The Hg abundance of meteorite…
