Aerosol Composition of Hot Giant Exoplanets Dominated by Silicates and Hydrocarbon Hazes
Peter Gao, Daniel P. Thorngren, Elspeth K. H. Lee, Jonathan J. Fortney, Caroline V. Morley, Hannah R. Wakeford, Diana K. Powell, Kevin B. Stevenson, Xi Zhang
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32 pages, 4 main text figures, 7 supplementary figures, 4 supplementary tables, published in Nature Astronomy
Aerosols are common in the atmospheres of exoplanets across a wide swath of temperatures, masses, and ages. These aerosols strongly impact observations of transmitted, reflected, and emitted light from exoplanets, obfuscating our understanding of exoplanet thermal structure and composition. Knowing the dominant aerosol composition would facilitate interpretations of exoplanet observations and theoretical understanding of their atmospheres. A variety of compositions have been proposed, including metal oxides and sulphides, iron, chromium, sulphur, and hydrocarbons. However, the relative contributions of these species to exoplanet aerosol opacity is unknown. Here we show that the aerosol composition of giant exoplanets observed in transmission is dominated by silicates and hydrocarbons. By constraining an aerosol microphysics model with trends in giant exoplanet transmission spectra, we find that silicates dominate aerosol opacity above planetary equilibrium temperatures of 950 K due to low nucleation energy barriers and high elemental abundances, while hydrocarbon aerosols dominate below 950 K due to an increase in methane abundance. Our results are robust to variations in planet gravity and atmospheric metallicity within the range of most giant transiting exoplanets. We predict that spectral signatures of condensed silicates in the mid-infrared are most prominent for hot (>1600 K), low-gravity (<10 m s$^{-2}$) objects.
Despite surface liquid water's importance to habitability, observationally diagnosing its presence or absence on exoplanets is still an open problem. Inspired within the Solar System by the differing sulfur cycles on Venus and Earth, we investigate thick sulfate (H2SO4-H2O) aerosol haze and high trace mixing ratios of SO2 gas as observable atmospheric features whose sustained existence is linked to the near absence of surface liquid water. We examine the fundamentals of the sulfur cycle on a rocky planet with an ocean and an atmosphere in which the dominant forms of sulfur are SO2 gas and H2SO…
We present a reanalysis (using the Minnaert limb-darkening approximation) of visible/near-infrared (0.3 - 2.5 micron) observations of Uranus and Neptune made by several instruments. We find a common model of the vertical aerosol distribution that is consistent with the observed reflectivity spectra of both planets, consisting of: 1) a deep aerosol layer with a base pressure > 5-7 bar, assumed to be composed of a mixture of H2S ice and photochemical haze; 2) a layer of photochemical haze/ice, coincident with a layer of high static stability at the methane condensation level at 1-2 bar; and 3) a…
Formation of hazes at microbar pressures has been explored by theoretical models of exoplanet atmospheres to explain Rayleigh scattering and/or featureless transmission spectra, however observational evidence of aerosols in the low pressure formation environments has proved elusive. Here, we show direct evidence of aerosols existing at $\sim$1 microbar pressures in the atmosphere of the warm sub-Saturn WASP-69b using observations taken with Space Telescope Imaging Spectrograph (STIS) and Wide Field Camera 3 (WFC3) instruments on the Hubble Space Telescope. The transmission spectrum shows a wav…
The Cassini-Huygens space mission revealed that Titan s thick brownish haze is initiated high in the atmosphere at about 1000 km of altitude, before a slow transportation down to the surface. Close to the surface at altitudes below 130 km, the Huygens probe provided information on the chemical composition of the haze. So far we do not have insights on a possible photochemical evolution of the aerosols composing the haze during their descent. We address here this atmospheric aerosol aging process, simulating in the laboratory how solar vacuum-ultraviolet (VUV) irradiation affects the aerosol op…
Numerous solar system atmospheres possess aerosols including the characteristic organic hazes of Titan and Pluto. Haze particles substantially impact atmospheric temperatures structures and may provide organic material to the surface of a world, thereby affecting its habitability. Observations of exoplanet atmospheres suggest the presence of aerosols, especially in cooler (<800 K), smaller (<0.3 times Jupiter's mass) exoplanets. It remains unclear if the aerosols muting the spectroscopic features of exoplanet atmospheres are condensate clouds or photochemical hazes, which is difficult to predi…
Recently, properties of exoplanet atmospheres have been constrained via multi-wavelength transit observation, which measures an apparent decrease in stellar brightness during planetary transit in front of its host star (called transit depth). Sets of transit depths so far measured at different wavelengths (called transmission spectra) are somewhat diverse: Some show steep spectral slope features in the visible, some contain featureless spectra in the near-infrared, some show distinct features from radiative absorption by gaseous species. These facts infer the existence of haze in the atmospher…
Having a short orbital period and being tidally locked makes WASP-43b an ideal candidate for JWST observations. Phase curve observations of an entire orbit will enable the mapping of the atmospheric structure across the planet, with different wavelengths of observation allowing different atmospheric depths to be seen. We provide insight into the details of the clouds that may form on WASP-43b in order to prepare the forthcoming interpretation of the JWST and follow-up data. We utilize 3D GCM results as input for a kinetic, non-equilibrium model for mineral cloud particles, and for a kinetic mo…
Some of the exoplanets so far observed show featureless or flat transmission spectra, possibly indicating the existence of clouds and/or haze in their atmospheres. Thanks to its large aperture size and broad wavelength coverage, JWST is expected to enable detailed investigation of exoplanet atmospheres, which could provide important constraints on the atmospheric composition obscured by clouds/haze. Here, we use four warm ($\lesssim 1000$ K) planets suitable for atmospheric characterization via transmission spectroscopy, GJ 1214b, GJ 436b, HD 97658b, and Kepler-51b, as examples to explore mole…
Recent transmission spectroscopy has revealed that clouds and hazes are common in the atmospheres of close-in exoplanets. In this study, using the photochemical, microphysical, and transmission spectrum models for close-in warm ($\lesssim$ 1000 K) exoplanet atmospheres that we newly developed in our preceding paper (Kawashima & Ikoma 2018), we investigate the vertical distributions of haze particles and gaseous species and the resultant transmission spectra over wide ranges of the model parameters including UV irradiation intensity, metallicity, carbon-to-oxygen ratio (C/O), eddy diffusion coe…
The photochemical haze produced in the upper atmosphere of Titan plays a key role in various atmospheric and surface processes on Titan. The surface energy, one important physical properties of the haze, is crucial for understanding the growth of the haze particles and can be used to predict their wetting behavior with solid and liquid species on Titan. We produced Titan analog haze materials, so-called "tholin", with different energy sources and measured their surface energies through contact angle and direct force measurements. From the contact angle measurement, we found that the tholins pr…
Hydrocarbon Hazes on Temperate sub-Neptune K2-18b supported by data from the James Webb Space Telescope
University College London（伦敦大学学院）；Universite de Reims Champagne Ardenne（兰斯香槟阿登大学）；King’s College London（伦敦国王学院）；Osservatorio Astronomico di Palermo（巴勒莫天文台）
Wet Removal and Cloud Enhancement: The Microphysics of Cloud-Haze Interactions on Sub-Neptunes
Department of Astronomy & Astrophysics, the University of Chicago（芝加哥大学天文与天体物理系）；Max Planck Institute for Astronomy, 69117 Heidelberg, Germany（马克斯·普朗克天文研究所）；Earth & Planets Laboratory, Carnegie Institution for Science, 5241 Broad Branch Road NW, Washington, DC 20015, USA（卡内基科学研究所地球与行星实验室）
Previous studies of haze formation in the atmosphere of the Early Earth have focused on N$_{2}$/CO$_{2}$/CH$_{4}$ atmospheres. Here, we experimentally investigate the effect of O$_{2}$ on the formation and composition of aerosols to improve our understanding of haze formation on the Neoproterozoic Earth. We obtained in situ size, particle density, and composition measurements of aerosol particles produced from N$_{2}$/CO$_{2}$/CH$_{4}$/O$_{2}$ gas mixtures subjected to FUV radiation (115-400 nm) for a range of initial CO$_{2}$/CH$_{4}$/O$_{2}$ mixing ratios (O$_{2}$ ranging from 2 ppm to 0.2\%…
Many of the exoplanets for which we can obtain the highest SNR transit spectra are tidally locked. The atmospheres on tidally-locked planets likely exhibit large differences between the day and night side of the planet, the poles, and the morning versus evening terminators. In this paper, we illustrate how the combined effects of aerosols and day-night temperature gradients shape transit spectra of tidally-locked exoplanets when full 3D structures are taken into account and evaluate the implications for retrievals of atmospheric properties. To do this, we have developed a new code, METIS, whic…
In recent years, it has become clear that a substantial fraction of transiting exoplanets have some form of aerosol present in their atmospheres. Transit spectroscopy - mostly of hot Jupiters, but also of some smaller planets - has provided evidence for this, in the form of steep downward slopes from blue to red in the optical part of the spectrum, and muted gas absorption features throughout. Retrieval studies seeking to constrain the composition of exoplanet atmospheres must therefore account for the presence of aerosols. However, clouds and hazes are complex physical phenomena, and the tran…
Volatile organic molecules formed by photochemistry in the upper atmosphere of Titan can undergo condensation as pure ices in the stratosphere and the troposphere as well as condense as ice layers onto the organic aerosols that are visible as the haze layers of Titan. As solar photons penetrate through Titan s atmosphere, shorter-wavelength photons are attenuated and longerwavelength photons make it into the lower altitudes, where aerosols become abundant. We conducted an experimental study to evaluate the long wavelength ( > 300 nm) photo-reactivity of these ices accreted on the Titan aerosol…
Photochemical hazes have been frequently used to interpret exoplanet transmission spectra that show an upward slope towards shorter wavelengths and weak molecular features. While previous studies have only considered spherical haze particles, photochemical hazes composed of hydrocarbon aggregate particles are common throughout the solar system. We use an aerosol microphysics model to investigate the effect of aggregate photochemical haze particles on transmission spectra of warm exoplanets. We find that the wavelength dependence of the optical depth of aggregate particle hazes is flatter than …
Titan, the biggest moon of Saturn, has a thick atmosphere which presents similarities with the one thought to be on Earth at its beginning. The study of Titan s photochemical haze is thus a precious tool in gaining knowledge of the primitive atmosphere of Earth. The chemistry occurring in Titan s atmosphere and the exact processes at act in the formation of the hazes remain largely unknown. The production of analogs samples on Earth has proved to be a useful tool to improve our knowledge of the aerosols formation on Titan. Such solid organic analogs samples, named tholins, were produced with t…
Spectral slopes in optical transmission spectra of exoplanetary atmospheres encapsulate information on the properties of exotic clouds. The slope is usually attributed to the Rayleigh scattering caused by tiny aerosol particles, whereas recent retrieval studies have suggested that the slopes are often steeper than the canonical Rayleigh slopes. Here, we propose that photochemical haze formed in vigorously mixing atmospheres can explain such super-Rayleigh slopes. We first analytically show that the spectral slope can be steepened by the vertical opacity gradient in which atmospheric opacity in…
Flow-Driven Limb-Asymmetry of Haze Distribution Part I: An Analytical Framework for Predicting the Size Distribution of Photochemical Hazes Across the Two Limbs of hot-Jupiters
University of Oxford（牛津大学）；University of Exeter（埃克塞特大学）；Johns Hopkins University（约翰斯·霍普金斯大学）
JWST will provide moderate resolution transit spectra with continuous wavelength coverage from the optical to the mid-infrared for the first time. In this paper, we illustrate how different aerosol species, size-distributions, and spatial distributions encode information in JWST transit spectra. We use the transit spectral modeling code METIS, along with Mie theory and several flexible treatments of aerosol size and spatial distributions to perform parameter sensitivity studies, calculate transit contribution functions, compute Jacobians, and retrieve parameters with Markov Chain Monte Carlo. …
Optical Constants of Photochemical Haze Analogs in N2-CH4-CO Atmospheres from 0.4 to 28.6 μm
National Key Laboratory of Deep Space Exploration/School of Earth and Space Sciences, University of Science and Technology of China（中国科学技术大学地球与空间科学学院深空探测重点实验室）；Department of Earth and Planetary Sciences, Johns Hopkins University（约翰斯·霍普金斯大学地球与行星科学系）；Space Telescope Science Institute（太空望远镜科学研究所）
The transmission spectra of exoplanet atmospheres observed with the Hubble Space Telescope (HST) in the near-infrared range (1.1-1.65$μ$m) frequently show evidence for some combination of clouds and hazes. Identification of systematic trends in exoplanet clouds and hazes is potentially important for understanding atmospheric composition and temperature structure. Here we report on the analysis of spectral modulation using a large, uniformly processed sample of HST/WFC3 transit spectra from 62 exoplanets. The spectral retrieval includes the capability to detect and represent atmospheres in whic…
Cloudy mornings and clear evenings on a gas giant exoplanet
Johns Hopkins University（约翰斯·霍普金斯大学）；University of California, Santa Cruz（加州大学圣克鲁兹分校）；Johns Hopkins Applied Physics Laboratory（约翰斯·霍普金斯大学应用物理实验室）；University of Exeter（埃克塞特大学）；University of Oxford（牛津大学）；Max Planck Institute for Astronomy（马克斯·普朗克天文学研究所）
Aerosols and hydrocarbons in the atmosphere of a white dwarf planet
University of St Andrews（圣安德鲁斯大学）；University of Michigan（密歇根大学）；Cornell University（康奈尔大学）；Northwestern University（西北大学）；Johns Hopkins Applied Physics Laboratory（约翰斯·霍普金斯大学应用物理实验室）；Johns Hopkins University（约翰斯·霍普金斯大学）；NASA Goddard Space Flight Center（美国宇航局戈达德太空飞行中心）；University of Victoria（维多利亚大学）；Steward Observatory, University of Arizona（亚利桑那大学斯图尔德天文台）；Space Telescope Science Institute（太空望远镜科学研究所）；Lunar and Planetary Laboratory, University of Arizona（亚利桑那大学月球与行星实验室）；Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）；NASA Ames Research Center（美国宇航局艾姆斯研究中心）
通过JWST NIRSpec PRISM的透射光谱对 WD 1856 b 进行大气探测，揭示其含碳氢化合物、气溶胶等，分析其质量、大气成分等，还表明该行星经历过与迁移相关的再加热事件。
Seasonal variation is significant in Titan's atmosphere due to the large change of solar insolation resulting from Titan's 26.7° axial tilt relative to the plane of Saturn's orbit. Here we present an investigation of hydrocarbon and nitrile species in Titan's upper atmosphere at 400-1200 km, which includes the mesosphere and the lower thermosphere, over more than one fourth of Titan's year (2006-2014, LS=318°-60°), using eighteen stellar occultation observations obtained by Cassini/UVIS. Vertical profiles of eight chemical species (CH4, C2H2, C2H4, C2H6, C4H2, C6H6, HCN, HC3N) and haze particl…
