本文通过三维模拟研究热木星 HD 189733b 大气中光化学霾的输送与分布,揭示小粒子在晨侧明暗线聚集、大粒子在昏侧聚集的规律,并指出模型光谱与观测短波陡坡不匹配的可能原因。
摘要:
光化学霾已被认为是许多热木星透射光谱中观测到的高空气溶胶的候选来源。我们展示了对热木星 HD 189733b 的三维模拟,以研究光化学霾如何被大气环流输送。模型包含球形、恒定尺寸的霾粒子,这些粒子受重力沉降并作为被动示踪物被风输送,粒子半径范围从 1 nm 到 300 μm。我们根据粒子尺寸识别出两种一般类型的霾分布:在小粒子区间(<30 nm),重力沉降不重要,霾在两个以夜面为中心、跨越晨侧明暗线的中纬度大涡旋中累积。因此,小霾粒子在晨侧明暗线比在昏侧明暗线更集中。在大粒子区间(>30 nm),霾在夜面迅速沉降,导致昏侧明暗线处有更多霾。对于小粒子,分别考虑霾质量混合比和温度的明暗线差异,可以在明暗线的透射光谱中产生显著差异。然而,当对 HD 189733b 将两种效应结合时,它们在很大程度上相互抵消,导致光谱中的明暗线差异非常小。基于 GCM 导出的霾分布的透射光谱无法重现当前 HD 189733b 透射观测中短波长的陡峭光谱斜率。霾的不同光学性质、由于霾加热导致的低压处更高温度、增强的次网格尺度混合或恒星黑子可能解释模型与观测之间的不匹配。
英文摘要:
Photochemical hazes have been suggested as candidate for the high-altitude aerosols observed in the transmission spectra of many hot Jupiters. We present 3D simulations of the hot Jupiter HD 189733b to study how photochemical hazes are transported by atmospheric circulation. The model includes spherical, constant-size hazes particles that gravitationally settle and are transported by the winds as passive tracers, with particle radii ranging from 1 nm to 300 $μ$m. We identify two general types of haze distribution based on particle size: In the small-particle regime (<30 nm), gravitational settling is unimportant, and hazes accumulate in two large mid-latitude vortices centered on the night side that extend across the morning terminator. Therefore, small hazes are more concentrated at the morning terminator than at the evening terminator. In the large-particle regime (>30 nm), hazes settle out quickly on the nightside, resulting in more hazes at the evening terminator. For small particles, terminator differences in haze mass mixing ratio and temperature considered individually can result in significant differences in the transit spectra of the terminators. When combining both effects for HD189733b, however, they largely cancel out each other, resulting in very small terminator differences in the spectra. Transit spectra based on the GCM-derived haze distribution fail to reproduce the steep spectral slope at short wavelengths in the current transit observations of HD 189733b. Differing optical properties of hazes, hotter temperatures at low pressures because of heating by hazes, enhanced sub-grid-scale mixing, or star spots might explain the mismatch between the model and observations.
We investigate the impact of photochemical hazes and disequilibrium gases on the thermal structure of hot-Jupiters, using a detailed 1-D radiative-convective model. We find that the inclusion of photochemical hazes results in major heating of the upper and cooling of the lower atmosphere. Sulphur containing species, such as SH, S$_2$ and S$_3$ provide significant opacity in the middle atmosphere and lead to local heating near 1 mbar, while OH, CH, NH, and CN radicals produced by the photochemistry affect the thermal structure near 1 $μ$bar. Furthermore we show that the modifications on the the…
Constraints on the Microphysics of Pluto's Photochemical Haze from New Horizons Observations
新视野号飞越冥王星证实了其大气层中存在薄雾。观测到的高相亮度与低相亮度之比很大,再加上霾的蓝色,表明霾粒子是分形聚集体,类似于土卫六上的光化学霾。因此,研究冥王星的薄雾可以揭示冥王星和泰坦大气之间的相似性和差异。我们使用社区气溶胶和大气辐射模型来模拟雾霾分布,假设分布是由来自光化学的颗粒的沉降和凝聚形成的。被认为是由纯粹的球形和纯粹的分形聚集体颗粒的霾。当光化学产物的向下通量等于柱积分甲烷破坏率~1.2 $\times$ 10 $^{-14}$ g cm $^{-2}$ s $^{-1}$时,模型结果与掩星观测结果之间的一致性可通过聚集粒子获得,而对于球形粒子,质量通量必须大2-3倍。这一通量几乎与以前通过将微物理模型结果与卡西尼号观测结果进行比较而获得的土卫六的霾产生通量相同。根据前向散射测量,聚集体粒子半径对粒子带电很敏感,粒子荷径比为30 e-/μm是在冥王星表面附近产生约0.1-0.2 μm聚集体所必需的。这样的粒子荷径比以前在土卫六上获得的粒子荷径比高2-4倍。由具有相同粒子荷径比的球体组成的雾具有小4倍的粒子。这些结果进一步表明,烟雾颗粒是分形聚集体。我们还考虑了HCN和C $_{2}$ -碳氢化合物的凝结对霾颗粒的影响,这可能在形成它们的分布中起重要作用。
Refractive indices of photochemical haze analogs for Solar System and exoplanet applications : a cross-laboratory comparative study between the PAMPRE and COSmIC experimental set-ups
Three dimensional temporal evolution of photochemical haze in exoplanet atmospheres I. Description and test application to HD 189733b
Center for Space and Habitability, University of Bern(伯尔尼大学太空与宜居性中心);University of Chicago(芝加哥大学);National Astronomical Observatory of Japan(日本国立天文台);University of California, Santa Cruz(加州大学圣克鲁兹分校)
Flow-Driven Limb-Asymmetry of Haze Distribution Part I: An Analytical Framework for Predicting the Size Distribution of Photochemical Hazes Across the Two Limbs of hot-Jupiters
University of Oxford(牛津大学);University of Exeter(埃克塞特大学);Johns Hopkins University(约翰斯·霍普金斯大学)
Photochemical hazes are suspected to obscure molecular features, such as water, from detection in the transmission spectra of exoplanets with atmospheric temperatures < 800 K. The opacities of laboratory produced organic compounds (tholins) from Khare et al. (1984) have become a standard for modeling haze in exoplanet atmospheres. However, these tholins were grown in an oxygen-free, Titan-like environment that is very different from typical assumptions for exoplanets, where C/O~0.5. This work presents the 0.13-10 micron complex refractive indices derived from laboratory transmission measuremen…
Optical Constants of Photochemical Haze Analogs in N2-CH4-CO Atmospheres from 0.4 to 28.6 μm
National Key Laboratory of Deep Space Exploration/School of Earth and Space Sciences, University of Science and Technology of China(中国科学技术大学地球与空间科学学院深空探测重点实验室);Department of Earth and Planetary Sciences, Johns Hopkins University(约翰斯·霍普金斯大学地球与行星科学系);Space Telescope Science Institute(太空望远镜科学研究所)
We present a reanalysis (using the Minnaert limb-darkening approximation) of visible/near-infrared (0.3 - 2.5 micron) observations of Uranus and Neptune made by several instruments. We find a common model of the vertical aerosol distribution that is consistent with the observed reflectivity spectra of both planets, consisting of: 1) a deep aerosol layer with a base pressure > 5-7 bar, assumed to be composed of a mixture of H2S ice and photochemical haze; 2) a layer of photochemical haze/ice, coincident with a layer of high static stability at the methane condensation level at 1-2 bar; and 3) a…
We present a study of photochemical hazes of exoplanet atmospheres based on a self-consistent model including haze microphysics, disequilibrium chemistry, and radiative feedbacks. We derive the haze properties required to match HST observations of ten hot-Jupiters. HAT-P-12b, HD-189733b, HD-209458b and WASP-6b require haze mass fluxes between 5x10$^{-15}$ and 9x10$^{-12} g.cm^{-2}.s^{-1}$ to match the observations. WASP-12b and WASP-19b with equilibrium temperatures above 2000 K are incompatible with the presence of haze and are better fitted by heavy metals. HAT-P-1b and WASP-31b do not show …
Pluto, Titan, and Triton make up a unique class of solar system bodies, with icy surfaces and chemically reducing atmospheres rich in organic photochemistry and haze formation. Hazes play important roles in these atmospheres, with physical and chemical processes highly dependent on particle sizes, but the haze size distribution in reducing atmospheres is currently poorly understood. Here we report observational evidence that Pluto's haze particles are bimodally distributed, which successfully reproduces the full phase scattering observations from New Horizons. Combined with previous simulation…
Photochemical hazes are important opacity sources in temperate exoplanet atmospheres, hindering current observations from characterizing exoplanet atmospheric compositions. The haziness of an atmosphere is determined by the balance between haze production and removal. However, the material-dependent removal physics of the haze particles is currently unknown under exoplanetary conditions. Here we provide experimentally-measured surface energies for a grid of temperate exoplanet hazes to characterize haze removal in exoplanetary atmospheres. We found large variations of surface energies for haze…
The atmosphere of K2-18 b: The role of hazes, clouds and photoelectrons
Université Reims Champagne Ardenne(兰斯香槟阿登大学);Institut d’Astrophysique de Paris, UMR CNRS 7095(巴黎天体物理研究所);University College London(伦敦大学学院);King’s College London(伦敦国王学院);Observatoire de Paris, Université PSL, Sorbonne Université, Université Paris Cité, CY Cergy Paris Université, CNRS(巴黎天文台)
Seasonal Variability of Pluto's Haze Formation Revealed by Laboratory Simulations
University of Science and Technology of China(中国科学技术大学);Johns Hopkins University(约翰斯·霍普金斯大学);Space Telescope Science Institute(太空望远镜科学研究所);NASA Goddard Space Flight Center(美国宇航局戈达德太空飞行中心);Univ. Grenoble Alpes, CNRS, IPAG(格勒诺布尔阿尔卑斯大学,法国国家科学研究中心,IPAG);Department of Materials Science and Engineering, Johns Hopkins University(约翰斯·霍普金斯大学材料科学与工程系)
We present a computationally efficient 1-D seasonal radiative model, with convective adjustment, of Jupiter's atmosphere. Our model takes into account radiative forcings from the main hydrocarbons (methane, ethane, acetylene), ammonia, collision-induced absorption, four cloud and haze layers (including a UV-absorbing "polar" stratospheric haze) and an internal heat flux. We detail sensitivity studies of the equilibrium temperature profile to several parameters. We discuss the expected seasonal, vertical and meridional thermal structure and compare it to that derived from Cassini and ground-bas…
Many of the exoplanets for which we can obtain the highest SNR transit spectra are tidally locked. The atmospheres on tidally-locked planets likely exhibit large differences between the day and night side of the planet, the poles, and the morning versus evening terminators. In this paper, we illustrate how the combined effects of aerosols and day-night temperature gradients shape transit spectra of tidally-locked exoplanets when full 3D structures are taken into account and evaluate the implications for retrievals of atmospheric properties. To do this, we have developed a new code, METIS, whic…
Chemistry of Temperate Super-Earth and Mini-Neptune Atmospheric Hazes from Laboratory Experiments
很少有实验工作来探索在与外太阳系或早期地球的大气成分或温度非常不同的大气中形成的光化学烟雾的性质。随着太阳系外行星的发现数量达到数千,这个未开发的相空间值得探索。这项研究提出了测量的化学性质的烟雾颗粒产生的实验室模拟系外行星大气。我们使用甚高分辨率质谱仪测量大气室实验中产生的固体颗粒的化学成分。检测到许多复杂的分子种类,其化学通式为C $_w$ H $_x$ N $_y$ O $_z$。我们检测的数据,包括单糖甘油醛,各种氨基酸和核苷酸碱基,和几个糖衍生物的分子式的益生元的利益。此外,实验性的系外行星霾类似物表现出不同的溶解度特性,这为进一步了解超级地球和迷你海王星大气中光化学霾的化学或物理变化的可能性提供了见解。这些系外行星模拟粒子可以帮助我们更好地了解化学大气过程,并提出遥远世界原位大气生物前化学的可能来源。
Context: Relatively large radii of some hot Jupiters observed in the ultraviolet (UV) and blue-optical are generally interpreted to be due to Rayleigh scattering by high-altitude haze particles. However, the haze composition and its production mechanisms are not fully understood, and observational information is still limited. Aims: We aim to study the presence of hazes in the atmospheres of HD 209458 b and HD 189733 b with high spectral resolution spectra by analysing the strength of water vapour cross-correlation signals across the red optical and near-infrared wavelength ranges. Methods: A …
Having a short orbital period and being tidally locked makes WASP-43b an ideal candidate for JWST observations. Phase curve observations of an entire orbit will enable the mapping of the atmospheric structure across the planet, with different wavelengths of observation allowing different atmospheric depths to be seen. We provide insight into the details of the clouds that may form on WASP-43b in order to prepare the forthcoming interpretation of the JWST and follow-up data. We utilize 3D GCM results as input for a kinetic, non-equilibrium model for mineral cloud particles, and for a kinetic mo…
It is widely anticipated that the James Webb Space Telescope (JWST) will be transformative for exoplanet studies. It has even been suggested that JWST could provide the first opportunity to search for biosignatures in an alien atmosphere using transmission spectroscopy. This claim is investigated, specifically for the proposed anoxic biosignature pair CH4-CO2. The most favourable known target is adopted (TRAPPIST-1e), with an assumed atmospheric composition similar to the Archean Earth. Compared to previous studies, a more systematic investigation of the effect that cloud/haze-layers have on t…
We have conducted laboratory experiments to study the chemistry in hot Jupiter atmospheres with C/O ratio of 0.35. We have compared our results with the ones obtained previously for atmospheres with a C/O ratio of 1 to investigate the influence of the C/O ratio on the chemistry and formation of photochemical organic aerosol. We found that the C/O ratio and the gas mixture compositions strongly influence the pathways responsible for the formation of CO2. Thermochemical reactions are primarily responsible for the formation of CO2 in low C/O ratio atmospheres, while photochemistry is the dominant…
我们使用1D模型来解决光化学和可能的烟雾形成的照射温暖的木星,51波江座b。本计划的重点是碳,但硫的光化学结果是重要的。有机光化学烟雾的情况是有趣的,但缺乏令人信服的。如果有机烟雾形成,如果51 Eri b的垂直混合比木星弱,它们最有可能这样做,并且它们将在甲烷和水光解的高度以下被发现。更新颖的结果是,光化学将H $_2$ S转化为元素硫,在此处理为S $_8$。在较冷的模型中,S $_8$预计会凝结成固体硫颗粒的光学厚云,而在较暖的模型中,S $_8$与其他几种硫同素异形体一起保持蒸汽状态,这些硫同素异形体在视觉上引人注目,并且可能是可观察的。对于51 Eri b,有和没有冷凝硫的模型之间的分界线是在700 K的有效温度,这是在其实际有效温度的误差范围内;硫冷凝的局部温度在280和320 K之间。我们讨论的硫光化学反应非常普遍,应该在广泛的温度范围内的各种世界中发现,无论是比这里研究的650-750 K范围更冷还是更热,我们表明硫光化学反应的产物在紫外线辐射比51 Eri b弱几个数量级的行星上几乎同样丰富。
Observations to characterize planets larger than Earth but smaller than Neptune have led to largely inconclusive interpretations at low spectral resolution due to hazes or clouds that obscure molecular features in their spectra. However, here we show that high-resolution spectroscopy (R $\sim$ 25,000 to 100,000) enables one to probe the regions in these atmospheres above the clouds where the cores of the strongest spectral lines are formed. We present models of transmission spectra for a suite of GJ1214b-like planets with thick photochemical hazes covering 1 - 5 $μ$m at a range of resolutions …