Aims. We aim to understand the unexpected presence of mm-wave molecular absorption at -200 \kms $< {\rm v} < -140$ \kms\ in a direction that is well away from regions of the Galactic bulge where CO emission at such velocities is prominent.
Methods. We compared 89 GHz Cycle 2 ALMA absorption spectra of \hcop, HCN, and HNC toward the extragalactic continuum source B1741-312 at l=-2.14\degr, b=-1.00\degr\ with existing CO, H I, and dust emission and absorption measurements. We placed the atomic and molecular gas in the bulge and disk using circular and non-circular galactic kinematics, deriving N(H I) from a combination of 21cm emission and absorption and we derive N(\HH) from scaling of the \hcop\ absorption. We then inverted the variation of near-IR reddening E(J-K) with distance modulus and scale E(J-K) to a total gas column density N(H) that may be compared to N(H I) and N(\HH).
Results. At galactocentric radii \Rgal\ $>$ 1.5 kpc, conventional measures such as the standard CO-\HH\ conversion factor and locally observed N(\hcop)/N(\HH) ratio separately imply that H I and \HH\ contribute about equally to N(H), and the gas-derived N(H) values are in broad agreement with those derived from E(J-K). Within the Galactic bulge at \Rgal $<$ 1.5 kpc, H I contributes less than 10\% of the material inferred from E(J-K), so that the molecular absorption detected here is needed to understand the extinction.
Alma Cycle 3 observations showed strong absorption from diffuse molecular gas in the bulge at -200 \kms\ $< {\rm v} < -140$ \kms\ toward J1744-3116 (l,b)= (-2.13d,-1d) We aimed to test if bulge molecular gas could also be seen toward the three other sufficiently strong mm-wave sources seen toward the bulgeat $|b| < 3$°We took absorption profiles of \hcop (1-0) and other species in ALMA Cy 4 toward J1713-3418, J1717-3341, J1733-3722 and J1744-3116. Strong molecular absorption from disk gas at $|\rmv| \la 30$ \kms\ was detected in all directions, and absorption from the 3 kpc arm was newly detec…
The star formation efficiency (SFE) has been shown to vary across different environments, particularly within galactic starbursts and deep within the bulges of galaxies. Various quenching mechanisms may be responsible, ranging from galactic dynamics to feedback from active galactic nuclei (AGN). Here, we use spatially-resolved observations of warm ionised gas emission lines from the imaging Fourier transform spectrograph SITELLE at the Canada-France-Hawaii Telescope (CFHT) and cold molecular gas (CO(2-1)) from the Atacama Large Millimeter/sub-millimeter Array (ALMA) to study the SFE in the bul…
Recent studies have revealed a strong relation between sample-averaged black-hole (BH) accretion rate (BHAR) and star formation rate (SFR) among bulge-dominated galaxies, i.e., "lockstep" BH-bulge growth, in the distant universe. This relation might be closely related to the BH-bulge mass correlation observed in the local universe. To understand further BH-bulge coevolution, we present ALMA CO(2-1) or CO(3-2) observations of 7 star-forming bulge-dominated galaxies at z=0.5-2.5. Using the ALMA data, we detect significant ($>3σ$) CO emission from 4 objects. For our sample of 7 galaxies, we measu…
We report on the first 1,432 sources observed using the Atacama Large Millimeter/submillimeter Array (ALMA), from the Bulge Asymmetries and Dynamical Evolution (BAaDE) survey, which aims to obtain tens of thousands of line-of-sight velocities from SiO masers in Asymptotic Giant Branch (AGB) stars in the Milky Way. A 71% detection rate of 86 GHz SiO masers is obtained from the infrared color-selected sample, and increases to 80% when considering the likely oxygen-rich stars using Midcourse Space Experiment (MSX) colors isolated in a region where [D]-[E] <= 1.38. Based on Galactic distributions,…
We study the role of cold gas in quenching star formation in the green valley by analysing ALMA $^{12}$CO (1-0) observations of three galaxies with resolved optical spectroscopy from the MaNGA survey. We present resolution-matched maps of the star formation rate and molecular gas mass. These data are used to calculate the star formation efficiency (SFE) and gas fraction ($f_{\rm~gas}$) for these galaxies separately in the central `bulge' regions and outer disks. We find that, for the two galaxies whose global specific star formation rate (sSFR) deviates most from the star formation main sequen…
Context: The bulk of the Molecular gas in the Central Molecular Zone (CMZ) of the Galactic center region shows warm kinetic temperatures, ranging from $>20$ K in the coldest and densest regions (n$\sim 10^{4-5}$ cm$^{-3}$) up to more than 100 K for densities of about n$\sim 10^3$ cm$^{-3}$. Recently, a more diffuse, hotter ($n \sim 100$ cm$^{-3}$, $T\sim 250$ K) gas component was discovered through absorption observations of H$_3^+$. This component may be widespread in the Galactic center, and low density gas detectable in absorption may be present even outside the CMZ along sightlines crossin…
The recent ALMA DSHARP survey provided illuminating results on the diversity of substructures in planet forming disks. These substructures trace pebble-sized grains accumulated at local pressure maxima, possibly due to planet-disk interactions or other planet formation processes. DSHARP sources are heavily biased to large and massive disks that only represent the high (dust flux) tail end of the disk population. Thus it is unclear whether similar substructures and corresponding physical processes also occur in the majority of disks which are fainter and more compact. Here we explore the presen…
We present observations and analysis of an unusual [C II] emission line in the very luminous QSO SDSS J155426.16+193703.0 at z~4.6. The line is extremely broad (FWHM 735 km/s) and seems to have a flat-topped or double-peaked line profile. A velocity map of the line shows a gradient across the source that indicates large-scale rotation of star-forming gas. Together, the velocity map and line profile suggest the presence of a massive rotating disc with a dynamical mass M_dyn > 5x10^10 M_sun. Using the assumption of a rotating disc origin, we employ an empirical relation between galaxy disc circu…
We present a dynamical analysis of a quasar-host galaxy at $z\simeq 6$ (SDSS J2310+1855) using a high-resolution ALMA observation of the [CII] emission line. The observed rotation curve was fitted with mass models that considered the gravitational contribution of a thick gas disc, a thick star-forming stellar disc, and a central mass concentration, which is likely due to a combination of a spheroidal component (i.e. a stellar bulge) and a supermassive black hole (SMBH). The SMBH mass of $5\times 10^9\ \rm M_{\odot}$, previously measured using the CIV and MgII emission lines, is not sufficient …
We have combined optical and near-infrared data of known RR Lyrae (RRL) stars in the bulge in order to study the spatial distribution of its metal-poor component by measuring precise reddening values and distances of 7663 fundamental-mode RRL stars with high-quality photometry. We obtain a distance to the Galactic center of R0 = 8.33 +/- 0.05 +/- 0.14 kpc. We find that the spatial distribution of the RRL stars differs from the structures traced by the predominantly metal-rich red clump (RC) stars. Unlike the RC stars, the RRL stars do not trace a strong bar, but have a more spheroidal, central…
We obtained FLAMES-GIRAFFE spectra (R=22,500) at the ESO Very Large Telescope for 650 bulge red giant branch (RGB) stars and performed spectral synthesis to measure Mg, Ca, Ti, and Si abundances. This sample is composed of 474 giant stars observed in 3 fields along the minor axis of the Galactic bulge and at latitudes b=-4, b=-6, b=-12. Another 176 stars belong to a field containing the globular cluster NGC 6553, located at b=-3 and 5 degrees away from the other three fields along the major axis. Our results confirm, with large number statistics, the chemical similarity between the Galactic bu…
The local Seyfert 2 galaxy NGC5135, thanks to its almost face-on appearance, a bulge overdensity of stars, the presence of a large-scale bar, an AGN and a Supernova Remnant, is an excellent target to investigate the dynamics of inflows, outflows, star formation and AGN feedback. Here we present a reconstruction of the gas morphology and kinematics in the inner regions of this galaxy, based on the analysis of Atacama Large Millimeter Array (ALMA) archival data. To our purpose, we combine the available $\sim$100 pc resolution ALMA 1.3 and 0.45 mm observations of dust continuum emission, the spec…
OH/IR stars in the inner Galactic bulge: I. Colour, CO line, and stellar light curve characteristics
Chalmers University of Technology(查尔姆斯理工大学);Koninklijke Sterrenwacht van België(比利时皇家天文台);Vrije Universiteit Brussel(布鲁塞尔自由大学);Rochester Institute of Technology(罗切斯特理工学院);Center for Astrophysics | Harvard & Smithsonian(哈佛-史密森天体物理中心)
We investigate the properties of a sample of 35 galaxies, detected with ALMA at 1.1 mm in the GOODS-ALMA field (area of 69 arcmin$^2$, resolution = 0.60", RMS $\simeq$ 0.18 mJy beam$^{-1}$). Using the UV-to-radio deep multiwavelength coverage of the GOODS-South field, we fit the spectral energy distributions of these galaxies to derive their key physical properties. The galaxies detected by ALMA are among the most massive at $z$ = 2-4 (M$_{\star,med}$ = 8.5$ \times$ 10$^{10}$ M$_\odot$) and are either starburst or located in the upper part of the galaxy star-forming main sequence. A significan…
Gaseous outflows are key phenomena in the evolution of galaxies, as they affect star formation (either positively or negatively), eject gas from the core or disk, and directly cause mixing of pristine and processed material. Active outflows may be detected through searches for broad spectral line emission or high-velocity gas, but it is also possible to determine the presence of past outflows by searching for extended reservoirs of chemically enriched molecular gas in the circumgalactic medium (CGM) around galaxies. In this work, we examine the CO(3-2) emission of a set of seven z~2.0-2.5 AGN …
We present new Atacama Large Millimeter/submillimeter Array (ALMA) observations of the dust continuum and [C II] 158 $μ$m fine structure line emission towards a far-infrared-luminous quasar, ULAS J131911.29$+$095051.4 at $z=6.13$, and combine the new Cycle 1 data with ALMA Cycle 0 data. The combined data have an angular resolution $\sim$ $0.3$, and resolve both the dust continuum and the [C II] line emission on few kpc scales. The [C II] line emission is more irregular than the dust continuum emission which suggests different distributions between the dust and [C II]-emitting gas. The combined…
NGC 1808 is a nearby barred starburst galaxy with an outflow from the nuclear region. To study the inflow and outflow processes related to star formation and dynamical evolution of the galaxy, we have carried out \(^{12}\)CO (\(J=1-0\)) mapping observations of the central \(r\sim4\) kpc of NGC 1808 using the Atacama Large Millimeter/submillimeter Array (ALMA). Four distinct components of molecular gas are revealed at high spatial resolution of 2\arcsec (\(\sim100\) pc): (1) a compact (\(r<200\) pc) circumnuclear disk (CND), (2) \(r\sim500\) pc ring, (3) gas-rich galactic bar, and (4) spiral ar…
We have surveyed the core regions of the z = 1.46 cluster XCS J2215.9-1738 with the Atacama Large Millimeter Array (ALMA) and the MUSE-GALACSI spectrograph on the VLT. We obtained high spatial resolution observations with ALMA of the 1.2 mm dust continuum and molecular gas emission in the central regions of the cluster. These observations detect 14 significant millimetre sources in a region with a projected diameter of just ~500kpc (~1'). For six of these galaxies we also obtain 12 CO(2-1) and 12 CO(5-4) line detections, confirming them as cluster members, and a further five of our millimetre …
We targeted the massive star forming region W33A using the Atacama Large Sub/Millimeter Array (ALMA) in band 6 (230 GHz) and 7 (345 GHz) to search for a sub-1000au disc around the central O-type massive young stellar object (MYSO) W33A MM1-Main. Our data achieves a resolution of ~0.2" (~500au) and resolves the central core, MM1, into multiple components and reveals complex and filamentary structures. There is strong molecular line emission covering the entire MM1 region. The kinematic signatures are inconsistent with only Keplerian rotation although we propose that the shift in the emission li…
We estimate the mass of the intermediate-mass black hole at the heart of the dwarf elliptical galaxy NGC 404 using Atacama Large Millimeter/submillimeter Array (ALMA) observations of the molecular interstellar medium at an unprecedented linear resolution of ~0.5 pc, in combination with existing stellar kinematic information. These ALMA observations reveal a central disc/torus of molecular gas clearly rotating around the black hole. This disc is surrounded by a morphologically and kinematically complex flocculent distribution of molecular clouds, that we resolve in detail. Continuum emission is…
The chemical composition of high-mass protostars reflects the physical evolution associated with different stages of star formation. In this study, the molecular inventory of the forming high-mass star AFGL 4176 is studied in detail at high angular resolution (~0.35 arcsec) using ALMA. This high resolution makes it possible to separate the emission associated with the inner hot envelope and disk around the forming star from that of its cool outer envelope. In addition, the high sensitivity of ALMA makes it possible to identify weak and optically thin lines and allows for many isotopologues to …
We present 0\farcs{14}-resolution Atacama Large Millimeter/submillimeter Array (ALMA) CO(2$-$1) observations of the circumnuclear gas disk in UGC 2698, a local compact galaxy. The disk exhibits regular rotation with projected velocities rising to 450 km s$^{-1}$ near the galaxy center. We fit gas-dynamical models to the ALMA data cube, assuming the CO emission originates from a dynamically cold, thin disk, and measured the mass of the supermassive black hole (BH) in UGC 2698 to be $M_{\mathrm{BH}} = (2.46 \pm{0.07}$ [$1σ$ stat] $^{+0.70}_{-0.78}$ [sys])$\times 10^9$ $M_\odot$. UGC 2698 is part…
Aims: A pilot project has been carried out to measure circumstellar CO emission from three OH/IR stars close to the Galactic centre. The intention was to find out whether it would be possible to conduct a large-scale survey for mass-loss rates using, for example, the Atacama Large Millimeter Array (ALMA). Such a survey would increase our understanding of the evolution of the Galactic bulge. Methods: Two millimetre-wave instruments were used: the Nobeyama Millimeter Array at 115 GHz and the Submillimeter Array at 230 GHz. An interferometer is necessary as a `spatial filter' in this region of sp…
We present new Atacama Large Millimeter/submillimeter Array (ALMA) results obtained from spatially resolved CO $J$=2-1 line ($0.4''$ resolution) and 870 $μ$m continuum ($0.2''$ resolution) observations of cluster galaxies in XMMXCS J2215.9-1738 at $z=1.46$. Our sample comprises 17 galaxies within $\sim0.5$ Mpc ($0.6R_{200}$) of the cluster center, all of which have previously been detected in the CO $J$=2-1 line at a lower resolution. The effective radii of both the CO $J$=2-1 line and 870 $μ$m dust continuum emissions are robustly measured for nine galaxies by modeling the visibilities. We fi…
We mapped two molecular cloud cores in the Orion A cloud with the ALMA ACA 7-m Array and with the Nobeyama 45-m radio telescope. These cores have bright N$_2$D$^+$ emission in single-pointing observations with the Nobeyama 45-m radio telescope, have relatively high deuterium fraction, and are thought to be close to the onset of star formation. One is a star-forming core, and the other is starless. These cores are located along filaments observed in N$_2$H$^+$, and show narrow linewidths of 0.41 km s$^{-1}$ and 0.45 km s$^{-1}$ in N$_2$D$^+$, respectively, with the Nobeyama 45-m telescope. Both…
We report ALMA observations of CO(3-2) emission in a sample of 7 Seyfert/LINER galaxies at the unprecedented spatial resolution of 0.1'' = 4-9 pc. Our aim is to explore the close environment of AGN, and the dynamical structures leading to its fueling. The selected galaxies host low-luminosity AGN, and have a wide range of activity types, and barred or ringed morphologies. The observed maps reveal the existence of circum-nuclear disk structures, defined by their morphology and decoupled kinematics. We call these structures "molecular tori", even though they appear often as disks, without holes …
We analyse the physical properties of a large, homogeneously selected sample of ALMA-located sub-mm galaxies (SMGs). This survey, AS2UDS, identified 707 SMGs across the ~1 sq.deg. field, including ~17 per cent, which are undetected at $K$>~25.7 mag. We interpret their ultraviolet-to-radio data using MAGPHYS and determine a median redshift of z=2.61+-0.08 (1$σ$ range of z=1.8-3.4) with just ~6 per cent at z>4. Our survey provides a sample of massive dusty galaxies at z>~1, with median dust and stellar masses of $M_d$=(6.8+-0.3)x10$^{8}$M$_\odot$ (thus, gas masses of ~10$^{11}$M$_\odot$) and $M_…
We present high spatial resolution (FWHM$\sim$0.14'') observations of the CO($8-7$) line in GDS-14876, a compact star-forming galaxy at $z=2.3$ with total stellar mass of $\log(M_{\star}/M_{\odot})=10.9$. The spatially resolved velocity map of the inner $r\lesssim1$~kpc reveals a continous velocity gradient consistent with the kinematics of a rotating disk with $v_{\rm rot}(r=1\rm kpc)=163\pm5$ km s$^{-1}$ and $v_{\rm rot}/σ\sim2.5$. The gas-to-stellar ratios estimated from CO($8-7$) and the dust continuum emission span a broad range, $f^{\rm CO}_{\rm gas}=M_{\rm gas}/M_{\star}=13-45\%$ and $f…
Feedback from AGN is thought to be key in shaping the life cycle of their host galaxies by regulating star-formation activity. Therefore, to understand the impact of AGN on star formation, it is essential to trace the molecular gas out of which stars form. In this paper we present the first systematic study of the CO properties of AGN hosts at z~2 for a sample of 27 X-ray selected AGN spanning two orders of magnitude in AGN bolometric luminosity (Lbol= 10^44.7-10^46.9 erg/s) by using ALMA Band 3 observations of the CO(3-2) transition (~1" angular resolution). To search for evidence of AGN feed…
We analyze Ha or CO rotation curves (RCs) extending out to several galaxy effective radii for 100 massive, large, star-forming disk galaxies (SFGs) across the peak of cosmic galaxy star formation (z~0.6-2.5), more than doubling the previous sample presented by Genzel et al. (2020) and Price et al. (2021). The observations were taken with SINFONI and KMOS integral-field spectrographs at ESO-VLT, LUCI at LBT, NOEMA at IRAM, and ALMA. We fit the major axis kinematics with beam-convolved, forward models of turbulent rotating disks with bulges embedded in dark matter (DM) halos, including the effec…
ALMA CO(2-1) Gas Dynamics in NGC 315: A Multi-Method Benchmark for Supermassive Black Hole Mass Measurement
University of Michigan(密歇根大学);Brigham Young University(杨百翰大学);University of Science, VNU-HCM(越南国立大学胡志明市分校科学大学);Viet Nam National University Ho Chi Minh City(越南国立大学胡志明市);University of Vienna(维也纳大学)
We employ high-resolution zoom-in cosmological simulations to analyze the emerging morphology of galaxies in dark matter halos at redshifts z > 2. We choose DM halos of similar masses of log (Mvir/Mo) ~11.65 +- 0.05 at the target redshifts of z_f = 6, 4 and 2. The rationale for this choice, among others, allows us to analyze how the different growth rate in these halos propagates down to galaxy scales. Halos were embedded in high or low overdensity regions, and two different versions of a galactic wind feedback have been employed. Our main results are: (1) Although our galaxies evolve in diffe…
We present high-resolution (0.3'') ALMA 870um imaging of 52 sub-millimeter galaxies (SMGs) in the Ultra Deep Survey (UDS) field and investigate the size and morphology of the sub-millimeter (sub-mm) emission on 2-10kpc scales. We derive a median intrinsic angular size of FWHM=0.30$\pm$0.04'' for the 23 SMGs in the sample detected at a signal-to-noise ratio (SNR) >10. Using the photometric redshifts of the SMGs we show that this corresponds to a median physical half-light diameter of 2.4$\pm$0.2kpc. A stacking analysis of the SMGs detected at an SNR <10 shows they have sizes consistent with the…
We present high angular resolution multi-wavelength data of the 3C 298 radio-loud quasar host galaxy (z=1.439) taken using the W.M. Keck Observatory OSIRIS integral field spectrograph with adaptive optics, Atacama Large Millimeter/submillimeter Array (ALMA), Hubble Space Telescope (HST) WFC3, and the Very Large Array (VLA). Extended emission is detected in the rest-frame optical nebular emission lines H$β$, [OIII], H$α$, [NII], and [SII], as well as molecular lines CO (J=3-2) and (J=5-4). Along the path of 3C 298's relativistic jets we detect conical outflows of ionized gas with velocities up …
As part of the mm-Wave Interferometric Survey of Dark Object Masses (WISDOM) project we present an estimate of the mass of the supermassive black hole (SMBH) in the nearby fast-rotating early-type galaxy NGC4429, that is barred and has a boxy/peanut-shaped bulge. This estimate is based on Atacama Large Millimeter/submillimeter Array (ALMA) cycle-2 observations of the 12CO(3-2) emission line with a linear resolution of ~13 pc (0"18x0"14). NGC4429 has a relaxed, flocculent nuclear disc of molecular gas that is truncated at small radii, likely due to the combined effects of gas stability and tida…
We present an analysis of the morphology and profiles of the dust continuum emission in 153 bright sub-millimetre galaxies (SMGs) detected with ALMA at S/N ratios of $>8$ in high-resolution $0.18''$ ($\sim1$kpc) 870$μ$m maps. We measure sizes, shapes and light profiles for the rest-frame far-infrared emission from these luminous star-forming systems and derive a median effective radius ($R_e$) of $0.10''\pm0.04''$ for our sample with a median flux of $S_{870}=5.6\pm0.2$mJy. We find that the apparent axial ratio ($b/a$) distribution of the SMGs peaks at $b/a\sim0.63\pm0.24$ and is best describe…
We present results of sub-arcsec ALMA observations of CO(2-1) and CO(5-4) toward a massive main sequence galaxy at z = 1.45 in the SXDS/UDS field, aiming at examining the internal distribution and properties of molecular gas in the galaxy. Our target galaxy consists of the bulge and disk, and has a UV clump in the HST images. The CO emission lines are clearly detected and the CO(5-4)/CO(2-1) flux ratio (R_52) is ~1, similar to that of the Milky Way. Assuming a metallicity dependent CO-toH_2 conversion factor and a CO(2-1)/CO(1-0) flux ratio of 2 (the Milky Way value), the molecular gas mass an…
The protoplanetary system HD 169142 is one of the few cases where a potential candidate protoplanet has been recently detected via direct imaging. To study the interaction between the protoplanet and the disk itself observations of the gas and dust surface density structure are needed. This paper reports new ALMA observations of the dust continuum at 1.3\,mm, $^{12}$CO, $^{13}$CO and C$^{18}$O $J=2-1$ emission from the system HD 169142 at angular resolution of $\sim 0".18 - 0".28$ ($\sim 20\,$au$ - 33\,$au). The dust continuum emission reveals a double-ring structure with an inner ring between…
Galaxy nuclei are a unique laboratory to study gas flows. High-resolution imaging of the gas flows in galactic nuclei are instrumental in the study of the fueling and the feedback of star formation and nuclear activity in nearby galaxies. Several fueling mechanisms can be now confronted in detail with observations done with state-of-the-art interferometers. Furthermore, the study of gas flows in galactic nuclei can probe the feedback of activity on the interstellar medium of galaxies. Feedback action from star formation and AGN activity is invoked to prevent galaxies from becoming overly massi…
We present ALMA data on the 3mm continuum emission, CO isotopologues (12CO, 13CO, C18O), and high-density molecular tracers (HCN, HCO+, HNC, HNCO, CS, CN, and CH3OH) in NGC4526. These data enable a detailed study of the physical properties of the molecular gas in a longtime resident of the Virgo Cluster; comparisons to more commonly-studied spiral galaxies offer intriguing hints into the processing of molecular gas in the cluster environment. Many molecular line ratios in NGC4526, along with our inferred abundances and CO/H2 conversion factors, are similar to those found in nearby spirals. One…
Planets form in protoplanetary disks and inherit their chemical compositions. It is thus crucial to map the distribution and investigate the formation of simple organics, such as formaldehyde and methanol, in protoplanetary disks. We analyze ALMA observations of the nearby disk-jet system around the T Tauri star DG Tau in the o-H$_2$CO $3_{1,2}-2_{1,1}$ and CH$_3$OH $3_{-2,2}-4_{-1,4}$ E, $5_{0,5}-4_{0,4}$ A transitions at an unprecedented resolution of $\sim0.15"$, i.e., $\sim18$ au at a distance of 121 pc. The H$_2$CO emission originates from a rotating ring extending from $\sim40$ au with a…
Formaldehyde (H$_2$CO) is an important precursor to organics like methanol (CH$_3$OH). It is important to understand the conditions that produce H$_2$CO and prebiotic molecules during star and planet formation. H$_2$CO possesses both gas-phase and solid-state formation pathways, involving either UV-produced radical precursors or CO ice and cold ($\lesssim 20$ K) dust grains. To understand which pathway dominates, gaseous H$_2$CO's ortho-to-para ratio (OPR) has been used as a probe, with a value of 3 indicating "warm" conditions and $<3$ linked to cold formation in the solid-state. We present s…
ALMA surveys have shown that CO emission in protoplanetary disks is much fainter than expected. Accordingly, CO-based gas masses and gas/dust ratios are orders of magnitude lower than previously thought. This may be explained either as fast gas dispersal, or as chemical evolution and locking up of volatiles in larger bodies leading to the low observed CO fluxes. The latter processes lead to enhanced C/O ratios in the gas, which may be reflected in enhanced abundances of molecules like C2H. The goal of this work is to employ C2H observations to understand whether low CO fluxes are caused by vol…