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arXiv 2102.11692cond-mat.stat-mech
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渗流阈值下多孔介质中渗透和反应的时增率

Time increasing rates of infiltration and reaction in porous media at the percolation thresholds

Ismael S. S. Carrasco, Fábio D. A. Aarão Reis

摘要:

溶质在分形多孔介质中的渗透通常是异常的,但溶质与材料的化学反应可能会增加孔隙度并影响渗透的演变。我们研究这个问题在二维和三维晶格随机分布的多孔网站在临界渗流阈值和边界接触的侵略性溶质的水库。溶质通过扩散渗透该介质,并且与不可渗透位点的反应以$r$的概率产生新的多孔位点,该概率与晶格位点尺度下的反应速率和扩散速率的比率成比例。$r\ll1$的数值模拟显示初始亚扩散缩放和长时间的Fickean缩放的渗透体积或面积,但随着时间的推移,渗透和反应的速率增加的中间制度。初始政权的异常指数同意以前应用于无限分歧分形的关系。我们开发了一个缩放的方法,解释了随后的时间增加的渗透率,这个速率的依赖于$r$,和交叉的Fickean制度。标度关系的指数依赖于临界渗流团簇的分形维数和这些团簇中随机游动的维数。反应速率的时间增加也通过该推理得到证明。随着$r$减小,中间状态的时间十年数增加,这表明在缓慢反应系统中更可能观察到时间增加速率。

英文摘要:

The infiltration of a solute in a fractal porous medium is usually anomalous, but chemical reactions of the solute and that material may increase the porosity and affect the evolution of the infiltration. We study this problem in two- and three-dimensional lattices with randomly distributed porous sites at the critical percolation thresholds and with a border in contact with a reservoir of an aggressive solute. The solute infiltrates that medium by diffusion and the reactions with the impermeable sites produce new porous sites with a probability $r$, which is proportional to the ratio of reaction and diffusion rates at the scale of a lattice site. Numerical simulations for $r\ll1$ show initial subdiffusive scaling and long time Fickean scaling of the infiltrated volumes or areas, but with an intermediate regime with time increasing rates of infiltration and reaction. The anomalous exponent of the initial regime agrees with a relation previously applied to infinitely ramified fractals. We develop a scaling approach that explains the subsequent time increase of the infiltration rate, the dependence of this rate on $r$, and the crossover to the Fickean regime. The exponents of the scaling relations depend on the fractal dimensions of the critical percolation clusters and on the dimensions of random walks in those clusters. The time increase of the reaction rate is also justified by that reasoning. As $r$ decreases, there is an increase in the number of time decades of the intermediate regime, which suggests that the time increasing rates are more likely to be observed is slowly reacting systems.

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