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arXiv 2007.03444cond-mat.mtrl-sci
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低温下Ag $_2$ ZnSnSe $_4$带隙和带尾的光学测量

Optical Determination of the Band Gap and Band Tail of Epitaxial Ag$_2$ZnSnSe$_4$ at Low Temperature

S. Perret, Y. Curé, L. Grenet, R. André, H. Mariette, J. Bleuse

摘要:

我们报告的精确测定的带隙E $_\text{g}$,和局部缺陷态的带尾的特征能量$U$,单晶银$_2$ ZnSnSe $_4$。光致发光激发和时间分辨的光致发光研究导致E $_\text{g} = 1223\pm3$ meV,和$U = 20\pm3$ meV,在6 K。这里开发的方法的兴趣是定量地考虑时间分辨的光致发光和光致发光激发光谱,只考虑标准教科书的态密度,和状态填充效应。这种方法不同于最常用于评估局域态的能量范围的方法,即通过测量光致发光发射和激发之间的能量位移-所谓的斯托克斯位移。本方法的优点在于,不必任意选择低功率激发来选择光致发光发射光谱及其峰值能量。

英文摘要:

We report on the precise determination of both the band gap E$_\text{g}$, and the characteristic energy $U$ of the band tail of localized defect states, for monocrystalline Ag$_2$ZnSnSe$_4$. Both photoluminescence excitation and time-resolved photoluminescence studies lead to E$_\text{g} = 1223\pm3$ meV, and $U = 20\pm3$ meV, at 6 K. The interest of the methodology developed here is to account quantitatively for the time-resolved photoluminescence and photoluminescence excitation spectra by only considering standard textbook density of states, and state filling effects. Such an approach is different from the one most often used to evaluate the energy extent of the localized states, namely by measuring the energy shift between the photoluminescence emission and the excitation one -- the so-called Stokes shift. The advantage of the present method is that no arbitrary choice of the low power excitation has to be done to select the photoluminescence emission spectrum and its peak energy.

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