Subsequent to the Moon's formation, late accretion to the terrestrial planets strongly modified the physical and chemical nature of silicate crusts and mantles. This alteration came in the form of melting through impacts, as well as the belated addition of volatiles and the highly siderophile elements (HSEs). Current debate centres on whether the lunar HSE record is representative of its whole late accretion history or alternatively that these were only retained in the mantle and crust after a particular time, and if so, when. Here we employ improved Monte Carlo impact simulations of late accretion onto the Moon and Mars and present an updated chronology based on new dynamical simulations of leftover planetesimals and the E-belt. We take into account the inefficient retention of colliding material. We compute the crater and basin densities on the Moon and Mars, the largest objects to strike these planets and the amount of material they accreted. Outputs are used to infer the mass in leftover planetesimals at a particular time period, which is then compared to the lunar HSE abundance. From this estimate we calculate a preferred lunar HSE retention age of ca. 4450 Ma which means that the modelled lunar mantle HSE abundances trace almost all of lunar late accretion. Based on our results, the surface ages of the lunar highlands are at least 4370 Ma. We find that the mass of leftover planetesimals with diameters Di<300 km at 4500 Ma that best fits the crater chronology is approximately 2x10^{-3} Earth mass (ME) while the mass of the E-belt was fixed at 4.5x10^{-4} ME. We also find that a leftover planetesimal mass in excess of 0.01 ME results in a lunar HSE retention age younger than major episodes of lunar differentiation and crust formation, which in turn violates geochemical constraints for the timing and intensity of late accretion to the Earth (Mojzsis et al., 2019).
Highly siderophile elements (HSEs) are strongly depleted in the bulk silicate Earth (BSE) but are present in near-chondritic relative abundances. The conventional explanation is that the HSEs were stripped from the mantle by the segregation of metal during core formation but were added back in near-chondritic proportions by late accretion, after core formation had ceased. Here we show that metal-silicate equilibration and segregation during Earth's core formation actually increased HSE mantle concentrations because HSE partition coefficients are relatively low at the high pressures of core for…
According to the generally accepted scenario, the last giant impact on the Earth formed the Moon and initiated the final phase of core formation by melting the Earth's mantle. A key goal of geochemistry is to date this event, but different ages have been proposed. Some argue for an early Moon-forming event, approximately 30 million years (Myr) after the condensation of the first solids in the Solar System, whereas others claim a date later than 50 Myr (and possibly as late as around 100 My) after condensation. Here we show that a Moon-forming event at 40 Myr after condensation, or earlier, is …
The efficient delivery of highly-siderophile elements to the core creates a mass accretion catastrophe for the Earth
Institute of Astronomy, University of Cambridge（剑桥大学天文学研究所）；Université de Paris, Institut de Physique du Globe de Paris, CNRS（巴黎大学巴黎地球物理学院，法国国家科学研究中心）；Imperial College London（伦敦帝国理工学院）；Department of Earth Sciences, University of Cambridge（剑桥大学地球科学系）
The Moon is known to have a small liquid core, and it is thought that in the distant past the core may have produced strong magnetic fields recorded in lunar samples. Here we implement a numerical model of lunar orbital and rotational dynamics that includes the effects of a liquid core. In agreement with previous work, we find that the lunar core is dynamically decoupled from the lunar mantle, and that this decoupling happened very early in lunar history. Our model predicts that the lunar core rotates sub-synchronously, and the difference between the core and the mantle rotational rates was si…
The Chang'E 5 (CE-5) samples represent the youngest mare basalt ever known and provide an access into the late lunar evolution. Recent studies have revealed that CE-5 basalts are the most evolved lunar basalt, yet controversy remains over the nature of their mantle sources. Here we combine Fe and Mg isotope analyses with a comprehensive study of petrology and mineralogy on two CE-5 basalt clasts. These two clasts have a very low Mg# (~29) and show similar Mg isotope compositions with Apollo low-Ti mare basalts as well as intermediate TiO2 and Fe isotope compositions between low-Ti and high-Ti …
Once the terrestrial planets had mostly completed their assembly, bombardment continued by planetesimals left-over from accretion. Highly siderophile element (HSE) abundances in Mars' mantle imply its late accretion supplement was 0.8 wt.%; Earth and the Moon obtained an additional 0.7 wt.% and 0.02 wt.%, respectively. The disproportionately high Earth/Moon accretion ratio is explicable by stochastic addition of a few remaining Ceres-sized bodies that preferentially targeted Earth. Here we show that Mars' late accretion budget also requires a colossal impact, a plausible visible remnant of whi…
The timeline of the lunar bombardment in the first Gy of the Solar System remains unclear. Some basin-forming impacts occurred 3.9-3.7Gy ago. Many other basins formed before, but their exact ages are not precisely known. There are two possible interpretations of the data: in the cataclysm scenario there was a surge in the impact rate approximately 3.9Gy ago, while in the accretion tail scenario the lunar bombardment declined since the era of planet formation and the latest basins formed in its tail-end. Here, we revisit the work of Morbidelli et al.(2012) that examined which scenario could be …
Lunar laser ranging (LLR) data and Apollo seismic data analyses, revealed independent evidence for the presence of a fluid lunar core. However, the size of the lunar fluid core remained uncertain by $\pm55$ km (encompassing two contrasting 2011 Apollo seismic data analyses). Here we show that a new description of the lunar interior's dynamical model provides a determination of the radius and geometry of the lunar core-mantle boundary (CMB) from the LLR observations. We compare the present-day lunar core oblateness obtained from LLR analysis with the expected hydrostatic model values, over a ra…
The presence of highly siderophile elements in Earth's mantle indicates that a small percentage of Earth's mass was delivered after the last giant impact in a stage of 'late accretion.' There is ongoing debate about the nature of late-accreted material and the sizes of late-accreted bodies. Earth appears isotopically most similar to enstatite chondrites and achondrites. It has been suggested that late accretion must have been dominated by enstatite-like bodies that originated in the inner disk, rather than ordinary or carbonaceous chondrites. Here, we examine the provenances of 'leftover' plan…
Overabundances in highly siderophile elements (HSEs) of Earth's mantle can be explained by conveyance from a singular, immense (3000 km in a diameter) "Late Veneer" impactor of chondritic composition, subsequent to lunar formation and terrestrial core-closure. Such rocky objects of approximately lunar mass (about 0.01 M_E) ought to be differentiated, such that nearly all of their HSE payload is sequestered into iron cores. Here, we analyze the mechanical and chemical fate of the core of such a Late Veneer impactor, and trace how its HSEs are suspended - and thus pollute - the mantle. For the s…
The importance of highly siderophile elements (HSEs) to track planetary late accretion has long been recognized. However, the precise nature of the Moon's accretional history remains enigmatic. There exists a significant mismatch of HSE budgets between the Earth and Moon, with the Earth disproportionally accreted far more HSEs than the Moon did. Several scenarios have been proposed to explain this conundrum, including the delivery of HSEs to Earth by a few big impactors, the accretion of pebble-sized objects on dynamically cold orbits that enhanced the Earth's gravitational focusing factor, an…
Carbon is an essential element for the existence and evolution of life on Earth. Its abundance in Earth's crust and mantle (the Bulk Silicate Earth, BSE) is surprisingly high given that carbon is strongly siderophile (metal-loving) at low pressures and temperatures, and hence should have segregated almost completely into Earth's core during accretion. Estimates of the concentration of carbon in the BSE lie in the range 100-260 ppm and are much higher than expected based on simple models of core-mantle differentiation. Here we show through experiments at the putative conditions of Earth's core …
We use the tidal deformations of the Moon induced by the Earth and the Sun as a tool for studying the inner structure of our satellite. Based on measurements of the degree-two tidal Love numbers k2 and h2 and dissipation coefficients from the GRAIL mission, Lunar Laser Ranging and Laser Altimetry on board of the LRO spacecraft, we perform Monte Carlo samplings for 120,000 possible combinations of thicknesses and viscosities for two classes of the lunar models. The first one includes a uniform core, a low viscosity zone (LVZ) at the core-mantle boundary, a mantle and a crust. The second one has…
We revisit the early evolution of the Moon's bombardment. Our work combines modeling (based on plausible projectile sources and their dynamical decay rates) with constraints from the lunar crater record, radiometric ages of the youngest lunar basins, and the abundance of highly siderophile elements in the lunar crust and mantle. We deduce that the evolution of the impact flux did not decline exponentially over the first billion years of lunar history, but also there was no prominent and "narrow" impact spike some 3.9 Gy ago, unlike that typically envisioned in the lunar cataclysm scenario. Ins…
Terrestrial and lunar rocks share chemical and isotopic similarities in refractory elements, suggestive of a common precursor. By contrast, the marked depletion of volatile elements in lunar rocks together with their enrichment in heavy isotopes compared to Earth s mantle suggests that the Moon underwent evaporative loss of volatiles. However, whether equilibrium prevailed during evaporation, and, if so, at what conditions (temperature, pressure and oxygen fugacity) remain unconstrained. Chromium may shed light on this question, as it has several thermodynamically-stable, oxidised gas species …
Despite its importance to questions of lunar origin, the chemical composition of the Moon is not precisely known. In recent years, however, the isotopic composition of lunar samples has been determined to high precision and found to be indistinguishable from the terrestrial mantle despite widespread isotopic heterogeneity in the Solar System. In the context of the giant-impact hypothesis, this level of isotopic homogeneity can evolve if the proto-lunar disk and post-impact Earth undergo turbulent mixing into a single uniform reservoir while the system is extensively molten and partially vapori…
The concept of Late Veneer has been introduced by the geochemical community to explain the abundance of highly siderophile elements in the Earth's mantle and their chondritic proportions relative to each other. However, in the complex scenario of Earth accretion, involving both planetesimal bombardment and giant impacts from chondritic and differentiated projectiles, it is not obvious what the "Late Veneer" actually corresponds to. In fact, the process of differentiation of the Earth was probably intermittent and there was presumably no well-defined transition between an earlier phase where al…
It is generally accepted that silicate-metal (`rocky') planet formation relies on coagulation from a mixture of sub-Mars sized planetary embryos and (smaller) planetesimals that dynamically emerge from the evolving circum-solar disc in the first few million years of our Solar System. Once the planets have, for the most part, assembled after a giant impact phase, they continue to be bombarded by a multitude of planetesimals left over from accretion. Here we place limits on the mass and evolution of these planetesimals based on constraints from the highly siderophile element (HSE) budget of the …
Recent high-precision measurements of the isotopic composition of lunar rocks demonstrate that the bulk silicate Earth and the Moon show an unexpectedly high degree of similarity. This is inconsistent with one of the primary results of classic dynamical simulations of the widely accepted giant impact model for the formation of the Moon, namely that most of the mass of the Moon originates from the impactor, not Earth. Resolution of this discrepancy without changing the main premises of the giant impact model requires total isotopic homogenisation of Earth and impactor material after the impact …
Subsequent to the Moon's formation, late accretion to the terrestrial planets modified their silicate crusts and mantles. We combine dynamical N-body and Monte Carlo simulations to determine impact probabilities, impact velocities, and expected mass augmentation onto the terrestrial planets from three sources: planetesimals left over from primary accretion, asteroids from the E-belt, and comets arriving from the outer Solar System. We present estimates of the amount of cometary material striking the terrestrial planets in an early episode of planetesimal-driven giant planet migration (Mojzsis …
The giant impact hypothesis remains the leading theory for lunar origin. However, current models struggle to explain the Moon's composition and isotopic similarity with Earth. Here we present a new lunar origin model. High-energy, high-angular momentum giant impacts can create a post-impact structure that exceeds the corotation limit (CoRoL), which defines the hottest thermal state and angular momentum possible for a corotating body. In a typical super-CoRoL body, traditional definitions of mantle, atmosphere and disk are not appropriate, and the body forms a new type of planetary structure, n…
The giant impact hypothesis for Moon formation successfully explains the dynamic properties of the Earth-Moon system but remains challenged by the similarity of isotopic fingerprints of the terrestrial and lunar mantles. Moreover, recent geochemical evidence suggests that the Earth's mantle preserves ancient (or "primordial") heterogeneity that predates the Moon-forming giant impact. Using a new hydrodynamical method, we here show that Moon-forming giant impacts lead to a stratified starting condition for the evolution of the terrestrial mantle. The upper layer of the Earth is compositionally …
Analyses of Lunar Laser Ranging data show that the spin-symmetry axis of the Moon is ahead of its expected Cassini state by an angle of $ϕ_p$ = 0.27 arcsec. This indicates the presence of one or more dissipation mechanisms acting on the lunar rotation. A combination of solid-body tides and viscous core-mantle coupling have been proposed in previous studies. Here, we investigate whether viscoelastic deformation within a solid inner core at the centre of the Moon can also account for a part of the observed phase lead angle $ϕ_p$. We build a rotational dynamic model of the Cassini state of the Mo…
The aim of this work is to combine the model of orbital and rotational motion of the Moon developed for DE430 with up-to-date astronomical, geodynamical, and geo- and selenophysical models. The parameters of the orbit and physical libration are determined in this work from LLR observations made at different observatories in 1970-2013. Parameters of other models are taken from solutions that were obtained independently from LLR. A new implementation of the DE430 lunar model, including the liquid core equations, was done within the EPM ephemeris. The postfit residuals of LLR observations make ev…
Composition of terrestrial planets records planetary accretion, core-mantle and crust-mantle differentiation, and surface processes. Here we compare the compositional models of Earth and Mars to reveal their characteristics and formation processes. Earth and Mars are equally enriched in refractory elements (1.9 $\times$ CI), although Earth is more volatile-depleted and less oxidized than Mars. Their chemical compositions were established by nebular fractionation, with negligible contributions from post-accretionary losses of moderately volatile elements. The degree of planetary volatile elemen…
The spin axes of the mantle, fluid core and solid inner core of the Moon precess at frequency $Ω_p=2π/18.6$ yr$^{-1}$ though with different orientations, leading to viscous friction at the core-mantle boundary (CMB) and inner core boundary (ICB). Here, we use a rotational model of the Moon with a range of inner core and outer core radii to investigate the relative importance of viscous dissipation at the CMB and ICB, and to show how this dissipation is connected to the phase lead angle ($ϕ_p$) of the mantle ahead of its Cassini state. We show that when the inner core radius is $>80$ km and the…
The final stage of terrestrial planet formation consists of the cleanup of residual planetesimals after the giant impact phase. Dynamically, a residual planetesimal population is needed to damp the high eccentricities of the terrestrial planets after the giant impact stage. Geochemically, highly siderophile element (HSE) abundance patterns inferred for the terrestrial planets and the Moon suggest that a total of about 0.01 M_Earth of chondritic material was delivered as `late veneer' by planetesimals to the terrestrial planets after the end of giant impacts. Here we combine these two independe…
Impacts that leave the Earth-Moon system with a large excess in angular momentum have recently been advocated as a means of generating a protolunar disc with a composition that is nearly identical to that of the Earth's mantle. We here investigate the accretion of the Moon from discs generated by such "non-canonical" impacts, which are typically more compact than discs produced by canonical impacts and have a higher fraction of their mass initially located inside the Roche limit. Our model predicts a similar overall accretional history for both canonical and non-canonical discs, with the Moon …
Given their tendency to be incorporated into the core during differentiation, the highly-siderophile elements (HSEs) in Earth's mantle are thought to have been accreted as a `late veneer' after the end of the giant impact phase. Bottke et al (2010) proposed that the large Earth-to-Moon HSE abundance ratio can be explained if the late veneer was characterized by large (D = 1000-4000km) impactors. Here we simulate the evolution of the terrestrial planets during a stochastic late veneer phase from the end of accretion until the start of the late heavy bombardment ~500 Myr later. We show that a la…
