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arXiv 1904.02497physics.atom-ph
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高精度氢光谱学中的压力漂移:II。碰撞近似和蒙特卡罗模拟

Pressure Shifts in High-Precision Hydrogen Spectroscopy: II. Impact Approximation and Monte-Carlo Simulations

A. Matveev, N. Kolachevsky, C. M. Adhikari, U. D. Jentschura

摘要:

我们调查碰撞位移的谱线涉及激发类氢状态,范德华系数最近被证明有很大的数值时,表示在原子单位。特别强调的是最近在Garching进行的氢2S-4P实验(以及正在进行的2S-6P实验),但提供了其他跃迁的数值输入数据(例如,也包括S国)。我们表明,频率偏移可以描述,以足够的精度,在影响近似。与压力相关的效应被分成两部分,(i)与束内部的原子的碰撞相关,以及(ii)与原子束中的原子与残余背景气体的碰撞相关。后者既包含原子氢也包含分子氢。考虑到实验装置的几何形状,通过蒙特卡罗模拟评估了束内碰撞的主导效应。而在Garching实验中,碰撞位移是10 Hz的量级,因此可以忽略不计,它可以决定性地取决于实验条件。我们提出的输入数据,可以用来描述当前和计划的实验兴趣的其他过渡的效果。

英文摘要:

We investigate collisional shifts of spectral lines involving excited hydrogenic states, where van der Waals coefficients have recently been shown to have large numerical values when expressed in atomic units. Particular emphasis is laid on the recent hydrogen 2S-4P experiment (and an ongoing 2S-6P experiment) in Garching, but numerical input data are provided for other transitions (e.g., involving S states), as well. We show that the frequency shifts can be described, to sufficient accuracy, in the impact approximation. The pressure related effects were separated into two parts, (i) related to collisions of atoms inside of the beam, and (ii) related to collisions of the atoms in the atomic beam with the residual background gas. The latter contains both atomic as well as molecular hydrogen. The dominant effect of intra-beam collisions is evaluated by a Monte-Carlo simulation, taking the geometry of the experimental apparatus into account. While, in the Garching experiment, the collisional shift is on the order of 10 Hz, and thus negligible, it can decisively depend on the experimental conditions. We present input data which can be used in order to describe the effect for other transitions of current and planned experimental interest.

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