Multiple topological Dirac cones in a mixed-valent Kondo semimetal: g-SmS

Observation of a new excitation in the mixed-valent state of YbInCu_4

Infrared measurements are used to obtain conductivity as a function of temperature and frequency in YbInCu_4, which exhibits an isostructural transition to a mixed-valent state at T_v \simeq 42 K. In addition to a gradual loss of spectral weight with decreasing temperature extending up to 1.5 eV, sharp resonances appear in the mixed-valent state at 0 and 0.25 eV . These features may be key to understanding both YbInCu_4 and the nature of the mixed-valent Kondo state.

From mixed valence to the Kondo lattice regime

Many heavy fermion materials are known to crossover from the Kondo lattice regime to the mixed-valent regime or vice-versa as a function of pressure or doping. We study this crossover theoretically by employing the periodic Anderson model within the framework of the dynamical mean field theory. Changes occurring in the dynamics and transport across this crossover are highlighted. As the valence is decreased (increased) relative to the Kondo lattice regime, the Kondo resonance broadens significantly, while the lower (upper) Hubbard band moves closer to the Fermi level. The resistivity develops …

Universal scaling in transport out of equilibrium through a single quantum dot using the noncrossing approximation

The universal scaling behavior is studied for nonequilibrium transport through a quantum dot. To describe the dot we use the standard Anderson impurity model and use the non-equilibrium non-crossing approximation in the limit of infinite Coulomb repulsion. After solving de hamiltonian, we calculate the conductance through the system as a function of temperature $T$ and bias voltage $V$ in the Kondo and in the mixed valent regime. We obtain a good scaling function in both regimes. In particular, in the mixed valent regime, we find excellent agreement with recent experiments and previous theoret…

混合价态氧磷族化合物 $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$ 中的近藤（Kondo）样行为

Kondo-like behavior in a mixed valent oxypnictide $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$

本研究合成了混合价态氧磷族化合物 $\mathrm{La_{3}Cu_{4}P_{4}O_{2}}$，通过磁、电、热测量及DFT计算，揭示了其13.7 K处的电阻率极小值源于近藤散射，并阐明了其与同构超导体因费米能级电子态差异而缺乏超导性的原因。

Optical study of the electronic phase transition of strongly correlated YbInCu_4

Infrared, visible and near-UV reflectivity measurements are used to obtain conductivity as a function of temperature and frequency in YbInCu_4, which exhibits an isostructural phase-transition into a mixed-valent phase below T_v=42 K. In addition to a gradual loss of spectral weight with decreasing temperature extending up to 1.5 eV, a sharp resonance appears at 0.25 eV in the mixed-valent phase. This feature can be described in terms of excitations into the Kondo (Abrikosov-Suhl) resonance, and, like the sudden reduction of resistivity, provides a direct reflection of the onset of coherence i…

From ferromagnetism to spin-density wave: Magnetism in the two channel periodic Anderson model

The magnetic properties of the two-channel periodic Anderson model for uranium ions, comprised of a quadrupolar and a magnetic doublet are investigated through the crossover from the mixed-valent to the stable moment regime using dynamical mean field theory. In the mixed-valent regime ferromagnetism is found for low carrier concentration on a hyper-cubic lattice. The Kondo regime is governed by band magnetism with small effective moments and an ordering vector $\q$ close to the perfect nesting vector. In the stable moment regime nearest neighbour anti-ferromagnetism dominates for less than hal…

Dynamical Bonding Driving Mixed Valency in a Metal Boride

Samarium hexaboride is an anomaly, having many exotic and seemingly mutually incompatible properties. It was proposed to be a mixed-valent semiconductor, and later - a topological Kondo insulator, and yet has a Fermi surface despite being an insulator. We propose a new and unified understanding of SmB$_6$ centered on the hitherto unrecognized dynamical bonding effect: the coexistence of two Sm-B bonding modes within SmB$_6$, corresponding to different oxidation states of the Sm. The mixed valency arises in SmB$_6$ from thermal population of these distinct minima enabled by motion of B. Our mod…