This thesis is devoted to studying two tasks: refrigeration and the creation of correlations. In the refrigeration part, two different paradigms of cooling, namely coherent and incoherent, are defined. The connection that these paradigms have with other existing refrigeration techniques such as heat bath algorithmic cooling (HBAC), the resource theoretic approach to quantum thermodynamics, and autonomous cooling is then made. Each paradigm is then investigated on its own. This in particular allows for the derivation of a general and attainable bound. The bound is striking in its simplicity: it depends on a single parameter of the environment/machine used to cool the system of interest. The creation of correlations part is devoted to the quantitative study of how much correlations can be created for a given amount of energy. After having precisely formulated the problem of interest, we solve it for arbitrary finite dimensional bipartite systems for vanishing background temperatures. For non-vanishing background temperature the symmetry of the problem breaks down, making it much harder to tackle. When both systems are copies of each other, enough symmetry is restored to formulate an upper bound valid for all (finite) dimensional systems and prove its attainability for dimension 3 and 4. We furthermore conjecture, as well as show evidence for, the bound to be attainable in any dimension.
Many organisms capitalize on their ability to predict the environment to maximize available free energy, and reinvest this energy to create new complex structures. This functionality relies on the manipulation of patterns - temporally ordered sequences of data. Here, we propose a framework to describe pattern manipulators -- devices that convert thermodynamic work to patterns or vice versa - and use them to build a 'pattern engine' that facilitates a thermodynamic cycle of pattern creation and consumption. We show that the least heat dissipation is achieved by the provably simplest devices; th…
We derive an optimal bound for arbitrary entanglement manipulation based on the transmission of a pulse in coherent states over a lossy channel followed by local operations and unlimited classical communication (LOCC). This stands on a theorem to reduce LOCC via a local unital qubit channel to local filtering. We also present an optimal protocol based on beam splitters and a quantum nondemolition (QND) measurement on photons. Even if we replace the QND measurement with photon detectors, the protocol outperforms known entanglement generation schemes.
Entanglement is central both to the foundations of quantum theory and, as a novel resource, to quantum information science. The theory of entanglement establishes basic laws, such as the non-increase of entanglement under local operations, that govern its manipulation and aims to draw from them formal analogies to the second law of thermodynamics. However, while in the second law the entropy uniquely determines whether a state is adiabatically accessible from another, the manipulation of entanglement under local operations exhibits a fundamental irreversibility which prevents the existence of …
Many fruitful analogies have emerged between the theories of quantum entanglement and thermodynamics, motivating the pursuit of an axiomatic description of entanglement akin to the laws of thermodynamics. A long-standing open problem has been to establish a true second law of entanglement, and in particular a unique function which governs all transformations between entangled systems, mirroring the role of entropy in thermodynamics. Contrary to previous promising evidence, here we show that this is impossible, and no direct counterpart to the second law of thermodynamics can be established. Th…
We find a minimal set of necessary and sufficient conditions for the existence of a local procedure that converts a finite pure state into one of a set of possible final states. This result provides a powerful method for obtaining optimal local entanglement manipulation protocols for pure initial states. As an example, we determine analytically the optimal distillable entanglement for arbitrary finite pure states. We also construct an explicit protocol achieving this bound.
We find the optimal universal way of manipulating a single qubit, |psi(theta,phi)>, such that (theta,phi)->(theta-k,phi-l). Such optimal transformations fall into two classes. For 0 =< k =< pi/2 the optimal map is the identity and the fidelity varies monotonically from 1 (for k=0) to 1/2 (for k=pi/2). For pi/2 =< k =< pi the optimal map is the universal-NOT gate and the fidelity varies monotonically from 1/2 (for k=pi/2) to 2/3 (for k=pi). The fidelity 2/3 is equal to the fidelity of measurement. It is therefore rather surprising that for some values of k the fidelity is lower than 2/3.
We analyze various scenarios for entangling two initially unentangled qubits. In particular, we propose an optimal universal entangler which entangles a qubit in unknown state $|Ψ>$ with a qubit in a reference (known) state $|0>$. That is, our entangler generates the output state which is as close as possible to the pure (symmetrized) state $(|Ψ>|0> +|0>|Ψ>)$. The most attractive feature of this entangling machine, is that the fidelity of its performance (i.e. the distance between the output and the ideally entangled -- symmetrized state) does not depend on the input and takes the constant val…
The first law of thermodynamics imposes not just a constraint on the energy-content of systems in extreme quantum regimes, but also symmetry-constraints related to the thermodynamic processing of quantum coherence. We show that this thermodynamic symmetry decomposes any quantum state into mode operators that quantify the coherence present in the state. We then establish general upper and lower bounds for the evolution of quantum coherence under arbitrary thermal operations, valid for any temperature. We identify primitive coherence manipulations and show that the transfer of coherence between …
It is not a problem to complement a classical bit, i.e. to change the value of a bit, a 0 to a 1 and vice versa. This is accomplished by a NOT gate. Complementing a qubit in an unknown state, however, is another matter. We show that this operation cannot be done perfectly. We define the Universal-NOT (U-NOT) gate which out of N identically prepared pure input qubits generates M output qubits in a state which is as close as possible to the perfect complement. This gate can be realized by classical estimation and subsequent re-preparation of complements of the estimated state. Its fidelity is th…
We obtain expressions for the optimal rates of one- shot entanglement manipulation under operations which generate a negligible amount of entanglement. As the optimal rates for entanglement distillation and dilution in this paradigm, we obtain the max- and min-relative entropies of entanglement, the two logarithmic robustnesses of entanglement, and smoothed versions thereof. This gives a new operational meaning to these entanglement measures. Moreover, by considering the limit of many identical copies of the shared entangled state, we partially recover the recently found reversibility of entan…
Constructing optimal thermodynamic processes in quantum systems relies on managing the balance between the average excess work and its stochastic fluctuations. Recently it has been shown that two different quantum generalisations of thermodynamic length can be utilised to determine protocols with either minimal excess work or minimal work variance. These lengths measure the distance between points on a manifold of control parameters, and optimal protocols are achieved by following the relevant geodesic paths given some fixed boundary conditions. Here we explore this problem in the context of G…
We establish a rigorous connection between fundamental resource theories at the quantum scale. Correlations and entanglement constitute indispensable resources for numerous quantum information tasks. However, their establishment comes at the cost of energy, the resource of thermodynamics, and is limited by the initial entropy. Here, the optimal conversion of energy into correlations is investigated. Assuming the presence of a thermal bath, we establish general bounds for arbitrary systems and construct a protocol saturating them. The amount of correlations, quantified by the mutual information…
In this paper, we propose feedback designs for manipulating a quantum state to a target state by performing sequential measurements. In light of Belavkin's quantum feedback control theory, for a given set of (projective or non-projective) measurements and a given time horizon, we show that finding the measurement selection policy that maximizes the probability of successful state manipulation is an optimal control problem for a controlled Markovian process. The optimal policy is Markovian and can be solved by dynamical programming. Numerical examples indicate that making use of feedback inform…
Classical and quantum error correction are presented in the form of Maxwell's demon and their efficiency analyzed from the thermodynamic point of view. We explain how Landauer's principle of information erasure applies to both cases. By then extending this principle to entanglement manipulations we rederive upper bounds on purification procedures thereby linking the ''no local increase of entanglement'' principle to the Second Law of thermodynamics.
Optimal (reversible) processes in thermodynamics can be modelled as step-by-step processes, where the system is successively thermalized with respect to different Hamiltonians by an external thermal bath. However, in practice interactions between system and thermal bath will take finite time, and precise control of their interaction is usually out of reach. Motivated by this observation, we consider finite-time and uncontrolled operations between system and bath, which result in thermalizations that are only partial in each step. We show that optimal processes can still be achieved for any non…
Thermodynamics serves as a universal means for studying physical systems from an energy perspective. In recent years, with the establishment of the field of stochastic and quantum thermodynamics, the ideas of thermodynamics have been generalized to small fluctuating systems. Independently developed in mathematics and statistics, the optimal transport theory concerns the means by which one can optimally transport a source distribution to a target distribution, deriving a useful metric between probability distributions, called the Wasserstein distance. Despite their seemingly unrelated nature, a…
Shanon's fundamental coding theorems relate classical information theory to thermodynamics. More recent theoretical work has been successful in relating quantum information theory to thermodynamics. For example, Schumacher proved a quantum version of Shannon's 1948 classical noiseless coding theorem. In this note, we extend the connection between quantum information theory and thermodynamics to include quantum error correction. There is a standard mechanism for describing errors that may occur during the transmission, storage, and manipulation of quantum information. One can formulate a criter…
Quantum resource manipulation may include an ancillary state called a catalyst, which aids the transformation while restoring its original form at the end, and characterizing the enhancement enabled by catalysts is essential to reveal the ultimate manipulability of the precious resource quantity of interest. Here, we show that allowing correlation among multiple catalysts can offer arbitrary power in the manipulation of quantum coherence. We prove that any state transformation can be accomplished with an arbitrarily small error by covariant operations with catalysts that may create a correlati…
Correlations lie at the heart of almost all scientific predictions. It is therefore of interest to ask whether there exist general limitations to the amount of correlations that can be created at a finite amount of invested energy. Within quantum thermodynamics such limitations can be derived from first principles. In particular, it can be shown that establishing correlations between initially uncorrelated systems in a thermal background has an energetic cost. This cost, which depends on the system dimension and the details of the energy-level structure, can be bounded from below but whether t…
The nitrogen-vacancy (NV) center spin represents an appealing candidate for quantum information processing. Besides the widely used microwave control, its coherent manipulation may also be achieved using laser as mediated by the excited energy levels. Nevertheless, the multiple levels of the excited state of NV center spin make the coherent transition process become complex and may affect the fidelity of coherent manipulation. Here, we adopt the strategy of optimal quantum control to accelerate coherent state transfer in the ground state manifold of NV center spin using laser. The results demo…
Heat engines are fundamental physical objects to develop nonequilibrium thermodynamics. The thermodynamic performance of the heat engine is determined by the choice of cycle and time-dependence of parameters. Here, we propose a systematic numerical method to find a heat engine cycle to optimize some target functions. We apply the method to heat engines with slowly varying parameters and show that the method works well. Our numerical method is based on the genetic algorithm which is widely applied to various optimization problems.
Entanglement of pure states of bipartite quantum systems has been shown to have a unique measure in terms of the von Neumann entropy of the reduced states of either of its subsystems. The measure is established under entanglement manipulation of an asymptotically large number of copies of the states. In this paper, different asymptotic measures of entanglement assigned to arbitrary sequences of bipartite pure states are shown to coincide only when the sequence is information stable, in terms of the quantum spectral information rates of the sequence of subsystem states. Additional bounds on the…
Thermodynamics is traditionally concerned with systems comprised of a large number of particles. Here we present a framework for extending thermodynamics to individual quantum systems, including explicitly a thermal bath and work-storage device (essentially a `weight' that can be raised or lowered). We prove that the second law of thermodynamics holds in our framework, and give a simple protocol to extract the optimal amount of work from the system, equal to its change in free energy. Our results apply to any quantum system in an arbitrary initial state, in particular including non-equilibrium…
We characterize finite-time thermodynamic processes of multidimensional quadratic overdamped systems. Analytic expressions are provided for heat, work, and dissipation for any evolution of the system covariance matrix. The Bures-Wasserstein metric between covariance matrices naturally emerges as the local quantifier of dissipation. General principles of how to apply these geometric tools to identify optimal protocols are discussed. Focusing on the relevant slow-driving limit, we show how these results can be used to analyze cases in which the experimental control over the system is partial.
We demonstrate the effectiveness of quantum optimal control techniques in harnessing irreversibility generated by non-equilibrium processes, implemented in unitarily evolving quantum many-body systems. We address the dynamics of a finite-size quantum Ising model subjected to finite-time transformations, which unavoidably generate irreversibility. We show that work can be generated through such transformation by means of optimal controlled quenches, while quenching the degree of irreversibility to very low values, thus boosting the efficiency of the process and paving the way to a fully control…
We analyze the role of indirect quantum measurements in work extraction from quantum systems in nonequilibrium states. In particular, we focus on the work that can be obtained by exploiting the correlations shared between the system of interest and an additional ancilla, where measurement backaction introduces a nontrivial thermodynamic tradeoff. We present optimal state-dependent protocols for extracting work from both classical and quantum correlations, the latter being measured by discord. We show that, while the work content of classical correlations can be fully extracted by performing lo…
We implement the reinforcement learning agent for a spin-1 atomic system to prepare spin squeezed state from given initial state. Proximal policy gradient (PPO) algorithm is used to deal with continuous external control field and final optimized protocol is given by a stochastic policy. In both mean-field system and two-body quantum system, RL agent finds the optimal policies. In many-body quantum system, it also gives polices that outperform purely greedy policy and optimized adiabatic passage. These polices given by RL agent have good physical interpretability in phase space and may help us …
We apply advanced methods of control theory to open quantum systems and we determine finite-time processes which are optimal with respect to thermodynamic performances. General properties and necessary conditions characterizing optimal drivings are derived, obtaining bang-bang type solutions corresponding to control strategies switching between adiabatic and isothermal transformations. A direct application of these results is the maximization of the work produced by a generic quantum heat engine, where we show that the maximum power is directly linked to a particular conserved quantity natural…
Despite being a well-established operational approach to quantify entanglement, Rényi entropy calculations have been plagued by their computational complexity. We introduce here a theoretical framework based on an optimal thermodynamic integration scheme, where the Rényi entropy can be efficiently evaluated using regularizing paths. This approach avoids slowly convergent fluctuating contributions and leads to low-variance estimates. In this way, large system sizes and high levels of entanglement in model or first-principles Hamiltonians are within our reach. We demonstrate it in the one-dimens…
The fluctuation-dissipation theorem is a fundamental result in statistical physics that establishes a connection between the response of a system subject to a perturbation and the fluctuations associated with observables in equilibrium. Here we derive its version within a resource-theoretic framework, where one investigates optimal quantum state transitions under thermodynamic constraints. More precisely, we first characterise optimal thermodynamic distillation processes, and then prove a relation between the amount of free energy dissipated in such processes and the free energy fluctuations o…
Entropy production is a key quantity in any finite-time thermodynamic process. It is intimately tied with the fundamental laws of thermodynamics, embodying a tool to extend thermodynamic considerations all the way to non-equilibrium processes. It is also often used in attempts to provide the quantitative characterization of logical and thermodynamic irreversibility, stemming from processes in physics, chemistry and biology. Notwithstanding its fundamental character, a unifying theory of entropy production valid for general processes, both classical and quantum, has not yet been formulated. Dev…
A shortcut to adiabaticity (STA) is concerned with the fast and robust manipulation of the dynamics of a quantum system that reproduces the effect of an adiabatic process. A recently proposed method enables the generation of shortcuts from a prescribed slow dynamics by simply rescaling the time variable of the quantum evolution operator [B. L. Bernardo, Phys. Rev. Research 2, 013133 (2020)]. This time-rescaling method does not demand knowledge about the eigenvalues and eigenstates of the Hamiltonian, and in many cases no additional coupling fields. Here, we use this approach to study the probl…
Optimal Finite-Time Thermodynamics of Effective Two-Level Systems
Atominstitut, TU Wien（维也纳工业大学原子研究所）；Institute for Quantum Optics and Quantum Information - IQOQI Vienna, Austrian Academy of Sciences（奥地利科学院维也纳量子光学与量子信息研究所）
