The Dirac semimetal PdTe${}_2$ becomes superconducting at a temperature $T_{c}=1.6$~K. Thermodynamic and muon spin rotation experiments support type-I superconductivity, which is unusual for a binary compound. A key property of a type-I superconductor is the intermediate state which presents a coexistence of superconducting and normal domains (flux structures) at magnetic fields lower than the thermodynamic critical field $H_{c}$. By means of scanning SQUID microscopy (SSM) we observe flux structures in the superconducting state of PdTe${}_2$. The flux structures are strongly history dependent with a transition from round shapes to laminar shapes as the magnetic field is more and more increased. The field amplitudes measured at the surface are indicative for the presence of Landau branching. The domain wall width in the intermediate state has been determined.
The superconductor PdTe$_2$ was recently classified as a Type II Dirac semimetal, and advocated to be an improved platform for topological superconductivity. Here we report magnetic and transport measurements conducted to determine the nature of the superconducting phase. Surprisingly, we find that PdTe$_2$ is a Type I superconductor with $T_c = 1.64$ K and a critical field $μ_0 H_c (0) = 13.6$ mT. Our crystals also exhibit the intermediate state as demonstrated by the differential paramagnetic effect. For $H > H_c$ we observe superconductivity of the surface sheath. This calls for a close exa…
The type II Dirac semimetal PdTe$_2$ is unique in the family of topological parent materials because it displays a superconducting ground state below 1.7 K. Despite wide speculations on the possibility of an unconventional topological superconducting phase, tunneling and heat capacity measurements revealed that the superconducting phase of PdTe$_2$ follows predictions of the microscopic theory of Bardeen, Cooper and Shriefer (BCS) for conventional superconductors. The superconducting phase in PdTe$_2$ is further interesting because it also displays properties that are characteristics of type-I…
The transition metal dichalcogenide PdTe$_2$ was recently shown to be a unique system where a type II Dirac semimetallic phase and a superconducting phase co-exist. This observation has led to wide speculation on the possibility of the emergence of an unconventional topological superconducting phase in PdTe$_2$. Here, through direct measurement of the superconducting energy gap by scanning tunneling spectroscopy (STS), and temperature and magnetic field evolution of the same, we show that the superconducting phase in PdTe$_2$ is conventional in nature. The superconducting energy gap is measure…
Type I superconductivity has recently been reported for the Dirac semimetal PdTe$_2$ (Tc approximately 1.6K) with, remarkably, multiple critical fields and a complex phase diagram. Here, measurements of the specific heat utilizing a thermal relaxation technique are presented. Conventional weak-coupling BCS superconductivity is confirmed by examining the temperature dependence of the specific heat in zero field. By probing the latent heat accompanying the superconducting transition, thermodynamic evidence for type I superconductivity is attained. The presence of the intermediate state is observ…
We report a doping study directed to intentionally induce disorder in PdTe$_2$ by the isoelectronic substitution of Pt. Two single-crystalline batches Pd$_{1-x}$Pt$_x$Te$_2$ have been prepared with nominal doping concentrations x = 0.05 and x = 0.10. Sample characterization by energy dispersive x-ray spectroscopy (EDX) revealed Pt did not dissolve homogeneously in the crystals. For the nominal value x = 0.10 small single crystals cut from the batch appeared to have x = 0.09, as well as the non stoichiometric composition Pd$_{0.97}$Pt$_{<0.004}$Te$_{2.03}$. Magnetic and heat capacity measuremen…
Superconducting gap structure was probed in type-II Dirac semimetal PdTe$_2$ by measuring the London penetration depth using tunnel diode resonator technique. At low temperatures, the data for two samples are well described by weak coupling exponential fit yielding $λ(T=0)=230$~nm as the only fit parameter at a fixed $Δ(0)/T_c\approx 1.76$, and the calculated superfluid density is consistent with a fully gapped superconducting state characterized by a single gap scale. Electrical resistivity measurements for in-plane and inter-plane current directions find very low and nearly temperature-indep…
We report our point-contact spectroscopy (PCS) study on the superconducting state of the type-II Dirac semimetal PdTe$_2$ with a superconducting transition temperature $T\rm_c \sim$ 1.65 K. Both mechanical- and soft- PCS differential conductance curves at 0.3 K show a consistent double-peak structure and they can be perfectly fitted by a single s-wave gap based on the Blonder-Tinkham-Klapwijk model. The gap follows a typical Bardeen-Cooper-Schrieffer temperature behavior, yielding $Δ_0 \sim$ 0.29 meV and 2$Δ_0$/$k\rm_{B}$$T\rm_{c}$ = 4.15 in the strong coupling regime. A sudden suppression of …
We report on the fabrication of Josephson junction devices with weak links utilizing the Weyl and higher-order topological semimetal $\text{WTe}_2$. We show that $\text{WTe}_2\text{/Pd}$ contact annealed at a low temperature of 80°C did not exhibit superconducting properties because neither $\text{WTe}_2$ nor Pd are superconductors in the ground state. Upon 180°C annealing, spontaneous formation of superconducting $\text{PdTe}$ due to Pd diffusion enabled us to obtain the interface between $\text{WTe}_2$ and superconductor suitable for the Josephson junction. This result is a facile technique …
The type-II Dirac semimetal PdTe2 was recently reported to be a type-I superconductor with a superconducting transition temperature Tc = 1.65 K. However, the recent results from tunneling and point contact spectroscopy suggested the unusual state of a mixture of type-I and type-II superconductivity. These contradictory results mean that there is no clear picture of the superconducting phase diagram and warrants a detailed investigation of the superconducting phase. We report here the muon spin rotation and relaxation ($μ$SR) measurements on the superconducting state of the topological Dirac se…
The Dirac semimetal PdTe$_2$ was recently reported to be a type-I superconductor ($T_c = $1.64 K, $μ_0 H_c (0) = 13.6$ mT) with unusual superconductivity of the surface sheath. We here report a high-pressure study, $p \leq 2.5$ GPa, of the superconducting phase diagram extracted from ac-susceptibility and transport measurements on single crystalline samples. $T_c (p)$ shows a pronounced non-monotonous variation with a maximum $T_c = $1.91 K around 0.91 GPa, followed by a gradual decrease to 1.27 K at 2.5 GPa. The critical field of bulk superconductivity in the limit $T \rightarrow 0$, $H_c(0,p…
Dirac semimetal PdTe2 single-crystal temperature-dependent ultrafast carrier and phonon dynamics were studied using ultrafast optical pump-probe spectroscopy. Two distinct carrier and coherent phonons relaxation processes were identified in the 5 K - 300 K range. Quantitative analysis revealed a fast relaxation process (τ_f) occurring on a subpicosecond time scale which originated from electron-phonon thermalization. This was followed by a slower relaxation process (τ_s) with a time scale of ~ 7-9.5 ps which originated from phonon-assisted electron-hole recombination. Two significant vibration…
Though the superconducting phase of the type-II Dirac semimetal PdTe$_2$ was shown to be conventional in nature, the phase continued to be interesting in terms of its magnetic properties. While certain experiments indicated an unexpected type-I superconducting phase, other experiments revealed formation of vortices under the application of magnetic fields. Recently, scanning tunneling spectroscopy (STS) experiments revealed the existence of a mixed phase where type-I and type-II behaviours coexist. Here, based on our temperature and magnetic field dependent STS experiments on Cu-intercalated P…
Usually, the superconducting quantum interference device (SQUID) consists of two Josephson junctions and the interference therein is modulated by a magnetic flux. In this work, we propose an electrically modulated SQUID consisting of single Josephson junction coupled by a time-reversal breaking Weyl semimetal thin film. For a low Fermi energy, the Josephson current is only mediated by Fermi arc surface states, and has an arbitrary ground-state phase difference \phi0 which is directly proportional to the product of the transverse electric field and the cross section area of the junction.For a s…
Two-dimensional transition metal dichalcogenide PdTe$_2$ recently attracts much attention due to its phase coexistence of type-II Dirac semimetal and type-I superconductivity. Here we report a 67 % enhancement of superconducting transition temperature in the 1T-PdSeTe in comparison to that of PdTe2 through partial substitution of Te atoms by Se. The superconductivity has been unambiguously confirmed by the magnetization, resistivity and specific heat measurements. 1T-PdSeTe shows type-II superconductivity with large anisotropy and non-bulk superconductivity nature with volume fraction ~ 20 % e…
The transition metal dichalcogenide PdTe$_2$ has attractive features based on its classification as a type-II Dirac semimetal and the occurrence of type-I superconductivity, providing a platform for discussion of a topological superconductor. Our recent work revealed that type-I superconductivity persists up to pressures of $\sim2.5$ GPa and the superconducting transition temperature $T_{\rm c}$ reaches a maximum at around 1 GPa, which is inconsistent with the theoretical prediction. To understand its non-monotonic variation and investigate superconductivity at higher pressures, we performed s…
The Dirac semimetal PdTe$_2$ was recently reported to be a type-I superconductor with $T_c = 1.64$ K and a critical field $μ_0H_c = 13.6$ mT. Since type-I superconductivity is unexpected for binary compounds, we have conducted muon spin rotation experiments to probe the superconducting phase on the microscopic scale via its intermediate state. For crystals with a finite demagnetization factor, $N$, the intermediate state forms in applied fields $(1-N)H_c < H_a < H_c$. We have carried out transverse field muon spin rotation measurements on a thin disk-like crystal with the field perpendicular t…
The interplay of nontrivial topology and superconductivity in condensed matter physics gives rise to exotic phenomena. However, materials are extremely rare where it is possible to explore the full details of the superconducting pairing. Here, we investigate the momentum dependence of the superconducting gap distribution in a novel Dirac material PdTe. Using high resolution, low temperature photoemission spectroscopy, we establish it as a spin-orbit coupled Dirac semimetal with the topological Fermi arc crossing the Fermi level on the (010) surface. This spin-textured surface state exhibits a …
By means of high-pressure resistivity measurements on single crystals, we investigate the charge transport properties of Cu$_x$PdTe$_2$, notable for the combination of topological type-II Dirac semimetallic properties with superconductivity up to $T_c = 2.5$ K. In both cases of pristine ($x = 0$) and intercalated ($x=0.05$) samples, we find an unconventional $T^4$ power law behavior of the low-temperature resistivity visible up to $\sim$40 K and remarkably stable under pressure up to 8.2 GPa. This observation is explained by the low carrier density $n$, which strongly reduces the $k$-region av…
One of the consequences of Cooper pairs having a finite momentum in the interlayer of a Josephson junction, is $π$-junction behavior. The finite momentum can either be due to an exchange field in ferromagnetic Josephson junctions, or due to the Zeeman effect. Here, we report the observation of Zeeman effect induced 0-$π$ transitions in Bi$_{1-x}$Sb$_x$, 3D Dirac semimetal-based Josephson junctions. The large g-factor of the Zeeman effect from a magnetic field applied in the plane of the junction allows tuning of the Josephson junctions from 0- to $π$- regimes. This is revealed by sign changes …
Low temperature ($\sim$ 20~K) electron irradiation with 2.5 MeV relativistic electrons was used to study the effect of controlled non-magnetic disorder on the normal and superconducting properties of the type-II Dirac semimetal PdTe$_2$. We report measurements of longitudinal and Hall resistivity, thermal conductivity and London penetration depth using tunnel-diode resonator technique for various irradiation doses. The normal state electrical resistivity follows Matthiessen rule with an increase of the residual resistivity at a rate of $\sim$0.77$ μΩ$cm/$(\textrm{C}/\textrm{cm}^2)$. London pen…
The notion of topological phases has been extended to higher-order and has been generalized to different dimensions. As a paradigm, Cd3As2 is predicted to be a higher-order topological semimetal, possessing three-dimensional (3D) bulk Dirac fermions, two-dimensional (2D) Fermi arcs, and one-dimensional (1D) hinge states. These topological states have different characteristic length scales in electronic transport, allowing to distinguish their properties when changing sample size. Here, we report an anomalous dimensional reduction of supercurrent transport by increasing the size of Dirac semime…
