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arXiv 2007.10710cond-mat.mtrl-scinucl-ex
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中子辐照T91回火马氏体钢中偏析驱动的Cu和Mn-Ni-Si共沉淀的原子探针表征

Atom probe characterisation of segregation driven Cu and Mn-Ni-Si co-precipitation in neutron irradiated T91 tempered-martensitic steel

T. P. Davis, M. A. Auger, N. Almirall, P. Hosemann, G. R. Odette, P. A. J. Bagot, M. P. Moody, D. E. J. Armstrong

摘要:

T91级和类似的9 Cr回火马氏体钢(也称为铁素体-马氏体)是用于快裂变核反应堆和聚变动力反应堆的主要候选结构合金。在低温(300至400 $^\circ$ C)中子辐照硬化和脆化这些钢,因此,重要的是调查这种模式的寿命限制性能退化的起源。T91钢试样分别在爱达荷国家实验室先进试验反应堆中在327 $^\circ$ C和377 $^\circ$ C下进行2.14 dpa和8.82 dpa的中子辐照。采用原子探针层析成像技术研究了富Mn-Ni-Si(MNSP)和富Cu(CRP)共沉淀物的偏析驱动形成。在较高的辐照温度和剂量下,析出物的尺寸和体积分数略有增加,而它们相应的成分非常相似,落在Fe基四元相图的Mn-Ni-Si投影中的Si(Mn,Ni)相场附近。虽然沉淀物的结构尚未被表征,但该组成范围明显不同于典型引用的G相。沉淀物由CRP和MNSP组成。这些特征经常在中子辐照反应堆压力容器(RPV)钢中观察到。然而,Si,Ni,Mn,P和Cu溶质浓度在T91中低于典型的RPV钢。因此,在T91沉淀主要发生在线和环位错的溶质偏析区域。这些结果与Ke等人提出的MNSP的辐射诱导偏析驱动沉淀的模型一致。未观察到富Cr α '($α$ ')相的形成。

英文摘要:

The T91 grade and similar 9Cr tempered-martensitic steels (also known as ferritic-martensitic) are leading candidate structural alloys for fast fission nuclear and fusion power reactors. At low temperatures (300 to 400 $^\circ$C) neutron irradiation hardens and embrittles these steels, therefore it is important to investigate the origin of this mode of life limiting property degradation. T91 steel specimens were separately neutron irradiated to 2.14 dpa at 327 $^\circ$C and 8.82 dpa at 377 $^\circ$C in the Idaho National Laboratory Advanced Test Reactor. Atom probe tomography was used to investigate the segregation driven formation of Mn-Ni-Si-rich (MNSPs) and Cu-rich (CRP) co-precipitates. The precipitates increase in size and, slightly, in volume fraction at the higher irradiation temperature and dose, while their corresponding compositions were very similar, falling near the Si(Mn,Ni) phase field in the Mn-Ni-Si projection of the Fe-based quaternary phase diagram. While the structure of the precipitates has not been characterized, this composition range is distinctly different than that of the typically cited G-phase. The precipitates are composed of CRP with MNSP appendages. Such features are often observed in neutron irradiated reactor pressure vessel (RPV) steels. However, the Si, Ni, Mn, P and Cu solutes concentrations are lower in the T91 than in typical RPV steels. Thus, in T91 precipitation primarily takes place in solute segregated regions of line and loop dislocations. These results are consistent with the model for radiation induced segregation driven precipitation of MNSPs proposed by Ke et al. Cr-rich alpha prime ($α$') phase formation was not observed.

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