We model the emission of methyl cyanide (CH3CN) lines towards the massive hot molecular core SgrB2(M). We aim at reconstructing the CH3CN abundance field and investigating the gas temperature distribution as well as the velocity field. SgrB2(M) was observed with the ALMA in a spectral line survey from 211 to 275 GHz. This frequency range includes several transitions of CH3CN (including isotopologues and vibrationally excited states). We employ the three-dimensional radiative transfer toolbox Pandora in order to retrieve the velocity and abundance field by modeling different CH3CN lines. For this purpose, we base our model on the results of a previous study that determined the physical structure of SgrB2(M), i.e.\ the distribution of dust dense cores, ionized regions and heating sources. The morphology of the CH3CN emission can be reproduced by a molecular density field that consists of a superposition of cores with modified Plummer-like density profiles. The averaged relative abundance of CH3CN with respect to H2 ranges from 4x10^{-11} to 2x10^{-8} in the northern part of SgrB2(M) and from 2x10^{-10} to 5x10^{-7} in the southern part. In general, we find that the relative abundance of CH3CN is lower at the center of the very dense and hot cores, causing the general morphology of the CH3CN emission to be shifted with respect to the dust continuum emission. The dust temperature calculated by the radiative transfer simulation based on the available luminosity reaches values up to 900 K. However, in some regions vibrationally excited transitions of CH3CN are underestimated by the model, indicating that the predicted gas temperature, which is assumed to be equal to the dust temperature, is partly underestimated. The determination of the velocity component along the line of sight reveals that a velocity gradient from the north to the south exists in SgrB2(M).
Methyl cyanide (CH3CN) and propyne (CH3CCH) are two molecules commonly used as gas thermometers for interstellar gas. They are detected in several astrophysical environments and in particular towards protostars. Using data of the low-mass protostar IRAS 16293-2422 obtained with the IRAM 30m single-dish telescope, we constrained the origin of these two molecules in the envelope of the source. The line shape comparison and the results of a radiative transfer analysis both indicate that the emission of CH3CN arises from a warmer and inner region of the envelope than the CH3CCH emission. We compar…
The saturated n-propyl cyanide was recently detected in Sagittarius B2(N). The next larger unbranched alkyl cyanide is n-butyl cyanide. We provide accurate rest frequency predictions beyond the millimeter wave range to search for this molecule in the Galactic center source Sagittarius B2(N) and facilitate its detection in space. We investigated the laboratory rotational spectrum of $n$-butyl cyanide between 75 GHz and 348 GHz. We searched for emission lines produced by the molecule in our sensitive IRAM 30 m molecular line survey of Sagittarius B2(N). We identified more than one thousand rotat…
Complex Organic Molecules in Protostars with ALMA Spectral Surveys (COMPASS) -- IV. Methyl cyanide isotopologues toward BHR71-IRS1
European Southern Observatory（欧洲南方天文台）；Institut de Recherche en Astrophysique et Planétologie（天体物理与行星学研究所）；Université de Toulouse（图卢兹大学）；CNRS（法国国家科学研究中心）；CNES（法国国家空间研究中心）；Niels Bohr Institute（尼尔斯·玻尔研究所）；University of Copenhagen（哥本哈根大学）；Max-Planck-Institut für Radioastronomie（马克斯·普朗克射电天文学研究所）；National Radio Astronomy Observatory（美国国家射电天文台）；Univ. Grenoble Alpes（格勒诺布尔阿尔卑斯大学）；IPAG（格勒诺布尔天体物理与行星学研究所）；National Tsinghua University（国立清华大学）；Physikalisch-Meteorologisches Observatorium Davos und Weltstrahlungszentrum (PMOD/WRC)（达沃斯物理气象观测站暨世界辐射中心）；Universität Bern（伯尔尼大学）；Seoul National University（首尔国立大学）
Methyl cyanide is an important trace molecule in space, especially in star-forming regions where it is one of the more common molecules used to derive kinetic temperatures. We want to obtain accurate spectroscopic parameters of minor isotopologs of methyl cyanide in their lowest excited $v_8 = 1$ vibrational states to support astronomical observations, in particular, with interferometers such as ALMA. The laboratory rotational spectrum of methyl cyanide in natural isotopic composition has been recorded from the millimeter to the terahertz regions. Transitions with good signal-to-noise ratios c…
In order to study the temperature distribution of the extended gas within the Orion Kleinmann-Low nebula, we have mapped the emission by methyl cyanide (CH3CN) in its J=6_K-5_K, J=12_K-11_K, J=13_K-12_K, and J=14_K-13_K transitions at an average angular resolution of ~10 arcsec (22 arcsec for the 6_K-5_K lines), as part of a new 2D line survey of this region using the IRAM 30m telescope. These fully sampled maps show extended emission from warm gas to the northeast of IRc2 and the distinct kinematic signatures of the hot core and compact ridge source components. We have constructed population …
Methyl cyanide is an important trace molecule in star-forming regions. It is one of the more common molecules used to derive kinetic temperatures in such sources. As preparatory work for Herschel, SOFIA, and in particular ALMA we want to improve the rest frequencies of the main as well as minor isotopologs of methyl cyanide. The laboratory rotational spectrum of methyl cyanide in natural isotopic composition has been recorded up to 1.63 THz. Transitions with good signal-to-noise ratio could be identified for CH$_3$CN, $^{13}$CH$_3$CN, CH$_3^{13}$CN, CH$_3$C$^{15}$N, CH$_2$DCN, and $^{13}$CH$_3…
A non-LTE radiative transfer treatment of cis-methyl formate (HCOOCH3) rotational lines is presented for the first time using a set of theoretical collisional rate coefficients. These coefficients have been computed in the temperature range 5-30 K by combining coupled-channel scattering calculations with a high accuracy potential energy surface for HCOOCH3-He. The results are compared to observations toward the Sagittarius B2(N) molecular cloud using the publicly available PRIMOS survey from the Green Bank Telescope. A total of 49 low-lying transitions of methyl formate, with upper levels belo…
We report the results of a survey in the CH3CN J= 12-11 transition toward a sample of massive proto-stellar candidates. The observations were carried out with the 10 m Submillimeter telescope on Mount Graham, AZ. We detected this molecular line in 9 out of 21 observed sources. In six cases this is the first detection of this transition. We also obtained full beam sampled cross-scans for five sources which show that the lower K-components can be extended on the arcminute angular scale. The higher K-components however are always found to be compact with respect to our 36" beam. A Boltzmann popul…
Deuteration is a powerful tracer of the history of the cold prestellar phase in star forming regions. Apart from methanol, little is known about deuterium fractionation of complex organic molecules in the interstellar medium, especially in high mass star forming regions. We use a spectral line survey performed with ALMA to search for deuterated complex organic molecules toward the hot molecular core Sgr B2(N2). Population diagrams and integrated intensity maps are constructed to fit rotational temperatures and emission sizes for each molecule. Column densities are derived by modelling the full…
We performed a spectral line survey called Exploring Molecular Complexity with ALMA (EMoCA) toward Sagittarius~B2(N) between 84.1 and 114.4 GHz with the Atacama Large Millimeter/submillimeter Array (ALMA) in its Cycles 0 and 1. We determined line intensities of n-propyl cyanide in the ground vibrational states of its gauche and anti conformers toward the hot molecular core Sagittarius B2(N2) which suggest that we should also be able to detect transitions pertaining to excited vibrational states. We wanted to determine spectroscopic parameters of low-lying vibrational states of both conformers …
The TOPGöt project studies a sample of 86 high-mass star-forming regions in different evolutionary stages from starless cores to ultra compact HII regions. The aim of the survey is to analyze different molecular species in a statistically significant sample to study the chemical evolution in high-mass star-forming regions, and identify chemical tracers of the different phases. The sources have been observed with the IRAM 30m telescope in different spectral windows at 1, 2, and 3 mm. In this first paper, we present the sample and analyze the spectral energy distributions (SEDs) of the TOPGöt so…
New and existing rotational spectra of methyl cyanide were analyzed to extend the global model of low-lying vibrational states and their interactions to $v_4=1$ at 920 cm$^{-1}$. The rotational spectra cover large portions of the 36$-$1439 GHz region and reach quantum numbers $J$ and $K$ of 79 and 16, respectively. Information on the $K$ level structure of CH$_3$CN is obtained from IR spectra. A spectrum of $2ν_8$ around 717 cm$^{-1}$, analyzed in our previous study, covered also the $ν_4$ band. The assignments in this band cover 880$-$952 cm$^{-1}$, attaining quantum numbers $J$ and $K$ of 61…
The increasing sensitivity and resolution of ground-based telescopes have enabled the detection of gas-phase complex organic molecules (COMs) across a variety of environments. Many of the detected species are expected to form on the icy surface of interstellar grains and transfer later into the gas phase. Therefore, icy material is regarded as a primordial source of COMs in the ISM. Upcoming JWST observations of interstellar ices in star-forming regions will reveal IR features of frozen molecules with unprecedented resolution and sensitivity. To identify COM features in the JWST data, lab IR s…
The discovery of amino acids in meteorites and the detection of glycine in samples returned from a comet to Earth suggest that the interstellar chemistry is capable of producing such complex organic molecules. Our goal is to investigate the degree of chemical complexity that can be reached in the ISM. We performed an unbiased, spectral line survey toward Sgr B2(N) and (M) with the IRAM 30m telescope in the 3mm window. The spectra were analyzed with a simple radiative transfer model that assumes LTE but takes optical depth effects into account. About 3675 and 945 spectral lines with a peak sign…
Methyl isocyanide (CH$_3$NC) is the isocyanide with the largest number of atoms confirmed in the interstellar medium (ISM), but it is not an abundant molecule, having only been detected towards a handful of objects. Conversely, its isomer, methyl cyanide (CH$_3$CN), is one of the most abundant complex organic molecules detected in the ISM, with detections in a variety of low- and high-mass sources. We use ALMA observations from the Protostellar Interferometric Line Survey (PILS) to search for methyl isocyanide and compare its abundance with that of its isomer methyl cyanide. We use a new line …
In recent years, organic molecules of increasing complexity have been found toward the prolific Galactic center source Sagittarius B2. We wish to explore the degree of complexity that the interstellar chemistry can reach in star-forming regions. We carried out a complete line survey of the hot cores Sgr B2(N) and (M) with the IRAM 30 m telescope in the 3 mm range. We analyzed this spectral survey in the LTE approximation. We modeled the emission of all known molecules simultaneously, which allows us to search for less abundant, more complex molecules. We compared the derived column densities w…
Spectra of methyl cyanide were recorded to analyze interactions in low-lying vibrational states and to construct line lists for radio astronomical observations as well as for infrared spectroscopic investigations of planetary atmospheres. The rotational spectra cover large portions of the 36$-$1627 GHz region. In the infrared (IR), a spectrum was recorded for this study in the region of 2$ν_8$ around 717 cm$^{-1}$ with assignments covering 684$-$765 cm$^{-1}$. Additional spectra in the $ν_8$ region were used to validate the analysis. The large amount and the high accuracy of the rotational dat…
Methyl mercaptan (CH3SH) is a known interstellar molecule with abundances high enough that the detection of some of its minor isotopologues is promising. The present study aims at providing accurate spectroscopic parameters for the (13)CH3SH isotopologue to facilitate its identification in the interstellar medium at millimetre and submillimetre wavelengths. Through careful analysis of recent CH3SH spectra from 49-510 GHz and 1.1-1.5 THz recorded at natural isotopic composition, extensive assignments were possible not only for the ground torsional state of (13)CH3SH, but also in the first and s…
It has recently been suggested that chemical processing can shape the spatial distributions of complex molecules in the Orion-KL region and lead to the nitrogen-oxygen "chemical differentiation" seen in previous observations of this source. Orion-KL is a very dynamic region, and it is therefore also possible that physical conditions can shape the molecular distributions in this source. Only high spatial resolution observations can provide the information needed to disentangle these effects. Here we present millimeter imaging studies of Orion-KL at various beam sizes using the Combined Array fo…
The rotational spectrum of the higher-energy trans conformational isomer of methyl formate has been assigned for the first time using several pulsed-jet Fourier transform microwave spectrometers in the 6-60 GHz frequency range. This species has also been sought toward the Sagittarius B2(N) molecular cloud using the publicly available PRIMOS survey from the Green Bank Telescope. We detect seven absorption features in the survey that coincide with laboratory transitions of trans-methyl formate, from which we derive a column density of 3.1 (+2.6, -1.2) \times 10^13 cm-2 and a rotational temperatu…
Complex organic molecules are readily detected in the inner regions of the gaseous envelopes of forming protostars. In particular, molecules that contain nitrogen are interesting due to the role nitrogen plays in the development of life and the compact scales such molecules have been found to trace around forming protostars. The goal of this work is to determine the inventory of one family of nitrogen-bearing organic molecules, complex nitriles (molecules with a $-$CN functional group) towards two hot corino sources in the low-mass protostellar binary IRAS 16293$-$2422. This work explores the …
In the search for the building blocks of life, nitrogen-bearing molecules are of particular interest since nitrogen-containing bonds are essential for the linking of amino acids and ultimately the formation of larger biological structures. The elusive molecule methylamine (CH$_3$NH$_2$) is thought to be a key pre-biotic species but has so far only been securely detected in the giant molecular cloud Sgr B2. We identify CH$_3$NH$_2$ and other simple nitrogen-bearing species towards three hot cores in NGC 6334I. Column density ratios are derived in order to investigate the relevance of the indivi…
Rate constants have been measured for the C(3P) + CH3CN reaction between 50 K and 296 K using a continuous-flow supersonic reactor. C(3P) atoms were created by the in-situ pulsed laser photolysis of CBr4 at 266 nm, while the kinetics of C(3P) atom loss were followed by direct vacuum ultra-violet laser induced fluorescence at 115.8 nm. Secondary measurements of product H(2S) atom formation were also made, allowing absolute H-atom yields to be obtained by comparison with those obtained for the C(3P) + C2H4 reference reaction. In parallel, quantum chemical calculations were performed to obtain th…
Digging into the Massive Protostar S255IR NIRS3: A Study of Nitrogen-Bearing Molecules and Their Prebiotic Chemistry
S. N. Bose National Centre for Basic Sciences（S.N. 玻色基础科学国家中心）；Midnapore City College（金奈浦城市学院）；Dinabandhu Andrews Institute of Technology and Management（迪南德胡·安德鲁斯技术与管理学院）；Sidho Kanho Birsha University（西多·坎霍·比尔沙大学）
Almost 200 different species have been detected in the interstellar medium (ISM) during the last decades, revealing not only simple species but complex molecules with more than 6 atoms. Other exotic compounds, like the weakly-bound dimer (H2)2, have also been detected in astronomical sources like Jupiter. We aim at detecting for the first time the CO-H2 van der Waals complex in the ISM, which if detected can be a sensitive indicator for low temperatures. We use the IRAM30m telescope, located in Pico Veleta (Spain), to search for the CO-H2 complex in a cold, dense core in TMC-1C (with a tempera…
Classical hot cores are rich in molecular emission, and they show a high abundance of complex organic molecules (COMs). The emergence of molecular complexity is poorly constrained in the early evolution of hot cores. Using the Atacama Large Millimeter Array we put observational constraints on the physical location of COMs in a high-mass protostellar envelope associated with the G328.2551-0.5321 clump. The protostar is single down to ~400au scales and we resolve the emission region of COMs. Using thermodynamic equilibrium modelling of the available 7.5 GHz bandwidth around ~345 GHz, we detect e…
Determining the level of chemical complexity within dense starless and gravitationally bound prestellar cores is crucial for constructing chemical models, which subsequently constrain the initial chemical conditions of star formation. We have searched for complex organic molecules (COMs) in the young starless core L1521E, and report the first clear detection of dimethyl ether (CH$_3$OCH$_3$), methyl formate (HCOOCH$_3$), and vinyl cyanide (CH$_2$CHCN). Eight transitions of acetaldehyde (CH$_3$CHO) were also detected, five of which (A states) were used to determine an excitation temperature to …
ALMA Observations of Molecular Complexity in the Large Magellanic Cloud: The N83 Star-Forming Region
NASA Goddard Space Flight Center（美国宇航局戈达德太空飞行中心）；University of Maryland, College Park（马里兰大学帕克分校）；Center for Research and Exploration in Space Science and Technology, NASA Goddard Space Flight Center（空间科学与技术研究探索中心，美国宇航局戈达德太空飞行中心）；Astrochemistry Laboratory, NASA Goddard Space Flight Center（天体化学实验室，美国宇航局戈达德太空飞行中心）；Kagawa University（香川大学）；University of Virginia（弗吉尼亚大学）；Keele University（基尔大学）
NGC 7129 FIRS 2 (hereafter FIRS 2) is an intermediate-mass (2 to 8 Msun) protostar located at a distance of 1250 pc. High spatial resolution observations are required to resolve the hot core at its center. We present a molecular survey from 218200 MHz to 221800 MHz carried out with the IRAM Plateau de Bure Interferometer. These observations were complemented with a long integration single-dish spectrum taken with the IRAM 30m telescope. We used a Local Thermodynamic Equilibrium (LTE) single temperature code to model the whole dataset. The interferometric spectrum is crowded with a total of ~30…
We studied the line emission from CH3CN and its deuterated isotopologue CH$_2$DCN towards the prototypical Class I object SVS13-A, where the deuteration of a large number of species has already been reported. Our goal is to measure the CH$_3$CN deuteration in a Class I protostar, for the first time, in order to constrain the CH$_3$CN formation pathways and the chemical evolution from the early prestellar core and Class 0 to the evolved Class I stages. We imaged CH2DCN towards SVS13-A using the IRAM NOEMA interferometer at 3mm in the context of the Large Program SOLIS (with a spatial resolution…
This study is part of the project ``CORE'', an IRAM/NOEMA large program consisting of observations of the millimeter continuum and molecular line emission towards 20 selected high-mass star forming regions. We focus on IRAS23385+6053, which is believed to be the least evolved source of the CORE sample. The observations were performed at ~1.4 mm and employed three configurations of NOEMA and additional single-dish maps, merged with the interferometric data to recover the extended emission. Our correlator setup covered a number of lines from well-known hot core tracers and a few outflow tracers.…
