We consider thermal relaxation process of a quantum system attached to a single or multiple reservoirs. Quantifying the degree of irreversibility by entropy production, we prove that the irreversibility of the thermal relaxation is lower-bounded by a relative entropy between the unitarily-evolved state and the final state. The bound characterizes the state discrepancy induced by the non-unitary dynamics, thus reflecting the dissipative nature of irreversibility. Intriguingly, the bound can be evaluated solely in terms of the initial and final states and the system Hamiltonian; hence, providing a feasible way to estimate entropy production without prior knowledge of the underlying coupling structure. Our finding refines the second law of thermodynamics and reveals a universal feature of thermal relaxation processes.
We establish that entropy production, which is crucial to the characterization of thermodynamic irreversibility, is obtained through a variational principle involving the Kulback-Leibler divergence. A simple application of this representation leads to an information-theoretical bound on entropy production in thermal relaxation processes; this is a stronger inequality than the conventional second law of thermodynamics. This bound is also interpreted as a constraint on the possible path of a thermal relaxation process in terms of information geometry. Our results reveal a hidden universal law in…
Some general aspects of nonlinear transport phenomena are discussed on the basis of two kinds of formulations obtained by extending Kubo's perturbational scheme of the density matrix and Zubarev's non-equilibrium statistical operator formulation. Both formulations are extended up to infinite order of an external force in compact forms and their relationship is clarified through a direct transformation.
*First-principles derivation of the entropy production in erectric static conduction. *The second-order (symmetric) density matrix contributes to the entropy production. *New schemes of steady states formulated using a relaxation-type von Neumann equation. *Stationary temperature is introduced to characterize steady states. *The mechanism of the entropy production in steady states is also clarified.
We discuss the non-equilibrium properties of a thermally driven micromachine consisting of three spheres which are in equilibrium with independent heat baths characterized by different temperatures. Within the framework of a linear stochastic Langevin description, we calculate the time-dependent average irreversibility that takes a maximum value for a finite time. This time scale is roughly set by the spring relaxation time. The steady-state average entropy production rate is obtained in terms of the temperatures and the friction coefficients of the spheres. The average entropy production rate…
We argue that two distinct probes of quantum chaos, i.e., the growth of noncommutativity of two unequal-time operators and the degree of irreversibility in a time-reversal test, are equivalent for initially localized states. We confirm this for interacting nonintegrable many-body systems and a quantum kicked rotor. Our results show that three-point out-of-time-ordered correlators dominate the growth of the squared commutator for initially localized states, in stark contrast to four-point out-of-time-ordered correlators that have extensively been studied for thermal initial states.
In this paper, the emergence of macroscopic-scale pseudo time-irreversibility is studied in the closed classical many-body system of pair interacting particles. First, exact continuum equations are derived to the Hamiltonian dynamics without the utilisation of statistical mechanics. Next, it is shown that the momentum density field incorporates the thermal degrees of freedom in the considered scaling limit, and therefore initial condition indicated pseudo time-irreversible solutions may exist to the dynamical equations. Numerical evidence for pseudo-irreversible thermal equilibration, heat and…
We consider a Brownian particle which, in addition to being in contact with a thermal bath, is driven by fluctuating forces which stem from active processes in the system, such as self-propulsion or collisions with other active particles. These active fluctuations do not fulfill a fluctuation-dissipation relation and therefore play the role of a non-equilibrium environment, which keeps the system permanently out of thermal equilibrium even in the absence of external forces. We investigate how the out-of-equilibrium character of the active matter system and the associated irreversibility is ref…
It is known that each single typical pure state in an energy shell of a large isolated quantum system well represents a thermal equilibrium state of the system. We show that such typicality holds also for nonequilibrium steady states (NESS's). We consider a small quantum system coupled to multiple infinite reservoirs. In the long run, the total system reaches a unique NESS. We identify a large Hilbert space from which pure states of the system are to be sampled randomly and show that the typical pure states well describe the NESS. We also point out that the irreversible relaxation to the uniqu…
In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation between the irreversibility and the entropy production starting from the deterministic equations of motion of the whole system consisting of a physical system and a surrounding thermal environment. The physical system is driven by a nonconservative force. The derivation assumes the Markov approximation that the environmental degrees of freedom equilibrate ins…
There are few exact results on optimal power conditions for a thermoelectric generator in the presence of both external and internal irreversibilities---modelled as non-ideal thermal contacts and Joule heating, respectively. Simplified cases, where only one kind of irreversibility is assumed, yield some well-known expressions for efficiency at maximum power (EMP), such as Curzon-Ahlborn efficiency for endoreversible model. In this work, we analyze situations under the simultaneous presence of internal and external irreversibilities. To simplify, we neglect heat leaks, and each kind of irrevers…
Developments in the thermodynamics of small quantum systems envisage non-classical thermal machines. In this scenario, energy fluctuations play a relevant role in the description of irreversibility. We experimentally implement a quantum heat engine based on a spin-1/2 system and nuclear magnetic resonance techniques. Irreversibility at microscope scale is fully characterized by the assessment of energy fluctuations associated with the work and heat flows. We also investigate the efficiency lag related to the entropy production at finite time. The implemented heat engine operates in a regime wh…
We provide an overview of our numerical and analytical studies of isolated interacting quantum systems that are quenched out of equilibrium instantaneously. We describe the relaxation process to a new equilibrium and obtain lower bounds for the relaxation time of full random matrices and realistic systems with two-body interactions. We show that the size of the time fluctuations after relaxation decays exponentially with system size for systems without too many degeneracies. We also discuss the conditions for thermalization and demonstrate that it can happen after local and global quenches in …
We study the validity of the eigenstate thermalization hypothesis (ETH) and its role for the occurrence of initial-state independent (ISI) equilibration in closed quantum many-body systems. Using the concept of dynamical typicality, we present an extensive numerical analysis of energy exchange in integrable and nonintegrable spin-1/2 systems of large size outside the range of exact diagonalization. In case of nonintegrable systems, our finite-size scaling shows that the ETH becomes valid in the thermodynamic limit and can serve as the underlying mechanism for ISI equilibration. In case of inte…
I formulate a quantum stochastic thermodynamics for the quantum trajectories of a continuously-monitored forced harmonic oscillator coupled to a thermal reservoir. Consistent trajectory-dependent definitions are introduced for work, heat, and entropy, through engineering the thermal reservoir from a sequence of two-level systems. Within this formalism the connection between irreversibility and entropy production is analyzed and confirmed by proving a detailed fluctuation theorem for quantum trajectories. Finally, possible experimental verifications are discussed.
Dense Rydberg gases are out-of-equilibrium systems where strong density-density interactions give rise to effective kinetic constraints. They cause dynamic arrest associated with highly-constrained many-body configurations, leading to slow relaxation and glassy behavior. Multi-component Rydberg gases feature additional long-range interactions such as excitation-exchange. These are analogous to particle swaps used to artificially accelerate relaxation in simulations of atomistic models of classical glass formers. In Rydberg gases, however, swaps are real physical processes, which provide dynami…
Breather stability and longevity in thermally relaxing nonlinear arrays depend sensitively on their interactions with other excitations. We review the relaxation of breathers in Fermi-Pasta-Ulam arrays, with a specific focus on the different relaxation channels and their dependence on the interparticle interactions, dimensionality, initial condition, and system parameters.
Microscopic Dynamical Entropy I: Quantifying Hamiltonian Irreversibility in Large and Small Systems
Wilczek Quantum Center, School of Physics and Astronomy, Shanghai Jiao Tong University（上海交通大学物理与天文学院）；DAMTP, Centre for Mathematical Sciences, University of Cambridge
Quantum stochastic methods based on effective wave functions form a framework for investigating the generally non-Markovian dynamics of a quantum-mechanical system coupled to a bath. They promise to be computationally superior to the master-equation approach, which is numerically expensive for large dimensions of the Hilbert space. Here, we numerically investigate the suitability of a known stochastic Schrödinger equation that is local in time to give a description of thermal relaxation and energy transport. This stochastic Schrödinger equation can be solved with a moderate numerical cost, ind…
The thermal transport properties of a two dimensional Fermi gas are explored, for the full range of temperatures and densities. The heat flux is established by solving the Uehling-Uhlebeck equation using a relaxation approximation given by Marle's collisional kernel and considering the temperature and chemical potential gradients as independent thermodynamic forces. It is shown that the corresponding transport coefficients are proportional to each other, which leads to the possibility of defining a generalized thermal force and a single transport coefficient. The behavior of such conductivity …
In most systems, thermal diffusion is intrinsically slow with respect to mechanical relaxation. We devise here a generic approach to accelerate the relaxation of the temperature field of a 1D object, in order to beat the mechanical time scales. This approach is applied to a micro-meter sized silicon cantilever, locally heated by a laser beam. A tailored driving protocol for the laser power is derived to quickly reach the thermal stationary state. The model is implemented experimentally yielding a significant acceleration of the thermal relaxation, up to a factor 30. An excellent agreement with…
The integral relaxation time for the difference of populations of the two potential wells for double-well classical spin systems is introduced. For the uniaxial symmetry, it is given by a quadrature. Unlike the previously introduced integral relaxation time for the magnetization, the former at low temperatures describes the rate of crossing the barrier under all conditions, including the strongly biased case. In the high-barrier case, the new integral relaxation time approaches the inverse of the lowest eigenvalue of the Fokker-Planck equation. It can be more conveniently found by numerical me…
We study spectral properties and the dynamics after a quench of one-dimensional spinless fermions with short-range interactions and long-range random hopping. We show that a sufficiently fast decay of the hopping term promotes localization effects at finite temperature, which prevents thermalization even if the classical motion is chaotic. For slower decays, we find that thermalization does occur. However, within this model, the latter regime falls in an unexpected universality class, namely, observables exhibit a power-law (as opposed to an exponential) approach to their thermal expectation v…
We consider isolated many-body quantum systems which do not thermalize, i.e., expectation values approach an (approximately) steady longtime limit which disagrees with the microcanonical prediction of equilibrium statistical mechanics. A general analytical theory is worked out for the typical temporal relaxation behavior in such cases. The main prerequisites are initial conditions which appreciably populate many energy levels and do not give rise to significant spatial inhomogeneities on macroscopic scales. The theory explains very well the experimental and numerical findings in a trapped-ion …
We study the dynamics of thermalization resulting from a time-dependent noise in a Quantum Ising Chain subject to a sudden quench of the transverse magnetic field. For weak noise the dynamics shows a pre-thermalized state at intermediate time scales, eventually drifting towards an asymptotic infinite temperature steady state characterized by diffusive behavior. By computing analytically the density of kinks, as well as the transverse and longitudinal magnetic field correlators, we characterize these two regimes, their observability and their signatures in the various physical quantities.
We present numerical and analytical results for the swiching times of magnetic nanoparticles with uniaxial anisotropy at elevated temperatures, including the vicinity of T_c. The consideration is based in the Landau-Lifshitz-Bloch equation that includes the relaxation of the magnetization magnitude M. The resulting switching times are shorter than those following from the naive Landau-Lifshitz equation due to (i) additional barrier lowering because of the reduction of M at the barrier and (ii) critical divergence of the damping parameters.
We investigate the evolution of a system composed of $N$ non-interacting point particles of mass $m$ in a container divided into two chambers by a movable adiabatic piston of mass $M\gg m$. Using a two-time-scale perturbation approach in terms of the small parameter $α=2m/(M+m)$, we show that the evolution towards thermal equilibrium proceeds in two stages. The first stage is a fast, deterministic, adiabatic relaxation towards mechanical equilibrium. The second stage, which takes place at times ${\cal O}(M)$, is a slow fluctuation-driven, diathermic relaxation towards thermal equilibrium. A ve…
We consider the thermal relaxation of a particle in a piecewise-constant potential landscape subject to thermal fluctuations in the overdamped limit. We study the connection between the occurrence of the Mpemba effect, the presence of metastable states, and phase transitions as a function of the potential. We find that the Mpemba effect exists even in cases without metastable states. In the considered physical system, the borders of the areas where the effect happens correspond to either eigenvector changes of direction or to phase transitions. Finally, we discuss the topological aspects of th…
At a composition far above the percolation threshold, the resistance of a composite sample increases with time due to Joule heating as a constant current of sufficiently large value is passed through the sample. If the current is less than a certain breakdown current ($I_b$) the resistance eventually reaches a steady value with a characteristic relaxation time $τ_h$. The latter diverges with current $I$ as $τ_h \sim {(1-I^2/ {I_b}^2)}^{-z}$. The value of the exponent $z$ displays large fluctuations leading to unusual scaling of the relaxation time. Comparisions with behaviour of thermodynamic …
We present a theory that allows us to accurately calculate the distribution functions and the emittance growth of a thermal charged-particle beam after it relaxes to equilibrium. The theory can be used to obtain the fraction of particles, which will evaporate from the beam to form a halo. The calculated emittance growth is found to be in excellent agreement with the simulations.
So far, only the energy thresholds of single discrete breathers in nonlinear Hamiltonian systems have been analytically obtained. In this work, the energy thresholds of discrete breathers in thermal equilibrium and the energy thresholds of long-lived discrete breathers which can remain after a long time relaxation are analytically estimated for nonlinear chains. These energy thresholds are size dependent. The energy thresholds of discrete breathers in thermal equilibrium are same as the previous analytical results for single discrete breathers. The energy thresholds of long-lived discrete brea…
The viscous and thermal relaxation rates of an interacting fermion gas are calculated as functions of temperature and scattering length, using a many-body scattering matrix which incorporates medium effects due to Fermi blocking of intermediate states. These effects are demonstrated to be large close to the transition temperature $T_c$ to the superfluid state. For a homogeneous gas in the unitarity limit, the relaxation rates are increased by nearly an order of magnitude compared to their value obtained in the absence of medium effects due to the Cooper instability at $T_c$. For trapped gases …
We revisit the issue of relaxation to thermal equilibrium in the so-called "sheet model", i.e., particles in one dimension interacting by attractive forces independent of their separation. We show that this relaxation may be very clearly detected and characterized by following the evolution of order parameters defined by appropriately normalized moments of the phase space distribution which probe its entanglement in space and velocity coordinates. For a class of quasi-stationary states which result from the violent relaxation of rectangular waterbag initial conditions, characterized by their v…
Thermal relaxation asymmetry persists under inertial effects
Institute of Physics, University of Freiburg（弗赖堡大学物理研究所）；Mathematical Physics and Stochastic Dynamics, Institute of Physics, University of Freiburg（弗赖堡大学物理学院数学物理与随机动力学）
At thermal equilibrium, the concept of effective central charge for massive deformations of two-dimensional conformal field theories (CFT) is well understood, and can be defined by comparing the partition function of the massive model to that of a CFT. This temperature-dependent effective charge interpolates monotonically between the central charge values corresponding to the IR and UV fixed points at low and high temperatures, respectively. We propose a non-equilibrium, time-dependent generalization of the effective central charge for integrable models after a quantum quench, $c_{\rm eff}(t)$…
