The composition of the lower mantle $-$ comprising 56% of Earth's volume $-$ remains poorly constrained. Among the major elements, Mg/Si ratios ranging from $\sim$0.9$-$1.1, such as in rocky solar-system building blocks (or chondrites), to $\sim$1.2$-$1.3, such as in upper-mantle rocks (or pyrolite), have been proposed. Geophysical evidence for subducted lithosphere deep in the mantle has been interpreted in terms of efficient mixing and thus homogeneous Mg/Si across most of the mantle. However, previous models did not consider the effects of variable Mg/Si on the viscosity and mixing efficiency of lower-mantle rocks. Here, we use geodynamic models to show that large-scale heterogeneity with viscosity variations of $\sim$20$\times$, such as due to the dominance of intrinsically strong (Mg,Fe)SiO$_3-$bridgmanite in low-Mg/Si domains, are sufficient to prevent efficient mantle mixing, even on large scales. Models predict that intrinsically strong domains stabilize degree-two mantle-convection patterns, and coherently persist at depths of $\sim$1,000$-$2,200 km up to the present-day, separated by relatively narrow up-/downwelling conduits of pyrolitic material. The stable manifestation of such "bridgmanite-enriched ancient mantle structures" (BEAMS) may reconcile the geographical fixity of deep-rooted mantle-upwelling centers, and fundamental geophysical changes near 1,000 km depth (e.g. in terms of seismic-tomography patterns, radial viscosity increase, lateral deflections of rising plumes and sinking slabs). Moreover, these ancient structures may provide a reservoir to host primordial geochemical signatures.
We have studied the ferrous (Fe2+) and ferric (Fe3+) iron concentrations in Al-free Fe containing Mg-silicate perovskite (Mg-Pv) at pressure (P), temperature (T), and oxygen fugacity (fO2) conditions related to the lower mantle using a thermodynamic model based on ab-initio calculations. We consider the oxidation reaction and the charge disproportionation reaction, both of which can produce Fe3+ in Mg-Pv. The model shows qualitatively good agreement with available experimental data on Fe3+/ΣFe (ΣFe = total Fe in system), spin transitions, and equations of state. We predict that under lower-man…
Highly siderophile elements (HSEs) are strongly depleted in the bulk silicate Earth (BSE) but are present in near-chondritic relative abundances. The conventional explanation is that the HSEs were stripped from the mantle by the segregation of metal during core formation but were added back in near-chondritic proportions by late accretion, after core formation had ceased. Here we show that metal-silicate equilibration and segregation during Earth's core formation actually increased HSE mantle concentrations because HSE partition coefficients are relatively low at the high pressures of core for…
In order to test planetary accretion and differentiation scenarios, we integrated a multistage core-mantle differentiation model with N-body accretion simulations. Impacts between embryos and planetesimals result in magma ocean formation and episodes of core formation. The core formation model combines rigorous chemical mass balance with metal-silicate element partitioning data. The primary constraint on the combined model is the composition of the Earth's primitive mantle, the composition of the Martian mantle, and the mass fractions of the metallic cores of Earth and Mars. The model is refin…
Recent high-precision measurements of the isotopic composition of lunar rocks demonstrate that the bulk silicate Earth and the Moon show an unexpectedly high degree of similarity. This is inconsistent with one of the primary results of classic dynamical simulations of the widely accepted giant impact model for the formation of the Moon, namely that most of the mass of the Moon originates from the impactor, not Earth. Resolution of this discrepancy without changing the main premises of the giant impact model requires total isotopic homogenisation of Earth and impactor material after the impact …
Carbon-enriched rocky exoplanets have been proposed around dwarf stars as well as around binary stars, white dwarfs and pulsars. However, the mineralogical make up of such planets is poorly constrained. We performed high-pressure high-temperature laboratory experiments ($P$ = 1$-$2 GPa, $T$ = 1523$-$1823 K) on carbon-enriched chemical mixtures to investigate the deep interiors of Pluto- to Mars-size planets the upper mantles of larger planets. Our results show that these exoplanets, when fully-differentiated, comprise a metallic core, a silicate mantle and a graphite layer on top of the silica…
In this paper we present a series of models for the deep water cycle on super-Earths experiencing plate tectonics. The deep water cycle can be modeled through parameterized convection models coupled with a volatile recycling model. The convection of the silicate mantle is linked to the volatile cycle through the water-dependent viscosity. Important differences in surface water content are found for different parameterizations of convection. Surface oceans are smaller and more persistent for single layer convection, rather than convection by boundary layer instability. Smaller planets have init…
The liquid metal-liquid silicate partitioning of molybdenum and tungsten during core formation must be well-constrained in order to understand the evolution of Earth and other planetary bodies, in particular because the Hf-W isotopic system is used to date early planetary evolution. We combine 48 new high pressure and temperature experimental results with a comprehensive database of previous experiments to re-examine the systematics of Mo and W partitioning. W partitioning is particularly sensitive to silicate and metallic melt compositions and becomes more siderophile with increasing temperat…
We investigate equilibrium chemistry between molten metal and silicate, and a hydrogen-rich envelope using 18 independent reactions among 25 phase components for sub-Neptune-like exoplanets. Both reactive metal and unreactive metal sequestered in an isolated core are modeled. The overarching effects of equilibration are oxidation of the envelope and reduction of the mantle and core. Hydrogen and oxygen typically comprise significant fractions of metal cores at chemical equilibrium, leading to density deficits that offer a possible alternative explanation for the low densities of the Trappist-1…
We present a survey of >4,000 star compositions from the Hypatia Catalog to examine whether rocky exoplanets (i.e., those with rocky surfaces, dominated by silicates) might be geologically similar to Earth, at least with respect to composition and mineralogy. To do so, we explore the variety of reported stellar compositions to then determine a possible range of exoplanetary mantle mineralogies. We find that exoplanetary mantles will likely be dominated by olivine and/or orthopyroxene, depending upon Fe partitioning during core formation. Some exoplanets may be magnesiowustite- or quartz-satura…
Carbon is an essential element for the existence and evolution of life on Earth. Its abundance in Earth's crust and mantle (the Bulk Silicate Earth, BSE) is surprisingly high given that carbon is strongly siderophile (metal-loving) at low pressures and temperatures, and hence should have segregated almost completely into Earth's core during accretion. Estimates of the concentration of carbon in the BSE lie in the range 100-260 ppm and are much higher than expected based on simple models of core-mantle differentiation. Here we show through experiments at the putative conditions of Earth's core …
Prior studies have hypothesized that some polluted white dwarfs record continent-like granitic crust--which is abundant on Earth and perhaps uniquely indicative of plate tectonics. But these inferences derive from only a few elements, none of which define rock type. We thus present the first estimates of rock types on exoplanets that once orbited polluted white dwarfs--stars whose atmospheric compositions record the infall of formerly orbiting planetary objects--examining cases where Mg, Si, Ca and Fe are measured with precision. We find no evidence for continental crust, or other crust types,…
The Earth, Venus, Mars, and some extrasolar terrestrial planets have a mass and radius that is consistent with a mass fraction of about 30% metallic core and 70% silicate mantle. At the inner frontier of the solar system, Mercury has a completely different composition, with a mass fraction of about 70% metallic core and 30% silicate mantle. Several formation or evolution scenarios are proposed to explain this metal-rich composition, such as a giant impact, mantle evaporation, or the depletion of silicate at the inner-edge of the proto-planetary disk. These scenarios are still strongly debated.…
The geology of Earth and super-Earth sized planets will, in many cases, only be observable via their atmospheres. Here, we investigate secondary volcanic atmospheres as a key base case of how atmospheres may reflect planetary geochemistry. We couple volcanic outgassing with atmospheric chemistry models to simulate the growth of C-O-H-S-N atmospheres in thermochemical equilibrium, focusing on what information about a planet's mantle fO$_2$ and bulk silicate H/C ratio could be determined by atmospheric observation. 800K volcanic atmospheres develop distinct compositional groups as the mantle fO$…
Large terrestrial planets are expected to have muted topography and deep oceans, implying that most super-Earths should be entirely covered in water, so-called waterworlds. This is important because waterworlds lack a silicate weathering thermostat so their climate is predicted to be less stable than that of planets with exposed continents. In other words, the continuously habitable zone for waterworlds is much narrower than for Earth-like planets. A planet's water is partitioned, however, between a surface reservoir, the ocean, and an interior reservoir, the mantle. Plate tectonics transports…
The amount of nitrogen in the atmosphere, oceans, crust, and mantle have important ramifications for Earth's biologic and geologic history. Despite this importance, the history and cycling of nitrogen in the Earth system is poorly constrained over time. For example, various models and proxies contrastingly support atmospheric mass stasis, net outgassing, or net ingassing over time. In addition, the amount available to and processing of nitrogen by organisms is intricately linked with and provides feedbacks on oxygen and nutrient cycles. To investigate the Earth system nitrogen cycle over geolo…
Mesosiderites are a type of stony-iron meteorites composed of a mixture of silicates and Fe-Ni metals. The mesosiderite silicates and metals are considered to have originated from the crust and metal core, respectively, of a differentiated asteroid. In contrast, mesosiderites rarely contain the olivine that is mainly included in a mantle. Although a giant impact onto a differentiated asteroid is considered to be a probable mechanism to mix crust and metal materials to form mesosiderites, it is not obvious how such a giant impact can form mesosiderite-like materials without including mantle mat…
The ever-expanding catalog of detected super-Earths calls for theoretical studies of their properties in the case of a substantial water layer. This work considers such water planets with a range of masses and water mass fractions (2 to 5 M_Earth, 0.02% to 50% H2 O). First, we model the thermal and dynamical structure of the near-surface for icy and oceanic surfaces, finding separate regimes where the planet is expected to maintain a subsurface liquid ocean and where it is expected to exhibit ice tectonics. Newly discovered exoplanets may be placed into one of these regimes given estimates of …
We comprehensively compile and review N content in geologic materials to calculate a new N budget for Earth. Using analyses of rocks and minerals in conjunction with N-Ar geochemistry demonstrates that the Bulk Silicate Earth (BSE) contains \sim7\pm4 times present atmospheric N (4\times10^18 kg N, PAN), with 27\pm16\times10^18 kg N. Comparison to chondritic composition, after subtracting N sequestered into the core, yields a consistent result, with BSE N between 17\pm13\times10^18 kg to 31\pm24\times10^18 kg N. In the chondritic comparison we calculate a N mass in Earth's core (180\pm110 to 30…
Knowing the isotopic composition of Theia, the proto-planet which collided with the Earth in the Giant Impact that formed the Moon, could provide interesting insights on the state of homogenization of the inner solar system at the late stages of terrestrial planet formation. We use the known isotopic and modeled chemical compositions of the bulk silicate mantles of Earth and Moon and combine them with different Giant Impact models, to calculate the possible ranges of isotopic composition of Theia in O, Si, Ti, Cr, Zr and W in each model. We compare these ranges to the isotopic composition of c…
Volatile molecules containing hydrogen, carbon, and nitrogen are key components of planetary atmospheres. In the pebble accretion model for rocky planet formation, these volatile species are accreted during the main planetary formation phase. For this study, we modelled the partitioning of volatiles within a growing planet and the outgassing to the surface. The core stores more than 90\% of the hydrogen and carbon budgets of Earth for realistic values of the partition coefficients of H and C between metal and silicate melts. The magma oceans of Earth and Venus are sufficiently deep to undergo …
Venus' mass and radius are similar to those of Earth. However, dissimilarities in atmospheric properties, geophysical activity and magnetic field generation could hint towards significant differences in the chemical composition and interior evolution of the two planets. Although various explanations for the differences between Venus and Earth have been proposed, the currently available data are insufficient to discriminate among the different solutions. Here we investigate the possible range of Venus structure models. We assume that core segregation happened as a single-stage event. The mantle…
Context: The long-term carbonate-silicate cycle plays an important role in the evolution of Earth's climate and, therefore, may also be an important mechanism in the evolution of the climates of Earth-like exoplanets. Aims: We investigate the effects of radiogenic mantle heating, core size, and planetary mass on the evolution of the atmospheric partial $CO_2$ pressure, and the ability of a long-term carbon cycle driven by plate tectonics to control the atmospheric $CO_2$ pressure. Methods: We developed a box-model which connects carbon cycling to parametrized mantle convection. The carbon cycl…
Low-spin ferrous iron suppresses mantle oxidation beyond Earth-like pressures
ETH Zürich（苏黎世联邦理工学院）；European Synchrotron Radiation Facility（欧洲同步辐射装置）；Université Paris Cité, Institut de Physique du Globe de Paris, CNRS（巴黎西岱大学，巴黎地球物理研究所，法国国家科学研究中心）；Nantes Université, Univ Angers, Le Mans Université, CNRS, Laboratoire de Planétologie et Géosciences, LPG UMR 6112（南特大学，昂热大学，勒芒大学，法国国家科学研究中心，行星学与地质学实验室）；School of Earth, Atmosphere and Environment, Monash University（蒙纳士大学地球、大气与环境学院）；Guangzhou Institute of Geochemistry, Chinese Academy of Sciences（中国科学院广州地球化学研究所）
The accretion of a terrestrial body and differentiation of its silicate/oxide mantle from iron core provide abundant energy for heating its interior to temperatures much higher than the present day Earth. The consequences of differentiation on the structure and composition of planets are typically addressed considering only the interaction of molten iron with an immiscible `rocky' phase. We demonstrate that mixing in a representative system of liquid or solid MgO and liquid iron to a single homogeneous liquid occurs at sufficiently low temperature to be present in the aftermath of a giant impa…
Overabundances in highly siderophile elements (HSEs) of Earth's mantle can be explained by conveyance from a singular, immense (3000 km in a diameter) "Late Veneer" impactor of chondritic composition, subsequent to lunar formation and terrestrial core-closure. Such rocky objects of approximately lunar mass (about 0.01 M_E) ought to be differentiated, such that nearly all of their HSE payload is sequestered into iron cores. Here, we analyze the mechanical and chemical fate of the core of such a Late Veneer impactor, and trace how its HSEs are suspended - and thus pollute - the mantle. For the s…
Internal redox reactions may irreversibly alter the mantle composition and volatile inventory of terrestrial and super-Earth exoplanets and affect the prospects for atmospheric observations. The global efficacy of these mechanisms, however, hinges on the transfer of reduced iron from the molten silicate mantle to the metal core. Scaling analysis indicates that turbulent diffusion in the internal magma oceans of sub-Neptunes can kinetically entrain liquid iron droplets and quench core formation. This suggests that the chemical equilibration between core, mantle, and atmosphere may be energetica…
Composition of terrestrial planets records planetary accretion, core-mantle and crust-mantle differentiation, and surface processes. Here we compare the compositional models of Earth and Mars to reveal their characteristics and formation processes. Earth and Mars are equally enriched in refractory elements (1.9 $\times$ CI), although Earth is more volatile-depleted and less oxidized than Mars. Their chemical compositions were established by nebular fractionation, with negligible contributions from post-accretionary losses of moderately volatile elements. The degree of planetary volatile elemen…
