A fluctuating interfacial profile in one dimension is studied via Langevin simulations of the Edwards-Wilkinson equation with non-conserved noise and the Mullins-Herring equation with conserved noise. The profile is subject to either periodic or Dirichlet (no-flux) boundary conditions. We determine the noise-driven time-evolution of the profile between an initially flat configuration and the instant at which the profile reaches a given height $M$ for the first time. The shape of the averaged profile agrees well with the prediction of weak-noise theory (WNT), which describes the most-likely trajectory to a fixed first-passage time. Furthermore, in agreement with WNT, on average the profile approaches the height $M$ algebraically in time, with an exponent that is essentially independent of the boundary conditions. However, the actual value of the dynamic exponent turns out to be significantly smaller than predicted by WNT. This "renormalization" of the exponent is explained in terms of the entropic repulsion exerted by the impenetrable boundary on the fluctuations of the profile around its most-likely path. The entropic repulsion mechanism is analyzed in detail for a single (fractional) Brownian walker, which describes the anomalous diffusion of a tagged monomer of the interface as it approaches the absorbing boundary. The present study sheds light on the accuracy and the limitations of the weak-noise approximation for the description of the full first-passage dynamics.
We consider Dyson models, Ising models with slow polynomial decay, at low temperature and show that its Gibbs measures deep in the phase transition region are not $g$-measures. The main ingredient in the proof is the occurrence of an entropic repulsion effect, which follows from the mesoscopic stability of a (single-point) interface for these long-range models in the phase transition region.
Contours associated to many interesting low-temperature statistical mechanics models (2D Ising model, (2+1)D SOS interface model, etc) can be described as self-interacting and self-avoiding walks on $\mathbb Z^2$. When the model is defined in a finite box, the presence of the boundary induces an interaction, that can turn out to be attractive, between the contour and the boundary of the box. On the other hand, the contour cannot cross the boundary, so it feels entropic repulsion from it. In various situations of interest a crucial technical problem is to prove that entropic repulsion prevails …
We consider near-critical two-dimensional statistical systems at phase coexistence on the half plane with boundary conditions leading to the formation of a droplet separating coexisting phases. General low-energy properties of two-dimensional field theories are used in order to find exact analytic results for one- and two-point correlation functions of both the energy density and order parameter fields. The subleading finite-size corrections are also computed and interpreted within an exact probabilistic picture in which interfacial fluctuations are characterized by the probability density of …
Consider the free field on a fractal graph based on a high-dimensional Sierpinski carpet (e.g. the Menger sponge), that is, a centered Gaussian field whose covariance is the Green's function for simple random walk on the graph. Moreover assume that a "hard wall" is placed at height zero so that the field stays positive everywhere. We prove the leading-order asymptotics for the local sample mean of the free field above the hard wall on any transient Sierpinski carpet graph, thereby extending a result of Bolthausen, Deuschel, and Zeitouni for the free field on $\mathbb{Z}^d$, $d \geq 3$, to the …
Floppy Networks (FNs) provide valuable insight into the origin of anomalous mechanical and thermal properties in soft matter systems, from polymers, rubber, and biomolecules to glasses and granular materials. Here, we use the very same FN concept to construct a quantitative microscopic theory of empty perovskites, a family of crystals with ReO$_3$ structure, which exhibit a number of unusual properties. One remarkable example is ScF$_3$, which shows a near-zero-temperature structural instability and large negative thermal expansion (NTE). We trace these effects to an FN-like crystalline archit…
Understanding interactions between membranes requires measurements on well-controlled systems close to natural conditions, in which fluctuations play an important role. We have determined, by grazing incidence X-ray scattering, the interaction potential between two lipid bilayers, one adsorbed on a solid surface and the other floating close by. We find that interactions in this highly hydrated model system are two orders of magnitude softer than in previously reported work on multilayer stacks. This is attributed to the weak electrostatic repulsion due to the small fraction of ionized lipids i…
We study a driven, spin-orbit coupled fermionic system in a lattice at the resonant regime where the drive frequency equals the Hubbard repulsion, for which non-trivial constrained dynamics emerge at fast timescales. An effective density-dependent tunneling model is derived, and examined in the sparse filling regime in 1D. The system exhibits entropic self-localization, where while even numbers of atoms propagate ballistically, odd numbers form localized bound states induced by an effective attraction from a higher configurational entropy. These phenomena occur in the strong coupling limit whe…
Non-equilibrium fluctuations of various stochastic variables, such as work and entropy production, have been widely discussed recently in the context of large deviations, cumulants and fluctuation relations. Typically, one looks at the distribution of these observables, at large fixed time. To characterize the precise stochastic nature of the process, we here address the distribution in the time domain. In particular, we focus on the first passage time distribution (FPTD) of entropy production, in several realistic models. We find that the fluctuation relation symmetry plays a crucial role in …
The paper addresses Brownian motion in the logarithmic potential with time-dependent strength, $U(x,t) = g(t) \log(x)$, subject to the absorbing boundary at the origin of coordinates. Such model can represent kinetics of diffusion-controlled reactions of charged molecules or escape of Brownian particles over a time-dependent entropic barrier at the end of a biological pore. We present a simple asymptotic theory which yields the long-time behavior of both the survival probability (first-passage properties) and the moments of the particle position (dynamics). The asymptotic survival probability,…
We study the crossing time statistic of diffusing point particles between the two ends of expanding and narrowing two-dimensional conical channels under a transverse external gravitational field. The theoretical expression for the mean first-passage time for such a system is derived under the assumption that the axial diffusion in a two-dimensional channel of smoothly varying geometry can be approximately described as a one-dimensional diffusion in an entropic potential with position-dependent effective diffusivity in terms of the modified Fick-Jacobs equation. We analyze the channel crossing …
The Fermi-Pasta-Ulam (FPU) one-dimensional Hamiltonian includes a quartic term which guarantees ergodicity of the system in the thermodynamic limit. Consistently, the Boltzmann factor $P(ε) \sim e^{-βε}$ describes its equilibrium distribution of one-body energies, and its velocity distribution is Maxwellian, i.e., $P(v) \sim e^{- βv^2/2}$. We consider here a generalized system where the quartic coupling constant between sites decays as $1/d_{ij}^α$ $(α\ge 0; d_{ij} = 1,2,\dots)$. Through {\it first-principle} molecular dynamics we demonstrate that, for large $α$ (above $α\simeq 1$), i.e., shor…
Graphene monolayer, with extremely low flexural stiffness, displays spontaneous rippling due to thermal fluctuations at a finite temperature. When a graphene membrane is placed on a solid substrate, the adhesive interactions between graphene and the substrate could considerably suppress thermal rippling. On the other hand, the statistical nature of thermal rippling adds an entropic contribution to the graphene-substrate interactions. In this paper we present a statistical mechanics analysis on thermal rippling of monolayer graphene supported on a rigid substrate, assuming a generic form of van…
We study the entropy time evolution of a quantum mechanical model, which is frequently used as a prototype for Anderson's localization. Recently Latora and Baranger [V. Latora, M. Baranger, Phys. Rev.Lett. 82, 520(1999)] found that there exist three entropy regimes, a transient regime of passage from dynamics to thermodynamics, a linear in time regime of entropy increase, namely a thermodynamic regime of Kolmogorov kind, and a saturation regime. We use the non-extensive entropic indicator recently advocated by Tsallis [ C. Tsallis, J. Stat. Phys. 52, 479 (1988)] with a mobile entropic index q,…
We study the dynamics of the passage of a polymer through a membrane pore (translocation), focusing on the scaling properties with the number of monomers $N$. The natural coordinate for translocation is the number of monomers on one side of the hole at a given time. Commonly used models which assume Brownian dynamics for this variable predict a mean (unforced) passage time $τ$ that scales as $N^2$, even in the presence of an entropic barrier. However, the time it takes for a free polymer to diffuse a distance of the order of its radius by Rouse dynamics scales with an exponent larger than 2, a…
When does a diffusing particle reach its target for the first time? This first-passage time (FPT) problem is central to the kinetics of molecular reactions in chemistry and molecular biology. Here we explain the behavior of smooth FPT densities, for which all moments are finite, and demonstrate universal yet generally non-Poissonian long-time asymptotics for a broad variety of transport processes. While Poisson-like asymptotics arise generically in the presence of an effective repulsion in the immediate vicinity of the target, a time-scale separation between direct and reflected indirect traje…
We consider a lattice model of a mixture of repulsive, attractive, or neutral monodisperse star (species A) and linear (species B) polymers with a third monomeric species C, which may represent free volume. The mixture is next to a hard, infinite plate whose interactions with A and C can be attractive, repulsive, or neutral. These two interactions are the only parameters necessary to specify the effect of the surface on all three components. We numerically study monomer density profiles using the method of Gujrati and Chhajer that has already been previously applied to study polydisperse and m…
