The phonon Casimir effect describes the phonon-mediated interaction between defects in condensed-matter systems. Using the path-integral formalism, we derive a general method for calculating the Helmholtz free energy due to vibrational modes in systems of arbitrary dimensionality and composition. Our results make it possible to extract the defect interaction energy at any temperature for various defect configurations. We demonstrate our approach in action by performing numerical calculations for mono- and diatomic chains, as well as a diatomic molecule, at zero and finite temperatures and validate our results using exact diagonalization.
Phonon Casimir effect is the long-range interaction between impurities in condensed matter systems, mediated by vacuum fluctuations of the phonon field. For pairs of impurities, this interaction has been shown to follow a quasi-power law at zero-temperature and evolve into an exponentially decaying form as the temperature is increased. This work introduces an approach to deal with systems of more than two impurities, both at zero and finite temperatures.
The thermal conductance of straight and corrugated monocrystalline silicon nanowires has been measured between 0.3 K and 5 K. The difference in the thermal transport between corrugated nanowires and straight ones demonstrates a strong reduction in the mean free path of the phonons. This averaged mean free path is remarkably smaller than the smaller diameter of the nanowire, evidencing a phonon thermal transport reduced below the Casimir limit. Monte Carlo simulations highlight that this effect can be attributed to significant multiple scattering of ballistic phonons occuring on the corrugated …
We discuss computational analysis of phononic thermal conduction in the suspended membrane geometry, in the experimentally commonly appearing case where heat can flow out radially in two dimensions from a central source. As we are mostly interested in the low-temperature behavior where bulk scattering of phonons becomes irrelevant, we study the limit where all phonon scattering takes place at the membrane surfaces. Moreover, we limit the discussion here to the case where this surface scattering is fully diffusive, the so called Casimir limit. Our analysis shows that in the two-dimensional case…
We find the Casimir energy, at finite temperature, for acoustic phonons in a Graphene sheet suspended over a rectangular trench, and the corresponding Casimir forces are interpreted as correction terms to the built-in tensions of the Graphene. We show that these corrections generally break the tensional isotropy of the membrane, and can increase or decrease the membrane tension. We demonstrate that for a narrow rectangular trench with side-lengths in the order of few nanometers and few micrometers, these temperature corrections are expected to be noticeable ($\sim 10^{-4} N/m$) at the room tem…
The natural transition from the radiative regime to the conductive regime of heat transfer between two identical isotropic dielectric solid materials, is questioned by investigating the possibility of induced phonon transfer in vacuum. We describe the process in a general way assuming a certain phonon coupling mechanism between the two identical solids, then we particularly illustrate the case of coupling through Casimir force. We analyze how this mechanism of heat transfer compares and competes with the near field thermal radiation using a local model of the dielectric function. We show that …
By calculating a Casimir energy for the acoustic phonons of Graphene, we find some temperature-dependent corrections for the pretension of a Graphene sheet suspended on a trench. We obtain values of the order of few mN/m for these corrections in fully as well as doubly clamped Graphene on a narrow trench with one nanometer width, at room temperature. These values are considerable compared to the experimental values, and can increase the fundamental resonance frequency of the Graphene. The values of these corrections increase by increasing the temperature, and so they can be utilized for tuning…
In stark contrast with three-dimensional (3D) nanostructures, we show that boundary scattering in two-dimensional (2D) nanoribbons alone does not lead to a finite phonon mean free path. If combined with an intrinsic scattering mechanism, 2D boundary scattering does reduce the overall mean free path, however the latter does not scale proportionally to the ribbon width, unlike the well known Casimir regime occurring in 3D nanowires. We show that boundary scattering can be accounted for by a simple Mathiessen type approach for many different 3D nanowire cross sectional shapes, however this is not…
In a previous publication, we discussed the formalism and some computational results for phononic thermal conduction in the suspended membrane geometry for radial heat flow from a central source, which is a common geometry for some low-temperature detectors, for example. We studied the case where only diffusive surface scattering is present, the so called Casimir limit, which can be experimentally relevant at temperatures below $\sim$ 10 K in typical materials, and even higher for ultrathin samples. Here, we extend our studies to much thinner membranes, obtaining numerical results for geometri…
Van der Waals (vdW) and Casimir interactions depend crucially on material properties and geometry, especially at molecular scales, and temperature can produce noticeable relative shifts in interaction characteristics. Despite this, common treatments of these interactions ignore electromagnetic retardation, atomism, or contributions of collective mechanical vibrations (phonons) to the infrared response, which can interplay with temperature in nontrivial ways. We present a theoretical framework for computing electromagnetic interactions among molecular structures, accounting for their geometry, …
The Casimir force was predicted in 1948 as a force arising between macroscopic bodies from the zero-point energy. At finite temperatures it has been shown that a thermal Casimir force exists due to thermal rather than zero-point energy and there are a growing number of experiments that characterise the effect at a range of temperatures and distances. Additionally, in the rapidly evolving field of cavity optomechanics there is an endeavor to manipulate phonons and enhance coherence. We demonstrate a new way to achieve this through the first observation of Casimir spring and dilution in macrosco…
We study the interaction of two localized impurities in a repulsive one-dimensional Fermi liquid via bosonization. In a previous paper [Phys. Rev. A 72, 023616 (2005)], it was shown that at distances much larger than the interparticle spacing the impurities interact through a Casimir-type force mediated by the zero sound phonons of the underlying quantum liquid. Here we extend these results and show that the strength and sign of this Casimir interaction depend sensitively on the impurities separation. These oscillations in the Casimir interaction have the same period as Friedel oscillations. T…
Isotopic dependence of the Casimir force is key to probing new physics and pushing novel technologies at the micro and nanoscale, but is largely unexplored. In 2002, an isotope effect of 10^(-4) was estimated for metals -- orders of magnitude beyond the experimental resolution. Here, by employing the Lifshitz theory, we reveal a significant isotope effect of over 10^(-1) for polar dielectrics. This effect arises from the isotope-mass-induced line shift of the zone-center optical phonons and is insensitive to the linewidth. We perform numerical analyses on both the imaginary and real-frequency …
Suppressing phonon propagation in nanowires is an essential goal towards achieving efficient thermoelectric devices. Recent experiments have shown unambiguously that surface roughness is a key factor that can reduce the thermal conductivity well below the Casimir limit in thin crystalline silicon nanowires. We use insights gained from the experimental studies to construct a simple analytically tractable model of the phonon-surface roughness interaction that provides a better theoretical understanding of the effects of surface roughness on the thermal conductivity, which could potentially help …
A fundamental prediction of quantum mechanics is that there are random fluctuations everywhere in a vacuum because of the zero-point energy. Remarkably, quantum electromagnetic fluctuations can induce a measurable force between neutral objects, known as the Casimir effect, which has attracted broad interests. The Casimir effect can dominate the interaction between microstructures at small separations and has been utilized to realize nonlinear oscillation, quantum trapping, phonon transfer, and dissipation dilution. However, a non-reciprocal device based on quantum vacuum fluctuations remains a…
Thermal rectification due to phonon confinement in nanoparticles
DLR Institute of Space Research（德国航空航天中心空间研究所）；PTB Berlin（德国联邦物理技术研究院柏林分院）；Physics Department “Aldo Pontremoli”, Università degli Studi di Milano（米兰大学阿尔多·蓬特雷莫利物理系）；Interdisciplinary Centre for Nanostructured Materials and Interfaces (CIMaINa)（纳米结构与界面跨学科中心）
Thermal transport properties of amorphous materials at low temperatures are governed by the interaction between phonons and localized excitations referred to as tunneling two level systems (TLS). The temperature variation of the thermal conductivity of these amorphous materials is considered as universal and is characterized by a quadratic power law. This is well described by the phenomenological TLS model even though its microscopic explanation is still elusive. Here, by scaling down to the nanometer scale amorphous systems much below the bulk phonon-TLS mean free path, we probed the robustne…
Significant progress has been made in recent studies of thermal and thermoelectric transport phenomena in nanostructures and low-dimensional systems. This article reviews several intriguing quantum and classical size effects on thermal and thermoelectric properties that have been predicted by theoretical calculations or observed in experiments. Attention is focused on the Casimir limit in phonon boundary scattering and the effect of phonon confinement on the lattice thermal conductivity of semiconductor nanowires (NWs) and nanomeshes; the effects of thickness, lateral size, and interface inter…
