We study the capacity of active matter to rise in thin tubes against gravity and other related phenomena, like, wetting of vertical plates and spontaneous imbibition, where a wetting liquid is drawn into a porous medium. This capillary action or capillarity is well known in classical fluids and originates from attractive interactions between the liquid molecules and the container walls, and from the attraction of the liquid molecules among each other. We observe capillarity in a minimal model for scalar active matter with purely repulsive interactions, where an effective attraction emerges due to slowdown during collisions between active particles and between active particles and walls. Simulations indicate that the capillary rise in thin tubes is approximately proportional to the active sedimentation length $λ$ and that the wetting height of a vertical plate grows superlinear with $λ$. In a disordered porous medium the imbibition height scales as $\langle h\rangle\proptoλϕ_m$, where $ϕ_m$ is its packing fraction.
We study capillary condensation in a bath consisting of active Brownian particles (ABPs) and the forces acting on the capillary close to the motility-induced phase separation (MIPS). The capillary is modelled as two parallel rods of high aspect ratio which are fixed in space. We consider a bath of ABPs having a self-propulsion speed much larger than the critical speed necessary for MIPS to occur. For a given particle speed, we gradually increase the packing fraction of ABPs, starting from a homogeneous dilute phase of ABPs and going towards the binodal of MIPS. Depending on the packing fractio…
We use numerical modelling to study the flow patterns of an active nematic confined in a cylindrical capillary, considering both planar and homeotropic boundary conditions. We find that active flow emerges not only along the capillary axis but also within the plane of the capillary, where radial vortices are formed. If topological defects are imposed by the boundary conditions, they act as local pumps driving the flow. At higher activity we demonstrate escape of the active defects and flow into the third dimension, indicating the importance of dimensionality in active materials. We argue that …
Spontaneous currents determine capillary rise in active matter
Center for Soft Condensed Matter Physics and Interdisciplinary Research & School of Physical Science and Technology, Soochow University（苏州大学物理科学与技术学院软凝聚态物理与交叉研究中心）
In passive fluid-fluid phase separation, a single interfacial tension sets both the capillary fluctuations of the interface and the rate of Ostwald ripening. We show that these phenomena are governed by two different tensions in active systems, and compute the capillary tension $σ_{cw}$ which sets the relaxation rate of interfacial fluctuations in accordance with capillary wave theory. We discover that strong enough activity can cause negative $σ_{cw}$. In this regime, depending on the global composition, the system self-organizes, either into a microphase-separated state in which coalescence …
The collective motion of chemically active particles at an air-liquid interface is studied theoretically as a dynamic self-organization problem. Based on a physical consideration, we propose a minimal model for self-propelled particles by combining hydrodynamic interaction, capillary interaction, driving force by Marangoni effect, and Marangoni flow. Our model has successfully captured the features of chemically active particles, that represent dynamic self-organized states such as crystalline, chain, liquid-like and spreading states.
This work reports an innovative humidity driven actuation concept based on Bangham effect using simple nanoporous sol-gel silica thin films as humidity responsive materials. Bilayer shaped actuators, consisting on a humidity-sensitive active nanostructured silica film deposited on a polymeric substrate (Kapton) were demonstrated as an original mean to convert water molecule adsorption and capillary condensation in useable mechanical work. Reversible silica surface energy modifications by water adsorption and the energy produced by the rigid silica film contraction, induced by water capillary c…
Hypothesis: Lateral accumulation and film defects during drying of hard particle coatings is a common problem, typically solved using polymeric additives and surface active ingredients, which require further processing of the dried film. Capillary suspensions with their tunable physical properties, devoid of polymers, offer new pathways in producing uniform and defect free particulate coatings. Experiments: We investigated the effect of small amounts of secondary liquid on the coating's drying behavior. Stress build-up and weight loss in a temperature and humidity controlled drying chamber wer…
We study a three-dimensional system of self-propelled Brownian particles interacting via the Lennard-Jones potential. Using Brownian Dynamics simulations in an elongated simulation box, we investigate the steady states of vapour-liquid phase coexistence of active Lennard-Jones particles with planar interfaces. We measure the normal and tangential components of the pressure tensor along the direction perpendicular to the interface and verify mechanical equilibrium of the two coexisting phases. In addition, we determine the non-equilibrium interfacial tension by integrating the difference of the…
Spontaneous emergence of organized states in materials driven by non-equilibrium conditions is of significant fundamental and technological interest. In many cases, the organized states are complex, hence, with some well-studied exceptions, their emergence is challenging to predict. In this article, we show that an unexpectedly diverse collection of dissipative organized states can emerge in a simple biphasic system consisting of two liquids under planar confinement. We drive the liquid-liquid interface, which is held together by capillary forces, out of thermodynamic equilibrium using DC elec…
Wetting-coupled phase separation as an energetic mechanism for active bacterial adhesion
Advanced Materials Thrust, Function Hub, The Hong Kong University of Science and Technology (Guangzhou)（香港科技大学（广州）功能枢纽先进材料交叉中心）；Institute of Chinese Medical Sciences & State Key Laboratory of Mechanism and Quality of Chinese Medicine, University of Macau（澳门大学中国医药研究国家重点实验室及中医药研究所）；Department of Pharmaceutical Sciences, Faculty of Health Sciences, University of Macau（澳门大学健康科学学院药学系）；Zhuhai UM Science and Technology Research Institute, University of Macau（澳门大学珠海科学技术研究院）；Platform for Structure and Functional Technology of Neural Network, Guangdong Institute of Intelligence Science and Technology（广东省智能科学技术研究院神经网络结构与功能技术平台）
Statistics and morphologies of stable droplets in scalar active fluids
Institute for Theoretical Physics IV, University of Stuttgart（斯图加特大学理论物理第四研究所）；STFC Hartree Centre（英国科学与技术设施委员会哈特里中心）；H. H. Wills Physics Laboratory, University of Bristol（布里斯托尔大学H.H.威尔斯物理实验室）
本研究针对标量活性流体中稳定液滴的特性，通过数值模拟Active Model B+模型，验证了噪声对相转变的偏移作用，发现单一参数可调控液滴的数量、密度与分形维数，还观测到液滴相深处的六方晶格转变，完善了活性流体相分离的理论认知。
Large-scale collective behavior in suspensions of many particles can be understood from the balance of statistical forces emerging beyond the direct microscopic particle interactions. Here we review some aspects of the collective forces that can arise in suspensions of self-propelled active Brownian particles: wall forces under confinement, interfacial forces, and forces on immersed bodies mediated by the suspension. Even for non-aligning active particles, these forces are intimately related to a non-uniform polarization of particle orientations induced by walls and bodies, or inhomogeneous de…
We study numerically the phase behavior of self-propelled elliptical particles interacting through the "hard" repulsive Gay-Berne potential at infinite Péclet number. Changing a single parameter, the aspect ratio, allows to continuously go from discoid active Brownian particles to elongated polar rods. Discoids show phase separation, which changes to a cluster state of polar domains, which then form polar bands as the aspect ratio is increased. From the simulations, we identify and extract the two effective parameters entering the mean-field description: the force imbalance coefficient and the…
Motility-induced phase separation (MIPS) arises generically in fluids of self-propelled particles when interactions lead to a kinetic slowdown at high densities. Starting from a continuum description of scalar active matter, akin to a generalized Cahn-Hilliard equation, we give a general prescription for the mean densities of coexisting phases in flux-free steady states that amounts, at a hydrodynamics scale, to extremizing an effective free energy. We illustrate our approach on two well-known models: self-propelled particles interacting either through a density-dependent propulsion speed or v…
We show that disordered boundaries destroy bulk phase separation in scalar active systems in dimension $d<d_c=3$. This is in strong contrast with the equilibrium case where boundaries have no impact on the bulk of phase-separated systems. The underlying mechanism is revealed by considering a localized deformation of an otherwise flat wall, from which the case of a disordered boundary can be inferred. We find long-ranged correlations of the density field as well as a cascade of eddies which we show prevent bulk phase separation in low enough dimensions. The results are derived for dilute system…
Suspensions of spherical active particles often show microphase separation. At a continuum level, coupling their scalar density to fluid flow, there are two distinct explanations. Each involves an effective interfacial tension: the first mechanical (causing flow) and the second diffusive (causing Ostwald ripening). Here we show how the negative mechanical tension of contractile swimmers creates, via a self-shearing instability, a steady-state life cycle of droplet growth interrupted by division whose scaling behavior we predict. When the diffusive tension is also negative, this is replaced by …
Recent experimental studies, both in vivo and in vitro, have revealed that membrane components that bind to the cortical actomyosin meshwork are driven by active fluctuations, whereas membrane components that do not bind to cortical actin are not. Here we study the statistics of density fluc- tuations and dynamics of particles advected in an active quasi-two dimensional medium comprising self-propelled filaments with no net orientational order, using a combination of agent-based Brow- nian dynamics simulations and analytical calculations. The particles interact with each other and with the sel…
We study the impact of a random quenched potentials and torques on scalar active matter. Microscopic simulations reveal that motility-induced phase separation is replaced in two-dimensions by an asymptotically homogeneous phase with anomalous long-ranged correlations and non-vanishing steady-state currents. Using a combination of phenomenological models and a field-theoretical treatment, we show the existence of a lower-critical dimension, $d_c=4$, below which phase separation is only observed for systems smaller than an Imry-Ma length-scale. We identify a weak-disorder regime in which the str…
We employ a millimeter-scale piezoelectric acoustic actuator, which generates MHz-frequency surface acoustic waves (SAWs) in a solid substrate, to actively coat a drop of water by a macroscopic film of silicon oil as a paradigm for a small scale and low power coating system. We build upon previous studies on SAW induced dynamic wetting of a solid substrate, also known as the acoustowetting phenomena, to actively drive a model low surface-energy liquid -- silicon oil -- coat a model liquid object -- a sessile drop of water. The oil film spreads along the path of the propagating SAW and comes in…
We present a continuum theory of self-propelled particles, without alignment interactions, in a momentum-conserving solvent. To address phase separation we introduce a scalar concentration field $ϕ$ with advective-diffusive dynamics. Activity creates a contribution $Σ_{ij}=-ζ((\partial_iϕ)(\partial_jϕ)-(\nablaϕ)^{2}δ_{ij}/d)$ to the deviatoric stress, where $ζ$ is odd under time reversal and $d$ is the number of spatial dimensions; this causes an effective interfacial tension contribution that is negative for contractile swimmers. We predict that domain growth then ceases at a length scale whe…
We employ Statistical Field Theory techniques for coarse-graining the steady-state properties of Active Ornstein-Uhlenbeck particles. The computation is carried on in the framework of the Unified Colored Noise approximation that allows an effective equilibrium picture. We thus develop a mean-field theory that allows to describe in a unified framework the phenomenology of scalar Active Matter. In particular, we are able to describe through spontaneous symmetry breaking mechanism two peculiar features of Active Systems that are (i) The accumulation of active particles at the boundaries of a conf…
Active matter with local polar or nematic order is subject to the well-known Simha-Ramaswamy instability. It is so far unclear how, despite this instability, biological tissues can undergo robust active anisotropic deformation during animal morphogenesis. Here we show that protein concentration gradients (e.g. morphogen gradients), which are known to control large-scale coordination among cells, can stabilize such deformations. To this end, we study a hydrodynamic model of an active polar material. To account for the effect of the protein gradient, the polar field is coupled to the boundary-pr…
Recent theories predict phase separation among orientationally disordered active particles whose propulsion speed decreases rapidly enough with density. Coarse-grained models of this process show time-reversal symmetry (detailed balance) to be restored for uniform states, but broken by gradient terms; hence detailed-balance violation is strongly coupled to interfacial phenomena. To explore the subtle generic physics resulting from such coupling we here introduce `Active Model B'. This is a scalar $ϕ^4$ field theory (or phase-field model) that minimally violates detailed balance via a leading-o…
Pair interactions between active particles need not follow Newton's third law. In this work we propose a continuum model of pattern formation due to non-reciprocal interaction between multiple species of scalar active matter. The classical Cahn-Hilliard model is minimally modified by supplementing the equilibrium Ginzburg-Landau dynamics with particle number conserving currents which cannot be derived from a free energy, reflecting the microscopic departure from action-reaction symmetry. The strength of the asymmetry in the interaction determines whether the steady state exhibits a macroscopic…
Due to their remarkable properties, systems that exhibit self-organization of their components resulting from intrinsic microscopic activity have been extensively studied in the last two decades. In a generic class of active matter, the interactions between the active components are represented via an effective density-dependent diffusivity in a mean-field single-particle description. Here, a new class of scalar active matter is proposed by incorporating a diffusivity edge into the dynamics: when the local density of the system surpasses a critical threshold, the diffusivity vanishes. The effe…
The interplay between phase separation and wetting of multicomponent mixtures is ubiquitous in nature and technology and recently gained significant attention across scientific disciplines, due to the discovery of biomolecular condensates. It is well understood that sessile droplets, undergoing phase separation in a static wetting configuration, exhibit microdroplet nucleation at their contact lines, forming an oil ring during later stages. However, very little is known about the dynamic counterpart, when phase separation occurs in a non-equilibrium wetting configuration, i.e., spreading dropl…
Evaporation-Induced Pattern Formation and Wetting in Active Microtubule-Kinesin Droplets
Harvard University（哈佛大学）；Max Planck Institute for Dynamics and Self-Organization（马克斯·普朗克动力学与自组织研究所）；University of Surrey（萨里大学）；Universität Konstanz（康斯坦茨大学）
Soochow University（苏州大学）；Department of Physics, Technion – Israel Institute of Technology（以色列理工学院物理系）；Department of Physics, Massachusetts Institute of Technology（麻省理工学院物理系）
Defect dynamics in a thin active nematic layer is studied by asymptotic matching of solutions in the defect core and the far field. The analysis is facilitated by the correspondence between the 2D nematic and complex scalar field models. Self-propulsion and topological interactions are identified as the primary drivers of the defect motion, surpassing the influence of both passive backflow and active flow induced by other defects.
