Hyperbolic Metamaterials via Hierarchical Block Copolymer Nanostructures
I. Murataj, M. Channab, E. Cara, C. F. Pirri, L. Boarino, A. Angelini, F. Ferrarese Lupi
备注:
This is the pre-peer reviewed version of the following article: I. Murataj et al. Adv. Optical Mater. 2021, 2001933, which has been published in final form at https://doi.org/10.1002/adom.202001933. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions
Hyperbolic metamaterials (HMMs) offer unconventional properties in the field of optics, enabling opportunities for confinement and propagation of light at the nanoscale. In-plane orientation of the optical axis, in the direction coinciding with the anisotropy of the HMMs, is desirable for a variety of novel applications in nanophotonics and imaging. Here, a method for creating localized HMMs with in-plane optical axis, based on block copolymer (BCP) blend instability, is introduced. The dewetting of BCP thin film over topographically defined substrates generates droplets composed of highly ordered lamellar nanostructures in hierarchical configuration. The hierarchical nanostructures represent a valuable platform for the subsequent pattern transfer into a Au/air HMM, exhibiting hyperbolic behavior in a broad wavelength range in the visible spectrum. A computed Purcell factor as high as 32 at 580 nm supports the strong reduction in the fluorescence lifetime of defects in nanodiamonds placed on top of the HMM.
Nanostructured submicron block copolymer dots by sacrificial stamping: a potential preconcentration platform for locally resolved sensing, chemistry and cellular interactions
Ultrafast excitation of Bloch plasmon polaritons in hyperbolic metamaterials with an extreme ultra-violet transient grating
Umeå University(于默奥大学);Elettra Sincrotrone Trieste(的里雅斯特同步辐射中心);CIC nanoGUNE BRTA(nanoGUNE研究中心);Ikerbasque, Basque Foundation for Science(伊卡巴斯克,巴斯克科学基金会);Università degli Studi di Modena e Reggio Emilia(摩德纳和雷焦艾米利亚大学);Wallenberg Initiative Materials Science for Sustainability(瓦伦堡可持续材料科学倡议)
Surface Exciton Polaritons and Near-Zero Permittivity Surface Waves Supported by Artificial Organic Hyperbolic Metamaterials
CINBIO, Universidade de Vigo(维戈大学);Centro de Física das Universidades do Minho e do Porto (CF-UM-UP), Universidade do Minho(米尼奥大学与波尔图大学物理中心);International Iberian Nanotechnology Laboratory (INL)(伊比利亚纳米技术国际实验室);Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC)(马德里材料科学研究所,西班牙高等科学研究理事会);ALBA Synchrotron Light Source(阿尔巴同步辐射光源)