Graphene grain boundaries have attracted interest for their ability to host nearly dispersionless electronic bands and magnetic instabilities. Here, we employ quantum transport and universal conductance fluctuations (UCF) measurements to experimentally demonstrate a spontaneous breaking of time reversal symmetry (TRS) across individual GBs of chemical vapour deposited graphene. While quantum transport across the GBs indicate spin-scattering-induced dephasing, and hence formation of local magnetic moments, below $T\lesssim 4$ K, we observe complete lifting of TRS at high carrier densities ($n \gtrsim 5\times 10^{12}$cm$^{-2}$) and low temperature ($T\lesssim 2$ K). An unprecedented thirty times reduction in the UCF magnitude with increasing doping density further supports the possibility of an emergent frozen magnetic state at the GBs. Our experimental results suggest that realistic GBs of graphene can be a promising resource for new electronic phases and spin-based applications.
It has been proposed that band-inverted electron-hole bilayers support a phase transition from an insulating phase with spontaneously broken time-reversal symmetry to a quantum spin Hall insulator phase as a function of increasing electron and hole densities. Here, we show that in the presence of proximity-induced superconductivity it is possible to realize Majorana zero modes in the time-reversal symmetry broken phase in the absence of magnetic field. We develop an effective low-energy theory for the system in the presence of time-reversal symmetry breaking order parameter to obtain analytica…
We propose a self-consistent scheme for the determination of the ground-state (GS) properties of interacting electrons in a magnetic field, and of systems whose GS's time-reversal-symmetry (TRS) is spontaneously broken. It is based on a newly-developed many-body perturbation theory that is valid, irrespective of the strength of correlation, provided the GS number densities $n_{\uparrow}({\bf r})$, $n_{\downarrow}({\bf r})$, and the {\sl total} paramagnetic particle flux density are pure-state non-interacting $v$-representable. Our approach can in particular be applied to (modulated) two-dimens…
Recently, new strongly interacting phases have been uncovered in mesoscopic systems with chaotic scattering at the boundaries by two of the present authors and R. Shankar. This analysis is reliable when the dimensionless conductance of the system is large, and is nonperturbative in both disorder and interactions. The new phases are the mesoscopic analogue of spontaneous distortions of the Fermi surface induced by interactions in bulk systems and can occur in any Fermi liquid channel with angular momentum $m$. Here we show that the phase with $m$ even has a diamagnetic persistent current (seen …
The band-inverted electron-hole bilayers, such as InAs/GaSb, are an interesting playground for the interplay of quantum spin Hall effect and correlation effects because of the small density of electrons and holes and the relatively small hybridization between the electron and hole bands. It has been proposed that Coulomb interactions lead to a time-reversal symmetry broken phase when the electron and hole densities are tuned from the trivial to the quantum spin Hall insulator regime. We show that the transport properties of the system in the time-reversal symmetry broken phase are consistent w…
Twisted double bilayer graphene (tDBG) comprises two Bernal-stacked bilayer graphene sheets with a twist between them. Gate voltages applied to top and back gates of a tDBG device tune both the flatness and topology of the electronic bands, enabling an unusual level of experimental control. Broken spin/valley symmetry metallic states have been observed in tDBG devices with twist angles $\sim $ 1.2-1.3$^\circ$, but the topologies and order parameters of these states have remained unclear. We report the observation of an anomalous Hall effect in the correlated metal state of tDBG, with hysteresi…
We study the boundary Majorana modes for the single component p-wave weak topological superconductors or superfluids, which form zero energy flat bands protected by time-reversal symmetry in the orbital channel. However, due to the divergence of density of states, the band flatness of the edge Majorana modes is unstable under spontaneously generated spatial variations of Cooper pairing phases. Staggered current loops appear near the boundary and thus time-reversal symmetry is spontaneously broken in the orbital channel. This effect can appear in both condensed matter and ultra-cold atom system…
We extend the coupled-wire construction of quantum Hall phases, and search for fractional topological insulating states in models of weakly coupled wires at zero external magnetic field. Focussing on systems beyond double copies of fractional quantum Hall states at opposite fields, we find that spin-spin interactions can stabilize a large family of fractional topological phases with broken time reversal invariance. The latter is manifest by spontaneous spin polarization, by a finite Hall conductivity, or by both. This suggests the possibility that fractional topological insulators may be unsta…
We report the study of spontaneous magnetization (i.e., spin-polarization) for time-reversal symmetry (TRS)-breaking superconductors with unitary pairing potentials, in the absence of external magnetic fields or Zeeman fields. Spin-singlet ($Δ_s$) and spin-triplet ($Δ_t$) pairings can coexist in superconductors whose crystal structure lacks inversion symmetry. The TRS can be spontaneously broken once a relative phase of $\pmπ/2$ is developed, forming a TRS-breaking unitary pairing state ($Δ_s\pm iΔ_t$). We demonstrate that such unitary pairing could give rise to spontaneous spin-polarization w…
In this work we present a comprehensive study of the spontaneous currents in time-reversal symmetry breaking (TRSB) multi-component superconductors with cubic crystalline symmetry. We argue, not limiting to cubic lattices, that spontaneous current on certain high-symmetry surfaces can exist only if the TRSB pairing simultaneously breaks a certain pair of mirror symmetries. This is shown to have exact correspondence with the Gingzburg-Landau (GL) theory and is verified by numerical Bogoliubov de-Gennes (BdG) calculations. In the course we extend the BdG to include effects of gap anisotropy and …
Using density functional theory calculations and the Greens's function formalism, we report the existence of magnetic edge states with a non-collinear spin texture present on different edges of the 1T' phase of the three monolayer transition metal dichalcogenides (TMDs): MoS$_2$, MoTe$_2$ and WTe$_2$. The magnetic states are gapless and accompanied by a spontaneous breaking of the time-reversal symmetry. This may have an impact on the prospects of utilizing WTe$_2$ as a quantum spin Hall insulator. It has previously been suggested that the topologically protected edge states of the 1T' TMDs co…
We investigate a bilayer system of critical HgTe quantum wells each featuring a spin-degenerate pair of massless Dirac fermions. In the presence of an electrostatic inter-layer Coulomb coupling, we determine the exciton condensate order parameter of the system self-consistently. Calculating the bulk topological $\mathbb Z_2$ invariant of the resulting mean field Hamiltonian, we discover a novel time reversal symmetric topological exciton condensate state coined the helical topological exciton condensate. We argue that this phase can exist for experimentally relevant parameters. Interestingly, …
The unique sensitivity of optical response to different types of symmetry breaking can be used to detect and identify spontaneously ordered many-body states in bilayer graphene. We predict a strong response at optical frequencies, sensitive to electronic phenomena at low energies, which arises because of nonzero inter-band matrix elements of the electric current operator. In particular, the polar Kerr rotation and reflection anisotropy provide fingerprints of the quantum anomalous Hall state and the nematic state, characterized by spontaneously broken time reversal symmetry and lattice rotatio…
Moir{é} superlattice realized in two-dimensional heterostructures offers an exciting platform to access strongly-correlated electronic states. In this work, we study transition metal dichalcogenides (TMD) Moir{é} superlattices with time-reversal-symmetry and nontrivial spin{/valley}-Chern numbers. Utilizing realistic material parameters and the method of exact diagonalization, we find that at a certain twisting angle and fractional filling, gapped fractional topological states, i.e., fractional Chern insulators, are naturally {stabilized} by simply introducing the Coulomb repulsion. In contras…
The off-diagonal components of thermal conductance tensor, thermal Hall conductivities (THCs), have extensively been studied in recent condensed matter experiments to investigate fractionalized quantum spin liquids, and quantum Hall systems. Under zero magnetic field, THCs spontaneously become non-zero for time-reversal symmetry (TRS) broken systems, and can have contributions from topologically protected edge states. Here we focus on an additional bulk effect, the impurity mechanism in TRS broken superconductors. Inspired by $Sr_2 Ru O_4$, the low temperature THC was calculated [Sup. Sci. and…
Both topological crystalline insulators surfaces and graphene host multi-valley massless Dirac fermions which are not pinned to a high-symmetry point of the Brillouin zone. Strain couples to the low-energy electrons as a time-reversal invariant gauge field, leading to the formation of pseudo-Landau levels (PLL). Here we study periodic pseudo-magnetic fields originating from strain superlattices. We study the low-energy Dirac PLL spectrum induced by the strain superlattice and analyze the effect of various polarized states. Through self-consistent Hartree-Fock calculations we establish that, du…
We investigate the properties of spontaneous currents generated at surfaces and interfaces of d-wave superconductors using the self-consistent quasiclassical Eilenberger equations. The influence of the roughness and reflectivity of the boundaries on the spontaneous current are studied. We show that these have very different effects at the surfaces compared to the interfaces, which reflects the different nature of the time reversal symmetry breaking states in these two systems. We find a signature of the ``anomalous proximity effect'' at rough d-wave interfaces. We also show that the existence …
Finite flux of the (time-reversal-symmetric) pseudo-magnetic field, which represents the effect of wrinkling of the graphene sheet for example, is shown to be a catalyst for spontaneous breaking of the time-reversal symmetry of Dirac fermions in two dimensions. Possible experimental consequences of this effect for graphene are discussed.
Chern insulator ferromagnets are characterized by a quantized anomalous Hall effect, and have so far been identified experimentally in magnetically-doped topological insulator (MTI) thin films and in bilayer graphene moir{é} superlattices. We classify Chern insulator ferromagnets as either spin or orbital, depending on whether the orbital magnetization results from spontaneous spin-polarization combined with spin-orbit interactions, as in the MTI case, or directly from spontaneous orbital currents, as in the moir{é} superlattice case. We argue that in a given magnetic state, characterized for …
We report self-consistent quasiclassical calculations of spontaneous currents and magnetic moments in finite size unconventional superconducting systems, namely: (i) in isolated d-wave superconductor islands where, in addition to the dominant order parameter (with a d_{x^2-y^2} symmetry), a subdominant order parameter of s or d_{xy} symmetry is added; (ii) in grain boundary junctions between two arbitrarily oriented d-wave superconductors, and between a d-wave and an s-wave superconductor. We show that the profile of the spontaneous current density and the magnetic field distribution depend on…
We consider the generic problem of a two-level quantum emitter near a two-dimensional Chern insulator in the dipole approximation, and study how the frequency-dependent response and electronic density of states of the insulator modifies the transition rate of the emitter between the ground and excited levels. To this end, we obtain the full real-frequency behavior of the conductivity tensor by performing a tight-binding calculation based on the Qi-Wu-Zhang model and using a Kubo formula, and derive the full electromagnetic Green tensor of the system, which breaks Onsager reciprocity. This enab…
We present an exactly solvable model of a spin-triplet $f$-wave topological superconductor on the honeycomb lattice in the presence of the Hubbard interaction for arbitrary interaction strength. First we show that the Kane-Mele model with the corresponding spin-triplet $f$-wave superconducting pairings becomes a full-gap topological superconductor possessing the time-reversal symmetry. We then introduce the Hubbard interaction. The exactly solvable condition is found to be the emergence of perfect flat bands at zero energy. They generate infinitely many conserved quantities. It is intriguing t…
Due to time-reversal symmetry (TRS), two dimensional topological insulators support counter-propagating helical edge modes. Here we show that, unlike the infinitely sharp edge potential utilized in traditional calculations, an experimentally more realistic smooth edge potential gives rise to edge reconstruction and, consequently, spontaneous TRS breaking. Such edge reconstruction may lead to breaking of the expected perfect conductance quantization, to a finite Hall resistance at zero magnetic field, and to a likely spin current. This calculation underpins the fragility of the topological prot…
We study the electromagnetic response of a chiral ${\rm d_{xy}+id_{x^2-y^2}}$ charge density wave state. Due to parity (${\cal P}$) and time reversal (${\cal T}$) violation, Chern-Simons terms emerge in the effective action of the U(1) gauge field. As a consequence electric and magnetic fields are coupled providing the possibility of observing the Spontaneous Quantum Hall Effect i.e. generation of Hall voltage via the sole application of an electric field. We show how the Chern-Simons terms are induced and discuss the topological origin of the quantization of Hall conductance.
It is shown that a pulsed current driven through Ni nanowires provokes an irreversible magnetization reversal at a field distant from the spontaneous switching field $H_{sw}$ by $ΔH$ of as much as 40 % of $H_{sw}$. The state of the magnetization is assessed by magnetoresistive measurements carried out on single, isolated nanowires. The reversible part of the magnetization follows that of a uniform rotation. The switching occurs between the two states accessible otherwise by normal field ramping. $ΔH$ is studied as a function of the angle between the applied field and the wire, and also of the …
We study theoretically the electron correlation effect in a three-dimensional Dirac fermion system which describes a topologically nontrivial state. It is shown within the mean-field approximation that time-reversal and inversion symmetries of the system are spontaneously broken in the region where both spin-orbit coupling and electron correlation are strong. This phase is considered as an analog of that in the lattice quantum chromodynamics. It is also shown that in the presence of magnetic impurities, electron correlation enhances the appearance of the Weyl semimetal phase between the topolo…
We investigate equilibrium properties, including structure of the order parameter, superflow patterns, and thermodynamics of low-temperature surface phases of layered d_{x^2-y^2}-wave superconductors in magnetic field. At zero external magnetic field, time-reversal symmetry and continuous translational symmetry along the edge are broken spontaneously in a second order phase transition at a temperature $T^*\approx 0.18 T_c$, where $T_c$ is the superconducting transition temperature. At the phase transition there is a jump in the specific heat that scales with the ratio between the edge length $…
Unique properties of a ballistic DND or grain boundary D-D junction, including doubly degenerate ground state with tunable potential barrier between the "up" and "down" states and non-quantized spontaneous magnetic flux, make it a good candidate for a solid state qubit. The role of quantum "spin" variable is played by the sign of equilibrium superconducting phase difference on the junction, which is revealed in the direction of spontaneous supercurrent flow in equilibrium. Possibilities of design-specific simultaneous operations with several integrated qubits are discussed.
Graphene multilayers with flat moiré minibands can exhibit the quantized anomalous Hall effect due to the combined influence of spontaneous valley polarization and topologically non-trival valley-projected bands. The sign of the Hall effect in these Chern insulators can be reversed either by applying an external magnetic field, or by driving a transport current through the system. We propose a current-driven mechanism whereby reversal occurs along lines in the (current $I$, magnetic-field $B$) control parameter space with slope $dI/dB = (e/h)\, M A_{M} \, (1-γ^2)/γ$, where $M$ is the magnetiza…
A boundary between two d-wave superconductors or an s-wave and a d-wave superconductor generally breaks time-reversal symmetry and can generate spontaneous currents due to proximity effect. On the other hand, surfaces and interfaces in d-wave superconductors can produce localized current-carrying states by supporting the T-breaking combination of dominant and subdominant order parameters. We investigate spontaneous currents in the presence of both mechanisms and show that at low temperature, counter-intuitively, the subdominant coupling decreases the amplitude of the spontaneous current due to…
