C$_3$N is a recently discovered 2D layered material structurally similar to graphene, which has demonstrated immense prospect for future nanoelectronics. In this work, we have designed and investigated the operation and performance of a C$_3$N island single electron transistor (SET) for the first time. Using First-principles based calculations, we investigated the effect of various molecular adsorptions on the electronic and conduction behaviour of the SET. C$_3$N was found to be the perfect host material for capturing CO$_2$. The charge stability diagram carries the signature of different molecules within the SET and their presence can be uniquely identified from various line scans and normalised differential conductance behaviour obtained from it. Our results suggests the usefulness of such nanoelectronic structures for sensing toxic gas molecules which can be operational over a wide temperature range with detection sensitivity upto a single molecular level.
We perform direct thermovoltage measurements in a single-electron transistor, using on-chip local thermometers, both in the linear and non-linear regimes. Using a model which accounts for co-tunneling, we find excellent agreement with the experimental data with no free parameters even when the temperature difference is larger than the average temperature (far-from-linear regime). This allows us to confirm the sensitivity of the thermovoltage on co-tunneling and to find that in the non-linear regime the temperature of the metallic island is a crucial parameter. Surprisingly, the metallic island…
A model of a superconducting tunnel junction which refrigerates a nearby metallic island without any particle exchange is presented. Heat extraction is mediated by charge fluctuations in the coupling capacitance of the two systems. The interplay of Coulomb interaction and the superconducting gap reduces the power consumption of the refrigerator. The island is predicted to be cooled from lattice temperatures of 200~mK down to close to 50~mK, for realistic parameters. The results emphasize the role of non-equilibrium correlations in bipartite mesoscopic conductors. This mechanism can be applied …
We study a Cooper pair transistor realized by a mesoscopic superconductor island that couples to a pair of $s$-wave superconducting leads. For a trivial island, the critical supercurrent between the leads exhibits a well-known $2e$-periodicity in the island-gate charge. Here, we show that for an island with spatially separated zero-energy Majorana or Andreev bound states the periodicity of the magnitude of the critical supercurrent transitions to $1e$ in the island-gate charge. Moreover, for Andreev bound states the current-phase relation displays a sign reversal when the parity of the charge …
The role of Chemistry in the road towards quantum devices is the design of elementary pieces with a built-in function. A brilliant example is the use of molecular transistors as nuclear spin detectors, which, up to now, has been implemented only on [TbPc$_2$]$^-$. We argue that this is an artificial constraint and critically discuss the limitations of current theoretical approaches to assess the potential of molecules for their use in spintronics. In connection with this, we review the recent progress in the preparation of highly coherent spin qubits based on vanadium dithiolate complexes and …
Understanding the intermolecular interactions and utilize these interactions to effectively control the transport behavior of single molecule is the key step from single molecule device to molecular circuits1-6. Although many single molecule detection techniques are used to detect the molecular interaction at single-molecule level1,4,5,7,8, probing and tuning the intermolecular interaction all by electrical approaches has not been demonstrated. In this work, we successful assemble a double molecule transistor incorporating two manganese phthalocyanine molecules, on which we probe and tune the …
Current-voltage characteristics of a single-electron transistor with a vibrating quantum dot were calculated assuming vibrons to be in a coherent (non-equilibrium) state. For a large amplitude of quantum dot oscillations we predict strong suppression of conductance and the lifting of polaronic blockade by bias voltage in the form of steps in $I-V$ curves. The height of the steps differs from the prediction of the Franck-Condon theory (valid for equilibrated vibrons) and the current saturates at lower voltages then for the case, when vibrons are in equilibrium state.