We study vibrational statistics in current-carrying model molecular junctions using master equation approach. Especially, we concentrate on the validity of using an effective temperature $T_{\rm eff}$ to characterize the nonequilibrium steady state of a vibrational mode. We identify cases where a single $T_{\rm eff}$ can not fully describe one vibrational state. In such cases, the probability distribution among different vibrational states does not follow the Boltzmann type. Consequently, the actual entropy (free energy) of the vibrational mode is lower (higher) than the corresponding thermal value given by $T_{\rm eff}$, indicating extra work can be extracted from these states. Our results will be useful for the study of non-thermal vibrational state in thermodynamics of nanoscale systems, and its usage in nanoscale heat engines.
We analyze various limits of vibrationally coupled resonant electron transport in single-molecule junctions. Based on a master equation approach, we discuss analytic and numerical results for junctions under a high bias voltage or weak electronic-vibrational coupling. It is shown that in these limits the vibrational excitation of the molecular bridge increases indefinitely, i.e. the junction exhibits a vibrational instability. Moreover, our analysis provides analytic results for the vibrational distribution function and reveals that these vibrational instabilities are related to electron-hole …
We observe large, reversible, bias driven changes in the vibrational energies of PCBM, based on simultaneous transport and surface-enhanced Raman spectroscopy (SERS) measurements on PCBM-gold junctions. A combination of linear and quadratic shifts in vibrational energies with voltage is analyzed and compared with similar measurements involving C60-gold junctions. A theoretical model based on density functional theory (DFT) calculations suggests that both a vibrational Stark effect and bias-induced charging of the junction contribute to the shifts in vibrational energies. In the PCBM case, a li…
Quantum interference effects and decoherence mechanisms in single-molecule junctions are analyzed employing a nonequilibrium Green's function approach. Electrons tunneling through quasi-degenerate states of a nanoscale molecular junction exhibit interference effects. We show that electronic-vibrational coupling, inherent to any molecular junction, strongly quenches such interference effects. As a result, the electrical current can be significantly larger than without electronic-vibrational coupling. The analysis reveals that the quenching of quantum interference is particularly pronounced if t…
Single-molecule junctions are found to show anomalous spikes in dI/dV spectra. The position in energy of the spikes are related to local vibration mode energies. A model of vibrationally induced two-level systems reproduces the data very well. This mechanism is expected to be quite general for single-molecule junctions. It acts as an intrinsic amplification mechanism for local vibration mode features and may be exploited as a new spectroscopic tool.
The influence of multiple vibrational modes on current fluctuations in electron transport through single-molecule junctions is investigated. Our analysis is based on a generic model of a molecular junction, which comprises a single electronic state on the molecular bridge coupled to multiple vibrational modes and fermionic leads, and employs a master equation approach. The results reveal that in molecular junctions with multiple vibrational modes already weak to moderate electronic-vibrational coupling may result in high noise levels, especially at the onset of resonant transport, in accordanc…
In nanoscale junctions the interaction between charge carriers and the local vibrations results in renormalization, damping and heating of the vibrational modes. We here formulate a nonequilibrium Green's functions based theory to describe such effects. Studying a generic junction model with an off-resonant electronic level, we find a strong bias dependence of the frequency renormalization and vibrational damping accompanied by pronounced nonlinear vibrational heating in junctions with intermediate values of the coupling to the leads. Combining our theory with ab-initio calculations we further…
The interaction between electronic and vibrational degrees of freedom in single-molecule junctions may result from the dependence of the electronic energies or the electronic states of the molecular bridge on the nuclear displacement. The latter mechanism leads to a direct coupling between different electronic states and is referred to as nonadiabatic electronic-vibrational coupling. Employing a perturbative nonequilibrium Green's function approach, we study the influence of nonadiabatic electronic-vibrational coupling in model molecular junctions. Thereby we distinguish between systems with w…
In a nanoscale molecular junction at finite bias voltage,the intra-molecular distribution of vibrational energy can strongly deviate from the thermal equilibrium distribution and specific vibrational modes can be selectively excited in a controllable way,regardless of the corresponding mode frequency. This is demonstrated for generic models of asymmetric molecular junctions with localized electronic states, employing a master equation as well as a nonequilibrium Green's function approach. It is shown that the applied bias voltage controls the excitation of specific vibrational modes coupled to…
We theoretically examine the effect of the coupling of the transport electrons to a vibrational mode of the molecule on the ac linear-response conductance of molecular junctions. Representing the molecule by a single electronic state, we find that at very low temperatures the frequency-dependent conductance is mainly enhanced (suppressed) by the electron-vibration interaction when the chemical potential is below (above) the energy of that state. The vertex corrections of the electron-vibration interaction induce an additional peak structure in the conductance, which can be observed by tuning t…
We propose a model for a molecular junction with internal anharmonic torsional vibrations interacting with an electric current. The Wangsness-Bloch-Redfield master equation approach is used to determine the stationary reduced density matrix of the molecule. The dependence of the current, excitation energy and angular momentum of the junction on the applied voltage is studied. Negative differential conductance is observed in the current-voltage characteristics. It is shown that a model with vibrationally dependent coupling to the electrodes, asymmetric with respect to the interchanging of elect…
In bulk systems, molecules are routinely identified by their vibrational spectrum using Raman or infrared spectroscopy. In recent years, vibrational excitation lines have been observed in low-temperature conductance measurements on single molecule junctions and they can provide a similar means of identification. We present a method to efficiently calculate these excitation lines in weakly coupled, gateable single-molecule junctions, using a combination of ab initio density functional theory and rate equations. Our method takes transitions from excited to excited vibrational state into account …
Shot noise in a voltage source changes the character of the quantum (dissipative) phase transition in an ultrasmall Josephson junction: The superconductor-insulator transition transforms into the superconductor-metal transition. In the metallic phase the IV curve probes the voltage distribution generated by shot noise, whereas in the superconducting phase it probes the counting statistics of electrons traversing the noise junction.
We present a detailed study of the non-linear thermoelectric properties of a molecular junction, represented by a dissipative Anderson-Holstein model. A single orbital level with strong Coulomb interaction is coupled to a localized vibrational mode and we account for both electron and phonon exchange with both electrodes, investigating how these contribute to the heat and charge transport. We calculate the efficiency and power output of the device operated as a heat to electric power converter and identify the optimal operating conditions, which are found to be qualitatively changed by the pre…
Vibrational modes of molecules are fundamental properties determined by intramolecular bonding, atomic masses, and molecular geometry, and often serve as important channels for dissipation in nanoscale processes. Although single-molecule junctions have been employed to manipulate electronic structure and related functional properties of molecules, electrical control of vibrational mode energies has remained elusive. Here we use simultaneous transport and surface-enhanced Raman spectroscopy measurements to demonstrate large, reversible, voltage-driven shifts of vibrational mode energies of C60 …
The transmission coefficient for vibrational waves crossing an abrupt junction between two thin elastic plates of different widths is calculated. These calculations are relevant to ballistic phonon thermal transport at low temperatures in mesoscopic systems and the Q for vibrations in mesoscopic oscillators. Complete results are calculated in a simple scalar model of the elastic waves, and results for long wavelength modes are calculated using the full elasticity theory calculation. We suggest that thin plate elasticty theory provide a useful and tractable approximation to the full three dimen…
We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic processes lead, in general, to a quenching of quantum interference effects. This quenching is more pronounced for increasing bias voltages and levels of vibrational excitation. As a result of this vibrationally induced decoherence, vibrational signatures in the transport characteristics of a molecular contact may strongly deviate from a simple Franck-Condon…
The coupling of the charge carriers passing through a molecule bridging two bulky conductors with local vibrational modes of the molecule, gives rise to distinct features in the electronic transport properties on one hand, and to nonequilibrium features in the vibrations' properties, e.g., their population, on the other. Here we explore theoretically a generic model for a molecular junction biased by an arbitrary dc voltage in the weak-coupling regime. We analyze the signature of the electron-vibration interaction on the full-counting statistics of the current fluctuations (i.e., the cumulant …
We investigate the nonequilibrium population of a vibrational mode in the steady state of a biased molecular junction, using a rate equation approach. We focus on the limit of weak electronic-vibrational coupling and show that, in the resonant transport regime and for sufficiently high bias voltages, the level of vibrational excitation increases with decreasing coupling strength, assuming a finite and non-zero value. An analytic behavior with respect to the electronic-vibrational coupling strength is only observed if the influence of environmental degrees of freedom is explicitly taken into ac…
On the elementary level, electronic current consists of individual electron tunnelling events that are separated by random time intervals. The waiting time distribution is a probability to observe the electron transfer in the detector electrode at time $t+τ$ given that an electron was detected in the same electrode at earlier time $t$. We study waiting time distribution for quantum transport in a vibrating molecular junction. By treating the electron-vibration interaction exactly and molecule-electrode coupling perturbatively, we obtain master equation and compute the distribution of waiting t…
We investigate theoretically the interplay of current-induced forces (CIF), Joule heating, and heat transport inside a current-carrying nano-conductor. We find that the CIF, due to the electron-phonon coherence, can control the spatial heat dissipation in the conductor. This yields a significant asymmetric concentration of excess heating (hot-spot) even for a symmetric conductor. When coupled to the electrode phonons, CIF drive different phonon heat flux into the two electrodes. First-principles calculations on realistic biased nano-junctions illustrate the importance of the effect.
We demonstrate that a suspended nanowire forming a weak link between two superconductors can be cooled to its motional ground state by a supercurrent flow. The predicted cooling mechanism has its origins in magnetic field induced inelastic tunneling of the macroscopic superconducting phase associated with the junction. Furthermore, we show the voltage-drop over the junction is proportional to the average population of the vibrational modes in the stationary regime, a phenomena which can be used to probe the level of cooling.
We consider an open molecular junction in which electrons are coupled to multi-mode phonons. Using a master equation approach for equilibrated phonons, we show that nearly-degenerate phonon modes can be mapped into an effective single mode, which can result in a noticeable reduction of computational costs. As an illustration, we apply our theory to the OPV-5 molecule and show that we can obtain the consistent conductance spectra while reducing the computational time by orders of magnitude
Vibronic effects in resonant electron transport through single-molecule junctions are analyzed. The study is based on generic models for molecular junctions, which include electronic states on the molecular bridge that are vibrationally coupled and exhibit Coulomb interaction. The transport calculations employ a master equation approach. The results, obtained for a series of models with increasing complexity, show a multitude of interesting transport phenomena, including vibrational excitation, rectification, negative differential resistance (NDR) as well as local cooling. While some of these …
We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation between the molecular conformation and conduction properties of a single-molecule junction. We demonstrate that the conductance through single molecules crucially depends on the contact material and configuration by virtue of their mechanical and electrical properties. Our findings prove that the charge transport via single molecules can be manipulated by varyi…
By using a propagation scheme for current matrices and an auxiliary mode expansion method, we investigate the transient dynamics of a single molecular junction coupled with a vibrational mode. Our approach is based on the Anderson-Holstein model and the dressed tunneling approximation for the electronic self-energy in the polaronic regime. The time-dependent currents after a sudden switching on the tunneling to leads and an abrupt upward step bias pulse are calculated. We show that the strong electron-phonon interaction greatly influences the nonlinear response properties of the system, and gi…
Understanding and controlling the flow of heat is a major challenge in nanoelectronics. When a junction is driven out of equilibrium by light or the flow of electric charge, the vibrational and electronic degrees of freedom are, in general, no longer described by a single temperature[1-6]. Moreover, characterizing the steady-state vibrational and electronic distributions {\it in situ} is extremely challenging. Here we show that surface-enhanced Raman emission may be used to determine the effective temperatures for both the vibrational modes and the flowing electrons in a biased metallic nanosc…
We report first-principles calculations of inelastic Seebeck coefficients in an aluminum monatomic junction. We compare the elastic and inelastic Seebeck coefficients with and without local heating. In the low temperature regime, the signature of normal modes in the profiles of the inelastic Seebeck effects is salient. The inelastic Seebeck effects are enhanced by the normal modes, and further magnified by local heating. In the high temperature regime, the inelastic Seebeck effects are weakly suppressed due to the quasi-ballistic transport.
We show that individual vibrational modes in single-molecule junctions with asymmetric molecule-lead coupling can be selectively excited by applying an external bias voltage. Thereby, a non-statistical distribution of vibrational energy can be generated, that is, a mode with a high frequency can be stronger excited than a mode with a lower frequency. This is of particular interest in the context of mode-selective chemistry, where one aims to break specific (not necessarily the weakest) chemical bond in a molecule. Such mode-selective vibrational excitation is demonstrated for two generic model…
The interplay of the tunneling transfer of charges and the emission and absorption of light can be investigated in a set-up, where a voltage-biased Josephson junction is placed in series to a microwave cavity. Here, we concentrate on the emission process and show that due to the inherent nonlinearity of the Josephson junction tunneling Cooper-pairs can create a variety of non-classical states of light. Depending on experimental parameters and tuning the device can be described by effective Hamiltonians, indicating specific photon creation mechanisms which lead to strongly bunched or anti-bunch…
We report the measurement of the current noise of a tunnel junction driven out-of-equilibrium by a temperature and/or voltage difference, i.e. the charge noise of heat and/or electrical current. This is achieved by a careful control of electron temperature below 1 K at the nanoscale, and a sensitive measurement of noise with wide bandwidth, from 0.1 to 1 GHz. An excellent agreement between experiment and theory with no fitting parameter is obtained. In particular, we find that the current noise of the junction of resistance R when one electrode is at temperature T and the other one at zero tem…
The interaction between electronic and nuclear degrees of freedom in single-molecule junctions is an essential mechanism, which may result in the current-induced rupture of chemical bonds. As such, it is fundamental for the stability of molecular junctions and for the applicability of molecular electronic devices. In this publication, we study current-induced bond rupture in molecular junctions using a numerically exact scheme, which is based on the hierarchical quantum master equation (HQME) method in combination with a discrete variable representation for the nuclear degrees of freedom. Empl…
Vibrational nonequilibrium effects in charge transport through single-molecule junctions are investigated. Focusing on molecular bridges with multiple electronic states, it is shown that electronic-vibrational coupling triggers a variety of vibronic emission and absorption processes, which influence the conductance properties and mechanical stability of single-molecule junctions profoundly. Employing a master equation and a nonequilibrium Green's function approach, these processes are analyzed in detail for a generic model of a molecular junction and for benzenedibutanethiolate bound to gold e…
Phase relaxation of electrons transferring through an electromechanical transistor is studied using the Aharonov-Bohm interferometer. With the approach of quantum master equation, the phase properties of an electron are numerically analyzed based on the interference fringes. Coherence of electron is partially destroyed by its scattering on excited levels of the local nanomechanical oscillator. Transmission amplitudes with respect to two adjacent mechanical vibrational levels have a phase difference of $π$. The character of phase shift by $π$ depends on the oscillator frequency only and is robu…
The multilayer multiconfiguration time-dependent Hartree (ML-MCTDH) theory within second quantization representation of the Fock space, a novel numerically exact methodology to treat many-body quantum dynamics for systems containing identical particles, is applied to study the effect of vibrational motion on electron transport in a generic model for single-molecule junctions. The results demonstrate the importance of electronic-vibrational coupling for the transport characteristics. For situations where the energy of the bridge state is located close to the Fermi energy, the simulations show t…
We investigate chemical bond formation and conductance in a molecular C60-junction under finite bias voltage using first-principles calculations based on density functional theory and nonequilibrium Green's functions (DFT-NEGF). At the point of contact formation we identify a remarkably strong coupling between the C60-motion and the molecular electronic structure. This is only seen for positive sample bias, although the conductance itself is not strongly polarity dependent. The nonequilibrium effect is traced back a sudden shift in the position of the voltage drop with a small C60-displacement…
Using first principle approaches, we investigate the effects of isotope substitution on the inelastic features in the hydrogen molecular junction. We observe thatlocal heating and inelastic current have significant isotope-substitution effects. Due to the contact characters, the energies of excited molecular vibrationsare inverse proportional to the square root of the mass. The heavier the molecule, the smaller the onset bias. In the $H_{2}$ and $D_{2}$ junctions, the heavier molecule has a smaller magnitude of electron-vibration interaction. Consequently, there is a crossing in the local temp…
The influence of vibrational motion on electron conduction through single molecules bound to metal electrodes is investigated employing first-principles electronic-structure calculations and projection-operator Green's function methods. Considering molecular junctions where a central phenyl ring is coupled via (alkane)thiol-bridges to gold electrodes, it is shown that -- depending on the distance between the electronic $π$-system and the metal -- electronic-vibrational coupling may result in pronounced vibrational substructures in the transmittance, a significantly reduced current as well as a…
We propose a realization of the superconducting diode effect in flux biased superconducting circuits of Josephson junctions. So far the observation of the superconducting diode effect has been limited to rather exotic material platforms. In theoretical proposals, it relied on a non-sinusoidal form of the current phase relation of Josephson junctions. Here, we show how the diode effect can be engineered in superconducting circuits without any such requirements. The only necessary ingredients are standard sinusoidal Josephson junctions and flux bias lines that are readily available in scalable i…
We report on room temperature magnetoresistance and low frequency noise in sub-100nm elliptic CoFeB/MgO/CoFeB magnetic tunnel junctions with ultrathin (0.9nm) barriers. For magnetic fields applied along the hard axis, we observe current induced magnetization switching between the antiparallel and parallel alignments at DC current densities as low as 4*106A/cm2. We attribute the low value of the critical current to the influence of localized reductions in the tunnel barrier, which affects the current distribution. The analysis of random telegraph noise, which appears in the field interval near …
Electronic devices composed of single molecules constitute the ultimate limit in the continued downscaling of electronic components. A key challenge for single-molecule electronics is to control the temperature of these junctions. Controlling heating and cooling effects in individual vibrational modes, can in principle, be utilized to increase stability of single-molecule junctions under bias, to pump energy into particular vibrational modes to perform current-induced reactions or to increase the resolution in inelastic electron tunneling spectroscopy by controlling the life-times of phonons i…
We study the dynamics of a quantum superconducting circuit which consists of a Josephson charge qubit, coupled capacitively to a current biased Josephson junction. Under certain conditions, the eigenstates of the qubit and the junction become entangled. We obtain the time evolution of these states in the limit of weak coupling. Rabi oscillations occur, as a result of the spontaneous emission and re-absorption of a single oscillation quantum in the junction. We discuss a possible way to experimentally determine the quantum state of the junction and hence observe the Rabi oscillations.
Bloch oscillations were predicted and observed long ago in Josephson junctions, which are thin insulating or conducting layers bridging two superconductors. Here we forward a scheme for utilizing these oscillations to amplify nano-metric mechanical vibrations. Highly coherent non-classical mechanical states can be produced and controlled by simply applying a DC bias current and an in-plane magnetic field. The vibrations induce peaks in the I-V characteristic of the junction and can be detected by simple DC voltage measurements.
We analyze the quantum efficiency of a microwave photon detector based on a current-biased Josephson junction. We consider the Jaynes-Cummings Hamiltonian to describe coupling between the photon field and the junction. We then take into account coupling of the junction and the resonator to the environment. We solve the equation of motion of the density matrix of the resonator-junction system to compute the quantum efficiency of the detector as a function of detection time, bias current, and energy relaxation time. Our results indicate that junctions with modest coherence properties can provide…
Reverse-biased graphene (Gr)/semiconductor Schottky diodes exhibit much enhanced sensitivity for gas sensing. However, carrier transport across the junctions is not fully understood yet. Here, Gr/SiC, Gr/GaAs and Gr/Si Schottky junctions under reverse-bias are investigated by temperature-dependent current-voltage measurements. A reduction in barrier height with increasing reverse-bias is observed for all junctions, suggesting electric-field enhanced thermionic emission. Further analysis of the field dependence of the reverse current reveals that while carrier transport in Gr/SiC Schottky junct…
We propose a mechanism which allows one to control the transmission of single electrons through a molecular junction. The principle utilizes the emergence of transmission sidebands when molecular vibrational modes are coupled to the electronic state mediating the transmission. We will show that if a molecule-metal junction is biased just below a molecular resonance one may induce the transmission of a single electron by externally exciting a vibrational mode of the molecule. The analysis is quite general but requires that the molecular orbital does not hybridize strongly with the metallic stat…
We develop a classical mapping approach suitable to describe vibrationally coupled charge transport in molecular junctions based on the Cartesian mapping for many-electron systems [J. Chem. Phys. 137, 154107 (2012)]. To properly describe vibrational quantum effects in the transport characteristics, we introduce a simple transformation rewriting the Hamiltonian in terms of occupation numbers and use a binning function to facilitate quantization. The approach provides accurate results for the nonequilibrium Holstein model for a range of bias voltages, vibrational frequencies and temperatures. It…
Problems of heat transport are ubiquitous to various technologies such as power generation, cooling, electronics, and thermoelectrics. In this paper we advocate for the application of the quantum self-consistent reservoir method, which is based on the generalized quantum Langevin equation, to study phononic thermal conduction in molecular junctions. The method emulates phonon-phonon scattering processes while taking into account quantum effects and far-from-equilibrium (large temperature difference) conditions. We test the applicability of the method by simulating the thermal conductance of mo…
A model of a superconducting tunnel junction coupled to a mechanical oscillator is studied at zero temperature in the case of linear coupling between the oscillator and tunneling electrons. It is found that the Josephson current flowing between two superconductors is modulated by the motion of the oscillator. Coupling to harmonic oscillator produces additional Shapiro steps in $I-V$ characteristic of Josephson junction whose position is tuned by the frequency of the vibration mode. We also find a new velocity dependent term originating from the backaction of the ac Josephson current. This term…
We theoretically investigate a near-quantum-limited parametric amplifier based on the nonlinear dynamics of quasiparticles flowing through a superconducting-insulator-superconducting junction. Photon-assisted tunneling, resulting from the combination of dc- and ac-voltage bias, gives rise to a strong parametric interaction for the electromagnetic modes reflected by the junction coupled to a transmission line. We show phase-sensitive and phase-preserving amplification, together with single- and two-mode squeezing. For an aluminum junction pumped at twice the center frequency, $ω_0/2π=6$~GHz, we…
We report an experimental demonstration of a local amplification of the spin Hall voltage using an expanding depletion zone at a pn-junction in GaAs/AlGaAs Hall-bar microdevices. It is demonstrated that the depletion zone can be spatially expanded by applying reverse bias by at least 10~$μ$m at low temperature. In the depleted regime, the spin Hall signals reached more than one order of magnitude higher values than in the normal regime at the same electrical current flowing through the micro-device. It is shown that the pn-bias has two distinct effects on the detected spin Hall signal. It cont…
Point contact spectroscopy on a H2O molecule bridging Pt electrodes reveals a clear crossover between enhancement and reduction of the conductance due to electron-vibration interaction. As single channel models predict such a crossover at transmission probability of t=0.5, we used shot noise measurements to analyze the transmission and observed at least two channels across the junction where the dominant channel has t=0.51+/-0.01 transmission probability at the crossover conductance, which is consistent with the predictions for single-channel models.
We unravel the critical role of vibrational mode softening in single-molecule electronic devices at high bias. Our theoretical analysis is carried out with a minimal model for molecular junctions, with mode softening arising due to quadratic electron-vibration couplings, and by developing a mean-field approach. We discover that the negative sign of the quadratic electron-vibration coupling coefficient can realize at high voltage a sharp negative differential resistance (NDR) effect with a large peak-to-valley ratio. Calculated current-voltage characteristics, obtained based on ab initio parame…
This work reports a novel time-domain expression for the current-response kernels of a Josephson tunnel junction between BCS superconductors with in general different energy gaps, and its use to simulate the classical dynamics of such junctions. The simulations show a dynamic regime characterized by the resonance between the Josephson oscillations and the gap oscillations in the asymptotics of the current kernels that has not been studied previously. The resonance manifests itself as a hysteresis in the dc current-voltage characteristics of the current-biased junctions in the voltage range abo…
We study current-induced vibrational cooling, heating, and instability in a donor-acceptor rectifying molecular junction using a full counting statistics approach. In our model, electron-hole pair excitations are coupled to a given molecular vibrational mode which is either harmonic or highly anharmonic. This mode may be further coupled to a dissipative thermal environment. Adopting a master equation approach, we confirm the charge and heat exchange fluctuation theorem in the steady-state limit, for both harmonic and anharmonic models. Using simple analytical expressions, we calculate the char…
We present and analyze a reservoir-engineering approach to stabilizing Fock states in a superconducting microwave cavity which does not require any microwave-frequency control drives. Instead, our system makes use of a Josephson junction biased by a dc voltage which is coupled both to a principle storage cavity and a second auxiliary cavity. Our analysis shows that Fock states can be stabilized with an extremely high fidelity. We also show how the same system can be used to prepare on-demand propagating Fock states, again without the use of microwave pulses.
We theoretically analyze the spectrum of a magnetic molecule when its charge and spin can couple to the molecular vibrations. More specifically, we show that the interplay between charge-vibron and spin-vibron coupling leads to a renormalization of the magnetic anisotropy parameters of the molecule. This effect is discussed for a model device consisting of an individual magnetic molecule embedded in a junction. We study the transport properties of the device and illustrate how the differential conductance is affected by the vibrationally induced renormalization of the magnetic anisotropy. Depe…
