Entanglement is central both to the foundations of quantum theory and, as a novel resource, to quantum information science. The theory of entanglement establishes basic laws, such as the non-increase of entanglement under local operations, that govern its manipulation and aims to draw from them formal analogies to the second law of thermodynamics. However, while in the second law the entropy uniquely determines whether a state is adiabatically accessible from another, the manipulation of entanglement under local operations exhibits a fundamental irreversibility which prevents the existence of such an order.
Here we show that a reversible theory of entanglement and a rigorous relationship with thermodynamics may be established when one considers all non-entangling transformations. The role of the entropy in the second law is taken by the asymptotic relative entropy of entanglement in the basic law of entanglement. We show the usefulness of this new approach to general resource theories and to quantum information theory.
We show that macroscopic thermodynamical properties - such as functions of internal energy and magnetization - can detect quantum entanglement in solids at nonzero temperatures in the thermodynamical limit. We identify the parameter regions (critical values of magnetic field and temperature) within which entanglement is witnessed by these thermodynamical quantities.
We point out formal correspondences between thermodynamics and entanglement. By applying them to previous work, we show that entropy of entanglement is the unique measure of entanglement for pure states.
We apply the axiomatic approach to thermodynamics presented by Giles to derive a unique measure of entanglement for bi-partite pure states. This implies that local manipulations of entanglement in quantum information theory and adiabatic transformations of states in thermodynamics have the same underlying mathematical structure. We discuss possible extensions of our results to mixed and multi-partite states.
We present a new inequality which holds in the thermodynamical processes with measurement and feedback controls with using only the Helmholtz free energy and the entanglement of formation: $W_{\mathrm{ext}}\le-ΔF-k_{B}TΔE_{F}$. The quantity $-ΔE_{F}$, which is positive, expresses the amount of entanglement transfer from the system $S$ to the probe $P$ through the interaction $\hat{U}_{SP}$ during the measurement. It is easier to achieve the upper bound in the new inequality than in the Sagawa-Ueda inequality [Phys. Rev. Lett. 100 080403 (2008)]. The new inequality has clear physical meaning: i…
A review is given on the thermodynamical structure of bipartite entanglement. By comparing it to the axiomatic formulation of thermodynamics presented by Giles it is shown that for finite dimensional systems the two theories are formally inequivalent. The same approach is used to demonstrate the full equivalence in the asymptotic limit for pure quantum states. For mixed states a different method for obtaining the second law is described applied to two different classes of operations, PPT-preserving and asymptotically non-entangling operations.
We define and analyse the concept of entanglement production during the evolution of a general quantum mechanical dissipative system. While it is important to minimise entropy production in order to achieve thermodynamical efficiency, maximising the rate of change of entanglement is important in quantum information processing. Quantitative relations are obtained between entropy and entanglement productions, under specific assumptions detailed in the text. We apply these to the processes of dephasing and decay of correlations between two initially entangled qubits. Both the Master equation trea…
Quantum correlation, or entanglement, is now believed to be an indispensable physical resource for certain tasks in quantum information processing, for which classically correlated states cannot be useful. Besides information processing, what kind of physical processes can exploit entanglement? In this paper, we show that there is indeed a more basic relationship between entanglement and its usefulness in thermodynamics. We derive an inequality showing that we can extract more work out of a heat bath via entangled systems than via classically correlated ones. We also analyze the work balance o…
We show that if the ground state entanglement exceeds the total entropy of a given system, then this system is in an entangled state. This is a universal entanglement witness that applies to any physical system and yields a temperature below which we are certain to find some entanglement. Our witness is then applied to generic bosonic and fermionic many body systems to derive the corresponding "critical" temperatures that have a very broad validity.
We present the minimal energy costs for the measurement and the information erase, using only the Helmholtz free energy and the entanglement of formation. The entanglement of formation appears in the form of difference which indicates the amount of entanglement transfer on the memory during the processes; the cost of the measurement is given by the entanglement gain, whereas the cost of the information erase is given by the loss of available entanglement. Putting together the present Letter and Rev. E 88, 042143 (2013), we can describe the violation and the restoration of the second law only i…
Theory of bipartite entanglement shares profound similarities with thermodynamics. In this letter we extend this connection to multipartite quantum systems where entanglement appears in different forms with genuine entanglement being the most exotic one. We propose thermodynamic quantities that capture signature of genuineness in multipartite entangled states. Instead of entropy, these quantities are defined in terms of energy -- particularly the difference between global and local extractable works (ergotropies) that can be stored in quantum batteries. Some of these quantities suffice as fait…
We discuss quantum entanglement in the context of the thermodynamic arrow of time. We review the role of correlations in entropy-decreasing events and prove that the occurrence of a transformation between two thermodynamic states constitutes a new type of entanglement witness, one not defined as a separating plane in state space between separable and entangled states, but as a physical process dependent on the local initial properties of the states. Extending work by Partovi, we consider a general entangled multipartite system that allows large reversals of the thermodynamic arrow of time. We …
The first step in quantum information theory is the identification of entanglement as a valuable resource. The next step is learning how to exploit this resource efficiently. We learn how to exploit entanglement efficiently by applying analogues of thermodynamical concepts. These concepts include reversibility, entropy, and the distinction between intensive and extensive quantities. We discuss some of these analogues and show how they lead to a measure of entanglement for pure states. We also ask whether these analogues are more than analogues, and note that, l o c a l l y, entropy of entangle…
We construct a rigourous model of quantum measurement. A two-state model of a negative temperature amplifier, such as a laser, is taken to a classical thermodynamic limit. In the limit, it becomes a classical measurement apparatus obeying the stochastic axioms of quantum mechanics. Thus we derive the probabilities from a deterministic Schroedinger's equation by procedures analogous to those of classical statistical mechanics. This requires making precise the notion of `macroscopic.'
Entanglement is one of the most striking features of quantum mechanics, and yet it is not specifically quantum. More specific to quantum mechanics is the connection between entanglement and thermodynamics, which leads to an identification between entropies and measures of pure state entanglement. Here we search for the roots of this connection, investigating the relation between entanglement and thermodynamics in the framework of general probabilistic theories. We first address the question whether an entangled state can be transformed into another by means of local operations and classical co…
We argue that on its face, entanglement theory satisfies laws equivalent to thermodynamics if the theory can be made reversible by adding certain bound entangled states as a free resource during entanglement manipulation. Subject to plausible assumptions, we prove that this is not the case in general, and discuss the implications of this for the thermodynamics of entanglement.
We show that entanglement can be utilized to extract thermodynamic work beyond classical correlation via feedback control based on measurement on part of a composite system. The net work gain due to entanglement is determined by the change in the mutual information content between the subsystems that is accessible by the memory.
The quantum deformation of the Hopf algebra describes the skeleton of quantum field theory, namely its characterizing feature consisting in the existence of infinitely many unitarily inequivalent representations of the canonical commutation relations. From this we derive the thermal properties of quantum field theory, with the entropy playing the role of the generator of the non-unitary time evolution. The entanglement of the quantum vacuum appears to be robust against interaction with the environment: on cannot ``unknot the knots" in the infinite volume limit.
Recently David Jennings and Terry Rudolph published two papers as reaction on Maccone's paper "Quantum Solution to the Arrow-of-Time Dilemma". In these papers, the authors suppose that second law of thermodynamics is not relevant for quantum systems. Unfortunately, these papers did not get relevant reply from Maccone. The reason of this is following. Both Maccone and the above-mentioned authors use thermodynamic law and thermodynamic-like terminology for non-thermodynamic systems, for example, microscopic system of three qubits. However, big size of a system (quantum or classic) is also not an…
We study the entanglement spectra of bilayer quantum Hall systems at total filling factor nu=1. In the interlayer-coherent phase at layer separations smaller than a critical value, the entanglement spectra show a striking similarity to the energy spectra of the corresponding monolayer systems around half filling. The transition to the incoherent phase can be followed in terms of low-lying entanglement levels. Finally, we describe the connection between those two types of spectra in terms of an effective temperature leading to relations for the entanglement entropy which are in full analogy to …
We study the entanglement distillability properties of thermal states of many-body systems. Following the ideas presented in [D.Cavalcanti et al., arxiv:0705.3762], we first discuss the appearance of bound entanglement in those systems satisfying an entanglement area law. Then, we extend these results to other topologies, not necessarily satisfying an entanglement area law. We also study whether bound entanglement survives in the macroscopic limit of an infinite number of particles.
We discuss the possibility of existence of entanglement in biological systems. Our arguments centre on the fact that biological systems are thermodynamic open driven systems far from equilibrium. In such systems error correction can occur which may maintain entanglement despite high levels of de-coherence. We also discuss the possibility of cooling (classical or quantum) at molecular level.
The entanglement between the position and coin state of a $N$-dimensional quantum walker is shown to lead to a thermodynamic theory. The entropy, in this thermodynamics, is associated to the reduced density operator for the evolution of chirality, taking a partial trace over positions. From the asymptotic reduced density matrix it is possible to define thermodynamic quantities, such as the asymptotic entanglement entropy, temperature, Helmholz free energy, etc. We study in detail the case of a $2$-dimensional quantum walk, in the case of two different initial conditions: a non-separable coin-p…
Classical and quantum error correction are presented in the form of Maxwell's demon and their efficiency analyzed from the thermodynamic point of view. We explain how Landauer's principle of information erasure applies to both cases. By then extending this principle to entanglement manipulations we rederive upper bounds on purification procedures thereby linking the ''no local increase of entanglement'' principle to the Second Law of thermodynamics.
We demonstrate that both Wigner's form of Bell's inequalities as well as a form of the second law of thermodynamics, as manifest in Carathéodory's principle, can be derived from the same simple experimental and statistical mechanical assumptions combined with the trivial behavior of integers. This suggests that Bell's theorem is merely a well-disguised statement of the second law. It also suggests that entanglement is necessary for quantum theory to be in full accord with the second law and thus builds on the results of Wiesniak, Vedral, and Brukner \cite{Marcin-Wiesniak:2008fv} who showed it …
The relation between the theory of entanglement and thermodynamics is very tight: a thermodynamic theory of quantum entanglement, as well as the establishment of rigorous formal connections between the laws of thermodynamics and the phenomenology of entanglement are currently open areas of investigation. In this quest, an interesting problem is embodied by the role played by entanglement in processes of work extraction from a working medium embodied by quantum information carriers. In this work, we experimentally address the question "Is there any intrinsic advantage for work extraction given …
We investigate an asymptotically spatially flat Robertson-Walker spacetime from two different perspectives. First, using von Neumann entropy, we evaluate the entanglement generation due to the encoded information in spacetime. Then, we work out the entropy of particle creation based on the quantum thermodynamics of the scalar field on the underlying spacetime. We show that the general behavior of both entropies are the same. Therefore, the entanglement can be applied to the customary quantum thermodynamics of the universe. Also, using these entropies, we can recover some information about the …
The entanglement in a general mixed spin chain with arbitrary spin $S$ and 1/2 is investigated in the thermodynamical limit. The entanglement is witnessed by the magnetic susceptibility which decides a characteristic temperature for an entangled thermal state. The characteristic temperature is nearly proportional to the interaction $J$ and the mixed spin $S$. The bound of negativity is obtained on the basis of the magnetic susceptibility. It is found that the macroscopic magnetic properties are affected by the quantum entanglement in the real solids. Meanwhile, the entanglement can be quantita…
We present a simple and general factorization law for quantum systems shared by two parties, which describes the time evolution of entanglement upon passage of either component through an arbitrary noisy channel. The robustness of entanglement-based quantum information processing protocols is thus easily and fully characterized by a single quantity.
Here we investigate the impact of temporal entanglement on a system's ability to perform thermodynamical work. We show that while the quantum version of the Jarzynski equality remains satisfied even in the presence of temporal entanglement, the individual thermodynamical work moments in the expansion of the free energy are, in fact, sensitive to the genuine quantum correlations. Therefore, while individual moments of the amount of thermodynamical work can be larger (or smaller) quantumly than classically, when they are all combined together into the (exponential of) free energy, the total effe…
Explaining the influence of strong coupling in the dynamics of open quantum systems is one of the most challenging issues in the rapidly growing field of quantum thermodynamics. By using a particular definition of heat, we develop a new approach to study thermodynamics in the strong coupling regime, which takes into account quantum resources as coherence and entanglement. We apply the method to calculate the time-dependent thermodynamic properties of a system and an environment interacting via the generalized amplitude-damping channel (GADC). The results indicate that the transient imbalance b…
Recent results on the stability of the spectral gap under general perturbations for frustration-free Hamiltonians, have motivated the following question: Does the entanglement entropy of quantum states that are connected to states satisfying an area law along gapped Hamiltonian paths, also satisfy an area law? We answer this question in the affirmative, combining recent advances in quasi-adiabatic evolution and Lieb-Robinson bounds with ideas from the proof of the 1D area law.
Asher Peres' proof that a violation of No Cloning Theorem would imply a violation of the Second Law of Thermodynamics is shown not to take into account the algorithmic-information's contribution to the Thermodynamical Entropy of the semi-permeable membranes of Peres' engine.
Pure state entanglement transformations have been thought of as irreversible, with reversible transformations generally only possible in the limit of many copies. Here, we show that reversible entanglement transformations do not require processing on the many copy level, but can instead be undertaken on individual systems, provided the amount of entanglement which is produced or consumed is allowed to fluctuate. We derive necessary and sufficient conditions for entanglement manipulations in this case. As a corollary, we derive an equation which quantifies the fluctuations of entanglement, whic…
We develop a thermodynamical theory to describe the behavior of the entanglement between a single two-level atom with a single mode of the electromagnetic field. The resonant Jaynes-Cummings model is used to study both the entanglement thermodynamics, in particular the entanglement temperature, and its connection with the average number of photons in the optical cavity. We find that this entanglement temperature has a strong dependence with the initial conditions of the atom. We show that the entanglement temperature between the photons and the atom defined in this work is the same temperature…
We investigate further the relationship between the entanglement spectrum of a composite many-body system and the energy spectrum of a subsystem making use of concepts of canonical thermodynamics. In many important cases the entanglement Hamiltonian is, in the limit of strong coupling between subsystems, proportional to the energy Hamiltonian of the subsystem. The proportionality factor is an appropriately defined coupling parameter, suggesting to interpret the latter as a inverse temperature. We identify a condition on the entanglement Hamiltonian which rigorously guarantees this interpretati…
We study Hofstadter bilayers, i.e. coupled hopping models on two-dimensional square lattices in a perpendicular magnetic field. Upon tracing out one of the layers, we find an explicit expression for the resulting entanglement spectrum in terms of the energy eigenvalues of the underlying monolayer system. For strongly coupled layers the entanglement Hamiltonian is proportional to the energetic Hamiltonian of the monolayer system. The proportionality factor, however, cannot be interpreted as the inverse thermodynamic temperature, but represents a phenomenological temperature scale. We derive an …
Does bound entanglement naturally appear in quantum many-body systems? We address this question by showing the existence of bound-entangled thermal states for harmonic oscillator systems consisting of an arbitrary number of particles. By explicit calculations of the negativity for different partitions, we find a range of temperatures for which no entanglement can be distilled by means of local operations, despite the system being globally entangled. We offer an interpretation of this result in terms of entanglement-area laws, typical of these systems. Finally, we discuss generalizations of thi…
We develop a general approach to compute the symmetry-resolved Rényi and von Neumann entanglement entropies (SREE) of thermodynamic macrostates in interacting integrable systems. Our method is based on a combination of the thermodynamic Bethe ansatz and the Gärtner-Ellis theorem from large deviation theory. We derive an explicit simple formula for the von Neumann SREE, which we show to coincide with the thermodynamic Yang-Yang entropy of an effective macrostate determined by the charge sector. Focusing on the XXZ Heisenberg spin chain, we test our result against iTEBD calculations for thermal …
Quantum thermodynamics addresses the emergence of thermodynamical laws from quantum mechanics. The link is based on the intimate connection of quantum thermodynamics with the theory of open quantum systems. Quantum mechanics inserts dynamics into thermodynamics giving a sound foundation to finite-time-thermodynamics. The emergence of the 0-law I-law II-law and III-law of thermodynamics from quantum considerations is presented. The emphasis is on consistence between the two theories which address the same subject from different foundations. We claim that inconsistency is the result of faulty an…
A common framework for quantum mechanics, thermodynamics and information theory is presented. It is accomplished by reinterpreting the mathematical formalism of Everett's many-worlds theory of quantum mechanics and augmenting it to include preparation according to a given ensemble. The notion of \emph{directed entanglement} is introduced through which both classical and quantum communication over quantum channels are viewed as entanglement transfer. This point is illustrated by proving the Holevo bound and quantum data processing inequality relying exclusively on the properties of directed ent…
We argue that the entanglement entropy for a very small subsystem obeys a property which is analogous to the first law of thermodynamics when we excite the system. In relativistic setups, its effective temperature is proportional to the inverse of the subsystem size. This provides a universal relationship between the energy and the amount of quantum information. We derive the results using holography and confirm them in two dimensional field theories. We will also comment on an example with negative specific heat and suggest a connection between the second law of thermodynamics and the strong …
We study the bipartite entanglement entropy of the two-dimensional (2D) transverse-field Ising model in the thermodynamic limit using series expansion methods. Expansions are developed for the Renyi entropy around both the small-field and large-field limits, allowing the separate calculation of the entanglement associated with lines and corners at the boundary between sub-systems. Series extrapolations are used to extract subleading power laws and logarithmic singularities as the quantum critical point is approached. In 1D, we find excellent agreement with exact results as well as quantum Mont…
The free rider problem is one of the most well-studied problems in economics. The solution proposed mainly is punitive in order to deter people from free riding. In this work, we introduce quantum strategies and study the problem in the thermodynamic limit by drawing analogies with the 1D Ising model. We observe that for maximum entanglement, irrespective of the payoffs, quantum strategy is the equilibrium solution, solving the free rider problem.
We demonstrate an area law bound on the ground state entanglement entropy of a wide class of gapless quantum states of matter using a strategy called local entanglement thermodynamics. The bound depends only on thermodynamic data, actually a single exponent, the hyper-scaling violation exponent $θ$. All systems in $d$ spatial dimensions obeying our scaling assumptions and with $θ< d-1$ obey the area law, while systems with $θ= d-1$ can violate the area law at most logarithmically. We also discuss the case of frustration-free Hamiltonians and show that to violate the area law more than logarith…
Thermodynamical equilibrium is considered as an effect of quantum entangling of the vacuum state of a system. An explicit mathematical model of multi- particle entangled pure quantum states is developed and analyzed. In the framework, the process of measurement results in probability distributions that exactly correspond to the heat equilibrium of a system in a thermostat.
Over the last decade, significant progresses have been achieved to create Bose-Einstein condensates (BEC) of magnetic excitations, i.e., magnons, at the room temperature, which is a novel quantum many-body system with a strong spin-spin correlation, and contains potential applications in magnonic spintronics. For quantum information science, the magnonic condensates can become an attractive source of quantum entanglement, which plays a central role in most of the quantum information processing tasks. Here we theoretically study the entanglement properties of a magnon gas above and below the co…
Many fruitful analogies have emerged between the theories of quantum entanglement and thermodynamics, motivating the pursuit of an axiomatic description of entanglement akin to the laws of thermodynamics. A long-standing open problem has been to establish a true second law of entanglement, and in particular a unique function which governs all transformations between entangled systems, mirroring the role of entropy in thermodynamics. Contrary to previous promising evidence, here we show that this is impossible, and no direct counterpart to the second law of thermodynamics can be established. Th…
We investigate the fundamental limitations imposed by thermodynamics for creating correlations. Considering a collection of initially uncorrelated thermal quantum systems, we ask how much classical and quantum correlations can be obtained via a cyclic Hamiltonian process. We derive bounds on both the mutual information and entanglement of formation, as a function of the temperature of the systems and the available energy. While for a finite number of systems there is a maximal temperature allowing for the creation of entanglement, we show that genuine multipartite entanglement---the strongest …
