Solid-state quantum registers are exceptional for storing quantum information at room temperature with long coherence time. Nevertheless, practical applications toward quantum supremacy require even longer coherence time to allow for more complex algorithms. In this work we propose a quantum register that lies in a decoherence-free subspace to be implemented with color centers in diamond. The quantum information is encoded in two logical states composed of two nearby nuclear spins, while an electron spin is used as ancilla for initialization and control. Moreover, by tuning an off-axis magnetic field we enable non-nuclear-spin-preserving transitions that we use for preparing the register through Stimulating Raman Adiabatic Passage. Furthermore, we use this sequence to manipulate the quantum register and an individual nuclear spin.
We present a theoretical scheme that allows to perform a universal set of holonomic gates on a two qubit register, formed by a $^{13}$C nuclear spin coupled to the electron spin of a nitrogen-vacancy center in diamond. Strong hyperfine interaction between the electron spin and the spins of the first three shells of $^{13}$C atoms allows to operate the state of the register on the submicrosecond timescale using microwave pulses only. We describe the system and the operating regime analytically and numerically, as well as simulate the initialization protocols.
We theoretically investigate spin decoherence of a single nitrogen-vacancy (NV) center in diamond. Using the spin coherent state P-representation method, coherence evolution of the NV center surrounded by nitrogen electron spins (N) is simulated. We find that spin decoherence time as well as free-induction decay of the NV center depend on the spatial configuration of N spins. Both the spin decoherence rate (1/T2) and dephasing rate (1/T2*) of the NV center increase linearly with the concentration of the N spins. Using the P-representation method, we also demonstrate extracting noise spectrum o…
The dynamical evolution of a quantum register of arbitrary length coupled to an environment of arbitrary coherence length is predicted within a relevant model of decoherence. The results are reported for quantum bits (qubits) coupling individually to different environments (`independent decoherence') and qubits interacting collectively with the same reservoir (`collective decoherence'). In both cases, explicit decoherence functions are derived for any number of qubits. The decay of the coherences of the register is shown to strongly depend on the input states: we show that this sensitivity is …
We model the decoherence and dephasing of nitrogen vacancy (NV) centers in diamond due to a noisy paramagnetic bath, with and without the presence of a rf field that couples levels of the ground electronic state manifold, using a simple quantum mechanical model that allows for analytical solutions. The model treats the NV three-level ground state system in the presence of fluctuating magnetic fields that arise from the environment, and that result in decoherence, dephasing and dissipation. We show that all 9 eigenmodes of the three-level system are coupled to each other due to interaction with…
We report on room-temperature coherent manipulation of the spin of a single nitrogen-vacancy center in diamond and a study of its coherence as a function of magnetic field. We use magnetic resonance to induce Rabi nutations, and apply a Hahn spin echo to remove the effect of low-frequency dephasing. A sharp rise in the decoherence rate is observed at magnetic fields where the nitrogen-vacancy center spin couples resonantly to substitutional nitrogen spins via the magnetic dipolar coupling. Finally, we find evidence that away from these energy resonances spin flips of nitrogen electrons are the…
Quantum registers of nuclear spins coupled to electron spins of individual solid-state defects are a promising platform for quantum information processing. Pioneering experiments selected defects with favourably located nuclear spins having particularly strong hyperfine couplings. For progress towards large-scale applications, larger and deterministically available nuclear registers are highly desirable. Here we realize universal control over multi-qubit spin registers by harnessing abundant weakly coupled nuclear spins. We use the electron spin of a nitrogen-vacancy centre in diamond to selec…
Nitrogen vacancy (NV-) color centers in diamond are a prime candidate for use in quantum information devices, owing to their spin-1 ground state, straightforward optical initialization and readout, and long intrinsic coherence times in a room-temperature solid. While the 13C nuclear spin is often a dominant source of magnetic noise, we observe transitions between electron-nuclear hyperfine states of NV- centers in 99% 13C diamond that are robust to decoherence. At magnetic field strengths ranging from 550 - 900 G, these transitions are observable by optically detected magnetic resonance (ODMR)…
We experimentally demonstrate that the decoherence of a spin by a spin bath can be completely eliminated by fully polarizing the spin bath. We use electron paramagnetic resonance at 240 gigahertz and 8 Tesla to study the spin coherence time $T_2$ of nitrogen-vacancy centers and nitrogen impurities in diamond from room temperature down to 1.3 K. A sharp increase of $T_2$ is observed below the Zeeman energy (11.5 K). The data are well described by a suppression of the flip-flop induced spin bath fluctuations due to thermal spin polarization. $T_2$ saturates at $\sim 250 μs$ below 2 K, where the …
In order to eliminate disturbing effects of decoherence, encoding of quantum information in decoherence-free subspaces has been suggested. We analyze the benefits of this concept for a quantum register that is realized in a spin chain in contact with a common bosonic bath. Within a dissipation-less model we provide explicit analytical results for the average fidelity of plain and encoded quantum registers. For the investigation of dissipative spin-boson couplings we employ a master equation of Bloch-Redfield type.
We consider decoherence of quantum registers, which consist of the qubits sited approximately periodically in space. The sites of the qubits are permitted to have a small random variance. We derive the explicit conditions under which the qubits can be assumed decohering independently. In other circumstances, the qubits are decohered cooperatively. We describe two kinds of collective decoherence. In each case, a scheme is proposed for reducing the collective decoherence. The schemes operate by encoding the input states of the qubits into some ''subdecoherent'' states.
We study a model of a quantum spin register interacting with an environment of spin particles in quantum-measurement limit. In the limit of collective decoherence we obtain the form of state vectors that constitute high-dimensional decoherence-free subspaces (DFS). In a more general setting we present sufficient and necessary conditions for existence of low-dimensional DFSs that can be used to construct subspaces of higher dimension.
We revisit decoherence process of a qubit register interacting with a thermal bosonic bath. We generalize the previous studies by considering not only the register's behavior but also of a part of its environment. In particular, we are interested in information flow from the register to the environment, which we describe using recently introduced multipartite quantum state structures called Spectrum Broadcast Structures. Working in two specific cases of: i) two-qubit register and ii) collective decoherence, we identify the regimes where the environment acquires almost complete information abou…
A model for a quantum register $\cal R$ made of $N$ replicas of a $d$-dimensional quantum system (cell) coupled with the environment, is studied by means of a Born-Markov Master Equation (ME). Dissipation and decoherence are discussed in various cases in which a sub-decoherent enconding can be rigorously found. For the qubit case ($d=2$) we have solved, for small $N,$ the ME by numerical direct integration and studied, as a function of the coherence length $ξ_c$ of the bath, fidelity and decoherence rates of states of the register. For large enough $ξ_c$ the singlet states of the global $su(2)…
Understanding the origins of spin lifetimes in hybrid quantum systems is a matter of current importance in several areas of quantum information and sensing. Methods that spectrally map spin relaxation processes provide insight into their origin and can motivate methods to mitigate them. In this paper, using a combination of hyperpolarization and precision field cycling over a wide range (1mT-7T), we map frequency dependent relaxation in a prototypical hybrid system of 13C nuclear spins in diamond coupled to Nitrogen Vacancy centers. Nuclear hyperpolarization through the optically pumped NV ele…
It is shown that a nonequilibrium environment can be instrumental in suppressing decoherence between distinct decoherence free subspaces in quantum registers. The effect is found in the framework of exact coherent-product solutions for model registers decohering in a bath of degenerate harmonic modes, through couplings linear in bath coordinates. These solutions represent a natural nonequilibrium extension of the standard solution for a decoupled initial register state and a thermal environment. Under appropriate conditions, the corresponding reduced register distribution can propagate in an u…
This study deals with the further development of nuclear spin model of scalable quantum register, which presents the one-dimensional chain of the magnetic atoms with nuclear spins 1/2, substituting the basic atoms in the plate of nuclear spin-free easy-axis 3D antiferromagnet. The decoherence rates of one qubit state and entanglement state of two removed qubits and longitudinal relaxation rates are caused by the interaction of nuclear spins-qubits with virtual spin waves in antiferromagnet ground state were calculated. It was considered also one qubit adiabatic decoherence, is caused by the in…
We demonstrate that the spin decoherence of nitrogen vacancy (NV) centers in diamond can be suppressed by a transverse magnetic field if the electron spin bath is the primary decoherence source. The NV spin coherence, created in "a decoherence-free subspace" is protected by the transverse component of the zero-field splitting, increasing the spin-coherence time about twofold. The decoherence due to the electron spin bath is also suppressed at magnetic fields stronger than ~25 gauss when applied parallel to the NV symmetry axis. Our method can be used to extend the spin-coherence time of simila…
We realize an elementary quantum network node consisting of a silicon-vacancy (SiV) color center inside a diamond nanocavity coupled to a nearby nuclear spin with 100 ms long coherence times. Specifically, we describe experimental techniques and discuss effects of strain, magnetic field, microwave driving, and spin bath on the properties of this 2-qubit register. We then employ these techniques to generate Bell-states between the SiV spin and an incident photon as well as between the SiV spin and a nearby nuclear spin. We also discuss control techniques and parameter regimes for utilizing the …
Diamond is a proven solid-state platform for spin-based quantum technology. The nitrogen-vacancy (NV) center in diamond has been used to realize small-scale quantum information processing (QIP) and quantum sensing under ambient conditions. A major barrier in the development of large-scale QIP in diamond is the connection of NV spin registers by a quantum bus at room temperature. Given that diamond is expected to be an ideal spin transport material, the coherent transport of spin directly between the spin registers offers a potential solution. Yet, there has been no demonstration of spin transp…
Protecting the dynamics of coupled quantum systems from decoherence by the environment is a key challenge for solid-state quantum information processing. An idle qubit can be efficiently insulated from the outside world via dynamical decoupling, as has recently been demonstrated for individual solid-state qubits. However, protection of qubit coherence during a multi-qubit gate poses a non-trivial problem: in general the decoupling disrupts the inter-qubit dynamics, and hence conflicts with gate operation. This problem is particularly salient for hybrid systems, wherein different types of qubit…
A hybrid quantum register consisting of nuclear spins in a solid-state platform coupled to a central electron spin is expected to combine the advantages of its elements. However, the potential to exploit long nuclear spin coherence times is severely limited by magnetic noise from the central electron spin during external interrogation. We overcome this obstacle and present protocols for addressing a decoherence-free nuclear spin subspace, which was not accessible by previously existing methods. We demonstrate the efficacy of our protocols using detailed numerical simulations of a nitrogen-vaca…
Understanding and mitigating decoherence is a key challenge for quantum science and technology. The main source of decoherence for solid-state spin systems is the uncontrolled spin bath environment. Here, we demonstrate quantum control of a mesoscopic spin bath in diamond at room temperature that is composed of electron spins of substitutional nitrogen impurities. The resulting spin bath dynamics are probed using a single nitrogen-vacancy (NV) centre electron spin as a magnetic field sensor. We exploit the spin bath control to dynamically suppress dephasing of the NV spin by the spin bath. Fur…
We investigate the decoherence process for a quantum register composed of N qubits coupled to an environment. We consider an environment composed of one common phonon bath and several electronic baths. This environment is relevant to the implementation of a charge based solid-state quantum computer. We explicitly compute the time evolution of all off-diagonal terms of the register's reduced density matrix. We find that in realistic configurations, "superdecoherence" and "decoherence free subspaces" do not exist for an N-qubit system. This means that all off-diagonal terms decay like exp(-q(t)N…
We study decoherence of a three-qubit array coupled to substrate phonons. Assuming an initial three-qubit entangled state that would be decoherence-free for identical qubit positions, allows us to focus on non-Markovian effects of the inevitable spatial qubit separation. It turns out that the coherence is most affected when the qubits are regularly spaced. Moreover, we find that up to a constant scaling factor, two-qubit entanglement is not influenced by the presence f the third qubit, even though all qubits interact via the phonon field.
Nuclear spins nearby nitrogen-vacancy (NV) centers in diamond are excellent quantum memory for quantum computing and quantum sensing, but are difficult to be initialized due to their weak interactions with the environment. Here we propose and demonstrate a magnetic-field-independent, deterministic and highly efficient polarization scheme by introducing chopped laser pulses into the double-resonance initialization method. With this method, we demonstrate initialization of single-nuclear-spin approaching $98.1\%$ and a $^{14}N$-$^{13}C$ double-nuclear-spin system approaching $96.8\%$ at room tem…
Optically-driven Rabi oscillations of single electron spins in a diamond nitrogen vacancy center are realized with two Raman-resonant optical pulses that are detuned from the respective dipole optical transitions. The Rabi oscillations are nuclear-spin selective and are robust against rapid decoherence of the underlying optical transitions, opening the door to generating phonon-mediated spin entanglement in an optically-driven spin-phonon system. A direct comparison between the Rabi oscillations and simulated Raman adiabatic passage along with a detailed theoretical analysis provide a wealth o…
Initializing quantum registers with high fidelity is a fundamental precondition for many applications like quantum information processing and sensing. The electronic and nuclear spins of a Nitrogen-Vacancy (NV) center in diamond form an interesting hybrid quantum register that can be initialized by a combination of laser, microwave, and radio-frequency pulses. However, the laser illumination, which is necessary for achieving electron spin polarization, also has the unwanted side-effect of depolarizing the nuclear spin. Here, we study how the depolarization dynamics of the $^{14}$N nuclear spin…
Based on the non-autonomous quantum master equation, we investigate the dissipative and decoherence properties of the two-level atom system interacting with the environment of thermal quantum radiation fields. For this system, by a novel algebraic dynamic method, the dynamical symmetry of the system is found, the quantum master equation is converted into a Schrödinger-like equation and the non-Hermitian rate (quantum Liouville) operator of the master equation is expressed as a linear function of the dynamical u(2) generators. Furthermore, the integrability of the non-autonomous master equation…
Nitrogen-vacancy (NV) centers in diamond have become an important tool for quantum technologies. All of these applications rely on long coherence times of electron and nuclear spins associated with these centers. Here, we study the energy level anti-crossings of an NV center in diamond coupled to a first-shell 13C nuclear spin in a small static magnetic field. These level anti-crossings occur for specific orientations of the static magnetic field due to the strong non-secular components of the Hamiltonian. At these orientations we observe decoherence-free subspaces, where the electron spin coh…
The coherent behavior of the single electron and single nuclear spins of a defect center in diamond and a 13C nucleus in its vicinity, respectively, are investigated. The energy levels associated with the hyperfine coupling of the electron spin of the defect center to the 13C nuclear spin are analyzed. Methods of magnetic resonance together with optical readout of single defect centers have been applied in order to observe the coherent dynamics of the electron and nuclear spins. Long coherence times, in the order of microseconds for electron spins and tens of microseconds for nuclear spins, re…
We propose a scheme of quantum information processing with NV-centers embedded inside diamond nanostructure. Single NV-center placed in the cavity plays role of an electron spin qubit which evolution is controlled by microwave pulses. Besides, it couples to the cavity field via optical photon exchange. In their turn, neighbor cavities are coupled to each other through the photon hopping to form a bus waveguide mode. This waveguide mode overlaps with all NV-centers. Entanglement between distant centers is organized by appropriate tuning of their optical frequency relative to the waveguide frequ…
Single-molecule nuclear magnetic resonance (NMR) is a crown-jewel challenge in the field of magnetic resonance spectroscopy and has important applications in chemical analysis and in quantum computing. Recently, it becomes possible to tackle this grand challenge thanks to experimental advances in preserving quantum coherence of nitrogen-vacancy (NV) center spins in diamond as a sensitive probe and theoretical proposals on atomic-scale magnetometry via dynamical decoupling control. Through decoherence measurement of NV centers under dynamical decoupling control, sensing of single $^{13}\textbf{…
We present a combined theoretical and experimental study of solid-state spin decoherence in an electronic spin bath, focusing specifically on ensembles of nitrogen vacancy (NV) color centers in diamond and the associated substitutional nitrogen spin bath. We perform measurements of NV spin free induction decay times $T_2^*$ and spin-echo coherence times $T_2$ in 25 diamond samples with nitrogen concentrations [N] ranging from 0.01 to 300\,ppm. We introduce a microscopic model and perform numerical simulations to quantitatively explain the degradation of both $T_2^*$ and $T_2$ over four orders …
A First-principles Computational Framework for Quantum Decoherence in Complex Diamond Spin Environments
Sungkyunkwan University（成均馆大学）；Ajou University（亚洲大学）；University of Chicago（芝加哥大学）；Korea Institute of Science and Technology（韩国科学技术院）；Korean Research Institute of Standards and Science（韩国计量科学研究院）；Ulm University（乌尔姆大学）；Korea University of Science and Technology（韩国科学技术院）；Argonne National Laboratory（阿贡国家实验室）
We review results on evaluation of loss of information in quantum registers due to their interactions with the environment. It is demonstrated that an optimal measure of the level of quantum noise effects can be introduced via the maximal absolute eigenvalue norm of deviation of the density matrix of a quantum register from that of ideal, noiseless dynamics. For a semiconductor quantum dot charge qubits interacting with acoustic phonons, explicit expressions for this measure are derived. For a broad class of environmental modes, this measure is shown to have the property that for small levels …
In idealized models of a quantum register and its environment, quantum information can be stored indefinitely by encoding it into a decoherence-free subspace (DFS). Nevertheless, perturbations to the idealized register-environment coupling will cause decoherence in any realistic setting. Expanding a measure for state preservation, the dynamical fidelity, in powers of the strength of the perturbations, we prove stability to linear order is a generic property of quantum state evolution. The effect of noise perturbation is quantified by a concise expression for the strength of the quadratic, lead…
Coherently coupled pairs or multimers of nitrogen-vacancy defect electron spins in diamond have many promising applications especially in quantum information processing (QIP) but also in nanoscale sensing applications. Scalable registers of spin qubits are essential to the progress of QIP. Ion implantation is the only known technique able to produce defect pairs close enough to allow spin coupling via dipolar interaction. Although several competing methods have been proposed to increase the resulting resolution of ion implantation, the reliable creation of working registers is still to be demo…
Ionized nitrogen molecules ($^{15}$N$_{2}^+$) are used as efficient point sources for creating NV$^-$ pairs in diamond with nanoscale spatial separation and up to 55 kHz magnetic coupling strength. Co-implantation of $^{12}$C$^+$ increased the yield of pairs, and a $^{13}$C-depleted diamond allowed 0.65 ms coherence times to be obtained. Further coupling to a third dark spin provided a strongly coupled three spin register. These results mark an important step towards realization of multi-qubit systems and scalable NV$^-$ quantum registers.
We theoretically study the decoherence and the dynamical decoupling control of nitrogen-vacancy center electron spins in high-purity diamond, where the hyperfine interaction with $^{13}$C nuclear spins is the dominating decoherence mechanism. The decoherence is formulated as the entanglement between the electron spin and the nuclear spins, which is induced by nuclear spin bath evolution conditioned on the electron spin state. The nuclear spin bath evolution is driven by elementary processes such as single spin precession and pairwise flip-flops. The importance of different elementary processes…
Dressed spin states, a spin coupling to continuous radiation fields, can fundamentally change how a spin responds to magnetic fluctuations. Using dressed spin states, we were able to protect an electron spin in diamond from decoherence. Dressing a spin with resonant microwaves at a coupling rate near 1 MHz leads to a 50 times reduction in the linewidth of the spin transition, limited by transit-time broadening. The spin decoherence and the energy level structure of the dressed states were probed with optical coherent-population-trapping processes. Compared with dynamical decoupling, where effe…
Magnetic resonance techniques provide a powerful tool for controlling spin systems, with applications ranging from quantum information processing to medical imaging. Nevertheless, the behavior of a spin system under strong excitation remains a rich dynamical problem. In this paper, we examine spin resonance of the nitrogen-vacancy center in diamond under conditions outside the regime where the usual rotating wave approximation applies, focusing on effects of multifrequency excitation and excitation with orientation parallel to the spin quantization axis. Strong-field phenomena such as multipho…
Decoherence of quantum objects in noisy environments is important in quantum sciences and technologies. It is generally believed that different processes coupled to the same noise source should have similar decoherence behaviors and stronger noises would cause faster decoherence. Here we show that in a quantum bath, the case can be the opposite. In particular, we predict that the multi-transition of a nitrogen-vacancy center spin-1 in diamond can have longer coherence time than the single-transitions, even though the former suffers twice stronger noises from the nuclear spin bath than the latt…
