We consider rapid cooling processes in classical, 3-dimensional, purely repulsive binary mixtures in which an initial infinite-temperature (ideal-gas) configuration is instantly quenched to zero temperature. It is found that such systems display two kinds of ordering processes, the type of which can be controlled by tuning the interactions between unlike particles. While strong inter-species repulsion leads to chemical ordering in terms of an unmixing process, weak repulsion gives rise to spontaneous crystallization, maintaining chemical homogeneity. This result indicates the existence of a transition in the topography of the underlying potential-energy landscape as the intra-species interaction strength is varied. Furthermore, the dual-type behavior appears to be universal for repulsive pair-interaction potential-energy functions in general, with the propensity for the crystallization process being related to their behavior in the neighborhood of zero separation.
We use Newtonian and overdamped Langevin dynamics to study long flexible polymers dragged by an external force at a constant velocity $v$. The work $W$ by that force depends on the initial state of the polymer and the details of the process. Jarzynski equality can be used to relate the non-equilibrium work distribution $P(W)$ obtained from repeated experiments to equilibrium free energy difference $ΔF$ between the initial and final states. We use the power law dependence of the geometrical and dynamical characteristics of the polymer on the number of monomers $N$ to suggest the existence of a …
We show the existence of a nonequilibrium tricritical point induced by a repulsive interaction in one dimensional asymmetric exclusion process. The tricritical point is associated with the particle-hole symmetry breaking introduced by the repulsion. The phase diagram and the crossover in the neighbourhood of the tricritical point for the shock formation at one of the boundaries are determined.
We consider binary mixtures of soft repulsive spherical particles and calculate the depletion interaction between two big spheres mediated by the fluid of small spheres, using different theoretical and simulation methods. The validity of the theoretical approach, a virial expansion in terms of the density of the small spheres, is checked against simulation results. Attention is given to the approach toward the hard-sphere limit, and to the effect of density and temperature on the strength of the depletion potential. Our results indicate, surprisingly, that even a modest degree of softness in t…
We have studied the nonequilibrium fluctuations occurring at the interface between two miscible phases of a near-critical binary mixture during a free diffusion process. The small-angle static scattered intensity is the superposition of nonequilibrium contributions due to capillary waves and to bulk fluctuations. A linearized hydrodynamics description of the fluctuations allows us to isolate the two contributions, and to determine an effective surface tension for the nonequilibrium interface. As the diffuse interface thickness increases, we observe the cross-over of the capillary-wave contribu…
In this article we derive expressions for Casimir-like pressures induced by nonequilibrium concentration fluctuations in liquid mixtures. The results are then applied to liquid mixtures in which the concentration gradient results from a temperature gradient through the Soret effect. A comparison is made between the pressures induced by nonequilibrium concentration fluctuations in liquid mixtures and those induced by nonequilibrium temperature fluctuations in one-component fluids. Some suggestions for experimental verification procedures are also presented.
We study weakly-repulsive Bose-Bose mixtures in two and three dimensions at zero temperature using the functional renormalization group (FRG). We examine the RG flows and the role of density and spin fluctuations. We study the condition for phase separation and find that this occurs at the mean-field point within the range of parameters explored. Finally, we examine the energy per particle and condensation depletion. We obtain that our FRG calculations compare favorably with known results from perturbative approaches for macroscopic properties.
We investigate magnetic properties and statistical effects in 1D strongly repulsive two-component fermions and in a 1D mixture of strongly repulsive polarized fermions and bosons. Universality in the characteristics of phase transitions, magnetization and susceptibility in the presence of an external magnetic field $H$ are analyzed from the exact thermodynamic Bethe ansatz solution. We show explicitly that polarized fermions with a repulsive interaction have antiferromagnetic behavior at zero temperature. A universality class of linear field-dependent magnetization persists for weak and finite…
Driven diffusive systems constitute paradigmatic models of nonequilibrium physics. Among them, a driven lattice gas known as the asymmetric simple exclusion process (ASEP) is the most prominent example for which many intriguing exact results have been obtained. After summarizing key findings, including the mapping of the ASEP to quantum spin chains, we discuss the recently introduced Brownian asymmetric simple exclusion process (BASEP) as a related class of driven diffusive system with continuous space dynamics. In the BASEP, driven Brownian motion of hardcore-interacting particles through one…
Computer simulations and theory are used to systematically investigate how the effective force between two big colloidal spheres in a sea of small spheres depends on the basic (big-small and small-small) interactions. The latter are modeled as hard-core pair potentials with a Yukawa tail which can be both repulsive or attractive. For a repulsive small-small interaction, the effective force follows the trends as predicted by a mapping onto an effective non-additive hard-core mixture: both a depletion attraction and an accumulation repulsion caused by small spheres adsorbing onto the big ones ca…
We combine the hyper-netted chain approximation of liquid state theory with the mode-coupling theory of the glass transition to analyze the structure and dynamics of soft spheres interacting via harmonic repulsion. We determine the locus of the fluid-glass dynamic transition in a temperature -- volume fraction phase diagram. The zero-temperature (hard sphere) glass transition influences the dynamics at finite temperatures in its vicinity. This directly implies a form of dynamic scaling for both the average relaxation time and dynamic susceptibilities quantifying dynamic heterogeneity. We discu…
We investigate motility-induced phase separation of active Brownian particles, which are modeled as purely repulsive spheres that move due to a constant swim force with freely diffusing orientation. We develop on the basis of power functional concepts an analytical theory for nonequilibrium phase coexistence and interfacial structure. Theoretical predictions are validated against Brownian dynamics computer simulations. We show that the internal one-body force field has four nonequilibrium contributions: (i) isotropic drag and (ii) interfacial drag forces against the forward motion, (iii) a sup…
We study the induced interaction between multiple probes locally interacting with driven colloids and trapped in a toroidal geometry. The effective binary forces between the probes break the action-reaction principle and their range decreases with the driving. We demonstrate how in the stationary nonlinear nonequilibrium regime these interactions induce stability of a crystal-like pattern, where the probes are equidistant, when the probe-colloid interaction is either completely attractive or completely repulsive.
We report a computer-simulation study of the equilibrium phase diagram of a three-dimensional system of particles with a repulsive step potential. Using free-energy calculations, we have determined the equilibrium phase diagram of this system. At low temperatures, we observe a number of distinct crystal phases. However, under certain conditions the system undergoes a glass transition in a regime where the liquid appears thermodynamically stable. We argue that the appearance of this amorphous low-temperature phase can be understood by viewing this one-component system as a pseudo-binary mixture…
Paramagnetic colloidal particles that are optically trapped in a linear array can form a zigzag pattern when an external magnetic field induces repulsive interparticle interactions. When the traps are abruptly turned off, the particles form a nonequilibrium expanding pattern with a zigzag symmetry, even when the strength of the magnetic interaction is weaker than that required to break the linear symmetry of the equilibrium state. We show that the transition to the equilibrium zigzag state is always potentially possible for purely harmonic traps. For anharmonic traps that have a finite height,…
Unlike fluids at thermal equilibrium, biomolecular mixtures in living systems can sustain nonequilibrium steady states, in which active processes modify the conformational states of the constituent molecules. Despite qualitative similarities between liquid--liquid phase separation in these systems, the extent to which the phase-separation kinetics differ remains unclear. Here we show that inhomogeneous chemical reactions can alter the nucleation kinetics of liquid--liquid phase separation in a manner that is consistent with classical nucleation theory, but can only be rationalized by introduci…
Effect of ionic solute on a near-critical binary aqueous mixture confined between charged walls with different adsorption preferences is considered within a simple density functional theory. For the near-critical system containing small amount of ions a Landau-type functional is derived based on the assumption that the correlation, $ξ$, and the Debye screening length, $κ^{-1}$, are both much larger than the molecular size. The corresponding approximate Euler-Lagrange equations aresolved analytically for ions insoluble in the organic solvent. Nontrivial concentration profile of the solvent is f…
Using an additivity property, we study particle-number fluctuations in a system of interacting self-propelled particles, called active Brownian particles (ABPs), which consists of repulsive disks with random self-propulsion velocities. From a fluctuation-response relation - a direct consequence of additivity, we formulate a thermodynamic theory which captures the previously observed features of nonequilibrium phase transition in the ABPs from a homogeneous fluid phase to an inhomogeneous phase of coexisting gas and liquid. We substantiate the predictions of additivity by analytically calculati…
We study binary mixtures of small active and big passive athermal particles interacting via soft repulsive forces on a frictional substrate. Athermal self propelled particles are known to phase separate into a dense aggregate and a dilute gas-like phase at fairly low packing fractions. Known as {\emph {motility induced phase separation}}, this phenomenon governs the behaviour of binary mixtures for small to intermediate size ratios of the particle species. An effective attraction between passive particles, due to the surrounding active medium, leads to true phase separation for large size rati…
Thermal energy agitates all matter and its competition with ordering tendencies is one of the most fundamental organizing principles in the physical world. Thus, it is natural to enquire if an effective temperature could result when external energy input enhances agitation. Potentially this could extend the insights of statistical thermodynamics to nonequilibrium systems, but despite proposals that the effective temperature concept may apply to synthetic active matter, biological motors, granular materials and turbulent fluids, its predictive value remains unclear. Here, combining computer sim…
The excitation spectrum of the density collective oscillations is computed for multi-component molecular mixtures both with Coulomb and (repulsive) short-range interactions. Distinct sound-like excitations appear, governed by the short-range interaction, which differ from the ordinary hydrodynamic sound. The dielectric function and the structure factor are also calculated. The "two-sounds phenomenon" can be understood by means of the predictions of this model.
When a binary liquid is confined by a strongly repulsive wall, the local density is depleted near the wall and an interface similar to that between the liquid and its vapor is formed. This analogy suggests that the composition of the binary liquid near this interface should exhibit spatial modulation similar to that near a liquid-vapor interface even if the interactions of the wall with the two components of the liquid are the same. The Guggenheim adsorption relation quantifies the concentrations of two components of a binary mixture near a liquid-vapor interface and qualitatively states that …
Colloids immersed in a critical binary liquid mixture are subject to critical Casimir forces (CCFs) because they confine its concentration fluctuations and influence the latter via effective surface fields. To date, CCFs have only been studied in thermodynamic equilibrium. However, due to the critical slowing down, the order parameter around a particle can easily be perturbed by any motion of the colloid or by solvent flow. This leads to significant but largely unexplored changes in the CCF. Here we study the drag force on a single colloidal particle moving in a near-critical fluid mixture and…
We simulate by lattice Boltzmann the steady shearing of a binary fluid mixture undergoing phase separation with full hydrodynamics in two dimensions. Contrary to some theoretical scenarios, a dynamical steady state is attained with finite domain lengths $L_{x,y}$ in the directions ($x,y)$ of velocity and velocity gradient. Apparent scaling exponents are estimated as $L_{x}\sim\dotγ^{-2/3}$ and $L_{y}\sim\dotγ^{-3/4}$. We discuss the relative roles of diffusivity and hydrodynamics in attaining steady state.
The separation of substances into different phases is ubiquitous in nature and important scientifically and technologically. This phenomenon may become drastically different if the species involved, whether molecules or supramolecular assemblies, interconvert. In the presence of an external force large enough to overcome energetic differences between the interconvertible species (forced interconversion), the two alternative species will be present in equal amounts, and the striking phenomenon of steady-state, restricted phase separation into mesoscales is observed. Such microphase separation i…
We review the depinning and nonequilibrium phases of collectively interacting particle systems driven over random or periodic substrates. This type of system is relevant to vortices in type-II superconductors, sliding charge density waves, electron crystals, colloids, stripe and pattern forming systems, and skyrmions, and could also have connections to jamming, glassy behaviors, and active matter. These systems are ideal for exploring the broader issues of characterizing transient and steady state nonequilibrium flow phases as well as nonequilibrium phase transitions between distinct dynamical…
A theoretical model of shape-anisometric particles embedded in a cubic lattice is formulated for binary mixtures combining rod-like, plate-like and spherical particles. The model aims at providing a tool for the prediction and interpretation of complex phase behavior in a variety of liquid crystalline colloids, biological and macromolecular systems. Introducing just repulsive interactions among the particles, a rich variety of phase structures and multiphasic equilibria is obtained, including isotropic, nematic, lamellar and columnar phases, demixing into phases of the same or different symmet…
We study the effects of interaction between bosons and fermions in a Bose-Fermi mixtures loaded in an optical lattice. We concentrate on the destruction of a bosonic Mott phase driven by repulsive interaction between bosons and fermions. Once the Mott phase is destroyed, the system enters a superfluid phase where the movements of bosons and fermions are correlated. We show that this phase has simultaneously correlations reminiscent of a conventional superfluid and of a pseudo-spin density wave order.
Accurate and useful analytic approximations are developed for order parameter profiles and interfacial tensions of phase-separated binary mixtures of Bose-Einstein condensates. The pure condensates 1 and 2, each of which contains a particular species of atoms, feature healing lengths $ξ_1$ and $ξ_2$. The inter-atomic interactions are repulsive. In particular, the effective inter-species repulsive interaction strength is $K$. A triple-parabola approximation (TPA) is proposed, to represent closely the energy density featured in Gross-Pitaevskii (GP) theory. This TPA allows us to define a model, …
The small wavenumber $k$ behavior of the structure factor $S(k)$ of overcompressed amorphous hard-sphere configurations was previously studied for a wide range of densities up to the maximally random jammed state, which can be viewed as a prototypical glassy state [A. Hopkins, F. H. Stillinger and S. Torquato, Phys. Rev. E, 86, 021505 (2012)]. It was found that a precursor to the glassy jammed state was evident long before the jamming density was reached as measured by a growing nonequilibrium length scale extracted from the volume integral of the direct correlation function $c(r)$, which beco…
Motivated by the recent experiments on Bose-Einstein mixtures with tunable interactions we study repulsive weakly interacting Bose mixtures at finite temperature. We obtain phase diagrams using Hartree-Fock theory which are directly applicable to experimentally trapped systems. Almost all features of the diagrams can be characterized using simple physical insights. Our work reveals two surprising effects which are dissimilar to a system at zero temperature. First of all, no pure phases exist, that is, at each point in the trap, particles of both species are always present. Second, even for ver…
