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arXiv 2106.09863cond-mat.supr-con
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Sm(O,F)BiS $_2$单晶的氟溶解度和超导性能

Fluorine solubility and superconducting properties of Sm(O,F)BiS$_2$ single crystals

Koki Kinami, Yuji Hanada, Masanori Nagao, Akira Miura, Shigeto Hirai, Yuki Maruyama, Satoshi Watauchi, Isao Tanaka

摘要:

用KI-KCl助熔剂生长了不同名义氟含量的Sm(O,F)BiS_2超导单晶。F在Sm(O,F)BiS 2单晶中O位的固溶极限约小于20at%。Sm(O,F)BiS 2单晶的F浓度几乎不受名义F含量的控制。这表明存在本征稳定相。在5 K左右显示出超导性。零电阻率的超导转变温度随着标称F含量的增加而增加,在O位小于70原子%的范围内,尽管F浓度和c轴晶格常数相似。

英文摘要:

Sm(O,F)BiS2 superconducting single crystals with various nominal F contents have been grown using KI-KCl flux. The solid solution limit of F at the O-site in Sm(O,F)BiS2 single crystals was approximately less than 20 at%. F concentrations of Sm(O,F)BiS2 single crystals were hardly controlled by nominal F contents. It suggests the existence of intrinsic stable phase. Superconductivity was shown at around 5 K. Superconducting transition temperature with zero resistivity were increased with increasing nominal F contents within less than 70 at% in O-site, despite similar F concentration and c-axis lattice constants.

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