From the sixties a deep and surprising connection has followed the development of superconductivity and quantum field theory. The Anderson-Higgs mechanism and the similarities between the Dirac and Bogoliubov-de Gennes equations are the most intriguing examples. In this last analogy, the massive Dirac particle is identified with a quasiparticle excitation and the fermion mass energy with the superconducting gap energy. Here we follow further this parallelism and show that it predicts an outstanding phenomenon: the superconducting Schwinger effect (SSE). As in the quantum electrodynamics Schwinger effect, where an electron-positron couple is created from the vacuum by an intense electric field, we show that an electrostatic field can generate two coherent excitations from the superconducting ground-state condensate. Differently from the dissipative thermal excitation, these form a new macroscopically coherent and dissipationless state. We discuss how the superconducting state is weakened by the creation of this kind of excitations. In addition to shed a different light and suggest a method for the experimental verification of the Schwinger effect, our results pave the way to the understanding and exploitation of the interaction between superconductors and electric fields.
We analyze conditions of applicability of grand-canonical mean-field Bardeen-Cooper-Schrieffer theory to the evaluation of an interaction energy in the ground state of small-sized superconductors. We argue that this theory fails to describe correctly an interaction energy, when an average distance between energy levels near the Fermi energy due to the size quantization becomes of the order of the single-pair binding energy. In conventional superconductors, this quantity is much smaller than the superconducting gap.
We investigate the photon-mediated heat flow between two Josephson-coupled Bardeen-Cooper-Schrieffer (BCS) superconductors. We demonstrate that in standard low temperature experiments involving temperature-biased superconducting quantum interference devices (SQUIDs), this radiative contribution is negligible if compared to the direct galvanic one, but it largely exceeds the heat exchanged between electrons and the lattice phonons. The corresponding thermal conductance is found to be several orders of magnitude smaller, for real experiments setup parameters, than the universal quantum of therma…
We use in-plane tunneling spectroscopy to study the temperature dependence of the local superconducting gap $Δ(T)$ in electron-doped copper oxides with various $T_c$'s and Ce-doping concentrations. We show that the temperature dependence of $Δ(T)$ follows the expectation of the Bardeen-Cooper-Schrieffer (BCS) theory of superconductivity, where $Δ(0)/k_{B}T_{c}\approx1.72\pm 0.15$ and $Δ(0)$ is the average superconducting gap across the Fermi surface, for all the doping levels investigated. These results suggest that the electron-doped superconducting copper oxides are weak coupling BCS superco…
Superfluidity and superconductivity are genuine many-body manifestations of quantum coherence. For finite-size systems the associated pairing gap fluctuates as a function of size or shape. We provide a parameter free theoretical description of pairing fluctuations in mesoscopic systems characterized by order/chaos dynamics. The theory accurately describes experimental observations of nuclear superfluidity (regular system), predicts universal fluctuations of superconductivity in small chaotic metallic grains, and provides a global analysis in ultracold Fermi gases.
We formulate a new Bardeen-Cooper-Schrieffer (BCS)-type theory at finite temperature, by deriving a set of variational equations of the free energy after the particle-number projection. With its broad applicability, this theory can be a useful tool for investigating the pairing phase transition in finite systems with the particle-number conservation. This theory provides effects of the symmetry-restoring fluctuation (SRF) for the pairing phenomena in finite fermionic systems, distinctively from those of additional quantum fluctuations. It is shown by numerical calculations that the phase trans…
Shortly after the Gor'kov microscopic derivation of the Ginzburg-Landau (GL) model via a small order parameter expansion in Bardeen-Cooper-Schrieffer theory of superconductivity, the derivation was carried to next-to-leading order in that parameter and its spatial derivatives. The aim was to obtain a generalized GL free energy that approximates the microscopic model better. Since 1960s, multiple works have claimed or implicitly assumed that this extended GL model corresponds to the free energy and has solutions in the form of local minima describing superconductivity, such as vortex solutions.…
In disordered superconductors, the local pairing field fluctuates in space, leading to the smearing of the BCS peak in the density of states and appearance of the subgap tail states. We analyze the universal mesoscopic contributions to these effects and show that they are enhanced by the Coulomb repulsion. In the vicinity of the quantum critical point, where superconductivity is suppressed by the "fermionic mechanism", strong smearing of the peak due to mesoscopic fluctuations is predicted.
Bardeen-Cooper-Schrieffer (BCS) theory describes a superconducting transition as a single critical point where the gap function or, equivalently, the order parameter vanishes uniformly in the entire system. We demonstrate that in superconductors described by standard BCS models, the superconducting gap survives near the sample boundaries at higher temperatures than superconductivity in the bulk. Therefore, conventional superconductors have multiple critical points associated with separate phase transitions at the boundary and in the bulk. We show this by revising the Caroli-De Gennes-Matricon …
Scanning tunneling spectroscopies in the subKelvin temperature range were performed on superconducting Silicon epilayers doped with Boron in the atomic percent range. The resulting local differential conductance behaved as expected for a homogeneous superconductor, with an energy gap dispersion below +/- 10%. The spectral shape, the amplitude and temperature dependence of the superconductivity gap follow the BCS model, bringing further support to the hypothesis of a hole pairing mechanism mediated by phonons in the weak coupling limit.
Time-reversal symmetry breaking (TRSB) with a Bardeen-Cooper-Schrieffer (BCS) -like superconductivity occurs in a small, but growing number of noncentrosymmetric (NCS) materials, although the mechanism is poorly understood. We present heat capacity, magnetization, resistivity, and muon spin resonance/relaxation ($μ$SR) measurements on polycrystalline samples of NCS La$_{7}$Pd$_{3}$. Transverse-field $μ$SR and heat capacity data show La$_{7}$Pd$_{3}$ is a type-II superconductor with a BCS-like gap structure, while zero-field $μ$SR results provide evidence of TRSB. We discuss the implications of…
We demonstrate the rise-and-fall of multiple pseudogaps in the Bardeen-Cooper-Schrieffer-Bose-Einstein-condensation (BCS-BEC) crossover in two-band fermionic systems having different pairing strengths in the deep band and in the shallow band. The striking features of this phenomenon are an unusual many-body screening of pseudogap state and the importance of pair-exchange couplings, which induces multiple pseudogap formation in the two bands. The multi-band configuration suppresses pairing fluctuations and the pseudogap opening in the strongly-interacting shallow band at small pair-exchange cou…
We develop a concise self-consistent perturbation expansion for superconductivity where all the pair processes are naturally incorporated without drawing "anomalous" Feynman diagrams. This simplification results from introducing an interaction vertex that is symmetric in the particle-hole indices besides the ordinary space-spin coordinates. The formalism automatically satisfies conservation laws, includes the Luttinger-Ward theory as the normal-state limit, and reproduces the Bardeen-Cooper-Schrieffer theory as the lowest-order approximation. It enables us to study the thermodynamic, single-pa…
Convergence of Ginzburg-Landau expansions: superconductivity in the Bardeen-Cooper-Schrieffer theory and chiral symmetry breaking in the Nambu-Jona-Lasinio model
We show how multi-level BCS Hamiltonians of finite systems in the strong pairing interaction regime can be accurately approximated using multi-dimensional shifted harmonic oscillator Hamiltonians. In the Shifted Harmonic Approximation (SHA), discrete quantum state variables are approximated as continuous ones and algebraic Hamiltonians are replaced by differential operators. Using the SHA, the results of the BCS theory, such as the gap equations, can be easily derived without the BCS approximation. In addition, the SHA preserves the symmetries associated with the BCS Hamiltonians. Lastly, for …
We study superconductivity in multilayer copper oxides, in the frame of a realistic microscopic formulation. Solving the full temperature dependent BCS gap equations, we obtain a maximum in the transition temperature Tc for M=3 or 4 CuO2 layers in the unit cell for appropriate values of the interlayer tunneling (negative pair tunneling), and via the consideration of the doping imbalance between the inner and outer layers. This is the ubiquitous experimental result for Ca intercalated copper oxides, as opposed to other intercalating elements. Further, using a restricted set of parameters, we ob…
We establish universal behavior in temperature dependencies of some observables in $(s+id)$-wave BCS superconductivity in the presence of a weak $s$ wave. There also could appear a second second-order phase transition. As temperature is lowered past the usual critical temperature $T_c$, a less ordered superconducting phase is created in $d$ wave, which changes to a more ordered phase in $(s+id)$ wave at $T_{c1}$ ($< T_c$). The presence of two phase transitions manifest in two jumps in specific heat at $T_c$ and $T_{c1}$. The temperature dependencies of susceptibility, penetration depth, and th…
Despite the multi-band spectrum of the widely-known Hofstadter butterfly, it turns out that the pairing correlations of the time-reversal-symmetric Hofstadter-Hubbard model are well-described by a single order parameter that is uniform in real space. By exploiting a BCS mean-field theory for the nearly-flat butterfly-bands regime of low magnetic-flux limit, here we reveal a number of unusual superfluid properties both in the ground state and at finite temperatures. Our thorough analysis includes but is not limited to the order parameter, condensate and superfluid fractions, and the critical BC…
Experimental discovery of near-room-temperature (NRT) superconductivity in highly-compressed H$_3$S, LaH$_1$$_0$ and YH$_6$ restores fundamental interest to electron-phonon pairing mechanism in superconductors. One of prerequisites of phonon-mediated NRT superconductivity in highly-compressed hydrides is strong electron-phonon interaction, which can be quantified by dimensionless ratios of Bardeen-Cooper-Schrieffer (BCS) theory vs $k{_B}T{_c}$/(${\hslash}$$ω{_l}{_n}$), where Tc is the critical temperature and $ω{_l}{_n}$ is the logarithmic phonon frequency (Mitrovic et al. 1984 Phys. Rev. B 29…
Starting from H. Fröhlich's second-quantized Hamiltonian for a $d$-dimensional electron gas in interaction with lattice phonons describing the quantum vibrations of a metal, we present a rigorous mathematical derivation of the superconducting state, following the principles laid out originally in 1957 by J. Bardeen, L. Cooper and J. Schrieffer. As in the series of papers written on the subject in the 90es, of which the present paper is a continuation, the representation of ions as a uniform charge background allows for a $(1+d)$-dimensional fermionic quantum-field theoretic reformulation of th…
We apply the functional path-integral approach to analyze how the presence of a spin-orbit coupling (SOC) affects the basic properties of a BCS-type paired state in a two-component Bose gas. In addition to a mean-field theory that is based on the saddle-point approximation for the inter-component pairing, we derive a Ginzburg-Landau theory by including the Gaussian fluctuations on top, and use them to reveal the crucial roles played by the momentum-space structure of an arbitrary SOC field in the stability of the paired state at finite temperatures. For this purpose, we calculate the critical …
In nonperturbative regimes, the superfluid instability in the two-dimensional Hubbard model can be described by an emergent BCS theory with small effective pairing constants. We compute the effective couplings using a controlled bold-line diagrammatic Monte Carlo approach, which stochastically sums all skeleton Feynman diagrams dressed in the one- and two-particle channels to high expansion orders, and map out the resulting superfluid ground-state phase diagram in a range of next-nearest-neighbor hopping $0 \leq t^{\prime} \leq 0.3t$, interaction strength $0 \leq U \leq 3t$, and lattice fillin…
Comparative study of quartet superfluid state: Quartet Bardeen-Cooper-Schrieffer theory and generalized Nambu-Gor'kov formalism
RIKEN Nishina Center for Accelerator-Based Science（理化学研究所西村加速器科学中心）；Department of Physics, Graduate School of Science, The University of Tokyo（东京大学理学研究科物理学系）；Quark Nuclear Science Institute, The University of Tokyo（东京大学夸克核科学研究所）；RIKEN Center for Interdisciplinary Theoretical and Mathematical Sciences (iTHEMS)（理化学研究所交叉理论数学科学中心）
For a two-dimensional conductor under the conditions of the Bardeen-Cooper-Schrieffer mechanism of superconductivity, a factor resulting in economy in kinetic energy upon the transition to the superconducting state and connected to the zero oscillations of macroscopic quantum oscillator is offered. The economy, in as turn, can result in greater rigity of superconducting state.
We show that a topological quantum phase transition, generating flat bands and altering Fermi surface topology, is a primary reason for the exotic behavior of the overdoped high-temperature superconductors represented by $\rm La_{2-x}Sr_xCuO_4$, whose superconductivity features differ from what is described by the classical Bardeen-Cooper-Schrieffer theory [J.I. Bozović, X. He, J. Wu, and A. T. Bollinger, Nature 536, 309 (2016)]. We demonstrate that 1) at temperature $T=0$, the superfluid density $n_s$ turns out to be considerably smaller than the total electron density; 2) the critical temper…
We consider the interface between a Bardeen-Cooper-Schrieffer superconductor and non-superconducting band insulator. We show that under certain conditions, such interfaces can have an elevated superconducting critical temperature, without increasing the strength of the pairing interaction at the interface. We identify the regimes where the interface critical temperature exceeds the critical temperature associated with a superconductor-vacuum interface.
We argue that the cosmological constant is exponentially suppressed in a candidate ground state of loop quantum gravity as a nonperturbative effect of a holographic Fermi-liquid theory living on a two-dimensional spacetime. Ashtekar connection components, corresponding to degenerate gravitational configurations breaking large gauge invariance and CP symmetry, behave as composite fermions that condense as in Bardeen-Cooper-Schrieffer theory of superconductivity. Cooper pairs admit a description as wormholes on a de Sitter boundary.
We present a microscopic study of the behavior of the order parameters near boundaries of a two-band superconducting material, described by the standard tight-binding Bardeen-Cooper-Schrieffer model. We find superconducting surface states. The relative difference between bulk and surface critical temperatures is a nontrivial function of the interband coupling strength. For superconductors with weak interband coupling, boundaries induce variations of the gaps with the presence of multiple length scales, despite non-zero interband Josephson coupling.
A number of observations point to the possibility that high-Tc cuprate superconductors may not be conventional Bardeen-Cooper-Schrieffer (BCS) superconductors, but rather derive from the Bose-Einstein condensation (BEC) of real-space pairs, which are mobile small bipolarons. A solution of the Gross-Pitaevskii equation describing bose-condensate tunnelling into a cuprate semiconductor is analytically found. It accounts qualitatively and quantitatively for nil and giant proximity effects discovered experimentally in cuprates.
The non-trivial geometry encoded in the Quantum Mechanical wavefunctions has important consequences for its single-particle as well as many-body dynamics. Yet, our understanding of how the geometry of the single-particle eigenstates are manifest in the characteristics of a many-particle system is still incomplete. Here, we demonstrate how the single-particle Berry curvature modifies the fluxoid quantization of a two dimensional Bardeen-Cooper-Schrieffer (BCS) superconductor, and discuss the experimental scenarios where this anomalous quantization is expected to be realized.
We predict a strong enhancement of the critical temperature in a conventional Bardeen-Cooper-Schrieffer (BCS) superconductor in the presence of a bosonic condensate of exciton-polaritons. The effect depends strongly on the ratio of the cutoff frequencies for phonon and exciton-polariton mediated BCS superconductivity, respectively. We also discuss a possible design of hybrid semiconductor-superconductor structures suitable for the experimental observation of such an effect.
A BCS (Bardeen-Cooper-Schrieffer) superconductor, which is placed out of equilibrium, can develop quantum instabilities, which manifest themselves in oscillations of the superconductor's order parameter (pairing amplitude $Δ$). These instabilities are a manifestations of the Cooper instability. Inelastic collisions are essential in resolving those instabilities. Incorporating the quantum instabilities and collisions in a unified approach based on Richardson's exact solution of the pairing Hamiltonian, we find that a BCS superconductor may end up in a state in which the spectrum has more than o…
The Bardeen-Cooper-Schrieffer (BCS) mean-field theory of the pairing interaction breaks down for nuclei and ultra-small metallic grains (nanoparticles). Finite-temperature pairing correlations in such finite-size systems can be calculated beyond the BCS theory in an auxiliary-field Monte Carlo approach. We identify thermal signatures of pairing correlations in both nuclei and nanoparticles that depend on the particle-number parity.
It is pointed out that erroneous Bardeen-Cooper-Schrieffer model equations have been used by Haranath Ghosh in his recent treatment of time-reversal symmetry-breaking superconductivity. Consequently, his numerical results are misleading, and his conclusions are not to the point.
In this paper, we review the low energy electronic structure of the kinetic energy driven d-wave cuprate superconductors. We give a general description of the charge-spin separation fermion-spin theory, where the constrained electron is decoupled as the gauge invariant dressed holon and spin. In particular, we show that under the decoupling scheme, the charge-spin separation fermion-spin representation is a natural representation of the constrained electron defined in a restricted Hilbert space without double electron occupancy. Based on the charge-spin separation fermion-spin theory, we have …
We review recent results concerning the mathematical properties of the Bardeen-Cooper-Schrieffer (BCS) functional of superconductivity, which were obtained in a series of papers partly in collaboration with R. Frank, E. Hamza, S. Naboko, and J.P. Solovej. Our discussion includes, in particular, an investigation of the critical temperature for a general class of interaction potentials, as well as a study of its dependence on external fields. We shall explain how the Ginzburg-Landau model can be derived from the BCS theory in a suitable parameter regime.
The isotope effect provided a crucial key to the development of the BCS (Bardeen-Cooper-Schrieffer) microscopic theory of superconductivity for conventional superconductors. In superconducting cooper oxides (cuprates) showing an unconventional type of superconductivity, the oxygen isotope effect is very peculiar: the exponential coefficient strongly depends on doping level. No consensus has been reached so far on the origin of the isotope effect in the cuprates. Here we show that the oxygen isotope effect in cuprates is in agreement with the bisoliton theory of superconductivity.
The Higgs mode associated with amplitude fluctuations of the superconducting gap in uniform superconductors usually is heavy, which makes its excitation and detection difficult. We report on the existence of a gapless Higgs mode in the Fulde-Ferrell-Larkin-Ovchinnikov states. This feature is originated from the Goldstone mode associated with the translation symmetry breaking. The existence of the gapless Higgs mode is demonstrated by using both a phenomenological model and microscopic Bardeen-Cooper-Schrieffer (BCS) theory. The gapless Higgs mode can avoid the decay into other low energy excit…
We discuss the charge and the spin tunneling currents between two Bardeen-Cooper-Schrieffer (BCS) superconductors, where one density of states is spin-split. In the presence of a large temperature bias across the junction, we predict the generation of a spin-polarized thermoelectric current. This thermo-spin effect is the result of a spontaneous particle-hole symmetry breaking in the absence of a polarizing tunnel barrier. The two spin components, which move in opposite directions, generate a spin current larger than the purely polarized case when the thermo-active component dominates over the…
Departing from the assumption that pairing is induced by an retarded external 'bosonic glue', we reformulate the Bardeen-Cooper-Schrieffer theory of superconductivity as a scaling theory. Conventional superconductors correspond with the asymptotically free case but the theory can be effortlessly generalized to handle quantum critical metals. We find that superconducting Tc's are strongly enhanced in the latter when retardation is strong while the coupling is weak. It appears that this simple scaling theory does account quite well for superconducting properties near quantum critical points.
Recent experiments on Nb-doped SrTiO$_3$ have shown that the superconducting energy gap to the transition temperature ratio maintains the Bardeen-Cooper-Schrieffer (BCS) value throughout its superconducting dome. Motivated by these and related studies, we show that the Cooper pairing mediated by a single soft transverse-optical phonon is the most natural mechanism for such a superconducting dome given experimental constraints, and present the microscopic theory for this pairing mechanism. Furthermore, we show that this mechanism is consistent with the $T^2$ resistivity in the normal state. Las…
We consider the Bardeen-Cooper-Schrieffer free energy functional for particles interacting via a two-body potential on a microscopic scale and in the presence of weak external fields varying on a macroscopic scale. We study the influence of the external fields on the critical temperature. We show that in the limit where the ratio between the microscopic and macroscopic scale tends to zero, the next to leading order of the critical temperature is determined by the lowest eigenvalue of the linearization of the Ginzburg-Landau equation.
Based on the Bardeen Cooper Schrieffer (BCS) theory of superconductivity, the coherent splitting of Cooper pairs from a superconductor to two spatially separated quantum dots has been predicted to generate nonlocal pairs of entangled electrons. In order to test this hypothesis, we propose a scheme to transfer the spin state of a split Cooper pair onto the polarization state of a pair of optical photons. We show that the produced photon pairs can be used to violate a Bell inequality, unambiguously demonstrating the entanglement of the split Cooper pairs.
Graphene has exhibited a wealth of fascinating properties, but is also known not to be a superconductor. Remarkably, we show that graphene can be made a conventional Bardeen-Cooper-Schrieffer superconductor by the combined effect of charge doping and tensile strain. While the effect of doping is obvious to enlarge Fermi surface, the effect of strain is profound to greatly increase the electron-phonon coupling. At the experimental accessible doping (4E+14cm-2) and strain (~16%) levels, the superconducting critical temperature Tc reaches as high as ~30 K, the highest for a single-element materia…
The doping dependent isotope effect on the critical temperature (Tc) is calculated for multi-band multi-condensate superconductivity near a 2.5 Lifshitz transition. We focus on multi-band effects that arises in nano-structures and in density wave metals (like spin density wave or charge density wave) as a result of the band folding. We consider a superlattice of quantum stripes with finite hopping between stripes near a 2.5 Lifshitz transition for appearing of a new sub-band making a circular electron-like Fermi surface pocket. We describe a particular type of BEC (Bose-Einstein Condensate) to…
A first-order phase transition is found in the multilayer cuprate superconductor, HgBa$_2$Ca$_4$Cu$_5$O$_y$ (Hg-1245), with a superconducting transition temperature of 108 K, under zero magnetic field. We observed a hysteretic specific heat jump around 41 K. We conclude that the Bardeen-Cooper-Schrieffer pairs have a residual entropy due to fluctuations in the phase difference between the five CuO$_2$ planes in a unit cell of Hg-1245, and that this fluctuation freezes below the first-order phase transition temperature.
The momentum dependence of the low energy quasiparticle spectrum and the related Bogoliubov angle in cuprate superconductors are studied within the kinetic energy driven superconducting mechanism. By calculation of the ratio of the low energy quasiparticle spectra at positive and negative energies, it is shown that the Bogoliubov angle increase monotonically across the Fermi crossing point. The results also show that the superconducting coherence of the low energy quasiparticle peak is well described by a simple d-wave Bardeen-Cooper-Schrieffer formalism, although the pairing mechanism is driv…
Electromagnetic responses in superconductors provide valuable information on the pairing symmetry as well as physical quantities such as the superfluid density. However, at the superconducting gap energy scale, optical excitations of the Bogoliugov quasiparticles are forbidden in conventional Bardeen-Cooper-Schrieffer superconductors when momentum is conserved. Accordingly, far-infrared optical responses have been understood in the framework of a dirty-limit theory by Mattis and Bardeen for over 60 years. Here we show, by investigating the selection rules imposed by particle-hole symmetry and …
Due to the value of the isotope shift in sulfur hydrides, a phonon-mediated pairing scenario of superconductivity is generally accepted for these high-temperature superconductors which is consistent with the Bardeen-Cooper-Schrieffer (BCS) framework. Knowing that a large electronic density of states enhances $T_c$, generalized Fermi surface topologies are used to increase it. A multi-band model within the BCS framework is proposed in this work for the description of sulfur hydride superconductors. This model is used to describe some properties of the $H_3S$ superconductor. Strong coupling effe…
We report on a new state of matter manifested by strongly correlated Fermi systems including various heavy-fermion (HF) metals, two-dimensional quantum liquids such as $\rm ^3He$ films, certain quasicrystals, and systems behaving as quantum spin liquids. Generically, these systems can be viewed as HF systems or HF compounds, in that they exhibit typical behavior of HF metals. At zero temperature, such systems can experience a so-called fermion-condensation quantum phase transition (FCQPT). Combining analytical considerations with arguments based entirely on experimental grounds we argue and de…
