We analyze Lindblad-Gorini-Kossakowski-Sudarshan-type generators for selected periodically driven open quantum systems. All these generators can be obtained by temporal coarse-graining procedures, and we compare different coarse-graining schemes. Similar as for undriven systems, we find that a dynamically adapted coarse-graining time, effectively yielding non-Markovian dynamics by interpolating through a series of different but invididually Markovian solutions, gives the best results among the different coarse-graining schemes, albeit at highest computational cost.
We present a first-principles derivation of the Markovian semi-group master equation without invoking the rotating wave approximation (RWA). Instead we use a time coarse-graining approach which leaves us with a free timescale parameter, which we can optimize. Comparing this approach to the standard RWA-based Markovian master equation, we find that significantly better agreement is possible using the coarse-graining approach, for a three-level model coupled to a bath of oscillators, whose exact dynamics we can solve for at zero temperature. The model has the important feature that the RWA has a…
The coarse-graining approach to deriving the quantum Markovian master equation is revisited, with close attention given to the underlying approximations. It is further argued that the time interval over which the coarse-graining is performed is a free parameter that can be given a physical measurement-based interpretation. In the case of the damping of composite systems to reservoirs of different temperatures, currently of much interest in the study of quantum thermal machines with regard to the validity of `local' and `global' forms of these equations, the coupling of the subsystems leads to …
This is a derivation of the quantum-optical master equation using coarse-graining of time, which brings new insights into a decades old technique. My derivation is quite similar to derivations using quantum stochastic methods or Kraus operators, though I go through the derivation without explicitly invoking any of these concepts, so it may be easier to follow as an introduction. I also address the major pitfall of nearly all microscopic derivations of the master equation, namely that they assume the state of the system and bath factorize for all times. I show why this assumption actually holds…
We study the coarse-graining approach to derive a generator for the evolution of an open quantum system over a finite time interval. The approach does not require a secular approximation but nevertheless generally leads to a Lindblad-Gorini-Kossakowski-Sudarshan generator. By combining the formalism with Full Counting Statistics, we can demonstrate a consistent thermodynamic framework, once the switching work required for the coupling and decoupling with the reservoir is included. Particularly, we can write the second law in standard form, with the only difference that heat currents must be de…
We compare different quantum Master equations for the time evolution of the reduced density matrix. The widely applied secular approximation (rotating wave approximation) applied in combination with the Born-Markov approximation generates a Lindblad type master equation ensuring for completely positive and stable evolution and is typically well applicable for optical baths. For phonon baths however, the secular approximation is expected to be invalid. The usual Markovian master equation does not generally preserve positivity of the density matrix. As a solution we propose a coarse-graining app…
We formulate an effective-description framework for the dynamics of open quantum systems by extending the time-coarse-graining formalism to open systems. Our coarse-graining procedure efficiently removes high-frequency processes which are responsible for coherences between lower- and upper-manifold states and are irrelevant when considering only low-energy dynamics. We investigate the regime of validity of the resulting coarse-grained master equation by applying it to multi-level atoms driven by far-detuned lasers. Except for such high-frequency coherences, we find good agreement between the e…
The progress in high-precision spectroscopy requires one to verify the accuracy of theoretical models such as the master equation describing spontaneous emission of atoms. For this purpose, we apply the coarse-graining method to derive a master equation of an atom interacting with the modes of the electromagnetic field. This master equation naturally includes terms due to quantum interference in the decay channels and fulfills the requirements of the Lindblad theorem without the need of phenomenological assumptions. We then consider the spectroscopy of the 2S-4P line of atomic Hydrogen and sho…
We present a short derivation and discussion of the master equation for an open quantum system weakly coupled to a heat bath and then its generalization to the case of with periodic external driving based on the Floquet theory. Further, a single heat bath is replaced by several ones. We present also the definition of heat currents which satisfies the second law of thermodynamics and apply the general results to a simple model of periodically modulated qubit.
A central problem in the theory of the dynamics of open quantum systems is the derivation of a rigorous and computationally tractable master equation for the reduced system density matrix. Most generally, the evolution of an open quantum system is described by a completely positive linear map. We show how to derive a completely positive Markovian master equation (the Lindblad equation) from such a map by a coarse graining procedure. We provide a novel and explicit recipe for calculating the coefficients of the master equation, using perturbation theory in the weak-coupling limit. The only para…
A novel scheme to simulate the evolution of a restricted set of observables of a quantum system is proposed. The set comprises the spectrum-generating algebra of the Hamiltonian. The idea is to consider a certain open-system evolution, which can be interpreted as a process of weak measurement of the distinguished observables performed on the evolving system of interest. Given that the observables are "classical" and the Hamiltonian is moderately nonlinear, the open system dynamics displays a large time-scales separation between the dephasing of the observables and the decoherence of the evolvi…
We derive a master equation for a superradiant medium which includes multilevel interference betwen the individual scatterers. The derivation relies on the Born-Markov approximation and implements the coarse graining formalism. The master equation fulfils the Lindblad form and contains terms describing single-atom multilevel interference, multi-atom interference between identical transitions, and multi-atom interference between different electronic transitions with parallel dipoles. This formalism is then applied to determine the excitation spectrum of two emitters using the parameters of the …
We investigate the long-time behavior of quantum N-level systems that are coupled to a Markovian environment and subject to periodic driving. As our main result, we obtain a general algebraic condition ensuring that all solutions of a periodic quantum master equation with Lindblad form approach a unique limit cycle. Quite intuitively, this criterion requires that the dissipative terms of the master equation connect all subspaces of the system Hilbert space during an arbitrarily small fraction of the cycle time. Our results provide a natural extension of Spohn's algebraic condition for the appr…
Master equations are a useful tool to describe the evolution of open quantum systems. In order to characterize the mathematical features and the physical origin of the dynamics, it is often useful to consider different kinds of master equations for the same system. Here, we derive an exact connection between the time-local and the integro-differential descriptions, focusing on the class of commutative dynamics. The use of the damping-basis formalism allows us to devise a general procedure to go from one master equation to the other and vice-versa, by working with functions of time and their La…
Heat transport in driven quantum systems: Comparison between the Floquet-Redfield equation and the master equation in the instantaneous eigenbasis
Aalto University School of Science（阿尔托大学科学学院）；Chalmers University of Technology（查尔姆斯理工大学）；Pritzker School of Molecular Engineering, University of Chicago（芝加哥大学普里茨克分子工程学院）
Optical Bloch Equations (OBE) describe the coherent exchange of energy between a quantum bit (qubit) and a quasi-resonant driving field in the presence of a thermal bath. Despite it being an ubiquitous process in quantum technologies, a sound thermodynamic analysis is still missing. We hereby provide such an analysis, by deriving the relevant framework from first principles. Building on a microscopic model of the bath, we first express heat, work and entropy production for the closed qubit-bath system where these definitions are unambiguous. We coarse-grain the obtained expressions, using a me…
We build quantum field theory on the thermodynamic master equation for dissipative quantum systems. The vacuum is represented by a thermodynamic equilibrium state in the low-temperature limit. All regularization is consistently provided by a friction mechanism; with decreasing friction parameter, only degrees of freedom on shorter and shorter length scales are damped out of a quantum field theory. No divergent integrals need to be manipulated. Renormalization occurs as a tool to refine perturbation expansions, not to remove divergences. Relativistic covariance is recovered in the final results…
Recent experiments show that periodic drives on dipolar systems lead to long-lived prethermal states. These systems are weakly coupled to the environment and reach prethermal states in a timescale much shorter than the timescale for thermalization. Such nearly-closed systems have previously been analyzed using Floquet formalism, which shows the emergence of a prethermal plateau. We use a fluctuation-regulated quantum master equation (FRQME) to describe these systems. In addition to the system-environment coupling, FRQME successfully captures the dissipative effect from the various local intera…
1 First Lecture: Basics 1.1 Physical Derivation of the Master Equation 1.2 Some Simple Implications 1.3 Steady State 1.4 Action to the Left 2 Second Lecture: Eigenvalues and Eigenvectors of L 2.1 A Simple Case First 2.2 The General Case 3 Third Lecture: Completeness of the Damping Bases 3.1 Phase Space Functions 3.2 Completeness of the Eigenvectors of L 3.3 Positivity Conservation 3.4 Lindblad Form of Liouville Operators 4 Fourth Lecture: Quantum-Optical Applications 4.1 Periodically Driven Damped Oscillator 4.2 Conditional and Unconditional Evolution 4.3 Physical Signicance of Statistical Ope…
Here we present a Lindblad master equation that approximates the Redfield equation, a well known master equation derived from first principles, without significantly compromising the range of applicability of the Redfield equation. Instead of full-scale coarse-graining, this approximation only truncates terms in the Redfield equation that average out over a time-scale typical of the quantum system. The first step in this approximation is to properly renormalize the system Hamiltonian, to symmetrize the gains and losses of the state due to the environmental coupling. In the second step, we swap…
For adiabatically and periodically manipulated dissipative quantum systems we derive, using Floquet theory, a simple Markovian master equation. Contrary to some previous works we explicitly take into account the time dependence of the Hamiltonian and, therefore, obtain a master equation with a time-dependent dissipative part. We illustrate our theory with two examples and compare our results with the previously proposed master equations. In particular, we consider the problem of Cooper pair pumping and demonstrate the inadequacy of the secular (rotating wave) approximation when calculating the…
We obtain a master equation for a parametrically driven optomechanical cavity. We use a more correct dissipation model that accounts for the modification of the quasienergy spectrum caused by the driving. When the natural frequency of the mechanical object oscillates periodically around its mean value, the master equation with the improved dissipation model is expressed using Floquet operators. We apply the corresponding master equation to model the laser cooling of the mechanical object. Using an adiabatic approximation, an analytical expression for the number of excitations of the mechanical…
We discuss dynamics of periodically-driven open quantum systems. The time evolution of the quantum state is described by the quantum master equation and the form of the dissipator is chosen so that the instantaneous stationary state is given by the Gibbs distribution. We find that the correlation between the population part and the coherence part of the density operator is induced by an adiabatic gauge potential. Although the introduction of the counterdiabatic term eliminates the correlation, additional correlations prevent a convergence to the Gibbs distribution. We study the performance of …
Memory effects in open quantum dynamics are often incorporated in the equation of motion through a superoperator known as the memory kernel, which encodes how past states affect future dynamics. However, the usual prescription for determining the memory kernel requires information about the underlying system-environment dynamics. Here, by deriving the transfer tensor method from first principles, we show how a memory kernel master equation, for any quantum process, can be entirely expressed in terms of a family of completely positive dynamical maps. These can be reconstructed through quantum p…
We investigate the energy distribution and quantum thermodynamics in periodically driven polaritonic systems in the stationary state at room temperature. Specifically, we consider an exciton strongly coupled to a harmonic oscillator and quantify the energy reorganization between these two systems and their interaction as a function of coupling strength, driving force, and detuning. After deriving the quantum master equation for the polariton density matrix with weak environment interactions, we obtain the dissipative time propagator and the long-time evolution of an equilibrium initial state. …
We apply the master equation with dynamical coarse graining approximation to a pair of detectors interacting with a scalar field. By solving the master equation numerically, we investigate evolution of negativity between comoving detectors in de Sitter space. For the massless conformal scalar field, it is found that a pair of detectors can perceive entanglement beyond the Hubble horizon scale if the initial separation of detectors is sufficiently small. At the same time, violation of the Bell-CHSH inequality on the super horizon scale is also detected. For the massless minimal scalar field, on…
Periodically driven closed quantum many-body systems are known to exhibit prethermal or quasi-steady-state dynamics. In this work, we theoretically show that such prethermal phases can appear in the dynamics of a dipolar two-spin-$1/2$ system coupled to a heat bath if the cross terms between the drive and dipolar interactions are taken into consideration. To this end, we use our recently-reported fluctuation-regulated quantum master equation [A. Chakrabarti and R. Bhattacharyya, Phys. Rev. A 97, 063837 (2018)], to show that the predicted dynamics can successfully explain the experimentally obs…
Using the parametrically driven harmonic oscillator as a working example, we study two different Markovian approaches to the quantum dynamics of a periodically driven system with dissipation. In the simpler approach, the driving enters the master equation for the reduced density operator only in the Hamiltonian term. An improved master equation is achieved by treating the entire driven system within the Floquet formalism and coupling it to the reservoir as a whole. The different ensuing evolution equations are compared in various representations, particularly as Fokker-Planck equations for the…
We study a class of multipartite open quantum dynamics for systems of arbitrary number of qubits. The non-Markovian quantum master equation can involve arbitrary single or multipartite and time-dependent dissipative coupling mechanisms, expressed in terms of strings of Pauli operators. We formulate the general constraints that guarantee the complete positivity of this dynamics. We characterize in detail underlying mechanisms that lead to memory effects, together with properties of the dynamics encoded in the associated system rates. We specifically derive multipartite "eternal" non-Markovian m…
The stroboscopic evolution of a time-periodically driven isolated quantum system can always be described by an effective time-independent Hamiltonian. Whether this concept can be generalized to open Floquet systems, described by a Markovian master equation with time-periodic Lindbladian generator, remains an open question. By using a two level system as a model, we explicitly show the existence of two well-defined parameter regions. In one region the stroboscopic evolution can be described by a Markovian master equation with a time-independent Floquet Lindbladian. In the other it cannot; but h…
Evaluating the time-dependent dynamics of driven open quantum systems is relevant for a theoretical description of many systems, including molecular junctions, quantum dots, cavity-QED experiments, cold atoms experiments and more. Here, we formulate a rigorous microscopic theory of an out-of-equilibrium open quantum system of non-interacting particles on a lattice weakly coupled to multiple baths and driven by periodically varying thermodynamic parameters like temperature and chemical potential of the bath. The particles can be either bosonic or fermionic and the lattice can be of any dimensio…
Floquet engineering of isolated systems is often based on the concept of the effective time-independent Floquet Hamiltonian, which describes the stroboscopic evolution of a periodically driven quantum system in steps of the driving period and which is routinely obtained analytically using high-frequency expansions. The generalization of these concepts to open quantum systems described by a Markovian master equation of Lindblad type turns out to be non-trivial: On the one hand, already for a two-level system two different phases can be distinguished, where the effective time-independent Floquet…
