One-particle energy eigenfunctions are used to obtain quantum averages in many particle systems. These are based on the effective local field due to fixed neighbors in classical phase space, while the averages account for the non-commutativity of the position and momentum operators. Used in Monte Carlo simulations for a one-dimensional Lennard-Jones fluid, the results prove more reliable than a high temperature expansion and a harmonic local field approach, and at intermediate temperatures agree with benchmark numerical results. Results are presented for distinguishable particles, fermions, and bosons.
Given are a first principles derivation and formulation of the probabilistic concepts that underly equilibrium quantum statistical mechanics. The transition to non-equilibrium probability is traversed briefly.
We present a concise derivation of Landauer's erasure principle from the postulates of statistical mechanics, along with a small number of additional but uncontroversial axioms.
In this paper, we investigate DNA denaturation through Statistical Mechanics and show that exceptional polynomials lead to DNA mutation. We consider a DNA model with two chains connected by Morse potential representing the H bonds, and then we calculate the partition function for this model. The partition function is converted into a Schrödinger like an equation. We exploit the techniques of SUSY quantum mechanics to model DNA mutation. We also compute the thermal denaturation of DNA for each mutated state.
We characterize the multipartite entanglement of a system of n qubits in terms of the distribution function of the bipartite purity over all balanced bipartitions. We search for those (maximally multipartite entangled) states whose purity is minimum for all bipartitions and recast this optimization problem into a problem of statistical mechanics.
In this paper we discuss and analyse the idea of trying to see (non-relativistic) quantum mechanics as a ``space-time statistical mechanics'', by using the classical statistical mechanical method on objective microscopic space-time configurations. It is argued that this could perhaps be accomplished by giving up the assumption that the objective ``state'' of a system is independent of a future measurement performed on the system. This idea is then applied in an example of quantum state estimation on a qubit system.
It is shown that the statistical conception of quantum mechanics is dynamical but not probabilistic, i.e. the statistical description in quantum mechanics is founded on dynamics. A use of the probability theory, when it takes place, is auxiliary. Attention is drawn to the fact that in the quantum mechanics there are two different objects: an individual object to be statistically described and a statistical average object, which is a result of the statistical description. Identification of the two different objects (a use of the same term for both) is an origin of many known quantum mechanics p…
These are the lecture notes for quantum and statistical mechanics courses that are given by DC at Ben-Gurion University. They are complementary to "Lecture Notes in Quantum Mechanics" [arXiv: quant-ph/0605180]. Some additional topics are covered, including: introduction to master equations; non-equilibrium processes; fluctuation theorems; linear response theory; adiabatic transport; the Kubo formalism; and the scattering approach to mesoscopics.
Classical statistical average values are generally generalized to average values of quantum mechanics, it is discovered that quantum mechanics is direct generalization of classical statistical mechanics, and we generally deduce both a new general continuous eigenvalue equation and a general discrete eigenvalue equation in quantum mechanics, and discover that a eigenvalue of quantum mechanics is just an extreme value of an operator in possibility distribution, the eigenvalue f is just classical observable quantity. A general classical statistical uncertain relation is further given, the general…
In this paper we develop the Hellmann-Feynman theorem in statistical mechanics without resorting to the eigenvalues and eigenvectors of the Hamiltonian operator. Present approach does not require the quantum-mechanical version of the theorem at $T=0$ and bypasses any discussion about degenerate states.
Based on the concept of ensemble, it is proved in the manuscript that the probability amplitude function can also been used to describe the classical statistical system. The motion equations of probability amplitude functions of classical statistical system are obtained, which are similar to that in quantum mechanics. It is also proved in the meantime that microsystems that obey quantum mechanics can also be described in the forms of classical statistical mechanics and deterministic classical mechanics. The quantum revised formula of classical interaction force and the revised Liouville's equa…
This review covers applications of quantum Monte Carlo methods to quantum mechanical problems in the study of electronic and atomic structure, as well as applications to statistical mechanical problems both of static and dynamic nature. The common thread in all these applications is optimization of many-parameter trial states, which is done by minimization of the variance of the local or, more generally for arbitrary eigenvalue problems, minimization of the variance of the configurational eigenvalue.
The classical-statistical limit of quantum mechanics is studied. It is proved that the limit $\hbar \to 0$ is the good limit for the operators algebra but it si not so for the state compact set. In the last case decoherence must be invoked to obtain the classical-statistical limit.
We argue here that, as it happens in Classical and Quantum Mechanics, where it has been proven that alternative Hamiltonian descriptions can be compatible with a given set of equations of motion, the same holds true in the realm of Statistical Mechanics, i.e. that alternative Hamiltonian descriptions do lead to the same thermodynamical description of any physical system.
We describe quantum entropic functionals and outline a research program dealing with entropic fluctuations in non-equilibrium quantum statistical mechanics.
Bell's inequalities in the form given by Wigner are derived from the so-called fundamental assumption of statistical mechanics. I then demonstrate the possible relationship between these inequalities and the second law, particularly if assuming the Pauli exclusion principle dictates the expected outcomes.
We implement Feynman's suggestion that the only missing notion needed for the puzzle of Quantum Measurement is the statistical mechanics of amplifying apparatus. We define a thermodynamic limit of quantum amplifiers which is a classically describable system in the sense of Bohr, and define macroscopic pointer variables for the limit system. Then we derive the probabilities of Quantum Measurement from the deterministic Schroedinger equation by the usual techniques of Classical Statistical Mechanics.
The fundamentals of Statistical Mechanics require a fresh definition in the context of the developments in Classical Mechanics of integrable and chaotic systems. This is done with the introduction of Micro Partitions ; a union of disjoint components in phase space. Partition functions including the invariants, Kolmogorov Entropy and Euler number are introduced. The ergodic hypothesis for partial ergodicity is discussed. In the context of Quantum Mechanics the presence of symmetry groups with irreducible representations gives rise to degenerate and non degenerate spectrum for the Hamiltonian. Q…
The authors of the recent paper [1] boldly claim to discover a new fully quantum approach to foundation of statistical mechanics: "Our conceptually novel approach is free of mathematically ambiguous notions such as probability, ensemble, randomness, etc." The aim of this note is to show that this approach is neither specific for quantum systems nor really conceptually different from the standard textbook arguments supporting microcanonical or canonical ensembles in statistical mechanics.
We show two fascinating topics lying between quantum information processing and statistical mechanics. First, we introduce an elaborated technique, the surface code, to prepare the particular quantum state with robustness against decoherence. Second, we show another interesting technique to employ quantum nature, quantum annealing. Through both of the topics, we would shed light on the birth of the interdisciplinary field between quantum mechanics and statistical mechanics.
The Dirac equation, usually obtained by `quantizing' a classical stochastic model is here obtained directly within classical statistical mechanics. The special underlying space-time geometry of the random walk replaces the missing analytic continuation, making the model `self-quantizing'. This provides a new context for the Dirac equation, distinct from its usual context in relativistic quantum mechanics.
Where does quantum mechanics part ways with classical mechanics? How does quantum randomness differ fundamentally from classical randomness? We cannot fully explain how the theories differ until we can derive them within a single axiomatic framework, allowing an unambiguous account of how one theory is the limit of the other. Here we derive nonrelativistic quantum mechanics and classical statistical mechanics within a common framework. The common axioms include conservation of average energy and conservation of probability current. But two axioms distinguish quantum mechanics from classical st…
The classical limit of the Schrodinger equation implies the orthodox statistical interpretation for degrees of freedom in finite-dimensional subspaces of the full Hilbert space, but the argument presented does not imply the Born interpretation for degrees of freedom that have a classical counterpart.
We point out that Fratini and Hayrapetyan ignored the randomness of mixing, a basic request to prepare a statistical ensemble rather than an ensemble in general. Their analysis is irrelevant for standard statistical ensembles, their conclusions about the limitations of standard theory become unjustified.
Quantum mechanics appears to contain ghosts from both classical statistical mechanics and special relativity. On one hand, both the Dirac and Schrödinger equations have classical analogs that emerge directly from classical statistical mechanics, unimpeded by major problems of interpretation. On the other hand, the formal analytic continuation that takes these classical equations to the quantum version introduces a velocity dependent phase. However, among classical theories, only in relativistic mechanics does one find path-dependent phase in the form of relativistic time dilation. This paper e…
A pedagogical derivation of statistical mechanics from quantum mechanics is provided, by means of open quantum systems. Besides, a new definition of Boltzmann entropy for a quantum closed system is also given to count microstates in a way consistent with the superposition principle. In particular, this new Boltzmann entropy is a constant that depends only on the dimension of the system's relevant Hilbert subspace. Finally, thermodynamics for quantum systems is investigated formally.
Quantum mechanics postulates the existence of states determined by a particle position at a single time. This very concept, in conjunction with superposition, induces much of the quantum-mechanical structure. In particular, it implies the time evolution to obey the Schroedinger equation, and it can be used to complete a truely basic derivation of the statistical axiom as recently proposed by Deutsch.
The statistical mechanics of quantum-classical systems with holonomic constraints is formulated rigorously by unifying the classical Dirac bracket and the quantum-classical bracket in matrix form. The resulting Dirac quantum-classical theory, which conserves the holonomic constraints exactly, is then used to formulate time evolution and statistical mechanics. The correct momentum-jump approximation for constrained system arises naturally from this formalism. Finally, in analogy with what was found in the classical case, it is shown that the rigorous linear response function of constrained quan…
Starting from the quantum theory of identical particles, we show how to define a classical mechanics that retains information about the quantum statistics. We consider two examples of relevance for the quantum Hall effect: identical particles in the lowest Landau level, and vortices in the Chern-Simons Ginzburg-Landau model. In both cases the resulting {\em classical} statistical mechanics is shown to be a nontrivial classical limit of Haldane's exclusion statistics.
We present a description of finite dimensional quantum entanglement, based on a study of the space of all convex decompositions of a given density matrix. On this space we construct a system of real polynomial equations describing separable states. We further study this system using statistical mechanical methods. Finally, we apply our techniques to Werner states of two qubits and obtain a sufficient criterion for separability.
We generalize classical statistical mechanics to describe the kinematics and the dynamics of systems whose variables are constrained by a single quantum postulate (discreteness of the spectrum of values of at least one variable of the theory). This is possible provided we adopt Feynman's suggestion of dropping the assumption that the probability for an event must always be a positive number. This approach has the advantage of allowing a reformulation of quantum theory in phase space without introducing the unphysical concept of probability amplitudes, together with all the problems concerning …
The second virial coefficient for non-Abelian Chern-Simons particles is recalculated. It is shown that the result is periodic in the flux parameter just as in the Abelian theory.
Existence and uniqueness results for the solution of the Gibbs-type formula from non-extensive mechanics are derived rigorously. A new conditional extremal problem is proposed to get in a more simple way the Gibbs-type formula itself.
We extend the mathematical theory of quantum hypothesis testing to the general $W^*$-algebraic setting and explore its relation with recent developments in non-equilibrium quantum statistical mechanics. In particular, we relate the large deviation principle for the full counting statistics of entropy flow to quantum hypothesis testing of the arrow of time.
These notes are intended as an introduction to a study of applications of noncommutative calculus to quantum statistical Physics. Centered on noncommutative calculus we describe the physical concepts and mathematical structures appearing in the analysis of large quantum systems, and their consequences. These include the emergence of algebraic approach and the necessity of employment of infinite dimensional structures. As an illustration, a quantization of stochastic processes, new formalism for statistical mechanics, quantum field theory and quantum correlations are discussed.
We develop a statistical mechanical interpretation of algorithmic information theory by introducing the notion of thermodynamic quantities, such as free energy, energy, statistical mechanical entropy, and specific heat, into algorithmic information theory. We investigate the properties of these quantities by means of program-size complexity from the point of view of algorithmic randomness. It is then discovered that, in the interpretation, the temperature plays a role as the compression rate of the values of all these thermodynamic quantities, which include the temperature itself. Reflecting t…
