The formation of the solar system's terrestrial planets concluded with a period of giant impacts. Previous works examining the volatile loss caused by the impact shock in the moon-forming impact find atmospheric losses of at most 20-30 per cent and essentially no loss of oceans. However, giant impacts also result in thermal heating, which can lead to significant atmospheric escape via a Parker-type wind. Here we show that H2O and other high-mean molecular weight outgassed species can be efficiently lost through this thermal wind if present in a hydrogen-dominated atmosphere, substantially altering the final volatile inventory of terrestrial planets. Specifically, we demonstrate that a giant impact of a Mars-sized embryo with a proto-Earth can remove several Earth oceans' worth of H2O, and other heavier volatile species, together with a primordial hydrogen-dominated atmosphere. These results may offer an explanation for the observed depletion in Earth's light noble gas budget and for its depleted xenon inventory, which suggest that Earth underwent significant atmospheric loss by the end of its accretion. Because planetary embryos are massive enough to accrete primordial hydrogen envelopes and because giant impacts are stochastic and occur concurrently with other early atmospheric evolutionary processes, our results suggest a wide diversity in terrestrial planet volatile budgets.
Terrestrial planets orbiting M dwarfs may soon be observed with the James Webb Space Telescope (JWST) to characterize their atmospheric composition and search for signs of habitability or life. These planets may undergo significant atmospheric and ocean loss due to the superluminous pre-main-sequence phase of their host stars, which may leave behind abiotically-generated oxygen, a false positive for the detection of life. Determining if ocean loss has occurred will help assess potential habitability and whether or not any O2 detected is biogenic. In the solar system, differences in isotopic ab…
Ocean planets are volatile rich planets, not present in our Solar System, which are thought to be dominated by deep, global oceans. This results in the formation of high-pressure water ice, separating the planetary crust from the liquid ocean and, thus, also from the atmosphere. Therefore, instead of a carbonate-silicate cycle like on the Earth, the atmospheric carbon dioxide concentration is governed by the capability of the ocean to dissolve carbon dioxide (CO2). In our study, we focus on the CO2 cycle between the atmosphere and the ocean which determines the atmospheric CO2 content. The atm…
We consider super-Earth sized planets which have a water mass fraction that is large enough to form an external mantle composed of high pressure water ice polymorphs and that lack a substantial H/He atmosphere. We consider such planets in their habitable zone so that their outermost condensed mantle is a global deep liquid ocean. For these ocean planets we investigate potential internal reservoirs of CO2; the amount of CO2 dissolved in the ocean for the various saturation conditions encountered, and the ocean-atmosphere exchange flux of CO2. We find that in steady state the abundance of CO2 in…
The energy associated with giant impacts is large enough to generate global magma oceans during Earth's accretion. However, geochemical evidence requiring a terrestrial magma ocean is scarce. Here we present evidence for at least two separate magma ocean outgassing episodes on Earth based on the ratio of primordial 3He to 22Ne in the present-day mantle. We demonstrate that the depleted mantle 3He/22Ne ratio is at least 10 while a more primitive mantle reservoir has a 3He/22Ne ratio of 2.3 to 3. The 3He/22Ne ratios of the mantle reservoirs are higher than possible sources of terrestrial volatil…
The deuterium-to-hydrogen (D/H or 2H/1H) ratio of Martian atmospheric water (~6x standard mean ocean water, SMOW) is higher than that of known sources, requiring planetary enrichment. A recent measurement by NASA's Mars Science Laboratory rover Curiosity of >3 Gyr clays yields a D/H ratio ~3x SMOW, demonstrating that most enrichment occurs early in Mars's history. As on Venus, Mars's D/H enrichment is thought to reflect preferential loss to space of 1H (protium) relative to 2H (deuterium), but the global environmental context of large and early hydrogen losses remain to be determined. Here, we…
Carbonate precipitation in oceans is essential for the carbonate-silicate cycle (inorganic carbon cycle) to maintain temperate climates. By considering the thermodynamics of carbonate chemistry, we demonstrate that the ocean pH decreases by approximately 0.5 for a factor of 10 increase in the atmospheric carbon dioxide content. The upper and lower limits of ocean pH are within 1-4 of each other, where the upper limit is buffered by carbonate precipitation and defines the ocean pH when the carbon cycle operates. If the carbonate compensation depth (CCD) resides above the ocean floor, then carbo…
Ocean-atmosphere chemistry on Earth has undergone dramatic evolutionary changes through its long history, with potentially significant ramifications for the emergence and long-term stability of atmospheric biosignatures. Though a great deal of work has centered on refining our understanding of false positives for remote life detection, much less attention has been paid to the possibility of false negatives, that is, cryptical biospheres that are widespread and active on a planet's surface but are ultimately undetectable or difficult to detect in the composition of a planet's atmosphere. Here, …
Recent observations of the potentially habitable planets TRAPPIST-1 e, f, and g suggest that they possess large water mass fractions of possibly several tens of wt% of water, even though the host star's activity should drive rapid atmospheric escape. These processes can photolyze water, generating free oxygen and possibly desiccating the planet. After the planets formed, their mantles were likely completely molten with volatiles dissolving and exsolving from the melt. In order to understand these planets and prepare for future observations, the magma ocean phase of these worlds must be underst…
The analyses of Titan's gravity field obtained by Cassini space mission suggest the presence of an internal ocean beneath its icy surface. The characterization of the geophysical parameters of the icy shell and the ocean is important to constrain the evolution models of Titan. The knowledge of the librations, that are periodic oscillations around a uniform rotational motion, can bring piece of information on the interior parameters. The objective of this paper is to study the librational response in longitude from an analytical approach for Titan composed of a deep atmosphere, an elastic icy s…
Terrestrial planets covered globally with thick oceans (termed ocean planets) in the habitable zone were previously inferred to have extremely hot climates in most cases. This is because ${\rm H_2O}$ high-pressure (HP) ice on the seafloor prevents chemical weathering and, thus, removal of atmospheric CO$_2$. Previous studies, however, ignored melting of the HP ice and horizontal variation in heat flux from oceanic crusts. Here we examine whether high heat fluxes near the mid-ocean ridge melts the HP ice and thereby removes atmospheric ${\rm CO_2}$. We develop integrated climate models of an Ea…
Probing thermal gradients of habitable-zone rocky planets as an anti-indicator of a global surface ocean using mid-infrared direct imaging
National Astronomical Observatory of Japan（日本国立天文台）；SOKENDAI（综合研究大学院大学）；University of Tokyo（东京大学）；ETH Zurich（苏黎世联邦理工学院）；Blue Marble Space Institute of Science（蓝色大理石空间科学研究所）；SETI Institute（搜寻地外文明研究所）；University of Osaka（大阪大学）；University of Colorado Boulder（科罗拉多大学博尔德分校）
The methane cycle is a key component of the Earth system that links planetary climate, biological metabolism, and the global biogeochemical cycles of carbon, oxygen, sulfur, and hydrogen. However, currently lacking is a numerical model capable of simulating a diversity of environments in the ocean where methane can be produced and destroyed, and with the flexibility to be able to explore not only relatively recent perturbations to Earth's methane cycle but also to probe methane cycling and associated climate impacts under the reducing conditions characteristic of most of Earth history and like…
Atmospheric evolution through outgassing and escape on young molten rocky exoplanets
Kapteyn Astronomical Institute, University of Groningen（格罗宁根大学卡普坦天文研究所）；Institute of Astronomy, University of Cambridge（剑桥大学天文学研究所）；Atmospheric Oceanic and Planetary Physics, University of Oxford（牛津大学大气海洋与行星物理系）；Netherlands eScience Center（荷兰电子科学中心）；Interuniversity Micro Electronics Centre（大学微电子中心）；Space Research Organisation Netherlands（荷兰太空研究组织）
Phosphorus is an essential element for life, and the phosphorous cycle is widely believed to be a key factor limiting the extent of Earth's biosphere and its impact on remotely detectable features of Earth's atmospheric chemistry. Continental weathering is conventionally considered to be the only source of bioavailable phosphorus to the marine biosphere, with submarine hydrothermal processes acting as a phosphorus sink. Here, we use a novel 29Si tracer technique to demonstrate that alteration of submarine basalt under anoxic conditions leads to significant soluble phosphorus release, with an e…
Earth's atmosphere has evolved as volatile species cycle between the atmosphere, ocean, biomass and the solid Earth. The geochemical, biological and astrophysical processes that control atmospheric evolution are reviewed from an "Earth Systems" perspective, with a view not only to understanding the history of Earth, but also to generalizing to other solar system planets and exoplanets.
GJ 1132 b is a nearby Earth-sized exoplanet transiting an M dwarf, and is amongst the most highly characterizable small exoplanets currently known. In this paper we study the interaction of a magma ocean with a water-rich atmosphere on GJ 1132b and determine that it must have begun with more than 5 wt% initial water in order to still retain a water-based atmosphere. We also determine the amount of O2 that can build up in the atmosphere as a result of hydrogen dissociation and loss. We find that the magma ocean absorbs at most ~10% of the O2 produced, whereas more than 90% is lost to space thro…
Massive and water-rich planets should be ubiquitous in the universe. Many of those worlds are expected to be subject to important irradiation from their host star, and display supercritical water layers surrounded by extended steam atmospheres. Irradiated ocean planets with such inflated hydrospheres have been recently shown to be good candidates for matching the mass-radius distribution of sub-Neptunes. Here we describe a model that computes a realistic structure for water-rich planets by combining an interior model with an updated equation of state (EoS) for water, and an atmospheric model t…
Is there oceanic superrotation on exoplanets? Atmospheric superrotation, characterized by west-to-east winds over the equator, is a common phenomenon in the atmospheres of Venus, Titan, Saturn, Jupiter, and tidally locked exoplanets. The stratospheric atmosphere of Earth is also superrotating during the westerly phase of the quasi-biennial oscillation (QBO). However, whether the same phenomenon can occur in ocean is poorly known. Through numerical simulations, here we show that oceanic superrotation does occur on tidally locked terrestrial planets around low-mass stars. Its formation (spun-up …
The hydrogen isotopic (D/H) ratio reflects the global cycling and evolution of water on Earth as it fractionates through planetary processes. We model the water cycle taking seafloor hydrothermal alteration, chemical alteration of continental crust, slab subduction, hydrogen escape from the early Earth, and degassing at mid-ocean ridges, hot spots, and arcs into account. The differences in D/H ratios between present-day oceans, oceanic and continental crust, and mantle are thought to reflect isotopic fractionation through seafloor alteration, chemical alteration, and slab dehydration. However,…
Terrestrial planets orbiting within the habitable zones of M-stars are likely to become tidally locked in a 1:1 spin:orbit configuration and are prime targets for future characterization efforts. An issue of importance for the potential habitability of terrestrial planets is whether they could experience snowball events (periods of global glaciation). Previous work using an intermediate complexity atmospheric Global Climate Model (GCM) with no ocean heat transport suggested that tidally locked planets would smoothly transition to a snowball, in contrast with Earth, which has bifurcations and h…
We present the thermal evolution and emergent spectra of solidifying terrestrial planets along with the formation of steam atmospheres. The lifetime of a magma ocean and its spectra through a steam atmosphere depends on the orbital distance of the planet from the host star. For a type-I planet, which is formed beyond a certain critical distance from the host star, the thermal emission declines on a timescale shorter than approximately $10^6$ years. Therefore, young stars should be targets when searching for molten planets in this orbital region. In contrast, a type-II planet, which is formed i…
The potential habitability of tidally locked planets orbiting M-dwarf stars has been widely investigated in recent work, typically with a non-dynamic ocean and without continents. On Earth, ocean dynamics are a primary means of heat and nutrient distribution. Continents are a critical source of nutrients, strongly influence ocean dynamics, and participate in climate regulation. In this work, we investigate how the size of a substellar land mass affects the oceans ability to transport heat and upwell nutrients on the tidally locked planet Proxima Centauri b using the ROCKE-3D coupled ocean-atmo…
The emergence of oxygenic photosynthesis created a new niche with dramatic potential to transform energy flow through Earth's biosphere. However, more primitive forms of photosynthesis that fix CO2 into biomass using electrons from reduced species like Fe(II) and H2 instead of water would have competed with Earth's early oxygenic biosphere for essential nutrients. Here, we combine experimental microbiology, genomic analyses, and Earth system modeling to demonstrate that competition for light and nutrients in the surface ocean between oxygenic phototrophs and Fe(II)-oxidizing, anoxygenic photos…
Past studies have demonstrated that atmospheric escape by the core-powered mass-loss mechanism can explain a multitude of observations associated with the radius valley that separates the super-Earth and sub-Neptune planet populations. Complementing such studies, in this work, we present a shortlist of planets that could be losing their atmospheres today if their evolution is indeed primarily dictated by core-powered mass-loss. We use Bayesian inference analysis on our planet evolution and mass-loss model to estimate the posteriors of the parameters that encapsulate the current state of a give…
The nearly logarithmic radiative impact of CO$_2$ means that planets near the outer edge of the liquid water habitable zone (HZ) require $\sim$10$^6$x more CO$_2$ to maintain temperatures conducive to standing liquid water on the planetary surface than their counterparts near the inner edge. This logarithmic radiative response also means that atmospheric CO$_2$ changes of a given mass will have smaller temperature effects on higher pCO$_2$ planets. Ocean pH is linked to atmospheric pCO$_2$ through seawater carbonate speciation and calcium carbonate dissolution/precipitation, and the response o…
Detecting Atmospheric CO2 Trends as Population-Level Signatures for Long-Term Stable Water Oceans and Biotic Activity on Temperate Terrestrial Exoplanets
MESSENGER observations suggest a magma ocean formed on proto-Mercury, during which evaporation of metals and outgassing of C- and H-bearing volatiles produced an early atmosphere. Atmospheric escape subsequently occurred by plasma heating, photoevaporation, Jeans escape, and photoionization. To quantify atmospheric loss, we combine constraints on the lifetime of surficial melt, melt composition, and atmospheric composition. Consideration of two initial Mercury sizes and four magma ocean compositions determine the atmospheric speciation at a given surface temperature. A coupled interior-atmosph…
Magma ocean interactions can explain JWST observations of the sub-Neptune TOI-270 d
School of Earth and Space Exploration, Arizona State University（亚利桑那州立大学地球与空间探索学院）；Department of Astronomy, University of Maryland（马里兰大学天文学系）；Space Telescope Science Institute（太空望远镜科学研究所）；Department of Astronomy & Astrophysics, University of Chicago（芝加哥大学天文学与天体物理学系）；Kapteyn Astronomical Institute, University of Groningen（格罗宁根大学卡普坦天文研究所）；Earth and Planets Laboratory, Carnegie Institution for Science（卡内基科学学会地球与行星实验室）
The weak orbital-phase dependent reflection signal of an exoplanet contains information on the planet surface, such as the distribution of continents and oceans on terrestrial planets. This light curve is usually studied in the time domain, but because the signal from a stationary surface is (quasi)periodic, analysis of the Fourier series may provide an alternative, complementary approach. We study Fourier spectra from reflected light curves for geometrically simple configurations. Depending on its atmospheric properties, a rotating planet in the habitable zone could have circular polar ice ca…
Recent studies have shown that ocean dynamics can have a significant warming effect on the permanent night sides of 1 to 1 tidally locked terrestrial exoplanets with Earth-like atmospheres and oceans in the middle of the habitable zone. However, the impact of ocean dynamics on the habitable zone's boundaries (inner edge and outer edge) is still unknown and represents a major gap in our understanding of this type of planets. Here we use a coupled atmosphere-ocean global climate model to show that planetary heat transport from the day to night side is dominated by the ocean at lower stellar flux…
Tidally locked terrestrial planets around low-mass stars are the prime targets for future atmospheric characterizations of potentially habitable systems, especially the three nearby ones--Proxima b, TRAPPIST-1e, and LHS 1140b. Previous studies suggest that if these planets have surface ocean they would be in an eyeball-like climate state: ice-free in the vicinity of the substellar point and ice-covered in the rest regions. However, an important component of the climate system--sea ice dynamics has not been well studied in previous studies. A fundamental question is: would the open ocean be sta…
Glint, the specular reflection of sunlight off Earth's oceans, may reveal the presence of oceans on an extrasolar planet. As an Earth-like planet nears crescent phases, the size of the ocean glint spot increases relative to the fraction of illuminated disk, while the reflectivity of this spot increases. Both effects change the planet's visible reflectivity as a function of phase. However, strong forward scattering of radiation by clouds can also produce increases in a planet's reflectivity as it approaches crescent phases, and surface glint can be obscured by Rayleigh scattering and atmospheri…
Geophysical and atmospheric implications of $f$O$_{2}$-dependent melting on rocky exoplanets
Kapteyn Astronomical Institute, University of Groningen（格罗宁根大学卡普坦天文研究所）；Netherlands eScience Center（荷兰e科学中心）；Interuniversity Micro Electronics Centre（跨大学微电子中心）；Institute of Geochemistry and Petrology, Department of Earth and Planetary Sciences, ETH Zürich（苏黎世联邦理工学院地球与行星科学系地球化学与岩石学研究所）；Institute of Astronomy, University of Cambridge（剑桥大学天文学研究所）
The influence of atmospheric composition on the climates of present-day and early Earth has been studied extensively, but the role of ocean composition has received less attention. We use the ROCKE-3D ocean-atmosphere general circulation model to investigate the response of Earth's present-day and Archean climate system to low vs. high ocean salinity. We find that saltier oceans yield warmer climates in large part due to changes in ocean dynamics. Increasing ocean salinity from 20 g/kg to 50 g/kg results in a 71% reduction in sea ice cover in our present-day Earth scenario. This same salinity …
Internal redox reactions may irreversibly alter the mantle composition and volatile inventory of terrestrial and super-Earth exoplanets and affect the prospects for atmospheric observations. The global efficacy of these mechanisms, however, hinges on the transfer of reduced iron from the molten silicate mantle to the metal core. Scaling analysis indicates that turbulent diffusion in the internal magma oceans of sub-Neptunes can kinetically entrain liquid iron droplets and quench core formation. This suggests that the chemical equilibration between core, mantle, and atmosphere may be energetica…
Two atmospheric responses to simulated astrophysical ionizing radiation events significant to life on Earth are production of odd-nitrogen species, especially NO2, and subsequent depletion of stratospheric ozone. Ozone depletion increases incident short-wavelength ultraviolet radiation (UVB, 280-315 nm) and longer ( > 600 nm) wavelengths of photosynthetically available radiation (PAR, 400 -700 nm). On the other hand, the NO2 haze decreases atmospheric transmission in the long-wavelength UVA (315-400 nm) and short wavelength PAR. Here we use the results of previous simulations of incident spect…
The ocean worlds science case for the Pollux spectropolarimeter
Aix-Marseille Université（艾克斯-马赛大学）；Institut Origines（起源研究所）；University of Liège（列日大学）；Univ. Grenoble Alpes（格勒诺布尔阿尔卑斯大学）；Southwest Research Institute（西南研究院）；Johns Hopkins University Applied Physics Laboratory（约翰斯·霍普金斯大学应用物理实验室）；UVSQ Paris Saclay（巴黎萨克雷凡尔赛大学）；Sorbonne Universite（索邦大学）；Space Research Institute, Austrian Academy of Sciences（奥地利科学院空间研究所）；Royal Institute of Technology KTH（瑞典皇家理工学院）
The discovery of potentially habitable planets around the ultracool dwarf star Trappist-1 naturally poses the question: could Trappist-1 planets be home to life? These planets orbit very close to the host star and are most susceptible to the UV radiation emitted by the intense and frequent flares of Trappist-1. Here we calculate the UV spectra (100 - 450 nm) of a superflare observed on Trappist-1 with the K2 mission. We couple radiative transfer models to this spectra to estimate the UV surface flux on planets in the habitable zone of Trappist-1 (planets $e$, $f$, and $g$), assuming atmospheri…
