Motility-induced wall aggregation of active Brownian particles (ABPs) is a well-studied phenomenon. Here, we study the aggregation of ABPs on porous walls, which allows the particles to penetrate through at large motility. We show that the active aggregates undergo a morphological transition from a connected dense-phase to disconnected droplets with an increase in wall porosity and the particle self-motility, similar to wetting-dewetting transitions in equilibrium fluids. We show that both morphologically distinct states are stable, and independent of initial conditions at least in some parameter regions. Our analysis reveals that changes in wall porosity affect the intrinsic properties of the aggregates and changes the effective wall-aggregate interfacial tension, consistent with the appearance of the morphological transition. Accordingly, a close analysis of the density, as well as orientational distribution, indicates that the underlying reason for such morphological transitions is not necessarily specific to the systems with porous walls, and it can be possible to observe in a larger class of confined, active systems by tuning the properties of confining walls.
We study the motility-induced aggregation of active Brownian particles (ABPs) on a porous, circular wall. We observe that the morphology of aggregated dense-phase on a static wall depends on the wall porosity, particle motility, and the radius of the circular wall. Our analysis reveals two morphologically distinct, dense aggregates; a connected dense cluster that spreads uniformly on the circular wall and a localized cluster that breaks the rotational symmetry of the system. These distinct morphological states are similar to the macroscopic structures observed in aggregates on planar, porous w…
Two-dimensional (2D) particulate aggregates formed due to competing interactions exhibit a range of non-equilibrium steady state morphologies from finite-size compact crystalline structures to non-compact string-like conformations. We report a transition in heterogeneous microscopic dynamics across this morphological hierarchy as a function of decreasing long-range repulsion relative to short-range attraction at a constant {\it low} density and temperature. Following a very slow cooling protocol to form steady state aggregates, we show that geometric frustration inherent to competing interacti…
$\mathit{Context.}$ The thermal conductivity of highly porous dust aggregates is a key parameter for many subjects in planetary science; however, it is not yet fully understood. $\mathit{Aims.}$ In this study, we investigate the thermal conductivity of fluffy dust aggregates with filling factors of less than $10^{-1}$. $\mathit{Methods.}$ We determine the temperature structure and heat flux of the porous dust aggregates calculated by $N$-body simulations of static compression in the periodic boundary condition. $\mathit{Results.}$ We derive an empirical formula for the thermal conductivity thr…
A dimensionless parameter $Λ$ is proposed to describe a hierarchy of morphologies in two-dimensional (2D) aggregates formed due to varying competition between short-range attraction and long-range repul- sion. Structural transitions from finite non-compact to compact to percolated structures are observed in the configurations simulated by molecular dynamics at a constant temperature and density. Configurational randomness across the transition, measured by the two-body excess entropy $S_2$, exhibits data collapse with the average potential energy $\bar{\mathcal{E}}$ of the systems. Independent…
Understanding the collisional outcomes of dust aggregates and dependence on material properties of the constituting particles is of great importance toward understanding planet formation. Recent numerical simulations have revealed that interparticle tangential friction plays a crucial role in energy dissipation during collisions between porous dust aggregates; however, the importance of friction on the collisional growth of dust aggregates remains poorly understood. Here we demonstrate the effects of interparticle tangential friction on the collisional growth of dust aggregates. We performed n…
Poly(ethylene oxide)-$\textit{b}$-poly(butylmethacrylate) (PEO-$\textit{b}$-PBMA) copolymers have recently been identified as excellent building blocks for the synthesis of hierarchical nanoporous materials. Nevertheless, while experiments have unveiled their potential to form bicontinuous phases and vesicles, a general picture of their phase and aggregation behavior is still missing. By performing Molecular Dynamics simulations, we here apply our recent coarse-grained model of PEO-$\textit{b}$-PBMA to investigate its self-assembly in water and tetrahydrofuran (THF) and unveil the occurrence o…
Context.Within the sequential accretion scenario of planet formation, planets are build up through a sequence sticking collisions. The outcome of collisions between porous dust aggregates is very important for the growth from very small dust particles to planetesimals. In this work we determine the necessary material properties of dust aggregates as a function the porosity. Aims: Continuum models such as SPH that are capable of simulating collisions of macroscopic dust aggregates require a set of material parameters. Some of them such as the tensile and shear strength are difficult to obtain f…
Context. A porous and/or fractal description can generally be applied where particles have undergone coagulation into aggregates. Aims. To characterise finite-sized, porous and fractal particles and to understand the possible limitations of these descriptions. Methods. We use simple structure, lattice and network considerations to determine the structural properties of irregular particles. Results. We find that, for finite-sized aggregates, the terms porosity and fractal dimension may be of limited usefulness and show with some critical and limiting assumptions, that highly-porous aggregates (…
Morphological transformations of amphiphilic AB diblock copolymers in mixtures of a common solvent (S1) and a selective solvent (S2) for the B block are studied using the simulated annealing method. We focus on the morphological transformation depending on the fraction of the selective solvent CS2, the concentration of the polymer CP, and the polymer-solvent interactions εij (i = A, B; j = S1, S2). Morphology diagrams are constructed as functions of CP, CS2, and/or εAS2. The copolymer morphological sequence from dissolved -> sphere -> rod-> ring/cage-> vesicle is obtained upon increasing CS2 a…
Most studies on melting under confinement focus only on the solid and liquid melt phases. Despite of its ubiquity, contributions from the capillary interface (liquid / vapor interface) are often neglected. In this study the melting behavior of small cylindrical aggregates in vapor attached to planar surfaces is analyzed. For the assumed boundary conditions (cylindrical solid with a non wetting top plane and a wettable side wall) solid and the liquid phases can coexist within a certain temperature range. Due to capillary instability, the liquid phase can form either an axisymmetric rouloid morp…
In this paper we explore the self-assembly patterns in a two dimensional colloidal system using extensive Langevin Dynamics simulations. The pair potential proposed to model the competitive interaction have a short range length scale between first neighbors and a second characteristic length scale between third neighbors. We investigate how the temperature and colloidal density will affect the assembled morphologies. The potential shows aggregate patterns similar to observed in previous works, as clusters, stripes and porous phase. Nevertheless, we observe at high densities and temperatures a …
Utilizing a 3D mean-field lattice-gas model, we analyze the effect of confinement on the nature of capillary phase transition in granular aggregates with varying disorder and their inverse porous structures obtained by interchanging particles and pores. Surprisingly, the confinement effects are found to be much less pronounced in granular aggregates as opposed to porous structures. We show that this discrepancy can be understood in terms of the surface-surface correlation length with a connected path through the fluid domain, suggesting that this length captures the true degree of confinement.…
It is shown that porous spherical particles can be obtained via the freezing of silica nanoparticle aqueous suspensions emulsified in a continuous oil phase. After two freeze-thaw cycles, nanoparticles turn aggregated into flocculated objects with microstructure that depends upon emulsion volume fraction and droplet size. For low volume fractions, regular microspheres are produced while for large ones, irregular beads with several tens of micrometer radius are formed. Electronic microscopy, mercury porosimetry and nitrogen adsorption are used to get insights into these porous particles typical…
We study the fluid inclusion of both Lennard-Jones particles and particles with competing interaction ranges --short range attractive and long range repulsive (SALR)-- in a disordered porous medium constructed as a controlled pore glass in two dimensions. With the aid of a full two-dimensional Ornstein-Zernike approach, complemented by a Replica Ornstein-Zernike integral equation, we explicitly obtain the spatial density distribution of the fluid adsorbed in the porous matrix and a good approximation for the average fluid-matrix correlations. The results illustrate the remarkable differences b…
From suspensions to porous multilayers: microstructure formation and particle packing in drying colloidal films
Helmholtz Institute Erlangen-Nürnberg for Renewable Energy (IET-2), Forschungszentrum Jülich（于利希研究中心埃尔朗根-纽伦堡亥姆霍兹可再生能源研究所（IET-2））；Friedrich-Alexander-Universität Erlangen-Nürnberg（埃尔朗根-纽伦堡弗里德里希·亚历山大大学）
The surface aggregates structure of dimethyldodecylamine-N-oxide (C12DAO) in three silica dispersions of different particle sizes (16 - 42 nm) was studied by small-angle neutron scattering (SANS) in a H2O/D2O solvent mixture matching the silica. At the experimental conditions (pH 9) the surfactant exists in its nonionic form and the structure of the adsorbed layer is not affected by added electrolyte. It is found that C12DAO forms spherical surface micelles of 2 nm diameter on the 16 nm silica particles, but oblate ellipsoidal surface micelles are formed on the 27 and 42 nm particles. The dime…
We herein report a theoretical study of the geometrical structure of porous dust aggregates formed via ballistic cluster-cluster aggregation (BCCA). We calculated the gyration radius $R_{\rm gyr}$ and the graph-based geodesic radius $R_{\rm geo}$ as a function of the number of constituent particles $N$. We found that $R_{\rm gyr} / r_{0} \sim N^{0.531 \pm 0.011}$ and $R_{\rm geo} / r_{0} \sim N^{0.710 \pm 0.013}$, where $r_{0}$ is the radius of constituent particles. Furthermore, we defined two constants that characterize the geometrical structure of fractal aggregates: $D_{\rm f}$ and $α$. Th…
