We theoretically study the low energy electromagnetic response of BCS type superconductors focusing on propagating collective modes that are observable with THz near field optics. The interesting frequency and momentum range is $ω< 2Δ$ and $q < 1/ξ$ where $Δ$ is the gap and $ξ$ is the coherence length. We show that it is possible to observe the superfluid plasmons, amplitude (Higgs) modes, Bardasis-Schrieffer modes and Carlson-Goldman modes using THz near field technique, although none of these modes couple linearly to far field radiation. Coupling of THz near field radiation to the amplitude mode requires particle-hole symmetry breaking while coupling to the Bardasis-Schrieffer mode does not and is typically stronger. For parameters appropriate to layered superconductors of current interest, the Carlson-Goldman mode appears in the near field reflection coefficient as a weak feature in the sub-THz frequency range. In a system of two superconducting layers with nanometer scale separation, an acoustic phase mode appears as the antisymmetric density fluctuation mode of the system. This mode produces well defined resonance peaks in the near-field THz response and has strong anticrossings with the Bardasis-Schrieffer and amplitude modes, enhancing their response. In a slab consisting of many layers of quasi-two dimensional superconductors, realized for example in samples of high T$_c$ cuprate compounds, many branches of propagating Josephson plasmon modes are found to couple to the THz near field radiation.
We report on high-order harmonic generation in the two-band superconductor MgB$_2$ driven by intense terahertz electromagnetic pulses. Third- and fifth-order harmonics are resolved in time domain and investigated as a function of temperature and in applied magnetic fields crossing the superconducting phase boundary. The high-order harmonics in the superconducting phase reflects nonequilibrium dynamics of the superconducting order parameter in MgB$_2$, which is probed via nonlinear coupling to the terahertz field. The observed temperature and field dependence of the nonlinear response allows to…
The nano-scale intrinsic Josephson junctions in highly anisotropic cuprate superconductors have potential for generation of terahertz electromagnetic waves. When the thickness of a superconductor sample is much smaller than the wavelength of electromagnetic waves in vacuum, the superconductor renders itself as a cavity. Unlike conventional lasers, the presence of the cavity does not guarantee a coherent emission because of the internal degree of freedom of the superconductivity phase in long junctions. We study the excitation of terahertz wave by solitons in a stack of intrinsic Josephson junc…
Ultrastrong magnon-photon coupling in superconductor/antiferromagnet/superconductor heterostructures at terahertz frequencies
Moscow Institute of Physics and Technology（莫斯科物理技术学院）；School of Physics, Huazhong University of Science and Technology（华中科技大学物理学院）；National Research University Higher School of Economics（国立研究型高等经济大学）
We show that a moving Josephson vortex in spatially modulated layered superconductors generates out-of-plane THz radiation. Remarkably, the magnetic and in-plane electric fields radiated are of the same order, which is very unusual for any good-conducting medium. Therefore, the out-of-plane radiation can be emitted to the vacuum without the standard impedance mismatch problem. Thus, the proposed design can be more efficient for tunable THz emitters than previous proposals, for radiation only propagating along the ab-plane.
We investigated the terahertz (THz)-pulse driven nonlinear response in the d-wave cuprate superconductor Bi2Sr2CaCu2O8+x (Bi2212) using a THz pump near-infrared probe scheme in the time domain. We have observed an oscillatory behavior of the optical reflectivity that follows the THz electric field squared and is strongly enhanced below Tc. The corresponding third-order nonlinear effect exhibits both A1g and B1g symmetry components, which are decomposed from polarization-resolved measurements. Comparison with a BCS calculation of the nonlinear susceptibility indicates that the A1g component is …
A new family of dynamic states are found in a stack of inductively coupled intrinsic Josephson junctions in the absence of an external magnetic field. In this state, $(2m_l+1)π$ phase kinks with integers $m_l$'s stack along the c axis and lock neighboring junction together. Large dc power is pumped into plasma oscillation via kinks at the cavity resonance. The plasma oscillation is uniform along the c axis with the frequency satisfying the ac Josephson relation. Thus this state supports strong terahertz radiation and seems to be compatible with the recent experimental observations.
Strong terahertz radiation from mesa structure of $\rm{Bi_2Sr_2CaCu_2O_{8+δ}}$ single crystal has been observed recently, where the mesa intrinsically forms a cavity. For a thick mesa of large number of junctions, there are many cavity modes with different wave vectors along the c-axis corresponding to almost degenerate bias voltages. The mechanism responsible for exciting the uniform mode which radiates coherent terahertz waves in experiments is unknown. In this work, we show that the in-plane dissipation selects the uniform mode. For perturbations with non-zero wave numbers along the c-axis,…
We demonstrate that parametric driving of suitable collective modes in cuprate superconductors results in a reflectivity $R>1$ for frequencies in the low terahertz regime. We propose to exploit this effect for the amplification of coherent terahertz radiation in a laser-like fashion. As an example, we consider the optical driving of Josephson plasma oscillations in a monolayer cuprate at a frequency that is blue-detuned from the Higgs frequency. Analogously, terahertz radiation can be amplified in a bilayer cuprate by driving a phonon resonance at a frequency slightly higher than the upper Jos…
We investigate the response of a stack of intrinsic Josephson junctions (IJJs) to terahertz (THz) electromagnetic (EM) irradiation. A significant amplification of the EM wave can be achieved by the IJJs stack when the incident frequency equals to one of the cavity frequencies. The irradiation excites pi phase kinks in the junctions, which stimulate the cavity resonance when the bias voltage is tuned. A large amount of dc energy is then pumped into the Josephson plasma oscillation, and the incident wave gets amplified. From the profound current step in IV characteristics induced at the cavity r…
We theoretically show that terahertz pulses with controlled amplitude and frequency can be used to switch between stable transport modes in layered superconductors, modelled as stacks of Josephson junctions. We find pulse shapes that deterministically switch the transport mode between superconducting, resistive and solitonic states. We develop a simple model that explains the switching mechanism as a destablization of the centre of mass excitation of the Josephson phase, made possible by the highly non-linear nature of the light-matter coupling.
We report the low-energy electrodynamics of a moderately clean A15 superconductor (SC) following ultrafast excitation to understand and manipulate terahertz (THz) quasi--particle (QP) transport by tuning pump photoexcitation of from competing orders. Using 35-fs optical pulses, we observe a non-thermal enhancement in the low frequency conductivity, opposite to that observed for THz pump, which persists up to an additional critical temperature, above the SC one, from an electronic order in the Martensitic normal state. In the SC state, the fluence dependence of pair breaking kinetics together w…
We predict a complete TM-TE transformation of the polarization of terahertz electromagnetic waves reflected from a strongly anisotropic boundary of a layered superconductor. We consider the case when the wave is incident on the superconductor from a dielectric prism separated from the sample by a thin vacuum gap. The physical origin of the predicted phenomenon is similar to the Wood anomalies known in optics, and is related to the resonance excitation of the oblique surface waves. We also discuss the dispersion relation for these waves, propagating along the boundary of the superconductor at s…
We study the nonlinear optical response in a superconducting NbN thin film with strong terahertz (THz)wave. Besides the expected third harmonic generation, we observe a new transient oscillation which softensin frequency with temperature increasing towards superconducting transition temperatureTc. We identify thisnew mode as the Higgs transient oscillation. To verify this proposal, we introduce a time-frequency resolvedtechnique, named spectrogram for visualizing THz spectrum. The dynamic decaying behavior of the mode isobserved, which is consistent with theoretical expectation about intrinsic…
We theoretically study the propagation of a Terahertz (THz) Gaussian beam through a thin sample of layered superconductor. We consider the beam axis and the superconducting layers to be perpendicular to the sample interface, while the electric field in the beam is perpendicular to the layers. We show that, in such a geometry, the Josephson current between the superconducting layers supports lensing of the beam instead of divergence on the Rayleigh range. Moreover, due to the nonlinearity, the focal length and waist of the transmitted beam depend on the incident beam intensity. These dependence…
Ultrafast responses of BCS superconductor Nb1-xTixN films in a nonadiabatic excitation regime were investigated by using terahertz (THz) pump-THz probe spectroscopy. After an instantaneous excitation with the monocycle THz pump pulse, a transient oscillation emerges in the electromagnetic response in the BCS gap energy region. The oscillation frequency coincides with the asymptotic value of the BCS gap energy, indicating the appearance of the theoretically-anticipated collective amplitude mode of the order parameter, namely the Higgs amplitude mode. Our result opens a new pathway to the ultraf…
Moving vortex lattice in type-II superconductors can result in the radiation of electromagnetic waves in the range of terahertz frequency. The vortex flow dynamics in superconductors follow the London equation. In this paper, the effects of the superconductor coherence length and the London penetration depth on the radiated power is investigated by solving the London equation in the presence of vortices. The results show that by decreasing the coherence length, the radiation power will significantly increase. Also, it is possible to obtain more radiated power with a sharp peak by increasing th…
We present a gauge-invariant density matrix description of non-equilibrium superconductor (SC) states with spatial and temporal correlations driven by intense terahertz (THz) lightwaves. We derive superconductor Bloch--Maxwell equations of motion that extend Anderson pseudo-spin models to include the Cooper pair center-of-mass motion and electromagnetic propagation effects. We thus describe quantum control of dynamical phases, collective modes, quasi-particle coherence, and high nonlinearities during cycles of carrier wave oscillations, which relate to our recent experiments. Coherent photogen…
The possibility of applying stacks of capacitive and inductively coupled and synchronized Josephson junctions as either high radiation power or wideband current controlled terahertz modulator is proposed and investigated. The properties of such modulators, which can be fabricated using the mesa structure of the layered high-Tc superconductors, are obtained numerically and analytically in the presence and absence of the external magnetic field with different vortex lattices. Based on these analyses, the peak frequency deviation of modulated signal with respect to input signal is calculated. Typ…
Solving coupled nonlinear sine-Gordon equations and Maxwell equations numerically, we study the electromagnetic and superconducting properties of the single crystal of high-$T_c$ superconductor $\rm{Bi_2Sr_2CaCu_2O_{8+δ}}$ with a static magnetic field applied parallel to the $ab$-plane and a dc current fed in along the c-axis. Cavity resonances of transverse plasma occur in the intrinsic Josephson junctions with frequencies in terahertz regime. It is revealed that the electromagnetic wave can transmit from the junctions into space. The emitted energy counted by the Poynting vector is about $40…
We predict the enhanced transmissivity of modulated slabs of layered superconductors for terahertz radiation due to the diffraction of the incident wave and the resonance excitation of the eigenmodes. The electromagnetic field is transferred from the irradiated side of a slab of layered superconductor to the other one by excited waveguide modes (WGMs) which do not decay deep into the slab, contrary to metals, where the enhanced light transmission is caused by the excitation of the evanescent surface waves. We show that a series of resonance peaks (with $T \sim 1$) can be observed in the depend…
Optical conductivity of a moderately disordered superconducting NbN film was investigated by terahertz time-domain spectroscopy in external magnetic field applied along the film plane. The film thickness of about 5 nm was comparable with the coherence length, so vortices should not form. This was confirmed by the fact that no marked difference between the spectra with terahertz electric field set perpendicular and parallel to the external magnetic field was observed. Simultaneous use of Maxwell-Garnett effective medium theory and the model of optical conductivity by Herman and Hlubina proved t…
Anomalous terahertz nonlinearity in disordered s-wave superconductor close to the superconductor-insulator transition
International Center for Quantum Materials, School of Physics, Peking University（北京大学物理学院量子材料国际中心）；School of Electronic Science and Engineering, Nanjing University（南京大学电子科学与工程学院）；Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences（中国科学院物理研究所凝聚态物理国家实验室）；Beijing Academy of Quantum Information Sciences（北京量子信息科学研究院）；School of Physical Sciences, University of Chinese Academy of Sciences（中国科学院大学物理科学学院）
We investigate the iron-based superconductor Ba$_{1-x}$K$_x$Fe$_2$As$_2$ using intense terahertz (THz) light. In the superconducting state a THz Kerr signal is observed and assigned to non-linear THz coupling to superconducting degrees of freedom. The polarization dependence of the THz Kerr signal is remarkably sensitive to the coexistence of a nematic order. In the absence of nematic order the $C_4$ symmetric polarization dependence of the THz Kerr signal is consistent with a coupling to the Higgs amplitude mode of the superconducting condensate. In the coexisting nematic and superconducting …
The recent growing interest in terahertz (THz) and sub-THz science and technology is due to its many important applications in physics, astronomy, chemistry, biology, and medicine. We review the problem of linear and non-linear THz and sub-THz Josephson plasma waves in layered superconductors and their excitations produced by moving Josephson vortices. We start by discussing the coupled sine-Gordon equations for the gauge-invariant phase difference of the order parameter in the junctions, taking into account the effect of breaking the charge neutrality, and deriving the spectrum of Josephson p…
We examine coupling interactions used to synchronize macroscopic Josephson oscillations induced in intrinsic Josephson junction (IJJ) mesa stacks made of a Bi2212 single crystal. Synchronized radiations of terahertz electromagnetic (EM) waves are detected under common voltage and current bias operations of two connected mesas with close individual radiation frequencies, while uncoupled and bimodal radiations are frequently observed in two mesas with different individual radiation frequencies. Detailed observations of the polarizations of the EM waves emitted when two mesas are biased in parall…
We measured reflectivity on static stripe-ordered La$_{1.84-y}$Nd$_y$Sr$_{0.16}$CuO$_4$ (LNSCO) $y$\,=\,0.1, 0.2, 0.3, and 0.4 by means of reflective terahertz time-domain spectroscopy (THz-TDS) with electric field polarized along c-axis, in which one can obtain lower frequency information than the conventional Fourier transform type spectrometer. Recently, two-dimensional superconducting (2DSC) property \cite{tajima,schafgans,li}, intra-layer perfect conductivity not accompanied with inter-layer superconducting behavior, was reported on LNSCO ($x$\,=0.15\,,\,$y$\,$\geq$\,0.2). We observed the…
Many applications in photonics require all-optical manipulation of plasma waves, which can concentrate electromagnetic energy on sub-wavelength length scales. This is difficult in metallic plasmas because of their small optical nonlinearities. Some layered superconductors support weakly damped plasma waves, involving oscillatory tunneling of the superfluid between capacitively coupled planes. Such Josephson plasma waves (JPWs) are also highly nonlinear, and exhibit striking phenomena like cooperative emission of coherent terahertz radiation, superconductor-metal oscillations and soliton format…
We propose and analyze a scheme for parametrically cooling bilayer cuprates based on the selective driving of a $c$-axis vibrational mode. The scheme exploits the vibration as a transducer making the Josephson plasma frequencies time-dependent. We show how modulation at the difference frequency between the intra- and interbilayer plasmon substantially suppresses interbilayer phase fluctuations, responsible for switching $c$-axis transport from a superconducting to resistive state. Our calculations indicate that this may provide a viable mechanism for stabilizing non-equilibrium superconductivi…
We show that strong electric fields of ~ 30 kV cm^(-1) at terahertz frequencies can significantly weaken the superconducting characteristics of cuprate superconductors. High-power terahertz time-domain spectroscopy (THz-TDS) was used to investigate the in-plane conductivity of YBa2Cu3O7-delta (YBCO) with highly intense single-cycle terahertz pulses. Even though the terahertz photon energy (~ 1.5 meV) was significantly smaller than the energy gap in YBCO (~ 20-30 meV), the optical conductivity was highly sensitive to the field strength of the applied terahertz transients. Possibly, this is due …
We predict that below T_c a regime of negative differential conductivity (NDC) can be reached. The superconductor should be supercooled to T<T_c in the normal phase under DC voltage. In such a nonequilibrium situation the NDC of the superconductor is created by the excess conductivity of the fluctuation Cooper pairs. We propose NDC of supercooled superconductors to be used as an active medium for generation of electric oscillations. Such generators can be used in the superconducting electronics as a new type THz source of radiation. Oscillations can be modulated by the change of the bias volta…
Recent advances in time-domain terahertz (THz) spectroscopy have unveiled that resonantly-enhanced strong THz third-harmonic generation (THG) mediated by the collective Higgs amplitude mode occurs in s-wave superconductors, where charge-density fluctuations (CDF) have also been shown to contribute to the nonlinear third-order susceptibility. It has been theoretically proposed that the nonlinear responses of Higgs and CDF exhibit essentially different polarization dependences. Here we experimentally discriminate the two contributions by polarization-resolved intense THz transmission spectroscop…
We report on the successful terahertz emission (0.6$\sim$1 THz) that is continuous and tunable in its frequency and power, by driving Josephson vortices in resonance with the collective standing Josephson plasma modes excited in stacked Bi$_2$Sr$_2$CaCu$_2$O$_{8+x}$ intrinsic Josephson junctions. Shapiro-step detection was employed to confirm the terahertz-wave emission. Our results provide a strong feasibility of developing long-sought solid-state terahertz-wave emission devices.
Experimental signature of transient symmetry breaking in a cavity superconductor
Research Institute of Superconductor Electronics (RISE) & Key Laboratory of Optoelectronic Devices and Systems with Extreme Performances of MOE,School of Electronic Science and Engineering, Nanjing University（南京大学电子科学与工程学院超导电子研究所及极端性能光电器件与系统教育部重点实验室）；Department of Physics, TU Dortmund University（多特蒙德工业大学物理系）
Intrinsic Josephson junctions in high-temperature superconductor Bi2Sr2CaCu2O8 are known for their capability to emit high-power terahertz photons with widely tunable frequencies. Hotspots, as inhomogeneous temperature distributions across the junctions, are believed to play a critical role in synchronizing the gauge-invariant phase difference among the junctions, so as to achieve coherent strong emission. Previous optical imaging techniques have indirectly suggested that the hotspot temperature can go higher than the superconductor critical temperature. However, such optical approaches often …
We theoretically study the transition radiation of bulk and surface electromagnetic waves by an electron crossing an interface between a layered superconductor and an isotropic dielectric. We assume that the direction of the electron motion and the orientation of the superconducting layers are perpendicular to the interface. We derive the analytical expressions for the strongly anisotropic radiation fields and for the time-integrated energy fluxes of bulk and oblique surface electromagnetic waves (OSWs). We show that the OSWs with frequencies close to the Josephson plasma frequency $ω_J$ provi…
Time-resolved synchronization analysis of stacked intrinsic Josephson junctions of a cuprate superconductor with frequency-modulated terahertz radiation spectra
Kyoto University（京都大学）；National Institute of Advanced Industrial Science and Technology (AIST)（产业技术综合研究所）
We present a dynamical theory for the phase differences along a stacked direction of intrinsic Josephson junctions (IJJ's) in layered multigap superconductors, motivated by the discovery of highly-anisotropic iron-based superconductors with thick perovskite-type blocking layers. The dynamical equations describing AC and DC intrinsic Josephson effects peculiar to multigap IJJ's are derived, and collective Leggett mode excitations in addition to the Josephson plasma established in single-gap IJJ's are predicted. The dispersion relations of their collective modes are explicitly displayed, and the…
We investigate the interplay between gap oscillations and damping in the dynamics of superconductors taken out of equilibrium by strong optical pulses with sub-gap Terahertz frequencies. A semi-phenomenological formalism is developed to include the damping within the electronic subsystem that arises from effects beyond BCS, such as interactions between Bogoliubov quasiparticles and decay of the Higgs mode. Such processes are conveniently expressed as $T_{1}$ and $T_{2}$ times in the standard pseudospin language for superconductors. Comparing with data on NbN that we report here, we argue that …
Sideband fingerprint of the Leggett mode in terahertz two-dimensional coherent spectroscopy of multiband superconductors
Max Planck Institute for Solid State Research（马克斯·普朗克固体研究所）；University of Tokyo（东京大学）；Cryogenic Research Center, University of Tokyo（东京大学低温研究中心）；RIKEN Center for Emergent Matter Science (CEMS)（理化学研究所涌现物质科学中心）；Trans-scale Quantum Science Institute, University of Tokyo（东京大学跨尺度量子科学研究所）
We report terahertz (THz) second harmonic generation (SHG) in superconductors (SC) with inversion symmetric equilibrium states that forbid even-order nonlinearities. Such SHG signal is observed in single-pulse emission by periodic driving with a multi-cycle THz electric field tuned below the SC energy gap and vanishes above the SC critical temperature. We explain the microscopic physics by a dynamical symmetry breaking principle at sub-THz-cycle by using quantum kinetic modeling of the interplay between strong THz-lightwave nonlinearity and pulse propagation. The resulting non-zero integrated …
Calculations of the pairing interaction in multi-band models of the Fe superconductors show that it is attractive in both the $A_{1g}$ (s-wave) and $B_{1g}$ (d-wave) channels. This raises the possibility that these materials may have collective excitonic modes. Here, assuming an s-wave groundstate, we investigate the d-wave collective excitonic mode and its coupling to the Raman scattering.
The study of interaction between different degrees of freedom in solids is of fundamental importance to understand the functionalities of materials. One striking example of such interaction is the intertwined coupling or competition between superconductivity (SC), charge density wave (CDW), pseudogap state (PG), and other exotic phases in cuprate superconductors. Recent emergence of nonlinear Terahertz (THz) third harmonic generation (THG) spectroscopy provides a powerful tool for exploring the collective (Higgs) modes of superconductivity order parameters, and its interaction with intertwined…
We present results of a microwave surface impedance study of the heavy fermion superconductor UBe13. We clearly observe an absorption peak whose frequency- and temperature-dependence scales with the BCS gap function. Resonant absorption into a collective mode, with energy approximately proportional to the superconducting gap, is proposed as a possible explantation.
Terahertz Electrodynamics and Kinetic Inductance of Disordered Titanium-Vanadium Alloy Thin Films
Free Electron Laser Utilization Laboratory, Raja Ramanna Center for Advanced Technology（自由电子激光利用实验室，拉贾·拉曼纳先进技术中心）；Homi Bhabha National Institute（霍米·巴哈国家研究所）
Effects of order parameter collective modes on electromagnetic response are studied for a clean spin-triplet superconductor with $k_x\pm ik_y$ orbital symmetry, which has been proposed as a candidate pairing symmetry for Sr$_2$RuO$_4$. It is shown that the $k_x \pm ik_y$ superconductor has characteristic massive collective modes analogous to the clapping mode in the A-phase of superfluid $^3$He. We discuss the contribution from the collective modes to ultrasound attenuation and electromagnetic absorption. We show that in the electromagnetic absorption spectrum the clapping mode gives rise to a…
Collective modes in two dimensional topological superconductors are studied by an extended random phase approximation theory while considering the influence of vector field of light. In two situations, the s-wave superconductors without spin-orbit-coupling (SOC), and the hybrid semiconductor and s-wave superconductor layers with strong SOC, we get the analytical results for longitudinal modes which are found to be indeed gapless. Further more, the effective modes volumes can be calculated, the electric and magnetic fields can be expressed as the creation and annihilation operators of such mode…
