Natural convection in porous media is a fundamental process for the long-term storage of CO2 in deep saline aquifers. Typically, details of mass transfer in porous media are inferred from the numerical solution of the volume-averaged Darcy-Oberbeck-Boussinesq (DOB) equations, even though these equations do not account for the microscopic properties of a porous medium. According to the DOB equations, natural convection in a porous medium is uniquely determined by the Rayleigh number. However, in contrast with experiments, DOB simulations yield a linear scaling of the Sherwood number with the Rayleigh number (Ra) for high values of Ra (Ra>>1,300). Here, we perform Direct Numerical Simulations (DNS), fully resolving the flow field within the pores. We show that the boundary layer thickness is determined by the pore size instead of the Rayleigh number, as previously assumed. The mega- and proto- plume sizes increase with the pore size. Our DNS results exhibit a nonlinear scaling of the Sherwood number at high porosity, and for the same Rayleigh number, higher Sherwood numbers are predicted by DNS at lower porosities. It can be concluded that the scaling of the Sherwood number depends on the porosity and the pore-scale parameters, which is consistent with experimental studies.
The relationship between the microstructure of a porous medium and the observed flow distribution is still a puzzle. We resolve it with an analytical model, where the local correlations between adjacent pores, which determine the distribution of flows propagated from one pore downstream, predict the flow distribution. Numerical simulations of a two-dimensional porous medium verify the model and clearly show the transition of flow distributions from $δ$-function-like via Gaussians to exponential with increasing disorder. Comparison to experimental data further verifies our numerical approach.
The flow of immiscible fluids inside a porous medium shows non-linearity in the form of a power law in the rheological properties of the fluids under steady state flow conditions. However, different experimental and numerical studies have reported different values for the exponent related to this power law. Here we explore how the rheological properties of the two-phase flow in porous media depends on the distribution of the pore sizes and how it affects the power-law exponent. The pore-size distribution controls fluctuation in the pore radii and their density in a porous material. We present …
We study the transport of inertial particles in water flow in porous media. Our interest lies in understanding the accumulation of particles including the possibility of clogging. We propose that accumulation can be a result of hydrodynamic effects: the tortuous paths of the porous medium generate regions of dominating strain/vorticity, which favour the accumulation/dispersion of the inertial particles. Numerical simulations show that essentially two accumulation regimes are identified: for low and for high flow velocities. When particles accumulate in high-velocity regions, at the entrance of…
In this paper, the pore network model to investigate the reaction-diffusion process in the hierarchically structured porous catalyst particle is extended to consider the phenomenon of deactivation by coking. In this framework, the interaction of internal particle pore structure and mass transfer under the condition of coke deposition are examined. A primitive experimental investigation has been performed as an introduction to the development of the model. Then, the effect of structural features namely macroporosity and pore size ratio, the deactivation properties, the maximum loading of coke a…
Present work attempts to identify the roles of flow- and geometric-variables on the scaling factor which is a necessary parameter for modeling the apparent viscosity of non-Newtonian fluid in porous media. While idealizing the porous media microstructure as arrays of circular and square cylinders, present study uses multi-relaxation time lattice Boltzmann method to conduct pore-scale simulation of shear thinning non-Newtonian fluid flow. Variation in the size and inclusion ratio of the solid cylinders generates wide range of porous media with varying porosity and permeability. Present study al…
In the above paper the authors treat the natural convection boundary layer flow in a Darcy-Brinkman-Forchheimer porous medium. In the energy equation the radiation effect has been taken into account. A two-parameter perturbation method is used for the solution of the equations. The first order results are presented in tables and figures. This is an interesting work but there are some weak points which are presented below:
In this paper, a pore-scale network modeling method, based on the flow continuity residual in conjunction with a Newton-Raphson non-linear iterative solving technique, is proposed and used to obtain the pressure and flow fields in a network of interconnected distensible ducts representing, for instance, blood vasculature or deformable porous media. A previously derived analytical expression correlating boundary pressures to volumetric flow rate in compliant tubes for a pressure-area constitutive elastic relation has been used to represent the underlying flow model. Comparison to a preceding eq…
Mineral dissolution in porous media coupled with single- or multi-phase flows is pervasive in natural and engineering systems including carbon capture and sequestration (CCS) and acid stimulation in reservoir engineering. Dissolution of minerals occurs as chemicals in the solid phase is transformed into ions in the aqueous phase, effectively modifying the physical, hydrological and geochemical properties of the solid matrix, and thus leading to the strong coupling between local dissolution rate and pore-scale flow. However, our fundamental understanding of this coupling effect at the pore leve…
In a range of physical systems, the first instability in Rayleigh-Bernard convection between nearly thermally insulating horizontal plates is large scale. This holds for thermal convection of fluids saturating porous media. Large-scale thermal convection in a horizontal layer is governed by remarkably similar equations both in the presence of a porous matrix and without it, with only one additional term for the latter case, which, however, vanishes under certain conditions (e.g., two-dimensional flows or infinite Prandtl number). We provide a rigorous derivation of long-wavelength equations fo…
We present a numerical study of convection in a horizontal layer comprising a fluid-saturated porous bed overlain by an unconfined fluid layer. Convection is driven by a vertical, destabilising temperature difference applied across the whole system, as in the canonical Rayleigh-Bénard problem. Numerical simulations are carried out using a single-domain formulation of the two-layer problem based on the Darcy-Brinkman equations. We explore the dynamics and heat flux through the system in the limit of large Rayleigh number, but small Darcy number, such that the flow exhibits vigorous convection i…
The problem of steady mixed convection boundary-layer flow on a cooled vertical permeable circular cylinder embedded in a fluid-saturated porous medium is studied. Here, we evaluate the flow and heat transfer characteristics numerically for various values of the governing parameters and demonstrate the existence of dual solutions beyond a critical point.
A new approach to the modelling of wetting fronts in porous media on the Darcy scale is developed, based on considering the types (modes) of motion the menisci go through on the pore scale. This approach is illustrated using a simple model case of imbibition of a viscous incompressible liquid into an isotropic porous matrix with two modes of motion for the menisci, the wetting mode and the threshold mode. The latter makes it necessary to introduce an essentially new technique of conjugate problems that allows one to link threshold phenomena on the pore scale with the motion on the Darcy scale.…
We present pore-scale simulations of two-phase flows in a reconstructed fibrous porous layer. The three dimensional microstructure of the material, a fuel cell gas diffusion layer, is acquired via X-ray computed tomography and used as input for lattice Boltzmann simulations. We perform a quantitative analysis of the multiphase pore-scale dynamics and we identify the dominant fluid structures governing mass transport. The results show the existence of three different regimes of transport: a fast inertial dynamics at short times, characterised by a compact uniform front, a viscous-capillary regi…
Convection heat transfer in porous media is a universal phenomenon in nature, and it is also frequently encountered in scientific and engineering fields. An in-depth understanding of the fundamental mechanism of convection heat transfer in porous media requires efficient and powerful numerical tools. In this paper, a cascaded lattice Boltzmann (CLB) method for convection heat transfer in porous media at the representative elementary volume (REV) scale is presented. In the CLB method, the flow field is solved by an isothermal CLB model with the D2Q9 lattice based on the generalized non-Darcy mo…
We report a numerical study of Rayleigh--Bénard convection through random porous media using pore-scale modelling, focusing on the Lagrangian dynamics of fluid particles and heat transfer for varied porosities $ϕ$. Due to the interaction between the porous medium and the coherent flow structures, the flow is found to be highly heterogeneous, consisting of convection channels with strong flow strength and stagnant regions with low velocities. The modifications of flow field due to porous structure have a significant influence on the dynamics of fluid particles. Evaluation of the particle displa…
The macroscopic spreading and mixing of solute plumes in saturated porous media is ultimately controlled by processes operating at the pore scale. Whilst the conventional picture of pore-scale mechanical dispersion and molecular diffusion leading to persistent hydrodynamic dispersion is well accepted, this paradigm is inherently two-dimensional (2D) in nature and neglects important three-dimensional (3D) phenomena. We discuss how the kinematics of steady 3D flow at the porescale generate chaotic advection, involving exponential stretching and folding of fluid elements,the mechanisms by which i…
A ubiquitous arrangement in nature is a free-flowing fluid coupled to a porous medium, for example a river or lake lying above a porous bed. Depending on the environmental conditions, thermal convection can occur and may be confined to the clear fluid region, forming shallow convection cells, or it can penetrate into the porous medium, forming deep cells. Here, we combine three complementary approaches -- linear stability analysis, fully nonlinear numerical simulations, and a coarse-grained model -- to determine the circumstances that lead to each configuration. The coarse-grained model yields…
In this article we investigate the permeability of a porous medium as given in Darcy's law. The permeability is described by an effective hydraulic pore radius in the porous medium, the fluctuation in local hydraulic pore radii, the length of streamlines, and the fractional volume conducting flow. The effective hydraulic pore radius is related to a characteristic hydraulic length, the fluctuation in local hydraulic radii is related to a constriction factor, the length of streamlines is characterized by a tortuosity, and the fractional volume conducting flow from inlet to outlet is described by…
We present a numerical study of nonlinear electrokinetic transport in porous media, focusing on the role of heterogeneity in a porous microstructure on ion concentration polarization and over-limiting current. For simplicity, the porous medium is modeled as a network of long, thin charged cylindrical pores, each governed by one-dimensional effective transport equations. For weak surface conduction, when sufficiently large potential is applied, we demonstrate that electrokinetic transport in a porous network can be dominated by electroconvection via internally induced flow loops, which is not p…
In various areas of science, technology, environment protection, construction, it is very important to study processes of porous materials interaction with different substances in different aggregation states. From the point of view of ecology and environmental protection it is particularly actual to investigate processes of porous materials interaction with water in liquid and gaseous phases. Since one mole of water contains $6,022140857\cdot 10^{23}$ molecules of $\mathtt{H_2O}$, macroscopic approaches considering the water vapor as continuum media in the framework of classical aerodynamics …
We perform a numerical study of the heat transfer and flow structure of Rayleigh-Bénard (RB) convection in (in most cases regular) porous media, which are comprised of circular, solid obstacles located on a square lattice. This study is focused on the role of porosity $ϕ$ in the flow properties during the transition process from the traditional RB convection with $ϕ=1$ (so no obstacles included) to Darcy-type porous-media convection with $ϕ$ approaching 0. Simulations are carried out in a cell with unity aspect ratio, for the Rayleigh number $Ra$ from $10^5$ to $10^{10}$ and varying porosities…
We extend the two-scale expansion approach of periodic homogenization to include time scales and thus can tackle the full instationary Navier-Stokes-Cahn-Hilliard model at the pore scale as microscale. Time scale separation allows us to keep microscale dynamics, responsible e.g. for hysteresis, and arrive at a numerically tractable micro-macro model including coupled generalized Darcy's laws.
We present a theoretical framework for immiscible incompressible two-phase flow in homogeneous porous media that connects the distribution of local fluid velocities to the average seepage velocities. By dividing the pore area along a cross-section transversal to the average flow direction up into differential areas associated with the local flow velocities, we construct a distribution function that allows us not only to re-establish existing relationships between the seepage velocities of the immiscible fluids, but also to find new relations between their higher moments. We support and demonst…
This study refutes the premise that the distribution of flow speeds in complex porous media can be described by a simple function such as a normal or exponential variation. In many complex porous media, including those relevant for subsurface storage and recovery applications, a separation of scales exists between larger inter-granular pores and micro-porosity inside the grains, leading to different flow signatures that need to be described by multimodal functions with distinct flow field characteristics. We demonstrate this finding by devising a novel methodology to simulate fluid flow in car…
We study the effect of spatially-correlated heterogeneity on isothermal drying of porous media. We combine a minimal pore-scale model with microfluidic experiments with the same pore geometry. Our simulated drying behavior compare favorably with experiments, considering the large sensitivity of the emergent behavior to the uncertainty associated with even small manufacturing errors. We show that increasing the correlation length in particle sizes promotes preferential drying of clusters of large pores, prolonging liquid connectivity and surface wetness and thus higher drying rates for longer p…
During evaporation in porous media, two types of corner films are distinguished. A continuous corner film is connected to the bulk liquid, while a discontinuous one is not. To disclose their effects on evaporation in porous media, a pore network model with both continuous and discontinuous corner films is developed, which considers the capillary and viscous forces as well as the effects of corner films on the threshold pressures of pores. The capillary valve effect induced by the sudden geometrical expansion between the small and large pores is also taken into account in the model. The develop…
The paper presents a theoretical study using the Karman-Pohlhausen method for describing the transient heat exchange between the boundary-layer free convection and a vertical flat plate embedded in a porous medium. The unsteady behavior is developed after the generation of an impulsive heat flux step at the right-hand side of the plate. Two cases are considered according to whether the plate has a finite thickness or no thickness. The time and space evolution of the interface temperature is evidenced.
Theoretical and experimental investigations of water vapor interaction with porous materials are carried out both at the macro level and at the micro level. At the macro level, the influence of the arrangement structure of individual pores on the processes of water vapor interaction with porous material as a continuous medium is studied. At the micro level, it is very interesting to investigate the dependence of the characteristics of the water vapor interaction with porous media on the geometry and dimensions of the individual pore. In this paper, a study was carried out by means of mathemati…
We study the interplay of pore-scale mixing and network-scale advection through heterogeneous porous media, and its role for the evolution and asymptotic behavior of hydrodynamic dispersion. In a Lagrangian framework, we identify three fundamental mechanisms of pore-scale mixing that determine large scale particle motion, namely, the smoothing of intra-pore velocity contrasts, the increase of the tortuosity of particle paths, and the setting of a maximum time for particle transitions. Based on these mechanisms, we derive a theory that predicts anomalous and normal hydrodynamic dispersion based…
In the above paper the author treats the boundary layer flow along a vertical flat plate, immersed in a Darcy Brinkman Forchheimer porous medium. The porosity and the permeability of the porous medium are variable across the boundary layer. In addition a magnetic field with constant strength is applied normal to the plate. The fluid temperature at the plate is constant and different from that of the ambient fluid. This temperature difference creates a buoyancy force and the flow is characterized as mixed convection. The partial differential equations of the boundary layer flow are transformed …
In this paper, a double multiple-relaxation-time lattice Boltzmann model is developed for simulating transient solid-liquid phase change problems in porous media at the representative elementary volume scale. The model uses two different multiple-relaxation-time lattice Boltzmann equations, one for the flow field and the other for the temperature field with nonlinear latent heat source term. The model is based on the generalized non-Darcy formulation, and the solid-liquid phase change interface is traced through the liquid fraction which is determined by the enthalpy method. The model is valid…
Pore-shape and its spatial organization control intrinsic permeability of porous media
Institute of Earth Science, University of Lausanne（洛桑大学地球科学研究所）；Department of Civil and Environmental Engineering, Massachusetts Institute of Technology（麻省理工学院土木与环境工程系）；Department of Water Resources and Drinking Water, Eawag, Swiss Federal Institute of Aquatic Science and Technology（瑞士联邦水科学与技术研究所（Eawag）水资源与饮用水系）；Department of Civil and Environmental Engineering, Politecnico di Milano（米兰理工大学土木与环境工程系）；Sonny Astani Department of Civil and Environmental Engineering, Viterbi School of Engineering, University of Southern California（南加州大学维特比工程学院索尼·阿斯塔尼土木与环境工程系）
We perform linear and nonlinear stability analysis for thermal convection in a fluid overlying a saturated porous medium. We use a coupled system, with the Navier-Stokes equations and Darcy's equation governing the free-flow and the porous regions respectively. Incorporating a dynamic pressure term in the Lions interface condition (which specifies the normal force balance across the fluid-medium interface) permits an energy bound on the typically uncooperative nonlinear advection term, enabling new nonlinear stability results. Within certain regimes, the nonlinear stability thresholds agree cl…
The thesis investigates the flow of non-Newtonian fluids in porous media using pore-scale network modeling. Non-Newtonian fluids show very complex time and strain dependent behavior and may have initial yield stress. Their common feature is that they do not obey the simple Newtonian relation of proportionality between stress and rate of deformation. They are generally classified into three main categories: time-independent, time-dependent and viscoelastic. Two three-dimensional networks representing a sand pack and Berea sandstone were used. An iterative numerical technique is used to solve th…
This investigation deals with the analysis of stagnation point heat transfer and corresponding flow features of hydromagnetic viscous incompressible fluid over a vertical shrinking sheet. The considered sheet is assumed to be permeable and subject to addition of stagnation point to control the generated vorticity in the boundary layer. The sheet is placed on the right side of the fluid saturated porous medium which is having permeability of specified form. Nonlinear convection waves in the flow field are realized due to the envisaged nonlinear relation between density and temperature. The equa…
Wetting phenomena play a key role in flows through porous media. Relative permeability and capillary pressure-saturation functions show a high sensitivity to wettability, which has different definitions at the continuum- and pore-scale. At the continuum-scale, the state of wetting is defined as Amott-Harvey or USBM (United States Bureau of Mines) by capillary pressure drainage and imbibition cycles. At the pore-scale, the concept of contact angle is used, which until recently was not experimentally possible to determine within an opaque porous medium. Recent progress on measurements of pore-sc…
Electrical conductivity is an inherent property of a hydrophobic porous media (HPM) and has critical applications. This research aims to provide a solution for predicting the electrical conductivity of nanoscale HPM with heterogeneous pore structure. Molecular dynamics (MD) simulations are compared with the modified Poisson-Boltzmann (MPB) model for understanding ionic charge density distributions in nanopores. The effective medium approximation (EMA) participates in calculating the effective conductance and conductivity of the nanoscale HPM. The results show that the surface charge density af…
Polymer solutions are often injected in porous media for applications such as oil recovery and groundwater remediation. As the fluid navigates the tortuous pore space, elastic stresses build up, causing the flow to become unstable at sufficiently large injection rates. However, it is poorly understood how the spatial and temporal characteristics of this unstable flow depend on pore space geometry. We elucidate this dependence by systematically varying the spacing between pore constrictions in a model porous medium. We find that when the pore spacing is large, unstable eddies form upstream of e…
