Quantum chemistry is one of the important applications of quantum information technology. Especially, an estimation of the energy gap between a ground state and excited state of a target Hamiltonian corresponding to a molecule is essential. In the previous approach, an energy of the ground state and that of the excited state are estimated separately, and the energy gap can be calculated from the subtraction between them. Here, we propose a direct estimation of the energy gap between the ground state and excited state of the target Hamiltonian with quantum annealing. The key idea is to combine a Ramsey type measurement with the quantum annealing. This provides an oscillating signal with a frequency of the energy gap, and a Fourier transform of the signal let us know the energy gap. Based on typical parameters of superconducting qubits, we numerically investigate the performance of our scheme when we estimate an energy gap between the ground state and first excited state of the Hamiltonian. We show robustness against non-adiabatic transitions between the ground state and first-excited state. Our results pave a new way to estimate the energy gap of the Hamiltonian for quantum chemistry.
The shortest vector problem (SVP) is one of the lattice problems and is mathematical basis for the lattice-based cryptography, which is expected to be post-quantum cryptography. The SVP can be mapped onto the Ising problem, which in principle can be solved by quantum annealing (QA). However, one issue in solving the SVP using QA is that the solution of the SVP corresponds to the first excited state of the problem Hamiltonian. Therefore, QA, which searches for ground states, cannot provide a solution with high probability. In this paper, we propose to adopt an excited-state search of the QA to …
Quantum annealing (QA) is one of the ways to search the ground state of the problem Hamiltonian. Here, we propose the QA scheme to search arbitrary excited states of the problem Hamiltonian. In our scheme, an $n$-th excited state of the trivial Hamiltonian is initially prepared and is adiabatically changed into an $n$-th excited state of the target Hamiltonian. Although our scheme is general such that we can search any excited states, we especially discuss the first excited state search in this paper. As a comparison, we consider a non-adiabatic scheme to find the first excited state with non-…
We have proposed the energy landscape transformation of Ising problems (ELTIP), which changes the combination of the state and eigenvalue without changing all the original eigenvalues [arXiv:2202.05927]. We study how the ELTIP affects the anti-crossing between two levels of the ground and first excited states during quantum annealing. We use a 5-spin maximum-weighted independent set for the problem to numerically investigate the anticrossing. For comparison, we introduce a non-stoquastic Hamiltonian that adds antiferromagnetic interaction to the normal transverse magnetic field. Annealing with…
We study a quantum annealer where bosons mediate the Ising-type interactions between qubits. We compare the efficiency of ground state preparation for direct and mediated couplings, for which Ising and spin-boson Hamiltonian are employed respectively. This comparison is done numerically for a small frustrated antiferromagnet, with a careful choice of the optimal adiabatic passage that reveals the features of the boson-mediated interactions. Those features can be explained by taking into account what we called excited solutions: states with the same spin correlations as the ground-state but wit…
Beyond Ground States: Physics-Inspired Optimization of Excited States of Classical Hamiltonians
ICFO-Institut de Ciencies Fotoniques, The Barcelona Institute of Science and Technology（光子科学研究所，巴塞罗那科技研究所）；ICREA-Institucio Catalana de Recerca i Estudis Avançats（加泰罗尼亚研究高级学院）
Diabatic quantum annealing (DQA) is an alternative algorithm to adiabatic quantum annealing (AQA) that can be used to circumvent the exponential slowdown caused by small minima in the annealing energy spectrum. We present the locally suppressed transverse-field (LSTF) protocol, a heuristic method for making stoquastic optimization problems compatible with DQA. We show that, provided an optimization problem intrinsically has magnetic frustration due to inhomogeneous local fields, a target qubit in the problem can always be manipulated to create a double minimum in the energy gap between the gro…
Preparing ground states of Hamiltonians is important in the condensed matter physics and the quantum chemistry. The interaction Hamiltonians typically contain not only diagonal but also off-diagonal elements. Although quantum annealing provides a way to prepare a ground state of a Hamiltonian, we can only use the Hamiltonian with Ising interaction by using currently available commercial quantum annealing devices. In this work, we propose a quantum annealing for the XXZ model, which contains both Ising interaction and energy-exchange interaction, by using inductively coupled superconducting flu…
In a typical quantum annealing protocol, the system starts with a transverse field Hamiltonian which is gradually turned off and replaced by a longitudinal Ising Hamiltonian. The ground state of the Ising Hamiltonian encodes the solution to the computational problem of interest, and the state overlap with this ground state gives the success probability of the annealing protocol. The form of the annealing schedule can have a significant impact on the ground state overlap at the end of the anneal, so precise control over these annealing schedules can be a powerful tool for increasing success pro…
Sampling all ground states of a Hamiltonian with equal probability is a desired feature of a sampling algorithm, but recent studies indicate that common variants of transverse field quantum annealing sample the ground state subspace unfairly. In this note, we present perturbation theory arguments suggesting that this deficiency can be corrected by employing reverse annealing-inspired paths. We confirm that this conclusion holds in simulations of previously studied small instances with degeneracy, as well as larger instances on quantum annealing hardware.
We study the performance of the D-Wave 2X quantum annealing machine on systems with well-controlled ground-state degeneracy. While obtaining the ground state of a spin-glass benchmark instance represents a difficult task, the gold standard for any optimization algorithm or machine is to sample all solutions that minimize the Hamiltonian with more or less equal probability. Our results show that while naive transverse-field quantum annealing on the D-Wave 2X device can find the ground-state energy of the problems, it is not well suited in identifying all degenerate ground-state configurations a…
We propose a two qubit experiment for validating tunable antiferromagnetic $XX$ interactions in quantum annealing. Such interactions allow the time-dependent Hamiltonian to be non-stoquastic, and the instantaneous ground state can have negative amplitudes in the computational basis. Our construction relies on how the degeneracy of the Ising Hamiltonian's ground states is broken away from the end point of the anneal: above a certain value of the antiferromagnetic $XX$ interaction strength, the perturbative ground state at the end of the anneal changes from a symmetric to an antisymmetric state.…
Quantum chemistry calculations are important applications of quantum annealing. For practical applications in quantum chemistry, it is essential to estimate a ground state energy of the Hamiltonian with chemical accuracy. However, there are no known methods to guarantee the accuracy of the estimation of the energy calculated by quantum annealing. Here, we propose a way to improve the accuracy of the estimate of the ground state energy by combining quantum annealing with classical computation. In our scheme, before running the QA, we need a pre-estimation of the energies of the ground state and…
In the computational model of quantum annealing, the size of the minimum gap between the ground state and the first excited state of the system is of particular importance, since it is inversely proportional to the running time of the algorithm. Thus, it is desirable to keep the gap as large as possible during the annealing process, since it allows the computation to remain under the protection of the adiabatic theorem while staying efficient. We propose steered quantum annealing as a new method to enlarge the gap throughout the process, in the case of diagonal final Hamiltonians, based on the…
For quantum annealing, as opposed to circuit based quantum computing, the solution to a computational problem is encoded in the ground state of a quantum system. Therefore its susceptibility to environmental effects is a different but not less important open question essential to a scalable implementation. In this work we use renormalization group techniques to study the effect of Ohmic baths in a regime typical for practical adiabatic quantum computation. We show qualitative change to the effective Hamiltonian as well as the reduced qubit density matrix encoding entanglement between system an…
Adiabatic quantum computation (AQC) is a promising counterpart of universal quantum computation, based on the key concept of quantum annealing (QA). QA is claimed to be at the basis of commercial quantum computers and benefits from the fact that the detrimental role of decoherence and dephasing seems to have poor impact on the annealing towards the ground state. While many papers show interesting optimization results with a sizable number of qubits, a clear evidence of a full quantum coherent behavior during the whole annealing procedure is still lacking. In this paper we show that quantum non…
Quantum annealing is a heuristic algorithm for searching the ground state of an Ising model. Heuristic algorithms aim to obtain near-optimal solutions with a reasonable computation time. Accordingly, many algorithms have so far been proposed. In general, the performance of heuristic algorithms strongly depends on the instance of the combinatorial optimization problem to be solved because they escape the local minima in different ways. Therefore, combining several algorithms to exploit their complementary strength is effective for obtaining highly accurate solutions for a wide range of combinat…
The debate around the potential superiority of quantum annealers over their classical counterparts has been ongoing since the inception of the field by Kadowaki and Nishimori close to two decades ago. Recent technological breakthroughs in the field, which have led to the manufacture of experimental prototypes of quantum annealing optimizers with sizes approaching the practical regime, have reignited this discussion. However, the demonstration of quantum annealing speedups remains to this day an elusive albeit coveted goal. Here, we examine the power of quantum annealers to provide a different …
Closed-system quantum annealing is expected to sometimes fail spectacularly in solving simple problems for which the gap becomes exponentially small in the problem size. Much less is known about whether this gap scaling also impedes open-system quantum annealing. Here we study the performance of a quantum annealing processor in solving such a problem: a ferromagnetic chain with sectors of alternating coupling strength that is classically trivial but exhibits an exponentially decreasing gap in the sector size. The gap is several orders of magnitude smaller than the device temperature. Contrary …
We study the problem to infer the ground state of a spin-glass Hamiltonian using data from another Hamiltonian with interactions disturbed by noise from the original Hamiltonian, motivated by the ground-state inference in quantum annealing on a noisy device. It is shown that the average Hamming distance between the inferred spin configuration and the true ground state is minimized when the temperature of the noisy system is kept at a finite value, and not at zero temperature. We present a spin-glass generalization of a well-established result that the ground state of a purely ferromagnetic Ham…
We study the effect of the anneal path control per qubit, a new user control feature offered on the D-Wave 2000Q quantum annealer, on the performance of quantum annealing for solving optimization problems by numerically solving the time-dependent Schrödinger equation for the time-dependent Hamiltonian modeling the annealing problems. The anneal path control is thereby modeled as a modified linear annealing scheme, resulting in an advanced and retarded scheme. The considered optimization problems are 2-SAT problems with 12 Boolean variables, a known unique ground state and a highly degenerate f…
We confirmed the annealing time of Grover's search which is required to obtain desired success probability for quantum annealing by the imaginary-time and the real-time Schrödinger equation with two kinds of schedulings; one linearly decreases the quantum fluctuation and the other tunes the evolution rate of the Hamiltonian based on the adiabatic condition. With linear scheduling, the required annealing time for quantum annealing by the imaginary-time Schrödinger equation is of order $\log N$, which is very different from $O(N)$ required for the quantum annealing by the real-time Schrödinger e…
Quantum annealing tends to be more difficult as the energy landscape of the problem becomes complicated with many local minima. We have found a transformation for changing the energy landscape that swaps the eigenvalues and paired states without changing the eigenvalues of the instance at all. The transformation is basically a partial recombination of the two-spin interaction coefficient Jij and the longitudinal magnetic field interaction coefficient hi. The Hamming distance corresponding to a barrier between the states changes by the transformation, which in turn affects the ground state conv…
We study the problem to infer the original ground state of a spin-glass Hamiltonian out of the information from the Hamiltonian with interactions deviated from the original ones. Our motivation comes from quantum annealing on a real device in which the values of interactions are degraded by noise. We show numerically for quasi-one-dimensional systems that the Hamming distance between the original ground state and the inferred spin state is minimized when we stop the process of quantum annealing before the amplitude of the transverse field reaches zero in contrast to the conventional prescripti…
We solve a model that has basic features that are desired for quantum annealing computations: entanglement in the ground state, controllable annealing speed, ground state energy separated by a gap during the whole evolution, and a programmable computational problem that is encoded by parameters of the Ising part of the spin Hamiltonian. Our solution enables exact nonperturbative characterization of final nonadiabatic excitations, including a scaling of their number with the annealing rate and the system size. We prove that quantum correlations can accelerate computations and, at the end of the…
We formulate and analyze a double-slit proposal for quantum annealing, which involves observing the probability of finding a two-level system (TLS) undergoing evolution from a transverse to a longitudinal field in the ground state at the final time $t_f$. We demonstrate that for annealing schedules involving two consecutive diabatic transitions, an interference effect is generated akin to a double-slit experiment. The observation of oscillations in the ground state probability as a function of $t_f$ (before the adiabatic limit sets in) then constitutes a sensitive test of coherence between ene…
A mixed-integer linear programming (MILP) formulation is presented for parameter estimation of the Potts model. Two algorithms are developed; the first method estimates the parameters such that the set of ground states replicate the user-prescribed data set; the second method allows the user to prescribe the ground states multiplicity. In both instances, the optimization process ensures that the bandgap is maximized. Consequently, the model parameter efficiently describes the user data for a broad range of temperatures. This is useful in the development of energy-based graph models to be simul…
Quantum annealing (QA) is one of the efficient methods to calculate the ground-state energy of a problem Hamiltonian. In the absence of noise, QA can accurately estimate the ground-state energy if the adiabatic condition is satisfied. However, in actual physical implementation, systems suffer from decoherence. On the other hand, much effort has been paid into the noisy intermediate-scale quantum (NISQ) computation research. For practical NISQ computation, many error mitigation (EM) methods have been devised to remove noise effects. In this paper, we propose a QA strategy combined with the EM m…
We present Counterdiabatic Reverse Annealing, a novel quantum annealing protocol that extends the range of application of reverse annealing to the previously inaccessible short-time domain. This is achieved by exploiting approximate counterdiabatic driving expanded in low-order nested commutators. In this work, we offer a comparative study of the performance of this new technique to that of unassisted reverse annealing in terms of metrics such as the ground-state fidelity and the time to solution. We provide a quantitative measure of the energetic cost of counterdiabatic reverse annealing and …
Reverse annealing is a variant of quantum annealing, in which the system is prepared in a classical state, reverse-annealed to an inversion point, and then forward-annealed. We report on reverse annealing experiments using the D-Wave 2000Q device, with a focus on the $p=2$ $p$-spin problem, which undergoes a second order quantum phase transition with a gap that closes polynomially in the number of spins. We concentrate on the total and partial success probabilities, the latter being the probabilities of finding each of two degenerate ground states of all spins up or all spins down, the former …
We study a bifurcation mechanism of quantum annealing. Using spins with quantum number S=1, we construct a simple model to make a bifurcation. The qutrit can be composed by nesting two qubits. We numerically solve the Schroedinger equation to confirm that the bifurcation-based quantum annealing (BQA) works well and the ground state can be found efficiently. The result is compared with that by the standard quantum annealing (QA) using qubits. We find that the performance of the BQA is comparable to the standard QA, or gives better results in some cases.
Quantum annealing solves combinatorial optimization problems by finding the energetic ground states of an embedded Hamiltonian. However, quantum annealing dynamics under the embedded Hamiltonian may violate the principles of adiabatic evolution and generate excitations that correspond to errors in the computed solution. Here we empirically benchmark the probability of chain breaks and identify sweet spots for solving a suite of embedded Hamiltonians. We further correlate the physical location of chain breaks in the quantum annealing hardware with the underlying embedding technique and use thes…
Quantum annealing (QA) is a promising method for solving combinatorial optimization problems whose solutions are embedded into a ground state of the Ising Hamiltonian. This method employs two types of Hamiltonians: a driver Hamiltonian and a problem Hamiltonian. After a sufficiently slow change from the driver Hamiltonian to the problem Hamiltonian, we can obtain the target ground state that corresponds to the solution. The inclusion of non-stoquastic terms in the driver Hamiltonian is believed to enhance the efficiency of the QA. Meanwhile, decoherence is regarded as of the main obstacles for…
Toward an alternative approach to the quantum mechanic ground state search, we theoretically introduce a protocol in which energy of two identical systems are deterministically exchanged. The protocol utilizes a quantum interference between "forward" and "backward" time evolved states with respect to a given Hamiltonian. In addition, to make use the protocol for the ground state search, we construct a network with which we may be able to efficiently apply the protocol successively among multiple systems so that energy of one of them is gradually approaching the lowest one. Although rigorous an…
Quantum annealing aims at finding optimal solutions to complex optimization problems using a suitable quantum many body Hamiltonian encoding the solution in its ground state. To find the solution one typically evolves the ground state of a soluble initial Hamiltonian adiabatically to the ground state of the designated final Hamiltonian. Here we explore whether and when a full quantum representation of the dynamics leads to higher probability to end up in the desired ground when compared to a classical mean field approximation. As simple, nontrivial example we target the ground state of interac…
Conventional quantum annealing does not sample all ground states fairly. We demonstrate that fair sampling can be achieved by performing simulated annealing on a quantum annealer. We discuss the problems that occur when implementing this method and propose an alternative way to overcome them. We numerically verify the fair sampling ability of our method in a small-scale toy model.
A promising approach to solving hard binary optimisation problems is quantum adiabatic annealing (QA) in a transverse magnetic field. An instantaneous ground state --- initially a symmetric superposition of all possible assignments of $N$ qubits --- is closely tracked as it becomes more and more localised near the global minimum of the classical energy. Regions where the energy gap to excited states is small (e.g. at the phase transition) are the algorithm's bottlenecks. Here I show how for large problems the complexity becomes dominated by $O(\log N)$ bottlenecks inside the spin glass phase, …
The Potts model is a generalization of the Ising model with $Q>2$ components. In the fully connected ferromagnetic Potts model, a first-order phase transition is induced by varying thermal fluctuations. Therefore, the computational time required to obtain the ground states by simulated annealing exponentially increases with the system size. This study analytically confirms that the transverse magnetic-field quantum annealing induces a first-order phase transition. This result implies that quantum annealing does not exponentially accelerate the ground-state search of the ferromagnetic Potts mod…
Frustration-enhanced quantum annealing correction models with additional inter-replica interactions
Graduate School of Science and Technology, Keio University（庆应义塾大学理工学部）；Department of Applied Physics and Physico-Informatics, Keio University（庆应义塾大学应用物理与物理信息学系）；Keio University Sustainable Quantum Artificial Intelligence Center (KSQAIC), Keio University（庆应义塾大学可持续量子人工智能中心）；Human Biology-Microbiome-Quantum Research Center (WPI-Bio2Q), Keio University（庆应义塾大学人类生物学-微生物组-量子研究中心）
Suppressing unwanted transitions out of the instantaneous ground state is a major challenge in unitary adiabatic quantum computation. A recent approach consists in building counterdiabatic potentials approximated using variational strategies. In this contribution, we extend this variational approach to Lindbladian dynamics, having as a goal the suppression of diabatic transitions between pairs of Jordan blocks in quantum annealing. We show that, surprisingly, unitary counterdiabatic ansätze are successful for dissipative dynamics as well, allowing for easier experimental implementations compar…
The study of optimal control of quantum annealing by modulating the pace of evolution and by introducing a counterdiabatic potential has gained significant attention in recent times. In this work, we present a numerical approach based on genetic algorithms to improve the performance of quantum annealing, which evades the Landau-Zener transitions to navigate to the ground state of the final Hamiltonian with high probability. We optimize the annealing schedules starting from polynomial ansatz by treating their coefficients as chromosomes of the genetic algorithm. We also explore shortcuts to adi…
