arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 2103.04773cond-mat.mtrl-sciphysics.optics
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基于多级嵌段共聚物纳米结构的双曲型超材料

Hyperbolic Metamaterials via Hierarchical Block Copolymer Nanostructures

I. Murataj, M. Channab, E. Cara, C. F. Pirri, L. Boarino, A. Angelini, F. Ferrarese Lupi

摘要:

双曲型超材料(Hyperbolic Metamaterials,简称HAMTS)在光学领域提供了非传统的特性,使光在纳米尺度上的限制和传播成为可能。光轴的面内取向,在与各向异性的阻碍一致的方向上,是纳米光子学和成像中的各种新的应用所期望的。本文介绍了一种基于嵌段共聚物(BCP)共混物不稳定性的面内光轴局域化全息图的制作方法。BCP薄膜在形貌限定的基底上的去湿产生由高度有序的层状纳米结构以分级结构组成的液滴。分层纳米结构代表了一个有价值的平台,用于随后的图案转移到金/空气HMM,在可见光谱中的宽波长范围内表现出双曲线行为。在580 nm处高达32的计算的Purcell因子支持放置在HMM顶部的纳米金刚石中的缺陷的荧光寿命的强烈减少。

英文摘要:

Hyperbolic metamaterials (HMMs) offer unconventional properties in the field of optics, enabling opportunities for confinement and propagation of light at the nanoscale. In-plane orientation of the optical axis, in the direction coinciding with the anisotropy of the HMMs, is desirable for a variety of novel applications in nanophotonics and imaging. Here, a method for creating localized HMMs with in-plane optical axis, based on block copolymer (BCP) blend instability, is introduced. The dewetting of BCP thin film over topographically defined substrates generates droplets composed of highly ordered lamellar nanostructures in hierarchical configuration. The hierarchical nanostructures represent a valuable platform for the subsequent pattern transfer into a Au/air HMM, exhibiting hyperbolic behavior in a broad wavelength range in the visible spectrum. A computed Purcell factor as high as 32 at 580 nm supports the strong reduction in the fluorescence lifetime of defects in nanodiamonds placed on top of the HMM.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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