The nitrogen cycles on Pluto over seasonal and astronomical timescales
T. Bertrand, F. Forget, O. M. Umurhan, W. M. Grundy, B. Schmitt, S. Protopapa, A. M. Zangari, O. L. White, P. M. Schenk, K. N. Singer, A. Stern, H. A. Weaver, L… 展开作者
T. Bertrand, F. Forget, O. M. Umurhan, W. M. Grundy, B. Schmitt, S. Protopapa, A. M. Zangari, O. L. White, P. M. Schenk, K. N. Singer, A. Stern, H. A. Weaver, L. A. Young, K. Ennico, C. B. Olkin, the New Horizons Science Team
Pluto's landscape is shaped by the cycles of the volatile ices covering its surface. In particular, the Sputnik Planitia (SP) ice sheet displays a large diversity of terrains, with bright and dark plains, pits, topographic depressions and evidences of recent and past glacial flows. Outside SP, New Horizons also revealed numerous N2 ice deposits, in Tombaugh Regio and at mid-northern latitudes. These observations suggest a complex history involving volatile and glacial processes on different timescales. We present numerical simulations of volatile transport on Pluto performed with a model able to simulate the N2 cycle over millions of years (Myrs), taking into account the changes of obliquity and orbital parameters as experienced by Pluto. Results show that over one obliquity cycle, the latitudes of SP between 25°S-30°N are dominated by N2 condensation, while the latitudes between 30-50°N are dominated by N2 sublimation. We find that a net amount of 1 km of ice has sublimed at the northern edge of SP during the last 2 Myrs. By comparing these results with the observed geology of SP, we can relate the formation of the pits and the brightness of the ice to the ice flux occurring at the annual timescale, while the glacial flows at its eastern edge and the erosion of the water ice mountains all around the ice sheet are related to the astronomical timescale. We also perform simulations with a glacial flow scheme which shows that SP is currently at its minimum extent. We also explore the stability of N2 ice outside SP. Results show that it is not stable at the poles but rather in the equatorial regions, in particular in depressions, where thick deposits may persist over tens of Myrs, before being trapped in SP. Finally, another key result is that the minimum and maximum surface pressures obtained over the simulated Myrs remain in the range of mm-Pa and Pa, respectively.
Pluto's surface is geologically complex because of volatile ices that are mobile on seasonal and longer time scales. Here we analyzed New Horizons LEISA spectral data to globally map the nitrogen ice, including nitrogen with methane diluted in it. Our goal was to learn about the seasonal processes influencing ice redistribution, to calculate the globally averaged energy balance, and to place a lower limit on Pluto's N2 inventory. We present the average latitudinal distribution of nitrogen and investigate the relationship between its distribution and topography on Pluto by using maps that inclu…
We present spectra of Eris from the MMT 6.5 meter telescope and Red Channel Spectrograph (5700-9800 angstroms; 5 angstroms per pix) on Mt. Hopkins, AZ, and of Pluto from the Steward Observatory 2.3 meter telescope and Boller and Chivens spectrograph (7100-9400 angstroms; 2 angstroms per pix) on Kitt Peak, AZ. In addition, we present laboratory transmission spectra of methane-nitrogen and methane-argon ice mixtures. By anchoring our analysis in methane and nitrogen solubilities in one another as expressed in the phase diagram of Prokhvatilov and Yantsevich (1983), and comparing methane bands in…
The methane-nitrogen phase diagram of Prokhvatilov and Yantsevich (1983) indicates that at temperatures relevant to the surfaces of icy dwarf planets like Pluto, two phases contribute to the methane absorptions: nitrogen saturated with methane $\bf{\bar{N_{2}}}$:CH$_{4}$ and methane saturated with nitrogen $\bf{\bar{CH_{4}}}$:N$_{2}$. No optical constants are available so far for the latter component limiting construction of a proper model, in compliance with thermodynamic equilibrium considerations. New optical constants for solid solutions of methane diluted in nitrogen (N$_{2}$:CH$_{4}$) an…
N2 is abundant in Pluto's atmosphere and on its surface, but the supply is depleted by prodigious atmospheric escape. We demonstrate that cometary impacts could not have delivered enough N mass to resupply Pluto's N2 atmospheric escape over time; thus Pluto's N2 is likely endogenous, and therefore was either acquired early in its history or created by chemistry inside/on Pluto. We find that cratering could excavate a considerable amount of N2 to resupply the atmosphere against escape if the near-surface N2 reservoir is deep. However, we find that this process likely falls short of that necessa…
New Horizons observations suggest that CH4 on Pluto has a complex history, involving reservoirs of different composition, thickness and stability controlled by volatile processes occurring on different timescales. In order to interpret these observations, we use a Pluto volatile transport model able to simulate the cycles of N2 and CH4 ices over millions of years. By assuming fixed solid mixing ratios, we explore how changes in surface albedos, emissivities and thermal inertias impact volatile transport. This work is therefore a direct and natural continuation of the work by Bertrand et al. (2…
Seasonal Variability of Pluto's Haze Formation Revealed by Laboratory Simulations
University of Science and Technology of China（中国科学技术大学）；Johns Hopkins University（约翰斯·霍普金斯大学）；Space Telescope Science Institute（太空望远镜科学研究所）；NASA Goddard Space Flight Center（美国宇航局戈达德太空飞行中心）；Univ. Grenoble Alpes, CNRS, IPAG（格勒诺布尔阿尔卑斯大学，法国国家科学研究中心，IPAG）；Department of Materials Science and Engineering, Johns Hopkins University（约翰斯·霍普金斯大学材料科学与工程系）
Recently, a nitrogen iceberg was proposed as a possible origin for the first interstellar object, 1I/2017 U1, also known as `Oumuamua. Here, we show that the mass budget in exo-Pluto planets necessary to explain the detection of `Oumuamua as a nitrogen iceberg chipped off from a planetary surface requires a mass of heavy elements exceeding the total quantity locked in stars with 95\% confidence, making the scenario untenable because only a small fraction of the mass in stars ends in exo-Plutos.
On July 14th 2015, NASA's New Horizons mission gave us an unprecedented detailed view of the Pluto system. The complex compositional diversity of Pluto's encounter hemisphere was revealed by the Ralph/LEISA infrared spectrometer on board of New Horizons. We present compositional maps of Pluto defining the spatial distribution of the abundance and textural properties of the volatiles methane and nitrogen ices and non-volatiles water ice and tholin. These results are obtained by applying a pixel-by-pixel Hapke radiative transfer model to the LEISA scans. Our analysis focuses mainly on the large …
We present three near-infrared spectra of Pluto taken with the IRTF and SpeX, an optical spectrum of Triton taken with the MMT and the Red Channel Spectrograph, and previously published spectra of Pluto, Triton, and Eris. We combine these observations with a two-phase Hapke model, and gain insight into the ice mineralogy on Pluto, Triton, and Eris. Specifically, we measure the methane-nitrogen mixing ratio across and into the surfaces of these icy dwarf planets. In addition, we present a laboratory experiment that demonstrates it is essential to model methane bands in spectra of icy dwarf plan…
A unique feature of Pluto's large satellite Charon is its dark red northern polar cap. Similar colours on Pluto's surface have been attributed to organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location of this material on Charon implicates the temperature extremes that result from Charon's high obliquity and long seasons. The escape of Pluto's atmosphere provides a potential feed stock for production of complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charon's winter pole was proposed as an explanation on the basi…
The vast, deep, volatile-ice-filled basin informally named Sputnik Planum is central to Pluto's geological activity[1,2]. Composed of molecular nitrogen, methane, and carbon monoxide ices[3], but dominated by N2-ice, this ice layer is organized into cells or polygons, typically ~10-40 km across, that resemble the surface manifestation of solid state convection[1,2]. Here we report, based on available rheological measurements[4], that solid layers of N2 ice approximately greater than 1 km thick should convect for estimated present-day heat flow conditions on Pluto. More importantly, we show num…
Kuiper belt object (KBO) Eris is exceptionally bright with a greater visible geometric albedo than any other known KBO. Its infrared reflectance spectrum is dominated by methane, which should form tholins that darken the surface on timescales much shorter than the age of the Solar System. Thus one or more ongoing processes probably maintain its brightness. Eris is predicted to have a primarily nitrogen atmosphere that is in vapor pressure equilibrium with nitrogen-ice and is collisional (not ballistic). Eris's eccentric orbit is expected to result in two atmospheric regimes: (1) a period near …
Observations of Pluto's surface made by the New Horizons spacecraft indicates present-day nitrogen ice glaciation in and around the basin known as Sputnik Planum. Motivated by these observations, we have developed an evolutionary glacial flow model of solid nitrogen ice taking into account its published thermophysical and rheologies properties. This model assumes that glacial ice layers flow laminarly and have low aspect ratios which permits a vertically integrated mathematical formulation. We assess the conditions for the validity of laminar nitrogen ice motion by revisiting the problem of th…
The deep nitrogen-covered Sputnik Planitia (SP; informal name) basin on Pluto is located very close to the longitude of Pluto's tidal axis[1] and may be an impact feature [2], by analogy with other large basins in the solar system[3,4]. Reorientation[5-7] due to tidal and rotational torques can explain SP's location, but requires it to be a positive gravity anomaly[7], despite its negative topography. Here we argue that if SP formed via impact and if Pluto possesses a subsurface ocean, a positive gravity anomaly would naturally result because of shell thinning and ocean uplift, followed by lat…
We propose a scenario that explains the apparent nitrogen deficiency in comets in a way consistent with the fact that the surfaces of Pluto and Triton are dominated by nitrogen-rich ice. We use a statistical thermodynamic model to investigate the composition of the successive multiple guest clathrates that may have formed during the cooling of the primordial nebula from the most abundant volatiles present in the gas phase. These clathrates agglomerated with the other ices (pure condensates or stoichiometric hydrates) and formed the building blocks of comets. We report that molecular nitrogen i…
We report results from monitoring Pluto's 0.8 to 2.4 μm reflectance spectrum with IRTF/SpeX on 65 nights over the dozen years from 2001 to 2012. The spectra show vibrational absorption features of simple molecules CH4, CO, and N2 condensed as ices on Pluto's surface. These absorptions are modulated by the planet's 6.39 day rotation period, enabling us to constrain the longitudinal distributions of the three ices. Absorptions of CO and N2 are concentrated on Pluto's anti-Charon hemisphere, unlike absorptions of less volatile CH4 ice that are offset by roughly 90° from the longitude of maximum C…
Pluto and its satellites will be the most distant objects ever reconnoitered when NASA's New Horizons spacecraft conducts its intensive flyby of this system in 2015. The size-frequency distribution (SFD) of craters on the surfaces in the Pluto system have long been expected to provide a useful measure of the size distribution of Kuiper Belt Objects (KBOs) down to much smaller size scales than presently observed. However, currently predicted escape rates of Pluto's atmosphere suggest that of order one-half to several kilometers of nitrogen ice has been removed from Pluto's surface over geologic…
Context. Pluto's tenuous nitrogen (N2) atmosphere undergoes strong seasonal effects due to high obliquity and orbital eccentricity, and has been recently (July 2015) observed by the New Horizons spacecraft. Goals are (i) construct a well calibrated record of the seasonal evolution of surface pressure on Pluto and (ii) constrain the structure of the lower atmosphere using a central flash observed in 2015. Method: eleven stellar occultations by Pluto observed between 2002 and 2016 are used to retrieve atmospheric profiles (density, pressure, temperature) between $\sim$5 km and $\sim$380 km altit…
Evidence for possible N2 basal flow beneath Pluto northern Sputnik Planitia
Southwest Research Institute（西南研究所）；SETI Institute at NASA Ames Research Center（NASA阿姆斯研究中心SETI研究所）；INSTAAR, University of Colorado（科罗拉多大学INSTAAR）；Department of Geological Sciences and INSTAAR University of Colorado Boulder（科罗拉多大学博尔德分校地质科学系及INSTAAR）；Planetary Science Institute（行星科学研究所）
The existence of strong absorption bands of singly deuterated methane (CH3D) at wavelengths where normal methane (CH4) absorbs comparatively weakly could enable remote measurement of D/H ratios in methane ice on outer solar system bodies. We performed laboratory transmission spectroscopy experiments, recording spectra at wavelengths from 1 to 6 \mum to study CH3D bands at 2.47, 2.87, and 4.56 \mum, wavelengths where ordinary methane absorption is weak. We report temperature-dependent absorption coefficients of these bands when the CH3D is diluted in CH4 ice and also when it is dissolved in N2 …
The radiolysis of a nitrogen-acetone mixture, condensed at 11 K, by 40 MeV $^{58}$Ni$^{11+}$ ions is studied. These results are representative of studies concerning solar system objects exposed to cosmic rays. In the Kuiper Belt, region of Trans-Neptunian Objects (TNOs), acetone, molecular nitrogen and other small molecules were detected and may be present on icy surfaces. Bombardment by cosmic rays triggers chemical reactions leading to synthesis of larger molecules. In this work, destruction cross sections of acetone and nitrogen in solid phase are determined from a sequence of infrared spec…
Neptune's moon Triton shares many similarities with Pluto, including volatile cycles of N2, CH4 and CO, and represents a benchmark case for the study of surface-atmosphere interactions on volatile-rich KBOs. Within the context of New Horizons observations of Pluto as well as recent Earth-based observations of Triton, we adapt a Plutonian VTM to Triton, and test its ability to simulate its volatile cycles, thereby aiding our understanding of its climate. We present VTM simulations exploring the volatile cycles on Triton over long-term and seasonal timescales for varying model parameters. We exp…
A combination band due to a mechanism whereby a photon excites two or more vibrational modes ({\it e.g.} a bend and a stretch) of an individual molecule is commonly seen in laboratory and astronomical spectroscopy. Here, we present evidence of a much less commonly seen combination band $-$ one where a photon simultaneously excites two adjacent molecules in an ice. In particular, we present near-infrared spectra of laboratory CO/N$_2$ ice samples where we identify a band at 4467.5 cm$^{-1}$ (2.239 $μ$m) that results from single photons exciting adjacent pairs of CO and N$_2$ molecules. We also …
