When materials are in the diffusive regime, i.e. when the scattering length is less than the sample size, charge transport is mediated by diffusons and cooperons. We argue that these charge carriers are not always spread out throughout the sample, like waves. When the scattering length is smaller than the sample size, diffusons and cooperons follow trajectories inside the sample which have an effective width determined by the scattering length. The net effect is particle-like motion. We discuss three experiments whose results confirm the existence of cooperons following particle-like trajectories. One experiment, with magnetic field perpendicular to a topological insulator surface, resolved and measured the areas of Cooperon loops. The other two experiments, with magnetic field parallel to wires where conduction occurred on the wire surface, measured the number of times that a Cooperon trajectory wound around the wire.
We report electrical transport measurements on individual disordered carbon nanotubes, grown catalytically in a nanoporous anodic aluminum oxide template. In both as-grown and annealed types of nanotubes, the low-field conductance shows as exp[-(T_{0}/T)^{1/2}] dependence on temperature T, suggesting that hopping conduction is the dominant transport mechanism, albeit with different disorder-related coefficients T_{0}. The field dependence of low-temperature conductance behaves an exp[-(xi_{0}/xi)^{1/2}] with high electric field xi at sufficiently low T. Finally, both annealed and unannealed na…
The low-energy spectrum of graphene nanoribbons with armchair edges (armchair nanoribbons) is described as the superposition of two non-equivalent Dirac points of graphene. In spite of the lack of well-separated two valley structures, the single-channel transport subjected to long-ranged impurities is nearly perfectly conducting, where the backward scattering matrix elements in the lowest order vanish as a manifestation of internal phase structures of the wavefunction. For multi-channel energy regime, however, the conventional exponential decay of the averaged conductance occurs. Since the int…
We study the effect of electrostatic disorder on the conductivity of a three-dimensional antiferromagnetic insulator (a stack of quantum anomalous Hall layers with staggered magnetization). The phase diagram contains regions where the increase of disorder first causes the appearance of surface conduction (via a topological phase transition), followed by the appearance of bulk conduction (via a metal-insulator transition). The conducting surface states are stabilized by an effective time-reversal symmetry that is broken locally by the disorder but restored on long length scales. A simple self-c…
We present the electrical transport characteristics of a batch of nano-crystalline diamond films of varying nitrogen concentrations and explain the conduction mechanism by the disordered quasi-superlattice model applied to semiconductor heterostructures. Synthesized by the hot filament chemical vapour deposition technique, the degree of structural disorder in the films, confirmed from Raman spectroscopy, is found to be controllable, resulting in the transition of conduction mechanism from localized and activated to the metallic conduction regime. Hence through high field magneto-resistance mea…
We present a theory of current conduction through buckyball(C60) molecules on silicon by coupling a density functional treatment of the molecular levels embedded in silicon with a non-equilibrium Green's function (NEGF) treatment of quantum transport. Several experimental variations in conductance-voltage(G-V) characteristics are quantitatively accounted for by varying the detailed molecule-silicon bonding geometries. We identify how variations in contact surface microstructure influence the number, positions and shapes of the conductance peaks, while varying separations of the scanning probe …
We report Kondo resonances in the conduction of single-molecule transistors based on transition metal coordination complexes. We find Kondo temperatures in excess of 50 K, comparable to those in purely metallic systems. The observed gate dependence of the Kondo temperature is inconsistent with observations in semiconductor quantum dots and a simple single-dot-level model. We discuss possible explanations of this effect, in light of electronic structure calculations.
Electronic conduction through single molecules is affected by the molecular electronic structure as well as by other information that is extremely difficult to assess, such as bonding geometry and chemical environment. The lack of an independent diagnostic technique has long hampered single-molecule conductance studies. We report simultaneous measurement of the conductance and the Raman spectra of nanoscale junctions used for single-molecule electronic experiments. Blinking and spectral diffusion in the Raman response of both para-mercaptoaniline and a fluorinated oligophenylyne ethynylene cor…
We investigate intra-Landau-level collective excitations in a bilayer disordered two-dimensional electron system exposed to a perpendicular magnetic field. The energy spectrum is calculated within the random phase approximation by taking into account electron-impurity scattering in the self-consistent Born approximation which includes consistent vertex corrections. Signatures of these bilayer excitations in drag and collective excitation measurements are identified.
Electronic quantum effects in disordered conductors are controlled by the dephasing rate of conduction electrons. This rate is expected to vanish with the temperature. We consider the very intriguing recently reported apparent saturation of this dephasing rate in several systems at very low temperatures. We show that the ``standard model'' of a conductor with static defects can {\em not} have such an effect. However, allowing some dynamics of the defects may produce it.
Short-range order in strongly disordered structures plays an important role in their heat conduction property. Using numerical and analytical methods, we show that short-range spatial correlation (with a correlation length of $Λ_{m}$) in the mass distribution of the one-dimensional (1D) alloy-like random binary lattice leads to a dramatic enhancement of the high-frequency phonon transmittance but also increases the low-frequency phonon opacity. High-frequency semi-extended states are formed while low-frequency modes become more localized. This results in ballistic heat conduction at finite len…
A strict method is used to calculate the current-voltage characteristics of a double-stranded DNA. A more reliable model considering the electrostatic potential drop along an individual DNA molecular wire between the contacts is considered and the corresponding Green's Function is obtained analytically using Generating Function method, which avoids difficult numerical evaluations. The obtained results indicate that the electrostatic drop along the wire always increases the conductor beyond the threshold than without considering it, which is in agreement with recent experiments. The present met…
In this article we present numerical results of conduction in a disordered quasi-1D wire in the possible presence of magnetic impurities. Our analysis leads us to the study of universal properties in different conduction regimes such as the localized and metallic ones. In particular, we analyse the cross-over between universality classes occurring when the strength of magnetic disorder is increased. For this purpose, we use a numerical Landauer approach, and derive the scattering matrix of the wire from electron's Green's function.
The influence of vibrational motion on electron conduction through single molecules bound to metal electrodes is investigated employing first-principles electronic-structure calculations and projection-operator Green's function methods. Considering molecular junctions where a central phenyl ring is coupled via (alkane)thiol-bridges to gold electrodes, it is shown that -- depending on the distance between the electronic $π$-system and the metal -- electronic-vibrational coupling may result in pronounced vibrational substructures in the transmittance, a significantly reduced current as well as a…
Charge transport is well understood in both highly ordered materials (band conduction) or highly disordered ones (hopping conduction). In moderately disordered materials -- including many organic semiconductors -- the approximations valid in either extreme break down, making it difficult to accurately model the conduction. In particular, describing wavefunction delocalisation requires a quantum treatment, which is difficult in disordered materials that lack periodicity. Here, we present the first three-dimensional model of partially delocalised charge and exciton transport in materials in the …
We calculate the thermal conductivity of interacting electrons in disordered metals. In our analysis we point out that the interaction affects thermal transport through two distinct mechanims, associated with quantum interference corrections and energy exchange of the quasi particles with the electromagnetic environment, respectively. The latter is seen to lead to a violation of the Wiedemann-Franz law. Our theory predicts a strong enhancement of the Lorenz ratio $κ/σT$ over the value which is predicted by the Wiedemann-Franz law, when the electrons encounter a large environmental impedance.
We study the electronic properties of GaAs nanowires composed of both the zincblende and wurtzite modifications using a ten-band k.p model. In the wurtzite phase, two energetically close conduction bands are of importance for the confinement and the energy levels of the electron ground state. These bands form two intersecting potential landscapes for electrons in zincblende/wurtzite nanostructures. The energy difference between the two bands depends sensitively on strain, such that even small strains can reverse the energy ordering of the two bands. This reversal may already be induced by the …
We identify experimental signatures in the current-voltage (I-V) characteristics of weakly contacted molecules directly arising from excitations in their many electron spectrum. The current is calculated using a multielectron master equation in the Fock space of an exact diagonalized model many-body Hamiltonian for a prototypical molecule. Using this approach, we explain several nontrivial features in frequently observed I-Vs in terms of a rich spectrum of excitations that may be hard to describe adequately with standard one-electron self-consistent field (SCF) theories.
Geometry incommensurability between weakly coupled shells in multi-walled carbon nanotubes is shown to be the origin of unconventional electronic conduction mechanism, power-law scaling of the conductance, and remarkable magnetotransport and low temperature dependent conductivity when the dephasing mechanism is dominated by weak electron-electron coupling.
A good understanding of the electronic conduction processes through nanocontacts is a crucial step for the implementation of functional nanoelectronic devices. We have studied the current-voltage ($I$-$V$) characteristics of nanocontacts between single metallic RuO$_2$ nanowires (NWs) and contacting Au electrodes which were pre-patterned by simple photolithography. Both the temperature behavior of contact resistance in the low-bias voltage ohmic regime and the $I$-$V$ curves in the high-bias voltage non-ohmic regime have been investigated. We found that the electronic conduction processes in t…
While mesoscopic conducting loops are sensitive to external magnetic fields, as seen by observations of the Aharonov-Bohm (AB) effect in such structures, the field needed to observe the AB periodicity in small molecular rings is unrealistically large. The present study aims to identify conditions under which magnetic field dependence can be observed in electronic conduction through such molecules. We consider molecular ring structures modeled both within the tight-binding (Hückel) model and as continuous rings. In fact, much of the observed qualitative behavior can be rationalized in terms of …
We present numerical studies of conduction in graphene nanoribbons with different types of disorder. We find that even when defect scattering depresses the conductance to values two orders of magnitude lower than 2e^2/h, equally spaced conductance plateaus occur at moderately low temperatures due to enhanced electron backscattering near subband edge energies if bulk vacancies are present in the ribbon. This work accounts quantitatively for the surprising conductance quantization observed by Lin et al. [Phys. Rev. B 78, 161409 (2008)] in ribbons with such low conductances.
We investigate the dc response of a 1D disordered ring coupled to a reservoir and driven by a magnetic flux with a linear dependence on time. We identify two regimes: (i) A localized or large length L regime, characterized by a dc conductance, g_{dc}, whose probability distribution P(g_{dc}) is identical to the one exhibited by a 1D wire of the same length L and disorder strength placed in a Landauer setup. (ii) A "multifloquet" regime for small L and weak coupling to the reservoir, which exhibits large currents and conductances that can be g_{dc} > 1, in spite of the fact that the ring contai…
The electronic conduction of a novel, three-terminal molecular architecture, analogous to a heterojunction bipolar transistor is studied. In this architecture, two diode arms consisting of donor-acceptor molecular wires fuse through a ring, while a gate modulating wire is a π-conjugated wire. The calculated results show the enhancement or depletion mode of a transistor by applying a gate field along the positive or negative direction. A small gate field is required to switch on the current in the proposed architecture. The changes in the electronic conduction can be attributed to the intrinsic…
Electrically tunable interfacial thermal conduction via electronic structure engineering in ${Au}$/$Bi_{1-x}$$Sb_{x}$ topological insulators
The Ohio State University（俄亥俄州立大学）；Korea Institute of Science and Technology (KIST)（韩国科学技术院）；Korea Advanced Institute of Science and Technology (KAIST)（韩国科学技术院）；Pohang University of Science and Technology (POSTECH)（浦项科技大学）；Carnegie Mellon University（卡内基梅隆大学）；E. O. Lawrence Berkeley National Laboratory（劳伦斯伯克利国家实验室）
The inhomogenous real-space electronic structure of gapless and gapped disordered bilayer graphene is calculated in the presence of quenched charge impurities. For gapped bilayer graphene we find that for current experimental conditions the amplitude of the fluctuations of the screened disorder potential is of the order of (or often larger than) the intrinsic gap $Δ$ induced by the application of a perpendicular electric field. We calculate the crossover chemical potential, $Δ_{\rm cr}$, separating the insulating regime from a percolative regime in which less than half of the area of the bilay…
In this paper, electrical and electronic properties of strained mono-layer InTe for two structures, $α$, and $β$ phases, is investigated. The band structure is obtained using density functional theory (DFT). The minimum energy and effective mass of the conduction band and second conduction band for different strains are calculated. A FET with using InTe as the channel material is investigated. Voltage-current characteristics of InTe FET is calculated and I$_{ON}$/I$_{OFF}$ ratio is obtained with respect to biaxial strain.
Boron (B)/phosphorus (P) doped single wall carbon nanotubes (B-PSWNTs) are studied by using the First- Principle method based on density function theory (DFT). Mayer bond order, band structure, electrons density and density of states are calculated. It concludes that the B-PSWNTs have special band structure which is quite different from BN nanotubes, and that metallic carbon nanotubes will be converted to semiconductor due to boron/phosphorus co-doping which breaks the symmetrical structure. The bonding forms in B-PSWNTs are investigated in detail. Besides, Mulliken charge population and the q…
While using first-principles-based Boltzmann transport equation approach to predict the thermal conductivity of crystalline semiconductor materials has been a routine, the validity of the approach is seldom tested for high-temperature conditions. Most previous studies only focused on the phononic contribution, and neglected the electronic part. Meanwhile, the treatment on phonon transport is not rigorous as a few ingredients, such as four-phonon scatterings, phonon renormalization and thermal expansion, are ignored. In this paper, we present a Boltzmann transport equation study on high-tempera…
In molecular electronic conduction, exotic lattice morphologies often give rise to exotic behaviors. Among 2D systems, graphene is a notable example. Recently, a stable amorphous version of graphene called Monolayer Amorphous Carbon (MAC) was synthesized. MAC poses a new set of questions regarding the effects of disorder on conduction. In this Letter, we perform ensemble-level computational analysis of the coherent electronic transmission through MAC nano-fragments in search of defining characteristics. Our analysis, relying on a semi-empirical Hamiltonian (Pariser-Parr-Pople) and Landauer the…
The Green functions play a big role in the calculation of the local density of states of the carbon nanostructures. We investigate their nature for the variously oriented and disclinated graphene-like surface. Next, we investigate the case of a small perturbation generated by two heptagonal defects and from the character of the local density of states in the border sites of these defects we derive their minimal and maximal distance on the perturbed cylindrical surface. For this purpose, we transform the given surface into a chain using the Haydock recursion method. We will suppose only the nea…
The electronic conductance of a benzene molecule connected to gold electrodes via thiol, thiolate, and amino anchoring groups is calculated using nonequilibrium Green functions in combination with the fully selfconsistent GW approximation. The calculated conductance of benzenedithiol and benzenediamine is five times lower than predicted by standard density functional theory (DFT) in very good agreement with experiments. In contrast, the widely studied benzenedithiolate structure is found to have a significantly higher conductance due to the unsaturated sulfur bonds. These findings suggest that…
Small numbers of nitrogen dopants dramatically modify the electronic properties of GaAs, generating very large shifts in the conduction-band energies with nonlinear concentration dependence, and impurity-associated spatially-localized resonant states within the conduction band. Cross-sectional scanning tunneling microscopy provides the local electronic structure of single nitrogen dopants at the (110) GaAs surface, yielding highly anisotropic spatial shapes when the empty states are imaged. Measurements of the resonant states relative to the GaAs surface states and their spatial extent allow a…
We propose a tight-binding model to investigate electronic transport properties of single helical protein molecules incorporating both the helical symmetry and the possibility of multiple charge transfer pathways. Our study reveals that due to existence of both the multiple charge transfer pathways and helical symmetry, the transport properties are quite rigid under influence of envi- ronmental fluctuations which indicates that these biomolecules can serve as better alternatives in nanoelectronic devices than its other biological counterparts e.g., single-stranded DNA.
In the framework of density functional theory (DFT) calculations we investigate the electronic and thermal properties of porous graphene (PG) structures passivated with halogen atoms as possible candidates for efficient thermoelectric devices. Armchair and zig-zag halogenated PG nanoribbons are analyzed comparatively. The electronic properties are consistent with the expected behavior for the two types of terminations, however with marked influences introduced by the different halogen atoms. Depending on the pore sizes and halogen type pseudo-gaps in the phononic band structure are visible in …
We study heat conduction in quantum disordered harmonic chains connected to general heat reservoirs which are modeled as infinite collection of oscillators. Formal exact expressions for the thermal current are obtained and it is shown that, in some special cases, they reduce to Landauer-like forms. The asymptotic system size dependence of the current is analysed and is found to be similar to the classical case. It is a power law dependence and the power depends on the spectral properties of the reservoirs.
We study the problem of electronic conduction in mesoscopic systems when the electrons are allowed to interact not only with static impurities, but also with a scatterer (a phase breaker(PB)) that possesses internal degrees of freedom. We first analyze the role of the PB in reducing the coherent interference effects in a one-electron quantum-mechanical system. In the many-electron system we can make a number of quite general statements within the framework of linear-response theory and the random-phase approximation. We cannot calculate the conductivity tensor in full generality: we thus resor…
We investigate electron and phonon transport through edge disordered zigzag graphene nanoribbons based on the same methodological tool of nonequilibrium Green functions. We show that edge disorder dramatically reduces phonon thermal transport while being only weakly detrimental to electronic conduction. The behavior of the electronic and phononic elastic mean free paths points to the possibility of realizing an electron-crystal coexisting with a phonon-glass. The calculated thermoelectric figure of merit (ZT) values qualify zigzag graphene nanoribbons as a very promising material for thermoele…
Effects of conduction electrons on magnetization dynamics, represented by spin torques, are calculated microscopically in the first order in spatial gradient and time derivative of magnetization. Special attention is paid to the so-called $β$-term and the Gilbert damping, $α$, in the presence of electrons' spin-relaxation processes, which are modeled by quenched magnetic (and spin-orbit) impurities. The obtained results such as $α\ne β$ hold for localized as well as itinerant ferromagnetism.
A transfer matrix approach is used to study the electronic transport in graphene superlattices with long-range correlated barrier spacements. By considering the low-energy electronic excitations as massless Dirac fermions, we compute by transmission spectra of graphene superlattices with potential barriers having spacements randomly distributed with long-range correlations governed by a power-law spectral density $S(k)\propto 1/k^α$. We show that at large incidence angles, the correlations in the disorder distribution do not play a significant role in the electronic transmission. However, long…
Indium tin oxide (Sn-doped In$_2$O$_{3-δ}$ or ITO) is an interesting and technologically important transparent conducting oxide. This class of material has been extensively studied for decades, with research efforts focusing on the application aspects. The fundamental issues of the electronic conduction properties of ITO from 300 K down to low temperatures have rarely been addressed. Studies of the electrical-transport properties over a wide range of temperature are essential to unraveling the underlying electronic dynamics and microscopic electronic parameters. We show that one can learn rich…
We performed measurements at helium temperatures of the electronic transport in an InAs quantum wire ($R_{wire} \sim 30$\,k$Ω$) in the presence of a charged tip of an atomic force microscope serving as a mobile gate. The period and the amplitude of the observed quasiperiodic oscillations are investigated in detail as a function of electron concentration in the linear and non-linear regime. We demonstrate the influence of the tip-to-sample distance on the ability to locally affect the top subband electrons as well as the electrons in the disordered sea. Furthermore, we introduce a new method of…
The evolution of electronic wave packets (WPs) through grain boundaries (GBs) of various structures in graphene was investigated by the numerical solution of the time-dependent Schroedinger equation. WPs were injected from a simulated STM tip placed above one of the grains. Electronic structure of the GBs was calculated by ab-initio and tight-binding methods. Two main factors governing the energy dependence of the transport have been identified: the misorientation angle of the two adjacent graphene grains and the atomic structure of the GB. In case of an ordered GB made of a periodic repetitio…
We present a detailed study of the conduction properties of a molecular wire where hopping processes between electronic sites are coupled to a vibrational mode of the molecule. The latter is sandwiched between two electronic leads at finite temperatures. We show that the electro-mechanical coupling can lead to a strong enhancement of the lead-to-lead conduction. Moreover, under suitable driving of the molecular vibrational mode, the device can act as a transistor passing sharply from enhanced conduction to short-circuit configuration.
We study inelastic vibration-assisted charge transfer effects in two-site molecular junctions, focusing on signatures of vibrational anharmonicity on the electrical characteristics and the thermoelectric response of the junction. We consider three types of oscillators: harmonic, anharmonic-Morse allowing bond dissociation, and harmonic-quartic, mimicking a confinement potential. Using a quantum master equation method which is perturbative in the electron-vibration interaction we find that the (inelastic) electrical and thermal conductances can be largely affected by the nature of the vibration…
We present an atomistic theory of electronic transport through single organic molecules that reproduces the important features of the current-voltage characteristics observed in recent experiments. We trace these features to their origin in the electronic structure of the molecules and their local atomic environment. We demonstrate how conduction channels arise from the molecular orbitals and elucidate which specific properties of the individual orbitals determine their contribution to the current.
The transfer of electrons between a solid surface and adsorbed atomic or molecular species is fundamental in natural and synthetic processes, being at the heart of most catalytic reactions and many sensors. In special cases, metallic conduction can be induced at the surface of, for example, Si-terminated SiC1, or mixed-terminated ZnO2, in the presence of a hydrogen adlayer. Generally, only the surface atoms are significantly affected by adsorbates. However, remotely changing electronic states far from the adsorbed layer is possible if these states are electrostatically coupled to the surface. …
It is believed, that a disordered one-dimensional (1D) wire with coherent electronic conduction is an insulator with the mean resistance <ρ> \simeq e^{2L/ξ} and resistance dispersion Δ_ρ \simeq e^{L/ξ}, where L is the wire length and ξis the electron localisation length. Here we show that this 1D insulator undergoes at full coherence the crossover to a 1D "metal", caused by thermal smearing and resonant tunnelling. As a result, Δ_ρ is smaller than unity and tends to be L/ξ- independent, while <ρ> grows with L/ξfirst nearly linearly and then polynomially, manifesting the so-called medium locali…
We numerically investigate the transport properties of disordered interacting electrons in three dimensions in the metallic as well as in the insulating phases. The disordered many-particle problem is modeled by the quantum Coulomb glass which contains a random potential, long-range unscreened Coulomb interactions and quantum hopping between different sites. We have recently developed the Hartree-Fock based diagonalization (HFD) method which amounts to diagonalizing the Hamiltonian in a suitably chosen energetically truncated basis. This method allows us to investigate comparatively large syst…
We report interlayer electronic transport in CaMnBi$_{2}$ single crystals. Quantum oscillations and angular magnetoresistance suggest coherent electronic conduction and valley polarized conduction of Dirac states. Small cyclotron mass, large mobility of carriers and nontrivial Berry's phase are consistent with the presence of Dirac fermions on the side wall of the warped cylindrical Fermi surface. Similar to SrMnBi$_{2}$ that features an anisotropic Dirac cone, our results suggest that magnetic field-induced changes in the interlayer conduction are also present in layered bismuth-based materia…
We provide a theoretical estimate of the thermoelectric current and voltage over a Phenyldithiol molecule. We also show that the thermoelectric voltage is (1) easy to analyze, (2) insensitive to the detailed coupling to the contacts, (3) large enough to be measured and (4) give valuable information, which is not readily accessible through other experiments, on the location of the Fermi energy relative to the molecular levels. The location of the Fermi-energy is poorly understood and controversial even though it is a central factor in determining the nature of conduction (n- or p-type). We also…
We show that a discrete tight-binding model representing either a random or a quasiperiodic array of bonds, can have the entire energy spectrum or a substantial part of it absolutely continuous, populated by extended eigenfunctions only, when atomic sites are coupled to the lattice locally, or non-locally from one side. The event can be fine-tuned by controlling only the host-adatom coupling in one case, while in two other cases cited here an additional external magnetic field is necessary. The delocalization of electronic states for the group of systems presented here is sensitive to a subtle…
We investigate the conductivity $σ$ of graphene nanoribbons with zigzag edges as a function of Fermi energy $E_F$ in the presence of the impurities with different potential range. The dependence of $σ(E_F)$ displays four different types of behavior, classified to different regimes of length scales decided by the impurity potential range and its density. Particularly, low density of long range impurities results in an extremely low conductance compared to the ballistic value, a linear dependence of $σ(E_F)$ and a wide dip near the Dirac point, due to the special properties of long range potenti…
We present results of conductance-noise experiments on disordered films of crystalline indium oxide with lateral dimensions 2microns to 1mm. The power-spectrum of the noise has the usual 1/f form, and its magnitude increases with inverse sample-volume down to sample size of 2microns, a behavior consistent with un-correlated fluctuators. A colored second spectrum is only occasionally encountered (in samples smaller than 40microns), and the lack of systematic dependence of non-Gaussianity on sample parameters persisted down to the smallest samples studied (2microns). Moreover, it turns out that …
We present and discuss an original method to synthesize disordered Nanostructured (NS) VO$_x$ films with controlled stoichiometry and tunable electronic structures. In these NS films, the original lattice symmetry of the bulk vanadium oxides is broken and atoms are arranged in a highly disordered structure . The stoichiometry-dependent disorder as a function of the oxygen concentration has been characterized by in-situ X-ray Absorption Near-Edge Structure (XANES) spectroscopy identifying the spectroscopic fingerprints. Results show structural rearrangements that deviate from the octahedral sym…
It is well known that conductivity of disordered metals is suppressed in the limit of low frequencies and temperatures by quantum corrections. Although predicted by theory to exist up to much higher energies, such corrections have so far been experimentally proven only for $\lesssim$80 meV. Here, by a combination of transport and optical studies, we demonstrate that the quantum corrections are present in strongly disordered conductor MoC up to at least $\sim$4 eV, thereby extending the experimental window where such corrections were found by a factor of 50. The knowledge of both, the real and …
