Silicon and hydrogen chemistry under laboratory conditions mimicking the atmosphere of evolved stars
Mario Accolla, Gonzalo Santoro, Pablo Merino, Lidia Martínez, Guillermo Tajuelo-Castilla, Luis Vázquez, Jesús M. Sobrado, Marcelino Agúndez, Miguel Jiménez-Redo… 展开作者
Mario Accolla, Gonzalo Santoro, Pablo Merino, Lidia Martínez, Guillermo Tajuelo-Castilla, Luis Vázquez, Jesús M. Sobrado, Marcelino Agúndez, Miguel Jiménez-Redondo, Víctor J. Herrero, Isabel Tanarro, José Cernicharo, José Ángel Martín-Gago
Silicon is present in interstellar dust grains, meteorites and asteroids, and to date thirteen silicon-bearing molecules have been detected in the gas-phase towards late-type stars or molecular clouds, including silane and silane derivatives. In this work, we have experimentally studied the interaction between atomic silicon and hydrogen under physical conditions mimicking those at the atmosphere of evolved stars. We have found that the chemistry of Si, H and H$_2$ efficiently produces silane (SiH$_4$), disilane (Si$_2$H$_6$) and amorphous hydrogenated silicon (a-Si:H) grains. Silane has been definitely detected towards the carbon-rich star IRC\,+10216, while disilane has not been detected in space yet. Thus, based on our results, we propose that gas-phase reactions of atomic Si with H and H$_2$ are a plausible source of silane in C-rich AGBs, although its contribution to the total SiH$_4$ abundance may be low in comparison with the suggested formation route by catalytic reactions on the surface of dust grains. In addition, the produced a-Si:H dust analogs decompose into SiH$_4$ and Si$_2$H$_6$ at temperatures above 500 K, suggesting an additional mechanism of formation of these species in envelopes around evolved stars. We have also found that the exposure of these dust analogs to water vapor leads to the incorporation of oxygen into Si-O-Si and Si-OH groups at the expense of SiH moieties, which implies that, if this type of grains are present in the interstellar medium, they will be probably processed into silicates through the interaction with water ices covering the surface of dust grains.
We report an unbiased radio line survey towards the circumstellar envelopes of evolved stars at the frequency range from 20 to 25 GHz, aiming to obtain a more complete unbiased picture of the chemical evolution in the final stages of stellar evolution. The observation sample includes the asymptotic giant branch (AGB) star IRC+10216, the proto-planetary nebulae (PPNs) CRL\,2688 and CRL\,618, and the young planetary nebula (PN) NGC\,7027, representing an evolutionary sequence spanning about 10,000 years. Rotational transitions from cyanopolyyne chains and inversion lines from ammonia are detecte…
We study a group of evolved M-stars in the Large Magellanic Cloud, characterized by a peculiar spectral energy distribution. While the $9.7~μ$m feature arises from silicate particles, the whole infrared data seem to suggest the presence of an additional featureless dust species. We propose that the circumstellar envelopes of these sources are characterized by a dual dust chemistry, with an internal region, harbouring carbonaceous particles, and an external zone, populated by silicate, iron and alumina dust grains. Based on the comparison with results from stellar modelling that describe the du…
{CircumStellar Envelopes (CSEs) of stars are complex chemical objects for which theoretical models encounter difficulties in elaborating a comprehensive overview of the occurring chemical processes. Along with photodissociation, ion-neutral reactions and dissociative recombination might play an important role in controlling molecular growth in outer CSEs. The aim of this work is to provide experimental insights into pathways of photochemistry-driven molecular growth within outer CSEs to draw a more complete picture of the chemical processes occurring within these molecule-rich environments. A …
We present deep CCS and HC$_7$N observations of the L1495-B218 filaments in the Taurus molecular cloud obtained using the K-band focal plane array on the 100m Green Bank Telescope. We observed the L1495-B218 filaments in CCS $J_N$ = 2$_1$$-$1$_0$ and HC$_7$N $J$ = 21$-$20 with a spectral resolution of 0.038 km s$^{-1}$ and an angular resolution of 31$''$. We observed strong CCS emission in both evolved and young regions and weak emission in two evolved regions. HC$_7$N emission is observed only in L1495A-N and L1521D. We find that CCS and HC$_7$N intensity peaks do not coincide with NH$_3$ or …
The formation of Polycyclic Aromatic Hydrocarbons in the circumstellar outflows of evolved stars is reviewed, with an emphasis on carbon stars on the Asymptotic Giant Branch. Evidence for PAHs present in their winds is provided by meteoritic studies and recent observations of the Unidentified Infrared bands. We detail the chemical processes leading to the closure of the first aromatic ring as well as the growth mechanisms leading to amorphous carbon grains. Existing studies on PAH formation in evolved stellar envelopes are reviewed and new results for the modelling of the inner wind of the arc…
The circumstellar ammonia (NH$_3$) chemistry in evolved stars is poorly understood. Previous observations and modelling showed that NH$_3$ abundance in oxygen-rich stars is several orders of magnitude above that predicted by equilibrium chemistry. In this article, we characterise the spatial distribution and excitation of NH$_3$ in the O-rich circumstellar envelopes (CSEs) of four diverse targets: IK Tau, VY CMa, OH 231.8+4.2, and IRC +10420 with multi-wavelength observations. We observed the 1.3-cm inversion line emission with the Very Large Array (VLA) and submillimetre rotational line emiss…
We aim to quantify the effect of chemistry on the infall velocity in the prestellar core L1544. Previous observational studies have found evidence for double-peaked line profiles for the rotational transitions of several molecules, which cannot be accounted for with the models presently available for the physical structure of the source, without ad hoc up-scaling of the infall velocity. We ran one-dimensional hydrodynamical simulations of the collapse of a core with L1544-like properties (in terms of mass and outer radius), using a state-of-the-art chemical model with a very large chemical net…
Grain surface chemistry is key to the composition of protoplanetary disks around young stars. The temperature of grains depends on their size. We evaluate the impact of this temperature dependence on the disk chemistry. We model a moderately massive disk with 16 different grain sizes. We use POLARIS to calculate the dust grain temperatures and the local UV flux. We model the chemistry using the 3-phase astrochemical code NAUTILUS. Photoprocesses are handled using frequency-dependent cross-sections, and a new method to account for self and mutual shielding. The multi-grain model outputs are com…
Context: While star formation on large molecular cloud scales and on small core and disk scales has been investigated intensely over the past decades, the connection of the large-scale interstellar material with the densest small-scale cores has been a largely neglected field. Methods: Using NOEMA and the IRAM 30\,m telescope, we mapped large areas (640\,arcmin$^2$) of the archetypical star formation complex Cygnus X at 3.6\,mm wavelengths in line and continuum emission. Results: The scope and outline of The Cygnus Allscale Survey of Chemistry and Dynamical Environments (CASCADE) is presented.…
We report a search for the diatomic hydrides SiH, PH, and FeH along the line of sight toward the chemically rich circumstellar envelopes of IRC+10216 and VY Canis Majoris. These molecules are thought to form in high temperature regions near the photospheres of these stars, and may then further react via gas-phase and dust-grain interactions leading to more complex species, but have yet to be constrained by observation. We used the GREAT spectrometer on SOFIA to search for rotational emission lines of these molecules in four spectral windows ranging from 600 GHz to 1500 GHz. Though none of the …
Thermally irreversible sulfur chemisorption on silicate grains as a major sulfur reservoir in molecular clouds
Institute of Low Temperature Science, Hokkaido University（北海道大学低温科学研究所）；Department of Chemistry, Hiroshima University（广岛大学化学系）；Departamento de Astrofísica Molecular, Instituto de Física Fundamental, CSIC（西班牙国家研究委员会基础物理研究所分子天体物理学部）；RIKEN Pioneering Research Institute（理研先锋研究机构）
The object W33 is a giant molecular cloud that contains star forming regions at various evolutionary stages from quiescent clumps to developed H II regions. Since its star forming regions are located at the same distance and the primary material of the birth clouds is probably similar, we conducted a comparative chemical study to trace the chemical footprint of the different phases of evolution. We observed six clumps in W33 with the Atacama Pathfinder Experiment (APEX) telescope at 280 GHz and the Submillimeter Array (SMA) at 230 GHz. We detected 27 transitions of 10 different molecules in th…
For decades, the detection of phosphorus-bearing molecules in the interstellar medium was restricted to high-mass star-forming regions (as e.g. SgrB2 and Orion KL) and the circumstellar envelopes of evolved stars. However, recent higher-sensitivity observations have revealed that molecules such as PN and PO are present not only toward cold massive cores and low-mass star-forming regions with PO/PN ratios >1, but also toward the Giant Molecular Clouds in the Galactic Center known to be exposed to highly energetic phenomena such as intense UV radiation fields, shock waves and cosmic rays. In thi…
Interstellar molecules are thought to build up in the shielded environment of molecular clouds or in the envelope of evolved stars. This follows many sequential reaction steps of atoms and simple molecules in the gas phase and/or on (icy) grain surfaces. However, these chemical routes are highly inefficient for larger species in the tenuous environment of space as many steps are involved and, indeed, models fail to explain the observed high abundances. This is definitely the case for the C$_{60}$ fullerene, recently identified as one of the most complex molecules in the interstellar medium. Ob…
The recently discovered Indus stellar stream exhibits a diverse chemical signature compared to what is found for most other streams due to the abundances of two outlier stars, Indus$\_$0 and Indus$\_$13. Indus$\_$13, exhibits an extreme enhancement in rapid neutron-capture ($r$-)process elements with $\mathrm{[Eu/Fe]} = +1.81$. It thus provides direct evidence of the accreted nature of $r$-process enhanced stars. In this paper we present a detailed chemical analysis of the neutron-capture elements in Indus$\_$13, revealing the star to be slightly actinide poor. The other outlier, Indus$\_0$, d…
Ultraviolet (UV) photodissociation of CO controls the abundances and distribution of CO and its photodissociation products. This significantly influences the gas-phase chemistry in the circumstellar envelope (CSE) around evolved stars. A better understanding of CO photodissociation in outflows also provides a more precise estimate of mass-loss rates. We aim to update the CO photodissociation rate in an expanding spherical envelope assuming that the interstellar radiation field (ISRF) photons penetrate through the envelope. This will allow us to precisely estimate the CO abundance distributions…
We present mid-IR observations of the Galactic Luminous Blue Variable (LBV) HR Car and its associated nebula carried out with the Spitzer Space Telescope using both IRAC and IRS, as part of a GTO program aimed to study stellar ejecta from evolved stars. Our observations reveal a rich mid-IR spectrum of the inner nebula showing both solid state and atomic gas signatures. Strong low-excitation atomic fine structure lines such as $ 26.0 μ$m [\ion{Fe}{2}] and $ 34.8 μ$m [\ion{Si}{2}], indicate, for the first time, the presence of a PDR in this object class. While the physics and chemistry of the l…
HCN, HNC, and their isotopologues are ubiquitous molecules that can serve as chemical thermometers and evolutionary tracers to characterize star-forming regions. Despite their importance in carrying information that is vital to studies of the chemistry and evolution of star-forming regions, the collision rates of some of these molecules have not been available for rigorous studies in the past. We perform an up-to-date gas and dust chemical characterization of two different star-forming regions, TMC 1-C and NGC 1333-C7, using new collisional rates of HCN, HNC, and their isotopologues. We invest…
Aluminum oxide (alumina, Al$_{2}$O$_{3}$) is a promising candidate as a primary dust condensate in the atmospheres of oxygen-rich evolved stars. Therefore, alumina \textit{seed} particles might trigger the onset of stellar dust formation and of stellar mass loss in the wind. However, the formation of alumina dust grains is not well understood.} {To shed light on the initial steps of cosmic dust formation (i.e. nucleation) in oxygen-rich environments by a quantum-chemical bottom-up approach.} {Starting with an elemental gas-phase composition, we construct a detailed chemical-kinetic network des…
We present JCMT SCUBA-2 $450μ$m and $850μ$m observations of 14 Asymptotic Giant Branch (AGB) stars (9 O--rich, 4 C-rich and 1 S--type) and one Red Supergiant (RSG) in the Solar Neighbourhood. We combine these observations with \emph{Herschel}/PACS observations at $70μ$m and $160μ$m and obtain azimuthally-averaged surface-brightness profiles and their PSF subtracted residuals. The extent of the SCUBA-2 850 $μ$m emission ranges from 0.01 to 0.16 pc with an average of $\sim40\%$ of the total flux being emitted from the extended component. By fitting a modified black-body to the four-point SED at …
We present synthetic continuum and $^{13}$CO and C$^{18}$O line emission observations of dense and cold filaments. The filaments are dynamically evolved using 3D-MHD simulations that include one of the largest on-the-fly chemical networks used to date, which models the detailed evolution of H$_2$ and CO. We investigate the reliability of observable properties, in particular filament mass and width, under different simulation conditions like magnetic field orientation and cosmic ray ionisation rate. We find that filament widths of $\sim$0.1 pc can be probed with both line and continuum emission…
My thesis work aims to study the inter-relation between various physical and chemical conditions in a wide range of astrophysical environments. Our studied regions range from the super-hot regions (i.e., nebular, photon-dominated, or photodissociation regions, diffuse area, through which the lights of the background stars can reach us) to the super-cold regions (i.e., dense molecular clouds, proto-planetary disks, etc. where interstellar dust particles absorb all background visible and ultra-violet lights). The chemical complexity of the interstellar cloud gradually evolves due to the evolutio…
The initial stage of star formation is a complex area study because of its high density and low temperature. Under such conditions, many molecules become depleted from the gas phase by freezing out onto dust grains. However, the deuterated species could remain gaseous and are thus ideal tracers. We investigate the gas dynamics and NH$_2$D chemistry in eight massive pre/protocluster clumps. We present NH$_2$D 1$_{11}$-1$_{01}$ (at 85.926 GHz), NH$_3$ (1, 1) and (2, 2) observations in the eight clumps using the PdBI and the VLA, respectively. We find that the distribution between deuterium fract…
We have studied four complex organic molecules (COMs), methyl formate ($CH_3OCHO$), dimethyl ether ($CH_3OCH_3$), formamide ($NH_2CHO$), and ethyl cyanide ($C_2H_5CN$), towards a large sample of 39 high-mass star-forming regions representing different evolutionary stages, from early to evolved phases. We aim to identify potential correlations between the molecules and to trace their evolutionary sequence through the star formation process. We analysed spectra obtained at 3, 2, and 0.9 mm with the IRAM-30m telescope. We derived the main physical parameters for each species by fitting the molecu…
Our knowledge of the chemical properties of the circumstellar ejecta of the most massive evolved stars is particularly poor. We aim to study the chemical characteristics of the prototypical yellow hypergiant star, IRC +10420. For this purpose, we obtained full line surveys at 1 and 3mm atmospheric windows. We have identified 106 molecular emission lines from 22 molecular species. Approximately half of the molecules detected are N-bearing species, in particular HCN, HNC, CN, NO, NS, PN, and N2H+. We used rotational diagrams to derive the density and rotational temperature of the different molec…
The evolved massive binary star Eta Carinae underwent eruptive mass loss events that formed the complex bi-polar Homunculus nebula harboring tens of solar masses of unusually nitrogen-rich gas and dust. Despite expectations for the presence of a significant molecular component to the gas, detections have been observationally challenged by limited access to the far-infrared and the intense thermal continuum. A spectral survey of the atomic and rotational molecular transitions was carried out with the Herschel Space Observatory, revealing a rich spectrum of broad emission lines originating in th…
Abundances and partitioning of ices and gases produced by gas-grain chemistry are governed by adsorption and desorption on grains. Understanding astrophysical observations rely on laboratory measurements of adsorption and desorption rates on dust grains analogs. On flat surfaces, gas adsorption probabilities (or sticking coefficients) have been found close to unity for most gases. Here we report a strong decrease of the sticking coefficients of H2O and CO2 on substrates more akin to cosmic dust, such as submicrometer-sized particles of carbon and olivine, bare or covered with ice. This effect …
Phosphorus is a crucial element in prebiotic chemistry, especially the P$-$O bond, which is key for the formation of the backbone of the deoxyribonucleic acid. So far, PO had only been detected towards the envelope of evolved stars, and never towards star-forming regions. We report the first detection of PO towards two massive star-forming regions, W51 e1/e2 and W3(OH), using data from the IRAM 30m telescope. PN has also been detected towards the two regions. The abundance ratio PO/PN is 1.8 and 3 for W51 and W3(OH), respectively. Our chemical model indicates that the two molecules are chemica…
