Phonon Casimir effect is the long-range interaction between impurities in condensed matter systems, mediated by vacuum fluctuations of the phonon field. For pairs of impurities, this interaction has been shown to follow a quasi-power law at zero-temperature and evolve into an exponentially decaying form as the temperature is increased. This work introduces an approach to deal with systems of more than two impurities, both at zero and finite temperatures.
The thermal conductance of straight and corrugated monocrystalline silicon nanowires has been measured between 0.3 K and 5 K. The difference in the thermal transport between corrugated nanowires and straight ones demonstrates a strong reduction in the mean free path of the phonons. This averaged mean free path is remarkably smaller than the smaller diameter of the nanowire, evidencing a phonon thermal transport reduced below the Casimir limit. Monte Carlo simulations highlight that this effect can be attributed to significant multiple scattering of ballistic phonons occuring on the corrugated …
We discuss computational analysis of phononic thermal conduction in the suspended membrane geometry, in the experimentally commonly appearing case where heat can flow out radially in two dimensions from a central source. As we are mostly interested in the low-temperature behavior where bulk scattering of phonons becomes irrelevant, we study the limit where all phonon scattering takes place at the membrane surfaces. Moreover, we limit the discussion here to the case where this surface scattering is fully diffusive, the so called Casimir limit. Our analysis shows that in the two-dimensional case…
We find the Casimir energy, at finite temperature, for acoustic phonons in a Graphene sheet suspended over a rectangular trench, and the corresponding Casimir forces are interpreted as correction terms to the built-in tensions of the Graphene. We show that these corrections generally break the tensional isotropy of the membrane, and can increase or decrease the membrane tension. We demonstrate that for a narrow rectangular trench with side-lengths in the order of few nanometers and few micrometers, these temperature corrections are expected to be noticeable ($\sim 10^{-4} N/m$) at the room tem…
The natural transition from the radiative regime to the conductive regime of heat transfer between two identical isotropic dielectric solid materials, is questioned by investigating the possibility of induced phonon transfer in vacuum. We describe the process in a general way assuming a certain phonon coupling mechanism between the two identical solids, then we particularly illustrate the case of coupling through Casimir force. We analyze how this mechanism of heat transfer compares and competes with the near field thermal radiation using a local model of the dielectric function. We show that …
A non-equilibrium Green's function method is applied to model high-field quantum transport and electron-phonon resonances in semiconductor superlattices. The field-dependent density of states for elastic (impurity) scattering is found non-perturbatively in an approach which can be applied to both high and low electric fields. I-V curves, and specifically electron-phonon resonances, are calculated by treating the inelastic (LO phonon) scattering perturbatively. Calculations show how strong impurity scattering suppresses the electron-phonon resonance peaks in I-V curves, and their detailed sensi…
A generalized propagation matrix method is used to study how scattering off local Einstein phonons affects resonant electron transmission through quantum wells. In particular, the parity and the number of the phonon mediated satellite resonances are found to depend on the available scattering channels. For a large number of phonon channels, the formation of low-energy impurity bands is observed. Furthermore, an effective theory is developed which accurately describes the phonon generated sidebands for sufficiently small electron-phonon coupling. Finally, the current-voltage characteristics cau…
The effect of electron-optical phonon interaction on the hydrogenic impurity binding energy in a cylindrical quantum wire is studied. By using Landau and Pekar variational method, the hamiltonian is separated into two parts which contain phonon variable and electron variable respectively. A perturbative-variational technique is then employed to construct the trial wavefunction for the electron part. The effect of confined electron-optical phonon interaction on the binding energies of the ground state and an excited state are calculated as a function of wire radius. Both the electron-bulk optic…
We investigate temperature dependent transport properties of two-dimensional p-GaAs systems taking into account both hole-phonon and hole-impurity scattering effects. By analyzing the hole mobility data of p-GaAs in the temperature range 10 K$<T<$100 K, we estimate the value of the appropriate deformation potential for hole-phonon coupling. Due to the interplay between hole-phonon and hole-impurity scattering the calculated temperature-dependent resistivity shows interesting nonmonotonic behavior. In particular, we find that there is a temperature range (typically 2 K$<T<$10 K) in which the ca…
In a previous publication, we discussed the formalism and some computational results for phononic thermal conduction in the suspended membrane geometry for radial heat flow from a central source, which is a common geometry for some low-temperature detectors, for example. We studied the case where only diffusive surface scattering is present, the so called Casimir limit, which can be experimentally relevant at temperatures below $\sim$ 10 K in typical materials, and even higher for ultrathin samples. Here, we extend our studies to much thinner membranes, obtaining numerical results for geometri…
We consider a single impurity Anderson model (SIAM) in which the quantum dot(QD) is strongly coupled to a phonon bath in polaron regime. This coupling results in an effective e-e attraction. By computing the self energies using a current conserving approximation which is up to second order in this effective attraction, we show that if the interaction is strong enough, in non particle-hole(PH) symmetric case, the system would be bi-stable and we have hysteresis loop in the I-V characteristic. Moreover, the system shows negative differential conductance in some bias voltage intervals.
The phonon Casimir effect describes the phonon-mediated interaction between defects in condensed-matter systems. Using the path-integral formalism, we derive a general method for calculating the Helmholtz free energy due to vibrational modes in systems of arbitrary dimensionality and composition. Our results make it possible to extract the defect interaction energy at any temperature for various defect configurations. We demonstrate our approach in action by performing numerical calculations for mono- and diatomic chains, as well as a diatomic molecule, at zero and finite temperatures and vali…
The effects of substrate on the electronic properties of Graphene remains unclear. Many theoretical and experimental efforts have been done to clarify this discrepancy. In this work, we studied the electronic transport in armchair Graphene nanoribbons (AGNR) in the presence of substrate's disorder. The three main substrate's disorders -- surface roughness, charged impurity and surface optical phonon -- are investigated. Non-Equilibrium Green's function along with the tight-binding model is employed to investigate the electronic properties of Graphene Nanoribbons. The effects of these disorders…
By calculating a Casimir energy for the acoustic phonons of Graphene, we find some temperature-dependent corrections for the pretension of a Graphene sheet suspended on a trench. We obtain values of the order of few mN/m for these corrections in fully as well as doubly clamped Graphene on a narrow trench with one nanometer width, at room temperature. These values are considerable compared to the experimental values, and can increase the fundamental resonance frequency of the Graphene. The values of these corrections increase by increasing the temperature, and so they can be utilized for tuning…
Van der Waals (vdW) and Casimir interactions depend crucially on material properties and geometry, especially at molecular scales, and temperature can produce noticeable relative shifts in interaction characteristics. Despite this, common treatments of these interactions ignore electromagnetic retardation, atomism, or contributions of collective mechanical vibrations (phonons) to the infrared response, which can interplay with temperature in nontrivial ways. We present a theoretical framework for computing electromagnetic interactions among molecular structures, accounting for their geometry, …
In stark contrast with three-dimensional (3D) nanostructures, we show that boundary scattering in two-dimensional (2D) nanoribbons alone does not lead to a finite phonon mean free path. If combined with an intrinsic scattering mechanism, 2D boundary scattering does reduce the overall mean free path, however the latter does not scale proportionally to the ribbon width, unlike the well known Casimir regime occurring in 3D nanowires. We show that boundary scattering can be accounted for by a simple Mathiessen type approach for many different 3D nanowire cross sectional shapes, however this is not…
The spectral Matthiessen's rule is commonly used to calculate the total phonon scattering rate when multiple scattering mechanisms exist. Here we predict the spectral phonon relaxation time $τ$ of defective bulk silicon using normal mode analysis based on molecular dynamics, and show that the spectral Matthiessen's rule is not accurate due to the neglect of the coupling between anharmonic phonon-phonon scattering $τ_a^{-1}$ and phonon-impurity scattering $τ_i^{-1}$. As a result, the spectral Matthiessen's rule underestimates the total phonon scattering rate, and hence overestimates the thermal…
We develop a unified treatment of the piesoelectric coupling between two-dimensional electrons and bulk phonons in both cases of zero and strong magnetic fields, the latter corresponding to even denominator filling fractions. In contrast to the case of coupling via the deformation potential, the leading contributions due to impurity-renormalized electron-phonon vertices are not exactly cancelled by processes of inelastic electron-impurity scattering. Electron energy relaxation time, diffusion correction to the conductivity, and phonon emission rate by hot electrons are computed for realistic $…
We investigate the strain-induced coupling between a nitrogen-vacancy impurity and a resonant vibrational mode of a diamond nanoresonator. We show that under near-resonant laser excitation of the electronic states of the impurity, this coupling can modify the state of the resonator and either cool the resonator close to the vibrational ground state or drive it into a large amplitude coherent state. We derive a semi-classical model to describe both effects and evaluate the stationary state of the resonator mode under various driving conditions. In particular, we find that by exploiting resonant…
We study the interaction of two localized impurities in a repulsive one-dimensional Fermi liquid via bosonization. In a previous paper [Phys. Rev. A 72, 023616 (2005)], it was shown that at distances much larger than the interparticle spacing the impurities interact through a Casimir-type force mediated by the zero sound phonons of the underlying quantum liquid. Here we extend these results and show that the strength and sign of this Casimir interaction depend sensitively on the impurities separation. These oscillations in the Casimir interaction have the same period as Friedel oscillations. T…
Arrays of coupled phonon cavities each including an impurity qubit in silicon are considered. We study experimentally feasible architectures that can exhibit quantum many-body phase transitions of phonons, e.g. Mott insulator and superfluid states, due to a strong phonon-phonon interaction (which is mediated by the impurity qubit-cavity phonon coupling). We investigate closed equilibrium systems as well as driven dissipative non-equilibrium systems at zero and non-zero temperatures. Our results indicate that quantum many-body phonon systems are achievable both in on-chip nanomechanical systems…
We consider the nonlinear terahertz response of n-doped monolayer graphene at room temperature using a microscopic theory of carrier dynamics. Our tight-binding model treats the carrier-field interaction in the length gauge, includes phonon as well as short-range neutral-impurity scattering, and fully accounts for the intrinsic nonlinear response of graphene near the Dirac point. Treating each interaction microscopically allows us to separate contributions from current clipping, phonon creation, and elastic impurity scattering. Although neutral impurity scattering and phonon scattering are bot…
Here we report a scanning tunneling microscopy (STM) and spectroscopy (STS) study in the superconducting state of 2H-NbS2. We directly visualize the existence of incommensurate charge density wave (CDW) that is pinned by atomic impurities. In strong tunneling conditions, the incommensurate CDW is de-pinned from impurities by the electric field from STM tip. We perform STM-based inelastic tunneling spectroscopy (IETS) to detect phonon excitations in 2H-NbS2 and measure the influence of atomic impurities on local phonon excitations. In comparison with the calculated vibrational density of states…
We study the electric and thermal transport of the Dirac carriers in monolayer graphene using the Boltzmann-equation approach. Motivated by recent thermopower measurements [F. Ghahari, H.-Y.~Xie, T. Taniguchi, K. Watanabe, M.~S.~Foster, and P.~Kim, Phys.\ Rev.\ Lett.\ {\bf 116}, 136802 (2016)], we consider the effects of quenched disorder, Coulomb interactions, and electron--optical-phonon scattering. Via an unbiased numerical solution to the Boltzmann equation we calculate the electrical conductivity, thermopower, and electronic component of the thermal conductivity, and discuss the validity …
Suppressing phonon propagation in nanowires is an essential goal towards achieving efficient thermoelectric devices. Recent experiments have shown unambiguously that surface roughness is a key factor that can reduce the thermal conductivity well below the Casimir limit in thin crystalline silicon nanowires. We use insights gained from the experimental studies to construct a simple analytically tractable model of the phonon-surface roughness interaction that provides a better theoretical understanding of the effects of surface roughness on the thermal conductivity, which could potentially help …
Semiconductor superlattices have been extensively investigated for thermoelectric applications, to explore the effects of compositions, interface structures, and lattice strain environments on the reduction of thermal conductivity, and improvement of efficiency. Most studies assumed that their electronic properties remain unaffected compared to their bulk counterparts. However, recent studies demonstrated that electronic properties of silicon (Si)/germanium (Ge) superlattices show significant variations depending on compositions and growth substrates. These studies used a constant relaxation t…
Motivated by the recent experiment by Marguerite et al. [1] on imaging in graphene samples, we investigate theoretically the dissipation induced by resonant impurities in the quantum Hall regime. The impurity induced forward scattering of electrons at quantum Hall edges leads to an enhanced phonon emission, which reaches its maximum when the impurity state is tuned to resonance by a scanning tip voltage. Our analysis of the effect of the tip potential on the dissipation reveals peculiar thermal rings around the impurities, in consistency with experimental observations. Remarkably, this impurit…
We present a numerical study on the intraband optical conductivity of hot carriers at quasi-equilibria in photoexcited graphene based on the semiclassical Boltzmann transport equations (BTE) with the aim of understanding the effects of intrinsic optical phonon and extrinsic coulomb scattering caused by charged impurities at the graphene--substrate interface. Instead of using full-BTE solutions, we employ iterative solutions of the BTE and the comprehensive model for the temporal evolutions of hot-carrier temperature and hot-optical-phonon occupations to reduce computational costs. Undoped grap…
The Casimir force was predicted in 1948 as a force arising between macroscopic bodies from the zero-point energy. At finite temperatures it has been shown that a thermal Casimir force exists due to thermal rather than zero-point energy and there are a growing number of experiments that characterise the effect at a range of temperatures and distances. Additionally, in the rapidly evolving field of cavity optomechanics there is an endeavor to manipulate phonons and enhance coherence. We demonstrate a new way to achieve this through the first observation of Casimir spring and dilution in macrosco…
Electron backscattering in a Luttinger liquid with an impurity is investigated in the presence of zero point motion of the phonon lattice. The impurity can mean either a mass defect, an elastic defect or a pinning defect. The phonon spectrum is then affected by the presence of the defect, which enters in the renormalization group equations for backscattering. The RG equation becomes dependent on the energy cutoff for finite Debye frequency $ω_D$ giving rise to finite energy effects. We compute the local density of states and show how the renormalization group flow is affected by a finite $ω_D$…
We study the kinetics of 2D Bose gas cooling provided Bose particles interact with 3D phonons. At low temperatures phonon emission is prohibited by the energy and the momentum conservation. We show that both particle-particle scattering and impurity scattering assist the Bose gas cooling.
We introduce a quantum Monte Carlo technique to calculate exactly at finite temperatures the Green function of a fermionic quantum impurity coupled to a bosonic field. While the algorithm is general, we focus on the single impurity Anderson model coupled to a Holstein phonon as a schematic model for a molecular transistor. We compute the density of states at the impurity in a large range of parameters, to demonstrate the accuracy and efficiency of the method. We also obtain the conductance of the impurity model and analyze different regimes. The results show that even in the case when the effe…
We investigate the spin relaxation due to the random Rashba spin-orbit coupling in symmetric GaAs (110) quantum wells from the fully microscopic kinetic spin Bloch equation approach. All relevant scatterings, such as the electron-impurity, electron--longitudinal-optical-phonon, electron--acoustic-phonon, as well as electron-electron Coulomb scatterings are explicitly included. It is shown that our calculation reproduces the experimental data by Müller {\em et al.} [Phys. Rev. Lett. {\bf 101}, 206601 (2008)] for a reasonable choice of parameter values. We also predict that the temperature depen…
Magnetically-doped topological insulators are intensely studied in the search for exotic phenomena such as the quantum anomalous Hall effect. The interplay of electronic and impurity degrees of freedom leads to the Kondo effect, an increase in the resistivity at temperatures $T < T_K$, the Kondo temperature. We study this effect in chiral surface state transport at $T \ge T_K$ in the metallic regime, starting from the quantum Liouville equation and including Kondo scattering to all orders, as well as phonon and non-magnetic impurity scattering. Unlike spin-orbit coupled metals and semiconducto…
Understanding disorder in graphene is essential for electronic applications; in contrast to conventional materials, the extraordinarily low electron-phonon scattering1, 2 in graphene implies that disorder3-7 dominates its resistivity even at room temperature. Charged impurities5, 8-10 have been identified as an important disorder type in graphene on SiO2 substrates11, 12, giving a nearly linear carrier-density-dependent conductivity σ(n), and producing electron and hole puddles13-15 which determine the magnitude of graphene's minimum conductivity σmin10. Correlations of charged impurities are …
Transport and gain properties of a resonant-phonon terahertz quantum cascade laser are calculated using nonequilibrium Green's functions. Impurity scattering is shown to be responsible for contrasting nonlinear effects in the transport and the gain properties. For typical doping concentrations, the current density is found to be weakly sensitive to the impurity scattering strength. In contrast, the calculated gain is found to be very sensitive to the impurity scattering strength. This difference is attributed to the strong momentum dependence of the long-range coupling to charged impurities. S…
Using a simplified microscopic model of coupled spin and lattice excitations in a ferromagnetic insulator we evaluate the magnetic-field dependence of the spin Seebeck effect at low temperatures. The model includes Heisenberg exchange coupling, a harmonic lattice potential, and a pseudo-dipolar exchange interaction. Our approach goes beyond previous work [Phys. Rev. B 98, 134421 (2018)] in that it does not rely on the a priori assumption of a fast equilibration of the magnon and phonon distributions. Our theory shows that singular features in the magnetic-field dependence of the spin Seebeck e…
Disorder-induced broadening of optical vibrational eigenmodes in nanoparticles of nonpolar crystals is studied numerically. The methods previously used to treat phonons in defectless particles are adjusted for numerical evaluation of the disordered problem. Imperfections in the form of Gaussian and binary disorders as well as surface irregularities are investigated thoroughly in a wide range of impurity concentrations and disorder strengths. For dilute and weak point-like impurities the regimes of separated and overlapped phonon levels are obtained and the behavior of the linewidth predicted t…
Isotopic dependence of the Casimir force is key to probing new physics and pushing novel technologies at the micro and nanoscale, but is largely unexplored. In 2002, an isotope effect of 10^(-4) was estimated for metals -- orders of magnitude beyond the experimental resolution. Here, by employing the Lifshitz theory, we reveal a significant isotope effect of over 10^(-1) for polar dielectrics. This effect arises from the isotope-mass-induced line shift of the zone-center optical phonons and is insensitive to the linewidth. We perform numerical analyses on both the imaginary and real-frequency …
A fundamental prediction of quantum mechanics is that there are random fluctuations everywhere in a vacuum because of the zero-point energy. Remarkably, quantum electromagnetic fluctuations can induce a measurable force between neutral objects, known as the Casimir effect, which has attracted broad interests. The Casimir effect can dominate the interaction between microstructures at small separations and has been utilized to realize nonlinear oscillation, quantum trapping, phonon transfer, and dissipation dilution. However, a non-reciprocal device based on quantum vacuum fluctuations remains a…
We consider in depth the applicability of the Wiedemann-Franz (WF) law, namely that the electronic thermal conductivity ($κ$) is proportional to the product of the absolute temperature ($T$) and the electrical conductivity ($σ$) in a metal with the constant of proportionality, the so-called Lorenz number $L_0$, being a materials-independent universal constant in all systems obeying the Fermi liquid (FL) paradigm. It has been often stated that the validity (invalidity) of the WF law is the hallmark of an FL (non-Fermi-liquid (NFL)). We consider, both in two (2D) and three (3D) dimensions, a sys…
The variety of excitonic states in tungsten-based dichalcogenide monolayers stems from unique interplay between the spin and valley degrees of freedom. One of the exciton species is the indirect exciton (momentum or valley dark), which is responsible to a series of resonances when the monolayer is charge neutral. We investigate the short-range electron-hole exchange interaction of the indirect exciton, as well as its recombination mechanism mediated by impurities. The analysis provides thorough understanding of the energy and polarization of the zero-phonon indirect exciton resonance in the em…
We have studied the interplay of a local phonon mode embedded in a metallic host (Holstein impurity model) using Abelian bosonization. The phonon frequency softens, which takes place in two steps: first, their frequency starts softening, and acquires finite lifetime. Then oscillations disappear from the response, and two distinct, finite dampings characterize them. Similar behaviour shows up in the spin-boson model. Due to phonons, the electrons experience an attractive, dynamic interaction. As a result, the electronic charge response enhances similarly to the spin response in the Kondo model.…
We present computations of the thermal Hall coefficient of phonons scattering off a defect with multiple energy levels. Using a microscopic formulation based on the Kubo formula, we find that the leading contribution perturbative in the phonon-defect coupling is proportional to the phonon lifetime, and has a `side-jump' interpretation. Consequently, the thermal Hall angle is independent of the phonon lifetime. The contribution to the thermal Hall coefficient is at resonance when the phonon energy equals a defect level spacing. Our results are obtained for three different defect models, which a…
