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arXiv 1704.05705cond-mat.str-el
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自旋链化合物Cu(py)$_2$ Br $_2$的各向异性磁相互作用和自旋动力学:实验和理论研究

Anisotropic magnetic interactions and spin dynamics in the spin-chain compound Cu(py)$_2$Br$_2$: An experimental and theoretical study

J. Zeisner, M. Brockmann, S. Zimmermann, A. Weiße, M. Thede, E. Ressouche, K. Yu. Povarov, A. Zheludev, A. Klümper, B. Büchner, V. Kataev, F. Göhmann

摘要:

我们比较了准一维磁体Cu(py)$_2$ Br $_2$(CPB)的电子自旋共振(ESR)性质的理论结果和ESR实验结果.我们的测量在很宽的频率和温度范围内进行,深入了解这种化合物的自旋动力学,自旋结构和磁各向异性。通过分析室温下ESR参数(共振位移和线宽)的角度依赖性,我们发现化合物内部的两种弱耦合的不等价自旋链可以用Heisenberg-Ising链很好地描述,它们的磁各向异性轴垂直于链方向,并且几乎相互垂直。我们进一步从这些数据中确定完整的$g$张量。此外,在高温下的线宽的角度依赖性给我们访问的指数的各向同性海森堡链的动态关联函数的代数衰减。从静态磁化率的温度依赖性,我们提取的交换耦合的强度($J/k_B = 52.0\,\text{K}$)和各向异性参数($δ\approx -0.02$)的模型哈密顿量。一个独立的兼容值$δ$是通过比较准确的预测在低温下的共振位移与高频ESR数据记录在$4\,\text{K}$。由两个(几乎)垂直的各向异性轴所暗示的有序状态下的自旋结构与中子散射实验确定的传播矢量一致。除了未掺杂的样品,我们研究了部分取代Br的Cl离子的自旋动力学的影响。从ESR线宽对掺杂水平的依赖关系,我们推断出在这些系统中的各向同性交换$J$的各向异性组件$Jδ$的有效去耦。

英文摘要:

We compare theoretical results for electron spin resonance (ESR) properties of the Heisenberg-Ising Hamiltonian with ESR experiments on the quasi-one-dimensional magnet Cu(py)$_2$Br$_2$ (CPB). Our measurements were performed over a wide frequency and temperature range giving insight into spin dynamics, spin structure, and magnetic anisotropy of this compound. By analyzing the angular dependence of ESR parameters (resonance shift and linewidth) at room temperature we show that the two weakly coupled inequivalent spin chain types inside the compound are well described by Heisenberg-Ising chains with their magnetic anisotropy axes perpendicular to the chain direction and almost perpendicular to each other. We further determine the full $g$-tensor from these data. In addition, the angular dependence of the linewidth at high temperatures gives us access to the exponent of the algebraic decay of a dynamical correlation function of the isotropic Heisenberg chain. From the temperature dependence of static susceptibilities we extract the strength of the exchange coupling ($J/k_B = 52.0\,\text{K}$) and the anisotropy parameter ($δ\approx -0.02$) of the model Hamiltonian. An independent compatible value of $δ$ is obtained by comparing the exact prediction for the resonance shift at low temperatures with high-frequency ESR data recorded at $4\,\text{K}$. The spin structure in the ordered state implied by the two (almost) perpendicular anisotropy axes is in accordance with the propagation vector determined from neutron scattering experiments. In addition to undoped samples we study the impact of partial substitution of Br by Cl ions on spin dynamics. From the dependence of the ESR linewidth on doping level we infer an effective decoupling of the anisotropic component $Jδ$ from the isotropic exchange $J$ in these systems.

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