Solvent exchange (also called solvent shifting or Ouzo effect) is a generally used bottom-up process to mass-produce nanoscale droplets. In this process, a good solvent for some oil is displaced by a poor one, leading to oil nanodroplet nucleation and subsequent growth. Here we perform this process on a hydrophobic substrate so that sessile droplets so-called surface nanodroplets-develop, following the work of Zhang et al. [Zhang, X.; Lu, Z.; Tan, H.; Bao, L.; He, Y.; Sun, C.; Lohse, D. Proc. Natl. Acad. Sci. U.S.A. 2015, 122, 9253-9257]. In contrast to what was done in that paper, we chose a very well-controlled Hele-Shaw geometry with negligible gravitational effects, injecting the poor solvent in the center of the Hele-Shaw cell, and characterize the emerging nanodroplets as a function of radial distance and flow rates. We find that the mean droplet volume per area <Vol>_area strongly depends on the local Peclet number Pe and follows a universal scaling law <Vol>_area~Pe^(3/4). Moreover, the probability distribution function of the droplet volume strongly depends on the local Pe as well, regardless of the flow rates and radial distance, giving strong support to the theoretical model of the solvent exchange process developed in Zhang et al.'s work.
Parallel flow in a Hele-Shaw cell occurs when two immiscible liquids flow with relative velocity parallel to the interface between them. The interface is unstable due to a Kelvin-Helmholtz type of instability in which fluid flow couples with inertial effects to cause an initial small perturbation to grow. Large amplitude disturbances form stable solitons. We consider the effects of applied magnetic fields when one of the two fluids is a ferrofluid. The dispersion relation governing mode growth is modified so that the magnetic field can destabilize the interface even in the absence of inertial …
We study both experimentally and theoretically the descending motion due to gravity of a fluid drop surrounded by another immiscible fluid in a confined space between two parallel plates, i.e., in the Hele-Shaw cell. As a result, we show a new scaling regime of a nonlinear drag friction in viscous liquid that replaces the well-known Stokes' drag friction through a clear collapse of experimental data thanks to the scaling law. In the novel regime, the dissipation in the liquid thin film formed between the drop and cell walls governs the dynamics. The crossover of this scaling regime to another …
In Hele-Shaw flows at vanishing surface tension, the boundary of a viscous fluid develops cusp-like singularities. In recent papers [1, 2] we have showed that singularities trigger viscous shocks propagating through the viscous fluid. Here we show that the weak solution of the Hele-Shaw problem describing viscous shocks is equivalent to a semiclassical approximation of a special real solution of the Painleve I equation. We argue that the Painleve I equation provides an integrable deformation of the Hele-Shaw problem which describes flow passing through singularities. In this interpretation sho…
We investigate the flow of two immiscible, viscous fluids in a rotating Hele-Shaw cell, when one of the fluids is a ferrofluid and an external magnetic field is applied. The interplay between centrifugal and magnetic forces in determining the instability of the fluid-fluid interface is analyzed. The linear stability analysis of the problem shows that a non-uniform, azimuthal magnetic field, applied tangential to the cell, tends to stabilize the interface. We verify that maximum growth rate selection of initial patterns is influenced by the applied field, which tends to decrease the number of i…
A pair of concentric spheres separated by a small gap form a spherical Hele-Shaw cell. In this cell an interfacial instability arises when two immiscible fluids flow. We derive the equation of motion for the interface perturbation amplitudes, including both pressure and gravity drivings, using a mode coupling approach. Linear stability analysis shows that mode growth rates depend upon interface perimeter and gravitational force. Mode coupling analysis reveals the formation of fingering structures presenting a tendency toward finger tip-sharpening.
The Saffman-Taylor viscous fingering problem is investigated for the displacement of a non-Newtonian fluid by a Newtonian one in a radial Hele-Shaw cell. We execute a mode-coupling approach to the problem and examine the morphology of the fluid-fluid interface in the weak shear limit. A differential equation describing the early nonlinear evolution of the interface modes is derived in detail. Owing to vorticity arising from our modified Darcy's law, we introduce a vector potential for the velocity in contrast to the conventional scalar potential. Our analytical results address how mode-couplin…
We present a phase-field model for the dynamics of the interface between two inmiscible fluids with arbitrary viscosity contrast in a rectangular Hele-Shaw cell. With asymptotic matching techniques we check the model to yield the right Hele-Shaw equations in the sharp-interface limit and compute the corrections to these equations to first order in the interface thickness. We also compute the effect of such corrections on the linear dispersion relation of the planar interface. We discuss in detail the conditions on the interface thickness to control the accuracy and convergence of the phase-fie…
We solve numerically the nonlinear differential equation for the Hele-Shaw, Saffman-Taylor problem derived in the preceding work. Stationary solutions with no free phenomenological parameters are found to fit the measured patterns. The calculated finger half-widths as a function of the physical parameters of the cell, compare satisfactorily with experiment.
In this paper we study the effects of dynamic wetting on the immiscible displacement of a high viscosity fluid subject to the radial injection of a less viscous fluid in a Hele-Shaw cell. The displaced fluid can leave behind a trailing film that coats the cell walls, dynamically affecting the pressure drop at the fluid interface. By considering the non-linear pressure drop in a boundary element formulation, we construct a Picard scheme to iteratively predict the interfacial velocity and subsequent displacement in finite mobility ratio flow regimes. Dynamic wetting delays the onset of finger bi…
In this review article, we discuss recent studies on drops and bubbles in Hele-Shaw cells, focusing on how scaling laws exhibit crossovers from the three-dimensional counterparts and focusing on topics in which viscosity plays an important role. By virtue of progresses in analytical theory and high-speed imaging, dynamics of drops and bubbles have actively been studied with the aid of scaling arguments. However, compared with three dimensional problems, studies on the corresponding problems in Hele-Shaw cells are still limited. This review demonstrates that the effect of confinement in the Hel…
Viscous fingers in the lifting Hele-Shaw cell form a hierarchical pattern due to competition between growing fingers in a converging geometry. If the defending fluid is visco-plastic, a permanent three-dimensional pattern is formed, which is usually approximated as quasi-two-dimensional. We present here a Monte-Carlo simulation which attempts to reproduce the real 3-dimensional pattern in rectangular geometry using a very simple algorithm. We study the finger length distribution, the rate of increase of coverage of the invading fluid, the height profile of the final pattern and observe how the…
A model has been developed to describe the collision and possible coalescence of two driven deformable drops in the Hele-Shaw cell. The interdependence between hydrodynamic effects and interfacial deformations is characterised by a film capillary number: Ca_f = (μv/σ)(R_o/h_o)^(3/2) as revealed by an analytic perturbation solution of the governing equations for a system with continuous phase viscosity μ, interfacial tension σ, drop radius R_o, characteristic relative velocity v and separation h_o between the drops. Numerical solutions of the model demonstrate the importance of the full dynamic…
We demonstrate experimentally the existence of a purely elastic fingering instability which arises when air penetrates into an elastomer confined in a Hele-Shaw cell. Fingers appear sequentially and propagate within the bulk of the material as soon as a critical strain, independent of the elastic modulus, is exceeded. Their width depends non-linearly on the distance between the confining glass plates. A key element in the driving force of the instability is the adhesion of layers of gels to the plates, which results in a considerable expense of elastic energy during the growth of the air bubbl…
In this paper, the interaction between two immiscible fluids with a finite mobility ratio is investigated numerically within a Hele-Shaw cell. Fingering instabilities initiated at the interface between a low viscosity fluid and a high viscosity fluid are analysed at varying capillary numbers and mobility ratios using a finite mobility ratio model. The present work is motivated by the possible development of interfacial instabilities that can occur in porous media during the process of CO$_2$ sequestration, but does not pretend to analyse this complex problem. Instead, we present a detailed stu…
Hele-Shaw flow at vanishing surface tension is ill-defined. In finite time, the flow develops cusp-like singularities. We show that the ill-defined problem admits a weak {\it dispersive} solution when singularities give rise to a graph of shock waves propagating in the viscous fluid. The graph of shocks grows and branches. Velocity and pressure jump across the shock. We formulate a few simple physical principles which single out the dispersive solution and interpret shocks as lines of decompressed fluid. We also formulate the dispersive weak solution in algebro-geometrical terms as an evolutio…
Viscous Bending Mitigates the Spontaneous Meandering of Rivulets in Hele-Shaw Cells
Matière et Systèmes Complexes UMR 7057, Université Paris Cité, CNRS（复杂物质与系统联合研究实验室，巴黎西岱大学，法国国家科学研究中心）；Laboratory of Fluid Mechanics and Instabilities, EPFL（流体力学和不稳定性实验室，洛桑联邦理工学院）
We make a theoretical study of the behavior of a simple fluid displacing a shear thinning fluid confined in a Hele-Shaw cell. To study the Saffman-Taylor instability when the displaced fluid is non Newtonian we face the problem of having a field which is non laplacian. By means of an hodographic transformation we are able to solve the problem in the case of weak shear thinning while taking into account the non laplacian character of the equation. Our results predict that the finger width decreases towards zero for small values of the surface tension parameter which is inversely proportional to…
We implement a phase-field simulation of the dynamics of two fluids with arbitrary viscosity contrast in a rectangular Hele-Shaw cell. We demonstrate the use of this technique in different situations including the linear regime, the stationary Saffman-Taylor fingers and the multifinger competition dynamics, for different viscosity contrasts. The method is quantitatively tested against analytical predictions and other numerical results. A detailed analysis of convergence to the sharp interface limit is performed for the linear dispersion results. We show that the method may be a useful alternat…
The Saffman-Taylor viscous fingering instability occurs when a less viscous fluid displaces a more viscous one between narrowly spaced parallel plates in a Hele-Shaw cell. Experiments in radial flow geometry form fan-like patterns, in which fingers of different lengths compete, spread and split. Our weakly nonlinear analysis of the instability predicts these phenomena, which are beyond the scope of linear stability theory. Finger competition arises through enhanced growth of sub-harmonic perturbations, while spreading and splitting occur through the growth of harmonic modes. Nonlinear mode-cou…
We analyze the Saffman-Taylor viscous fingering problem in rectangular geometry. We investigate the onset of nonlinear effects and the basic symmetries of the mode coupling equations, highlighting the link between interface asymmetry and viscosity contrast. Symmetry breaking occurs through enhanced growth of sub-harmonic perturbations. Our results explain the absence of finger tip-splitting in the early flow stages, and saturation of growth rates compared with the predictions of linear stability.
Bubbles of inviscid fluid surrounded by a viscous fluid in a Hele-Shaw cell can merge and break-off. During the process of break-off, a thinning neck pinches off to a universal self-similar singularity. We describe this process and reveal its integrable structure: it is a solution of the dispersionless limit of the AKNS hierarchy. The singular break-off patterns are universal, not sensitive to details of the process and can be seen experimentally. We briefly discuss the dispersive regularization of the Hele-Shaw problem and the emergence of the Painlevé II equation at the break-off.
Viscous fingers in a channel with surface tension anisotropy are numerically studied. Scaling relations between the tip velocity v, the tip radius and the pressure gradient are investigated for two kinds of boundary conditions of pressure, when v is sufficiently large. The power-law relations for the anisotropic viscous fingers are compared with two-dimensional dendritic growth. The exponents of the power-law relations are theoretically evaluated.
We study a family of solutions to the Saffman-Taylor problem with zero surface tension at a critical regime. In this regime, the interface develops a thin singular finger. The flow of an isolated finger is given by the Whitham equations for the KdV integrable hierarchy. We show that the flow describing bubble break-off is identical to the Gurevich-Pitaevsky solution for regularization of shock waves in dispersive media. The method provides a scheme for the continuation of the flow through singularites.
The dynamics of the interface between two immiscible fluids in a rotating Hele-Shaw cell are studied experimentally, theoretically and by phase-field simulations of the H-S equations. As the central, denser fluid is centrifuged, it forms fingering patterns with long, thin radial filaments ended by a droplet, alternating with incoming fingers of the outer fluid. Simulations show the length (width) of the filaments to grow (decay) roughly exponentially, and the incoming finger tips to asymptotically approach a finite radius for n-fold symmetric initial conditions; these thus tend to a stationary…
Viscous fingers have been produced in the lifting Hele-Shaw cell, with concentric circular grooves etched onto the lower plate. The invading fluid (air) enters the defending newtonian fluid - olive oil as fingers proceeding radially inwards towards the centre. The fingers are interrupted at the circular groove, and reform as secondary fingers. The effect of the grooves is to speed up the fingering process considerably and the fingers now reach the centre much faster. We explain this by comparing the variation in velocity of the fingers in the normal HS cell and the grooved cells with time. In …
We report analytical results for the development of the viscous fingering instability in a cylindrical Hele-Shaw cell of radius a and thickness b. We derive a generalized version of Darcy's law in such cylindrical background, and find it recovers the usual Darcy's law for flow in flat, rectangular cells, with corrections of higher order in b/a. We focus our interest on the influence of cell's radius of curvature on the instability characteristics. Linear and slightly nonlinear flow regimes are studied through a mode-coupling analysis. Our analytical results reveal that linear growth rates and …
We show that unstable fingering patterns of two dimensional flows of viscous fluids with open boundary are described by a dispersionless limit of the KdV hierarchy. In this framework, the fingering instability is linked to a known instability leading to regularized shock solutions for nonlinear waves, in dispersive media. The integrable structure of the flow suggests a dispersive regularization of the finite-time singularities.
In Hele-Shaw flows, boundaries between fluids develop unstable viscous fingers. At vanishing surface tension, the fingers further evolve to cusp-like singularities. We show that the problem admits a {\it weak solution} where shock fronts triggered by a singularity propagate together with a fluid. Shocks form a growing, branching tree of a mass deficit, and a line distribution of vorticity where pressure and velocity of the fluid have finite discontinuities. Imposing that the flow remain curl-free at macroscale determines the shock graph structure. We present a self-similar solution describing …
We develop a systematic method to derive all orders of mode couplings in a weakly nonlinear approach to the dynamics of the interface between two immiscible viscous fluids in a Hele-Shaw cell. The method is completely general. It includes both the channel geometry driven by gravity and pressure, and the radial geometry with arbitrary injection and centrifugal driving. We find the finite radius of convergence of the mode-coupling expansion. In the channel geometry we carry out the calculation up to third-order couplings, which is necessary to account for the time-dependent Saffman-Taylor finger…
We investigate the equilibrium properties of a single area-minimising bubble trapped between two narrowly-separated parallel curved plates. We begin with the simple case of a a bubble trapped between concentric spherical plates. We develop a model that shows that the surface tension energy of the bubble is lower when confined between spherical plates as compared to a bubble trapped between flat plates. We confirm our findings by comparing against Surface Evolver simulations. Next, we derive a simple model for a bubble between arbitrarily curved parallel plates. The energy is found to be higher…
We investigate the large time behavior of an agent based model describing tumor growth. The microscopic model combines short-range repulsion and cell division. As the number of cells increases exponentially in time, the microscopic model is challenging in terms of computational time. To overcome this problem, we aim at deriving the associated macroscopic dynamics leading here to a porous media type equation. As we are interested in the long time behavior of the dynamics, the macroscopic equation obtained through usual derivation method fails at providing the correct qualitative behavior (e.g. …
