The condensation of spin-orbit-induced excitons in $(t_{2g})^4$ electronic systems is attracting considerable attention. In the large Hubbard U limit, antiferromagnetism was proposed to emerge from the Bose-Einstein Condensation (BEC) of triplons ($J_{\textrm{eff}} = 1$). In this publication, we show that even for the weak and intermediate U regimes, the spin-orbit exciton condensation is possible leading also to staggered magnetic order. The canonical electron-hole excitations (excitons) transform into local triplon excitations at large U , and this BEC strong coupling regime is smoothly connected to the intermediate U excitonic insulator region. We solved the degenerate three-orbital Hubbard model with spin-orbit coupling ($λ$) in one-dimensional geometry using the Density Matrix Renormalization Group, while in two-dimensional square clusters we use the Hartree-Fock approximation (HFA). Employing these techniques, we provide the full $λ$ vs U phase diagrams for both one- and two- dimensional lattices. Our main result is that at the intermediate Hubbard U region of our focus, increasing $λ$ at fixed U the system transitions from an incommensurate spin-density-wave metal to a Bardeen-Cooper-Schrieffer (BCS) excitonic insulator, with coherence length r coh of O(a) and O(10a) in 1d and 2d, respectively, with a the lattice spacing. Further increasing $λ$, the system eventually crosses over to the BEC limit (with r coh << a).
We present a unified theory of luminescence spectra for highly excited semiconductors, which is applicable both to the electron-hole BCS state and to the exciton Bose-Einstein condensate. The crossover behavior between electron-hole BCS state and exciton Bose-Einstein condensate clearly manifests itself in the calculated luminescence spectra. The analysis is based on the Bethe-Salpeter equation combined with the generalized random-phase-approximation, which enables us to consider the multiple Coulomb scattering and the quantum fluctuation associated with the center-of-mass motion of electron-h…
The BCS to Bose-Einstein condensation (BEC) crossover of electron-hole (e-h) pairs in optically excited semiconductors is studied using the two-band Hubbard model with both repulsive and attractive interactions. Applying the self-consistent t-matrix approximation combined with a local approximation, we examine the properties of a normal phase and an excitonic instability. The transition temperature from the normal phase to an e-h pair condensed one is studied to clarify the crossover from an e-h BCS-like state to an excitonic Bose-Einstein condensation, which takes place on increasing the e-h …
We explore the spontaneous formation of an excitonic insulator state at the semimetal-semiconductor transition of mixed-valence materials in the framework of the spinless Falicov-Kimball model with direct $f$-$f$ electron hopping. Adapting the projector-based renormalization method, we obtain a set of renormalization differential equations for the extended Falicov-Kimball model parameters and finally derive analytical expressions for the order parameter, as well as for the renormalized $c$- and $f$-electron dispersions, momentum distributions, and wave-vector resolved single-particle spectral …
The condensation of electron-hole (e-h) pairs is studied at zero temperature and in the presence of a weak spin-orbit coupling (SOC) in the inversion-layer quantum wells. Under realistic conditions, a perturbative SOC can have observable effects in the order parameter of the experimentally long-searched-for excitonic condensate. Firstly, the fermion exchange symmetry is absent for the e-h pairs indicating a counterexample to the known classification schemes of fermion pairing. With the lack of fermion exchange, the condensate spin has no definite parity. Additionally, the excitonic SOC breaks …
Photoinduced dynamics in an excitonic insulator is studied theoretically by using a two-orbital Hubbard model on the square lattice where the excitonic phase in the ground state is characterized by the BCS-BEC crossover as a function of the interorbital Coulomb interaction. We consider the case where the order has a wave vector $Q=(0,0)$ and photoexcitation is introduced by a dipole transition. Within the mean-field approximation, we show that the excitonic order can be enhanced by the photoexcitation when the system is initially in the BEC regime of the excitonic phase, whereas it is reduced …
Motivated by the possibility of pressure-induced exciton condensation in intermediate-valence Tm[Se,Te] compounds we study the Falicov-Kimball model extended by a finite f-hole valence bandwidth. Calculating the Frenkel-type exciton propagator we obtain excitonic bound states above a characteristic value of the local interband Coulomb attraction. Depending on the system parameters coherence between c- and f-states may be established at low temperatures, leading to an excitonic insulator phase. We find strong evidence that the excitonic insulator typifies either a BCS condensate of electron-hol…
Recently strong evidence has been found in favor of a BCS-like condensation of excitons in 1\textit{T}-TiSe$_2$. Theoretical photoemission intensity maps have been generated by the spectral function calculated within the excitonic condensate phase model and set against experimental angle-resolved photoemission spectroscopy data. Here, the calculations in the framework of this model are presented in detail. They represent an extension of the original excitonic insulator phase model of Jérome \textit{et al.} [Phys. Rev. {\bf 158}, 462 (1967)] to three dimensional and anisotropic band dispersions…
Excitonic insulator (EI) is an intriguing insulating phase of matter, where electrons and holes are bonded into pairs, so called excitons, and form a phase-coherent state via Bose-Einstein Condensation (BEC). Its theoretical concept has been proposed several decades ago, but the followed research is very limited, due to the rare occurrence of EI in natural materials and the lack of manipulating method of excitonic condensation. In this paper, we report the realization of a doping-controlled EI-to-semi-metal transition in Ta$_2$NiSe$_5$ using $in$-$situ$ potassium deposition. Combining with ang…
We study the spontaneous symmetry breaking of the excitonic insulator state induced by the Coulomb interaction $U$ in the two-dimensional extended Falicov-Kimball model. Using the variational cluster approximation (VCA) and Hartree-Fock approximation (HFA), we evaluate the order parameter, single-particle excitation gap, momentum distribution functions, coherence length of excitons, and single-particle and anomalous excitation spectra, as a function of $U$ at zero temperature. We find that in the weak-to-intermediate coupling regime, the Fermi surface plays an essential role and calculated res…
The stability of the excitonic condensation at low temperature driven by a coupling of electrons to vibrational degrees of freedom in semimetal two-dimensional electronic system is discussed. In the framework of the unrestricted Hartree-Fock approximation, we derive a set of equations to determine both the excitonic condensate order parameter and lattice displacement self-consistently. By lowering temperature we find out a semimetal-insulator transition in the system if the coupling is large enough. The insulating state typifies an excitonic condensation accompanied by a finite lattice distort…
BCS-BEC crossover of polaritonic condensates in mass-imbalanced semimetal/semiconductor microcavities
Hanoi University of Mining and Geology（河内矿业地质大学）；Graduate University of Science and Technology, Vietnam Academy of Science and Technology（越南科学技术高等研究院）；Institute of Physics, Vietnam Academy of Science and Technology（越南科学技术研究院物理研究所）；Duy Tan University（大慈大学）
Artificial moiré superlattices in 2d van der Waals heterostructure is a new venue for realizing and controlling correlated electronic phenomena. Recently, twisted bilayer WSe$_2$ emerged as a new robust moiré system hosting a correlated insulator at moiré half-filling over a range of twist angle. In this work, we present a theory of this insulating state as an excitonic density wave due to intervalley electron-hole pairing. We show that exciton condensation is strongly enhanced by a van Hove singularity near the Fermi level. Our theory explains the remarkable sensitivity of the insulating gap …
The microscopic quantum interference associated with excitonic condensation in Ta$_2$NiSe$_5$ is studied in the BCS-type mean-field approximation. We show that in ultrasonic attenuation the coherence peak appears just below the transition temperature $T_{\rm c}$ whereas in NMR spin-lattice relaxation the rate rapidly decreases below $T_{\rm c}$; these observations can offer a crucial experimental test for the validity of the excitonic condensation scenario in Ta$_2$NiSe$_5$. We also show that the excitonic condensation manifests itself in a jump of the heat capacity at $T_{\rm c}$ as well as i…
Based on the SO(2)-invariant slave-boson scheme, the static charge, orbital, and excitonic susceptibilities in the extended Falicov-Kimball model are calculated. Analyzing the phase without long-range order we find instabilities towards charge order, orbital order, and the excitonic insulator (EI) phase. The instability towards the EI is in agreement with the saddle-point phase diagram. We also evaluate the dynamic excitonic susceptibility, which allows the investigation of uncondensed excitons. We find qualitatively different features of the exciton dispersion at the semimetal-EI and at the s…
We act on the suggestion that an excitonic insulator state might separate---at very low temperatures---a semimetal from a semiconductor and ask for the nature of these transitions. Based on the analysis of electron-hole pairing in the extended Falicov-Kimball model, we show that tuning the Coulomb attraction between both species, a continuous crossover between a BCS-like transition of Cooper-type pairs and a Bose-Einstein condensation of preformed tightly-bound excitons might be achieved in a solid-state system. The precursor of this crossover in the normal state might cause the transport anom…
The three-chain Hubbard model for Ta$_2$NiSe$_5$ known as a candidate material for the excitonic insulator is investigated over the wide range of energy gap $D$ between the two-fold degenerate conduction bands and the nondegenerate valence band including both semiconducting ($D>0$) and semimetallic ($D<0$) cases. In the semimetallic case, the difference of the band degeneracy inevitably causes the imbalance of each Fermi wavenumber, resulting in a remarkable excitonic state characterized by the condensation of excitons with finite center-of-mass momentum $q$, the so-called Fulde-Ferrell-Larkin…
Exciton condensation in a two-band Hubbard model on a square lattice is studied with variational Monte Carlo method. We show that the phase transition from an excitonic insulator to a band insulator is induced by increasing the interband Coulomb interaction. To examine the character of the exciton condensation, the exciton pair amplitudes both in $\bm{k}$-space and in real space are calculated. Using these quantities, we discuss the BCS-BEC crossover within the excitonic insulator phase.
We employ mean-field approximation to investigate the interplay between the nontrivial band topology and the formation of excitonic insulator (EI) in a one-dimensional chain of atomic $s-p$ orbitals in the presence of repulsive inter-orbital Coulomb interaction. We find that our model, in a non-interacting regime, admits topological and trivial insulator phases, whereas, in strong Coulomb interaction limit, the chiral symmetry is broken and the system undergoes a topological-excitonic insulator phase transition. The latter phase transition stems from an orbital pseudomagnetization and band inv…
Using exact numerical techniques we investigate the nature of excitonic (electron-hole) bound states and the development of exciton coherence in the one-dimensional half-filled extended Falicov-Kimball model. The ground-state phase diagram of the model exhibits, besides band insulator and staggered orbital ordered phases, an excitonic insulator (EI) with power-law correlations. The criticality of the EI state shows up in the von Neumann entropy. The anomalous spectral function and condensation amplitude provide the binding energy and coherence length of the electron-hole pairs which, on their …
In this paper, we consider the spectral properties of the bilayer graphene with the local excitonic pairing interaction between the electrons and holes. We consider the generalized Hubbard model, which includes both intralayer and interlayer Coulomb interaction parameters. The solution of the excitonic gap parameter is used to calculate the electronic band structure, single-particle spectral functions, the hybridization gap, and the excitonic coherence length in the bilayer graphene. We show that the local interlayer Coulomb interaction is responsible for the semimetal-semiconductor transition…
A crossover between the Bose Einstein condensation (BEC) and BCS superconducting state is described topologically in the chiral symmetric fermion system with attractive interaction. Using a local Z_2 Berry phase, we found a quantum phase transition between the BEC and BCS phases without accompanying the bulk gap closing.
We present the calculation of the coherent spectral functions and density of states (DOS) for excitonic systems in the frame of the three dimensional extended Falicov-Kimball model. By using gauge-invariant U(1) transformation to the usual fermions, we represent the electron operator as a fermion attached to the U(1) phase-flux tube. The emergent bosonic gauge field, related to the phase variables is crucial for the Bose-Einstein condensation (BEC) of excitons. Employing the path-integral formalism, we manipulate the bosonic and fermionic degrees of freedom to obtain the effective actions rela…
The nonlocal correlation mechanism between excitonic pairs is considered for a two dimensional exciton system. On the base of the unitary decomposition of the usual electron operator, we include the electron phase degrees of freedom into the problem of interacting excitons. Applying the path integral formalism, we treat the excitonic insulator state (EI) and the Bose-Einstein condensation (BEC) of preformed excitonic pairs as two independent problems. For the BEC of excitons the phase field variables play a crucial role. We derive the expression of the local EI order parameter by integrating o…
The authors of a recent paper (PRA \textbf{87}, 013613 (2013)) argued that in fermionic systems with d-wave pairing the speed of sound is nonanalytic across the BCS-BEC crossover at the point where the chemical potential vanishes, regardless of the specific details of the interaction potential. On the contrary, the numerical results reported here suggest that the speed of sound across the BCS-BEC evolution of atomic Fermi gases with s- and d-wave pairings in two-dimensional square lattices is a smooth analytic function at the vanishing chemical potential.
Using the field-theoretical methods we studied the evolution from BCS description of a non-Fermi superconductor to that of Bose-Einstein condensation (BEC) in one loop approximation. We showed that the repulsive interaction between composite bosons is determined by the exponent $α$ of the Anderson propagator in a two dimensional model. For $\a\neq 0$ the crossover is also continous and for $\a=0$ we obtain the case of the Fermi liquid.
We pointed out in this work that in dealing with the BEC-BCS crossover problem, the dynamic effect of <b(t)>is not negligible. Accordingly, an equation of motion approach was devised to calculate the Green$^{\prime}$s functions. Based on our result, we concluded that instead of crossover, BCS states and Bose-Einstein condensation always coexist.
It is shown that a cluster expansion technique, which is usually applied in the high-temperature regime to calcutate virial coefficients, can be applied to evaluate the superfluid transition temperature of the BCS-BEC crossover à la Lee and Yang. The transition temperature is identified with the emergence of the singularity in the sum of a certain infinite series of cluster functions. In the weak-coupling limit, we reproduce the Thouless criterion and the number equation of Nozières and Schmitt-Rink, and hence the transition temperature of the BCS theory. In the strong-coupling limit, we repro…
By using a Path Integral formalism, we study the fluctuating fields in the order parameter for a 3D uniform Fermi gas at T<Tc. The BCS-BEC crossover condition is included into the analysis in the framework of the usual s-wave scattering approximation. The general expressions for the temperature dependence of the partition function and the quadratic average in the fluctuations fields are explicitly established in terms of the BCS-Gor'kov correlation propagators.
We determine the size of the critical region of the superfluid transition in the BCS-BEC crossover of a three-dimensional fermion gas, using a renormalization-group approach to a bosonic theory of pairing fluctuations. For the unitary Fermi gas, we find a sizable critical region $[T_G^-,T_G^+]$, of order $T_c$, around the transition temperature $T_c$ with a pronounced asymmetry: $|T_G^+-T_c|/|T_G^--T_c|\sim8$. The critical region is strongly suppressed on the BCS side of the crossover but remains important on the BEC side.
We have analyzed a single vortex at T=0 in a 3D superfluid atomic Fermi gas across a Feshbach resonance. On the BCS side, the order parameter varies on two scales: $k_{F}^{-1}$ and the coherence length $ξ$, while only variation on the scale of $ξ$ is seen away from the BCS limit. The circulating current has a peak value $j_{max}$ which is a non-monotonic function of $1/k_F a_s$ implying a maximum critical velocity $\sim v_F$ at unitarity. The number of fermionic bound states in the core decreases as we move from the BCS to BEC regime. Remarkably, a bound state branch persists even on the BEC s…
We report quantum Monte Carlo evidence of the existence of large gap superfluidity in electron-hole double layers over wide density ranges. The superfluid parameters evolve from normal state to BEC with decreasing density, with the BCS state restricted to a tiny range of densities due to the strong screening of Coulomb interactions, which causes the gap to rapidly become large near the onset of superfluidity. The superfluid properties exhibit similarities to ultracold fermions and iron-based superconductors, suggesting an underlying universal behavior of BCS-BEC crossovers in pairing systems.
We study the crossover of a quasi-two-dimensional Fermi gas trapped in the radial plane from the Bardeen-Cooper-Schrieffer (BCS) regime to the Bose-Einstein condensation (BEC) regime by crossing a wide Feshbach resonance. We consider two effective two-dimensional Hamiltonians within the mean-field level, and calculate the zero-temperature cloud size and number density distribution. For a model 1 Hamiltonian with renormalized atom-atom interaction, we observe a constant cloud size for arbitrary detunings. For a model 2 Hamiltonian with renormalized interactions between atoms and dressed molecul…
We study the superconducting transition in a two-dimensional electron gas with strong Rashba spin-orbit coupling. We assume low electron density, such that only the majority spin band participates in the transition. We show that the superconducting transition follows either the Bose-Einstein condensation (BEC), or the Bardeen-Cooper-Schrieffer (BCS) scenarios, depending on the position of the chemical potential with respect to the bottom of the majority band, and the strength of the Coulomb repulsion between electrons. Hence, the BEC-BCS crossover in this system can be driven either by the cha…
Theoretical predictions for the BCS-BEC crossover of trapped Fermi atoms are compared with recent experimental results for the density profiles of $^6$Li. The calculations rest on a single theoretical approach that includes pairing fluctuations beyond mean field. Excellent agreement with experimental results is obtained. Theoretical predictions for the zero-temperature chemical potential and gap at the unitarity limit are also found to compare extremely well with Quantum Monte Carlo simulations and with recent experimental results.
The crossover from Bardeen-Cooper-Schrieffer (BCS) superconductivity to Bose-Einstein condensation (BEC) is difficult to realize in quantum materials because, unlike in ultracold atoms, one cannot tune the pairing interaction. We realize the BCS-BEC crossover in a nearly compensated semimetal Fe$_{1+y}$Se$_x$Te$_{1-x}$ by tuning the Fermi energy, $ε_F$, via chemical doping, which permits us to systematically change $Δ/ ε_F$ from 0.16 to 0.5 were $Δ$ is the superconducting (SC) gap. We use angle-resolved photoemission spectroscopy to measure the Fermi energy, the SC gap and characteristic chang…
The strongly-correlated regime of the BCS-BEC crossover can be realized by diluting a system of two-component fermions with a short-range attractive interaction. We investigate this system via a novel continuous-space-time diagrammatic determinant Monte Carlo method and determine the universal curve $T_c/ε_F$ for the transition temperature between the normal and the superfluid states as a function of the scattering length with the maximum on the BEC side. At unitarity, we confirm that $T_c/ε_F = 0.152(7)$.
The pairing of interacting fermions leading to superfluidity has two limiting regimes: the Bardeen-Cooper-Schrieffer (BCS) scheme for weakly interacting degenerate fermions and the Bose-Einstein condensation (BEC) of bosonic pairs of strongly interacting fermions. While the superconductivity that emerges in most metallic systems is the BCS-like electron pairing, strongly correlated electrons with poor Fermi liquidity can condense into the unconventional BEC-like pairs. Quantum spin liquids harbor extraordinary spin correlation free from order and the superconductivity that possibly emerges by …
We observe a long-lived solitary wave in a superfluid Fermi gas of $^6$Li atoms after phase-imprinting. Tomographic imaging reveals the excitation to be a solitonic vortex, oriented transverse to the long axis of the cigar-shaped atom cloud. The precessional motion of the vortex is directly observed, and its period is measured as a function of the chemical potential in the BEC-BCS crossover. The long period and the correspondingly large ratio of the inertial to the bare mass of the vortex are in good agreement with estimates based on superfluid hydrodynamics that we derive here using the known…
The subject of BCS - Bose Einstein condensation (BEC) crossover is particularly exciting because of its realization in ultracold Fermi gases and its possible relevance to high temperature superconductors. In the paper we review that body of theoretical work on this subject which represents a natural extension of the seminal papers by Leggett and by Nozieres and Schmitt-Rink (NSR). The former addressed only the ground state, now known as the "BCS-Leggett" wave-function and the key contributions of the latter pertain to calculations of the superfluid transition temperature $T_c$. These two paper…
We investigate the quantum and thermal phase diagram of fermionic polar molecules loaded in a bilayer trapping potential with perpendicular dipole moment. We use both a BCS theory approach that is most realiable at weak-coupling and a strong-coupling approach that considers the two-body bound dimer states with one molecules in each layer as the relevant degree of freedom. The system ground state is a Bose-Einstein condensate (BEC) of dimer bound states in the low density limit and a paired superfluid (BCS) state in the high density limit. At zero temperature, the intralayer repulsion is found …
We present a stability analysis on a driven-dissipative electron-hole condensate in the BCS (Bardeen-Cooper-Schrieffer)-BEC (Bose-Einstein-condensation)-crossover region. Extending the combined BCS-Leggett theory with the generalized random phase approximation (GRPA) to the non-equilibrium case by employing the Keldysh formalism, we show that the pumping-and-decay of carriers causes a depairing effect on excitons. This phenomenon gives rise to an attractive interaction between excitons in the BEC regime, as well as a supercurrent that anomalously flows anti-parallel to $\nabla θ({\bf r})$ (whe…
We present a theoretical study of the ground state of the BCS-BEC crossover in dilute two-dimensional Fermi gases. While the mean-field theory provides a simple and analytical equation of state, the pressure is equal to that of a noninteracting Fermi gas in the entire BCS-BEC crossover, which is not consistent with the features of a weakly interacting Bose condensate in the BEC limit and a weakly interacting Fermi liquid in the BCS limit. The inadequacy of the 2D mean-field theory indicates that the quantum fluctuations are much more pronounced than those in 3D. In this work, we show that the …
