We present the spin quantum Otto machine under different optimization criterion when function either as a heat engine or a refrigerator. We examine the optimal performance of the heat engine and refrigerator depending on their efficiency, output power and maximum entropy production. For heat engine case, we obtain the expression for the upper and lower bounds efficiencies at maximum power and maximum ecological function. In addition, the spin quantum Otto refrigerator coefficient of performance is optimized for three different criterion -- cooling power, product of performance and power and ecological function. We further study the dimensionless power loss to the cold reservoir when the machine is operating as a heat engine as well as its counterpart for the refrigerator case. We find that the maximum operation of the heat engine (refrigerator) cycle is when optimized with respect to hot (cold) reservoir frequency.
We consider the optimization of the work output and fluctuations of a finite-time quantum Otto heat engine cycle consisting of compression and expansion work strokes of unequal duration. The asymmetry of the cycle is characterized by a parameter $r_u$ giving the ratio of the times for the compression and expansion work strokes. For such an asymmetric quantum Otto engine cycle, with working substance chosen as a harmonic oscillator or a two-level system, we find that the optimal values of $r_u$ maximising the work output and the reliability (defined as the ratio of average work output to its st…
We investigate quantum Otto engine and refrigeration cycles of a time-dependent harmonic oscillator operating under the conditions of maximum $Ω$-function, a trade-off objective function which represents a compromise between energy benefits and losses for a specific job, for both adiabatic and nonadiabatic (sudden) frequency modulations. We derive analytical expressions for the efficiency and coefficient of performance of the Otto cycle. For the case of adiabatic driving, we point out that in the low-temperature regime, the harmonic Otto engine (refrigerator) can be mapped to Feynman's ratchet…
We use fast periodic control to realize finite-time Otto cycles exhibiting quantum advantage. Such periodic modulation of the working medium - bath interaction Hamiltonian during the thermalization strokes can give rise to non-Markovian anti-Zeno dynamics, and corresponding reduction in the thermalization times. Faster thermalization can in turn significantly enhance the power output in engines, or equivalently, the rate of refrigeration in refrigerators. This improvement in performance of dynamically controlled Otto thermal machines arises due to the time-energy uncertainty relation of quantu…
The stochastic efficiency [G. Verley et al., Nat. Commun. 5, 4721 (2014)] was introduced to evaluate the performance of energy-conversion machines in micro-scale. However, such an efficiency generally diverges when no heat is absorbed while work is produced in a thermodynamic cycle. As a result, any statistical moments of the efficiency do not exist. In this study, we come up with a different version of the definition for the stochastic efficiency which is always finite. Its mean value is equal to the conventional efficiency, and higher moments characterize the fluctuations of the cycle. In ad…
The charging of a quantum battery by a four-stroke quantum machine that works either as an engine or a refrigerator is investigated. The presented analysis provides the energetic behavior of the combined system in terms of the heat and workflows of the machine, the average, and variance of the battery's energy as well as the coherent and incoherent parts of its ergotropy. To monitor the battery state its energy is measured either after the completion of any cycle or after a prescribed number of cycles is carried out. The resulting battery performances greatly differ for those two cases. During…
We investigate the performance of a quantum Otto refrigerator operating in finite time and exploiting local counterdiabatic techniques. We evaluate its coefficient of performance and cooling power when the working medium consists a quantum harmonic oscillator with a time-dependent frequency. We find that the quantum refrigerator outperforms its conventional counterpart, except for very short cycle times, even when the driving cost of the local counterdiabatic driving is included. We moreover derive upper bounds on the performance of the thermal machine based on quantum speed limits and show th…
In this letter, we analyze a conceptual design for the operation of an Otto cycle heat machine driven by adiabatic modifications on the electronic effective mass. Such tailoring of it can be implemented, for instance, via the application of external electron fields in some materials, as in Gallium Nitride (GaN). We show that due both the energy quantization on this structure and the adiabatic transformation of the effective mass, the machine performance can be improved. The realization of classically inconceivable Otto machines, with an incompressible working substance, can be realized as well…
Effects of Magnetic Anisotropy on 3-Qubit Antiferromagnetic Thermal Machines
Pontificia Universidad Católica de Valparaíso（天主教瓦爾帕萊索大學）；Universidad Técnica Federico Santa María（費德里科·聖塔瑪麗亞理工大學）；Millennium Nucleus in NanoBioPhysics (NNBP)（納米生物物理千年核）；Universidad Mayor（馬約爾大學）；Ohio University（俄亥俄大學）
Universitat de València-CSIC（瓦伦西亚大学-CSIC）；IFIC, Universitat de València-CSIC（IFIC，瓦伦西亚大学-CSIC）；JILA, NIST, and Department of Physics, University of Colorado（JILA，美国国家标准与技术研究院，科罗拉多大学物理系）；University of Colorado（科罗拉多大学）；IUMPA - Instituto Universitario de Matemática Pura y Aplicada, Universitat Politècnica de València（IUMPA-纯数学与应用数学大学研究所，巴伦西亚理工大学）；Adam Mickiewicz University（亚当·密茨凯维奇大学）；DIPC - Donostia International Physics Center（DIPC-圣塞巴斯蒂安国际物理中心）；IKERBASQUE, Basque Foundation for Science（IKERBASQUE，巴斯克科学基金会）；ICREA（加泰罗尼亚高级研究学院）；ETH Zurich（苏黎世联邦理工学院）
This paper presents a conceptual design for quantum heat machines using a pair of coupled double quantum dots (DQDs), each DQD with an excess electron to interact, as an working substance. We define a compression ratio as the ratio between the Coulomb couplings which describes the interaction between the electrons during the isochoric processes of the quantum Otto cycle and then we analyse the arising of different regimes of operations of our thermal machine. We also show how we can achieve a classically inconceivable Otto engine, when considering the effects due to the parameters related to t…
Quantum thermal machines make use of non-classical thermodynamic resources, one of which is interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to an external magnetic field and coupled via an isotropic Heisenberg exchange interaction. It has been earlier shown that the said interaction provides an enhancement of cycle efficiency for two spin-1/2 particles, with an upper bound which is tighter than the Carnot efficiency. However, the necessary conditions g…
Institute of Engineering Mathematics, Universiti Malaysia Perlis（马来西亚玻璃市大学工程数学研究所）；Department of Physics, University of Cross River State（克罗斯河州立大学物理系）；Department of Physics, National Open University of Nigeria（尼日利亚国家开放大学物理系）；School of Mathematics, Statistics and Physics, Newcastle University（纽卡斯尔大学数学、统计与物理学院）；Faculty of Electronic Engineering & Technology, Universiti Malaysia Perlis（马来西亚玻璃市大学电子工程与技术学院）
The efficiency of small thermal machines is typically a fluctuating quantity. We here study the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follows the 'universal' theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We relate this unusual property to the perfect anticorrelation between work output and heat input that generically occurs in the broad class of scale-invariant ad…
We investigate the performance of a quantum thermal machine operating in finite time based on shortcut-to-adiabaticity techniques. We compute efficiency and power for a quantum harmonic Otto engine by taking the energetic cost of the superadiabatic driving explicitly into account. We further derive generic upper bounds on both quantities, valid for any heat engine cycle, using the notion of quantum speed limits for driven systems. We demonstrate that these quantum bounds are tighter than those stemming from the second law of thermodynamics.
We derive cooling rate and coefficient of performance as well as their variances for a quantum Otto engine proceeding in finite-time cycle period. This machine consists of two driven strokes, where the system isolated from the heat reservoir undergoes finite-time unitary transformation, and two isochoric steps, where the finite-time system-bath interaction durations take the system away from the equilibrium even at the respective ends of the two stages. We explicitly calculate the statistics of cooling rate and coefficient of performance for the machine operating with an analytically solvable …
Bosonic Working Media in a Frustrated Rhombi Chain: Otto and Stirling Cycles from Flat Bands, Caging, and Flux Control
Facultad de Ingeniería, Universidad San Sebastián（圣塞巴斯蒂安大学工程学院）；Departamento de Física, Universidad Técnica Federico Santa María（智利技术费德里科·萨马拉大学物理系）；Department of Physics, Universitat Autònoma de Barcelona（巴塞罗那自治大学物理系）；Instituto de Física, Pontificia Universidad Católica de Valparaíso（天主教瓦尔帕莱索大学物理研究所）；Physical and Computational Sciences,Pacific Northwest National Laboratory（太平洋西北国家实验室物理与计算科学部）；Departamento de Física, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile（智利大学物理与数学科学学院物理系）
In this work we study how the non-Markovian character of the dynamics can affect the thermodynamic performance of a quantum thermal engine, by analysing the maximum power output of Carnot and Otto cycles departing from the quasi-static and infinite-time-thermalization regime respectively, introducing techniques for their control optimization in general dynamical models. In our model, non-Markovianity is introduced by allowing some degrees of freedom of the reservoirs to be taken into account explicitly and share correlations with the engine by Hamiltonian coupling. It is found that the non-Mar…
The performance of quantum heat engines is generally based on the analysis of a single cycle. We challenge this approach by showing that the total work performed by a quantum engine need not be proportional to the number of cycles. Furthermore, optimizing the engine over multiple cycles leads to the identification of scenarios with a quantum enhancement. We demonstrate our findings with a quantum Otto engine based on a two-level system as the working substance that supplies power to an external oscillator.
The operation of a quantum heat engine in finite time generally faces a trade-off between efficiency and power. Using shortcuts to adiabaticity (STA), this trade off can be avoided to engineer thermal machines that operate at maximum efficiency and tunable output power. We demonstrate the use of STA to engineer a scalable superadiabatic quantum Otto cycle and report recent experimental progress to tailor quantum friction in finite-time quantum thermodynamics. In the presence of quantum friction, it is also shown that the use of a many-particle working medium can boost the performance of the qu…
We present a quantum Otto engine model consisting of two isochoric and two adiabatic strokes, where the adiabatic expansion or compression is realized by adiabatically changing the shape of the potential. Here we show that such an adiabatic deformation may alter operation mode and enhance machine performance by increasing output work and efficiency, even with the advantage of decreasing work fluctuations. If the heat engine operates under maximal power by optimizing the control parameter, the efficiency shows certain universal behavior.
We demonstrate the existence of universal features in the finite-time thermodynamics of quantum machines by considering a many-body quantum Otto cycle in which the working medium is driven across quantum critical points during the unitary strokes. Specifically, we consider a quantum engine powered by dissipative energizing and relaxing baths. We show that under very generic conditions, the output work is governed by the Kibble-Zurek mechanism, i.e., it exhibits a universal power-law scaling with the driving speed through the critical points. We also optimize the finite-time thermodynamics as a…
Identifying optimal thermodynamical processes has been the essence of thermodynamics since its inception. Here, we show that differentiable programming (DP), a machine learning (ML) tool, can be employed to optimize finite-time thermodynamical processes in a quantum thermal machine. We consider the paradigmatic quantum Otto engine with a time-dependent harmonic oscillator as its working fluid, and build upon shortcut-to-adiabaticity (STA) protocols. We formulate the STA driving protocol as a constrained optimization task and apply DP to find optimal driving profiles for an appropriate figure o…
The impacts of quantum coherence on nonequilibrium thermodynamics become observable by dividing the heat and work into the conventional diagonal part and the other part relaying on the superpositions and the time derivative of Hamiltonian. Specializing to exactly-solvable dynamics of Larmor precession, we build a quantum Otto heat engine employing magnetic-driven atomic rotations. The coherence induced by the population transition guarantees the positive work output when the control protocol is time dependent. The time-dependent control of a quantum heat engine implements the correspondence be…
We study the performance of a quantum Otto cycle using a harmonic work medium and undergoing collisional dynamics with finite-size reservoirs. We span the dynamical regimes of the work strokes from strongly non-adiabatic to quasi-static conditions, and address the effects that non-Markovianity of the open-system dynamics of the work medium can have on the efficiency of the thermal machine. While such efficiency never surpasses the classical upper bound valid for finite-time stochastic engines, the behaviour of the engine shows clear-cut effects induced by both the finiteness of the evolution t…
Quantum heat engines are subjected to quantum fluctuations related to their discrete energy spectra. Such fluctuations question the reliable operation of quantum engines in the microscopic realm. We here realize an endoreversible quantum Otto cycle in the large quasi-spin states of Cesium impurities immersed in an ultracold Rubidium bath. Endoreversible machines are internally reversible and irreversible losses only occur via thermal contact. We employ quantum control over both machine and bath to suppress internal dissipation and regulate the direction of heat transfer that occurs via inelast…
Theoretical treatments of periodically-driven quantum thermal machines (PD-QTMs) are largely focused on the limit-cycle stage of operation characterized by a periodic state of the system. Yet, this regime is not immediately accessible for experimental verification. Here, we present a general thermodynamic framework that can handle the performance of PD-QTMs both before and during the limit-cycle stage of operation. It is achieved by observing that periodicity may break down at the ensemble average level, even in the limit-cycle phase. With this observation, and using conventional thermodynamic…
The thermodynamic properties of quantum heat engines are stochastic owing to the presence of thermal and quantum fluctuations. We here experimentally investigate the efficiency and nonequilibrium entropy production statistics of a spin-1/2 quantum Otto cycle. We first study the correlations between work and heat within a cycle by extracting their joint distribution for different driving times. We show that near perfect anticorrelation, corresponding to the tight-coupling condition, can be achieved. In this limit, the reconstructed efficiency distribution is peaked at the macroscopic efficiency…
We propose a system made of three quantum harmonic oscillators as a compact quantum engine for producing mechanical work. The three oscillators play respectively the role of the hot bath, the working medium and the cold bath. The working medium performs an Otto cycle during which its frequency is changed and it is sequentially coupled to each of the two other oscillators. As the two environments are finite, the lifetime of the machine is finite and after a number of cycles it stops working and needs to be reset. We analyse the entanglement and quantum discord generated during the strokes and s…
We study the optimization of the performance of arbitrary periodically driven thermal machines. Within the assumption of fast modulation of the driving parameters, we derive the optimal cycle that universally maximizes the extracted power of heat engines, the cooling power of refrigerators, and in general any linear combination of the heat currents. We denote this optimal solution as ``generalized Otto cycle'' since it shares the basic structure with the standard Otto cycle, but it is characterized by a greater number of fast strokes. We bound this number in terms of the dimension of the Hilbe…
Developments in the thermodynamics of small quantum systems envisage non-classical thermal machines. In this scenario, energy fluctuations play a relevant role in the description of irreversibility. We experimentally implement a quantum heat engine based on a spin-1/2 system and nuclear magnetic resonance techniques. Irreversibility at microscope scale is fully characterized by the assessment of energy fluctuations associated with the work and heat flows. We also investigate the efficiency lag related to the entropy production at finite time. The implemented heat engine operates in a regime wh…
